JPH0352808A - Material for face washing - Google Patents

Material for face washing

Info

Publication number
JPH0352808A
JPH0352808A JP2185467A JP18546790A JPH0352808A JP H0352808 A JPH0352808 A JP H0352808A JP 2185467 A JP2185467 A JP 2185467A JP 18546790 A JP18546790 A JP 18546790A JP H0352808 A JPH0352808 A JP H0352808A
Authority
JP
Japan
Prior art keywords
present
amount
quaternium
humectant
approximately
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2185467A
Other languages
Japanese (ja)
Inventor
Frank Tranner
フランク トラナー
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Intermountain Research and Development Corp
Original Assignee
Intermountain Research and Development Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Intermountain Research and Development Corp filed Critical Intermountain Research and Development Corp
Publication of JPH0352808A publication Critical patent/JPH0352808A/en
Pending legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/86Polyethers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/003Colloidal solutions, e.g. gels; Thixotropic solutions or pastes
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/02Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/0216Solid or semisolid forms
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39Derivatives containing from 2 to 10 oxyalkylene groups
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/41Amines
    • A61K8/416Quaternary ammonium compounds
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/49Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
    • A61K8/4906Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
    • A61K8/4913Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/60Sugars; Derivatives thereof
    • A61K8/608Derivatives containing from 2 to 10 oxyalkylene groups
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73Polysaccharides
    • A61K8/731Cellulose; Quaternized cellulose derivatives
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8152Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61KPREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00Cosmetics or similar toiletry preparations
    • A61K8/18Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/90Block copolymers
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61QSPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00Preparations for care of the skin
    • A61Q19/10Washing or bathing preparations
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0026Low foaming or foam regulating compositions

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Dermatology (AREA)
  • Emergency Medicine (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)

Abstract

PURPOSE: To obtain a clear, transparent, well-balanced, nonfrothy gel-like material for washing face, with neutral pH, quickly rinsable, and containing respective specific ingredients. CONSTITUTION: This material for washing face having the above-mentioned advantages comprises (A) 2-18wt.% of a nonionic cleansing/wound-cleaning agent benign to the skin, (B) 5-15wt.% of a moisturizer/wetting agent consisting of a transparent and viscous polyethylene glycol, (C) 5-10wt.% of a moisturizer/ skin softener consisting of ppG ether, (D) 1-10wt.% of a gelling agent, (E) 0.2-2wt.% of a viscosity stabilizer, (F) 0.2-2wt.% of a pH adjuster, (G) 0.1-2wt.% of an independent skin softener consisting of a quateronium, (H) an antimicrobial agent/microbial growth inhibitor, and such an amount of deionized water/ distilled water as to total 100wt.% so as to be at least (2:1) in the ratio (B+C+G)/A.

Description

【発明の詳細な説明】 (産業上の利用分野) 洗顔用の材料に関する。[Detailed description of the invention] (Industrial application field) Concerning face wash materials.

(従来技術) 従来、数多くの洗顔剤が提供されてきたが、これらのう
ちほとんどのものは、塩基性のpHであり、泡立つもの
が多く、また、かなり肌荒れをおこし、さらに即座に洗
い流せないものがほとんどを占めている。さらに、質の
悪い界面活性剤からなることに加えて、保湿剤が含まれ
ている場合の保湿剤に対して界面活性剤の占める割合が
たいていの場合かなり高く、また、元の肌荒れ感や不快
感を補うためにかなり香料がきついことが多い。
(Prior art) Many facial cleansers have been provided in the past, but most of these have a basic pH, often foam, cause considerable skin irritation, and cannot be washed off immediately. occupies the majority. Furthermore, in addition to being composed of poor quality surfactants, the ratio of surfactants to moisturizers is often quite high, and the initial roughness and irritation can be exacerbated. It is often heavily scented to compensate for the pleasure.

それに対して、本発明によって澄んだ透明なゲル状の洗
顔剤が提供される。この洗顔剤は肌にやさしい非イオン
性洗剤からなり、敏感な肌への使用にも適している。さ
らに、この洗剤は穏やかな皮膚傷清浄剤としても機能す
る。本発明の洗顔剤はさらに過多な香料を必要こせず、
また泡が立たず、すばやく洗い流せることを特徴として
おり、肌にしっとりくるように独立の保湿剤を含んでお
り、さらには、本発明のゲル状の洗顔剤を使用すること
によって、皮膚がさらに軟化し、かつ皮膚のはがれや乾
燥を防ぎ、より良好なバランスが得られる。さらに、本
発明のゲル状の洗顔剤は、保湿剤の洗剤又は界面活性剤
に対する比率(保湿剤:洗剤ないし界面活性剤)を少な
くとも2:1とし、かつpHを中性に保つことを特徴と
している。これゆえ、毎日の洗顔に適しており、かつ例
えば予め蒸らした手で軽くマッサージしながら適用し、
冷水ですばやく洗い流すことができ、洗い流した後も例
えば軽くたたく等によって顔を乾かすことができる。さ
らに、この洗顔剤は特に化粧を落とすのに適しており、
この場合には例えば洗顔剤を綿球に直接取り、さらに必
要とあれば、再度洗顔剤をきれいな綿球に直接とり、化
粧をした部分を軽くマッサージした後、温水・冷水の順
で洗い流し、軽くたたく等によって乾かすことができる
ものである。また、この洗顔剤は美しい透明なゲル状で
あり、かなり敏感な肌にも十分肌にやさしく、単一の肌
にやさしい洗剤兼傷清浄剤を含んでおり、pHは塩基性
ではなく中性で、独立の保湿剤を含み、保湿剤の界面活
性剤の対する割合が少なくとも2対1であり、泡が立た
ず、すばやく洗い流せることを特徴としており、これら
よりこの洗顔剤は化粧用としても適しており、かつ肌に
も非常に効果的にやさしく、すべての目的に優れた洗顔
用材料である。
In contrast, the present invention provides a clear, transparent gel-like facial cleanser. This facial cleanser is made from a skin-friendly non-ionic detergent and is suitable for use on sensitive skin. Additionally, this detergent also acts as a gentle skin wound cleanser. The face cleanser of the present invention also does not require an excessive amount of fragrance,
In addition, it does not form bubbles and can be washed off quickly, and contains an independent moisturizer to keep the skin moist.Furthermore, by using the gel-like facial cleanser of the present invention, the skin becomes even softer. It also prevents peeling and dryness of the skin, resulting in a better balance. Furthermore, the gel-like face cleanser of the present invention is characterized in that the ratio of humectant to detergent or surfactant (humectant: detergent or surfactant) is at least 2:1, and the pH is maintained at neutral. There is. Therefore, it is suitable for daily face washing, and can be applied by lightly massaging with pre-steamed hands.
It can be quickly rinsed off with cold water, and after rinsing, the face can be dried, for example by patting it dry. Additionally, this face wash is especially good for removing makeup;
In this case, for example, apply the face cleanser directly onto a cotton ball, and if necessary, apply the face cleanser again directly onto a clean cotton ball, lightly massage the makeup-covered area, rinse with warm and then cold water, and gently It can be dried by patting it, etc. This face wash also comes in a beautiful clear gel form and is gentle enough for even the most sensitive skin, contains a single skin-friendly detergent and blemish cleanser, and has a neutral rather than basic pH. , contains an independent moisturizing agent, has a ratio of moisturizing agent to surfactant of at least 2:1, is non-foaming, and can be washed off quickly, making this facial cleanser suitable for cosmetic use. It is an excellent facial cleansing material for all purposes, as it is very effective and gentle on the skin.

(発明の目的) 本発明の目的は、新規でかつ改良された洗顔用材料を提
供することであり、さらに詳しくは先に述べたようによ
り良いバランスを特徴とし、また、化粧用として適しか
つ敏感な肌にも使用するのに非常に効果的で十分肌にや
さしい新規なゲル状の洗顔用材料を提供することである
OBJECT OF THE INVENTION The object of the present invention is to provide a new and improved facial cleansing material, more particularly characterized by a better balance as mentioned above, and which is suitable for cosmetic use and sensitive skin. To provide a new gel-like facial cleansing material that is extremely effective and sufficiently gentle to be used even on sensitive skin.

いまひとつの本発明の目的は、傷清浄剤としても機能す
る肌にやさしい非イオン性洗剤を含有し、上記の特徴及
び長所を備え、さらに粗雑で好ましくない根本的特徴を
隠すために香料を必要とするといったこともない透明な
ゲル状の洗顔用材料を提供することである。
Another object of the present invention is to contain a skin-friendly non-ionic detergent which also functions as a wound cleanser, which has the above characteristics and advantages, and which does not require fragrance to mask the harsh and undesirable underlying characteristics. To provide a transparent gel-like facial cleansing material that does not cause any irritation.

さらに、本発明の目的は、下記により明らかとなってく
るが、他については本発明の属する分野に精通している
人には明らかである。
Further objects of the invention will become apparent from the following, while others will be apparent to those skilled in the art to which the invention pertains.

(発明の要旨) 本発明は下記により構成される。(Summary of the invention) The present invention is constituted by the following.

pHが中性であり、泡が立たず、すばやく洗い流せるこ
とを特徴とし、以下の成分から本質的になる澄んだ透明
なよくバランスのとれたゲル状の洗顔用材料。
A clear, transparent, well-balanced gel-like facial cleansing material that is characterized by its pH neutrality, non-foaming, and rapid wash-off, and consists essentially of the following ingredients:

(2)肌にやさしい非イオン性の洗剤兼傷清浄剤を約2
%〜18%、(3〉保湿剤兼湿潤剤を約5%〜15%、
(4)保湿剤兼皮膚軟化剤を約5%〜10%、(5)ゲ
ル化剤を約1%〜10%、(6)粘度安定剤を約0.2
%〜2%、(7)pH調整剤を約0.2%〜2%、(8
)独立した皮膚軟化剤を約0.1%〜2%、(9)防菌
剤又は菌の生育阻害剤を約0.05%〜0.2%、(1
o〉溶解剤を約0.01%〜0.1%、(l1)マスキ
ング剤を約0.01%〜0.1%、及び(1)総量を1
00%とする脱イオン水又は蒸留水からなる残部 (これらのパーセント(%)は、重量比であり、また、
(3) 、(4) 、(8)を加えたものの(2)に対
する割合は少なくとも2対1である。)洗剤兼傷清浄剤
がポロキサマー1 8 8 (Poloxamerl8
g)であり、保湿剤兼湿潤剤が室温で透明な粘性のある
液体であるポリエチレングリコールであり、保湿剤兼皮
膚軟化剤がPPG−10メチルグルコースエーテルであ
り、ゲル化剤がアクリル酸共重合体からなり、粘度安定
剤がラウリルピロリドンであり、pHFJ整剤がトリエ
タノールアミンであり、独立した皮膚軟化剤がクオータ
ーニウム− 2 2 (quatern1c+m−22
)であり、菌生育阻害剤がクオーターニウム−1 5 
(quaternium−15)であり、溶解剤がPE
G−40ヒマシ油であり、マスキング剤が精油である洗
顔用材料。
(2) Approximately 2 ounces of skin-friendly non-ionic detergent and wound cleanser
% ~ 18%, (3> Moisturizer and humectant about 5% ~ 15%,
(4) Approximately 5% to 10% moisturizing agent and emollient, (5) Approximately 1% to 10% gelling agent, (6) Approximately 0.2% viscosity stabilizer.
% to 2%, (7) pH adjuster approximately 0.2% to 2%, (8
) about 0.1% to 2% of an independent emollient, (9) about 0.05% to 0.2% of a fungicide or fungal growth inhibitor, (1
o> About 0.01% to 0.1% of solubilizing agent, (11) About 0.01% to 0.1% of masking agent, and (1) Total amount of 1
The remainder consists of deionized water or distilled water (these percentages are by weight;
The ratio of (3), (4), and (8) plus (2) is at least 2:1. ) Detergent and wound cleanser is poloxamer 1 8 8 (Poloxamerl 8
g), the humectant and humectant is polyethylene glycol which is a transparent viscous liquid at room temperature, the humectant and emollient is PPG-10 methyl glucose ether, and the gelling agent is acrylic acid copolymer. The viscosity stabilizer is laurylpyrrolidone, the pHFJ stabilizer is triethanolamine, and the independent emollient is quaternium-22 (quatern1c+m-22).
), and the fungal growth inhibitor is quaternium-1 5
(quaternium-15), and the solubilizer is PE.
A facial cleansing material that is made of G-40 castor oil and whose masking agent is an essential oil.

ポロキシ?−1 8 8 (Poloxamerl88
)が約5%量存在し、ポリエチレングリコールが約5%
量のPEG−8からなり、PEG−10メチルグルコー
スエーテルが約5%量存在し、アクリル酸共重合体が約
2.5%量存在し、ラウリルピロリドンが約0.5%量
存在し、トリエタノールアミンが約0.5%量存在し、
クオーターニウム−2 2 (quaterni ur
fi−22)が約0.1%量存在し、クオーターニウム
−1 5 /ql..atCrnium−15)が約0
6 05%量存在し、PEG−40ヒマシ油が約0.0
15%量存在し、 精油が約0. 015%量存在する洗顔 用材料。
Poloxy? -1 8 8 (Poloxamerl88
) is present in an amount of approximately 5%, and polyethylene glycol is present in an amount of approximately 5%
PEG-8 in an amount of about 5%, PEG-10 methyl glucose ether present in an amount of about 5%, acrylic acid copolymer present in an amount of about 2.5%, laurylpyrrolidone present in an amount of about 0.5%; ethanolamine is present in an amount of about 0.5%;
Quaternium-2 2 (quaternium ur
fi-22) is present in an amount of approximately 0.1%, and quaternium-1 5 /ql. .. atCrnium-15) is approximately 0
6.05% amount, and PEG-40 castor oil is present in an amount of about 0.0
It is present in an amount of 15% and contains approximately 0.0% essential oil. Facial cleansing material present in an amount of 0.015%.

(実施例) 次に実施例を示して、 本発明を具体的に説明す るが、 本発明はこれらの実施例に限定されるものではない。(Example) Next, an example is shown, The present invention will be explained in detail. However, The present invention is not limited to these examples.

水の減量分を調べ、減量した水を加え、15分間混合す
る。混合によって空気を溶液中に巻き込むため、バッチ
(密閉容器に入れておく)は、40℃の保温謔に入れて
、空気を除去し、適当な容器に注入し、冷却する。
Check the loss of water, add the reduced amount of water and mix for 15 minutes. In order to entrain air into the solution through mixing, the batch (held in a closed container) is placed in a 40° C. thermos to remove air, poured into a suitable container, and cooled.

仕様 色 外観 臭い 透明・・無色 軟ゲル 標準物に対して 軽いラベンダー臭 7.0〜7.1 (No.4回転子 L2rpm ) 70〜90 比重    1.02 pH B型粘度計 本発明の実施例1のゲル状の洗顔用材料に関する臨床評
価を行ったところ、敏感な肌に対して適用した時にさえ
、十分満足できかつ良いバランスがとれていることがわ
かった。また、泡が立たずに、容易に洗い流せ、そして
中に含まれている皮膚軟化剤は清潔な状態で皮膚に残り
、また皮膚がむけてしまったり、乾燥したりすることな
く、爽快な皮膚感触である上、小さな傷やひび又は斑点
も、中に含まれている肌にやさしい非イオン性洗剤兼傷
清浄剤(PIuron1c P−88 )によって効果
的に落とせるという長所がある。
Specifications Color Appearance Odor Transparent...Light lavender odor compared to colorless soft gel standard 7.0-7.1 (No. 4 rotor L2 rpm) 70-90 Specific gravity 1.02 pH B-type viscometer Examples of the present invention A clinical evaluation of the gel-like facial cleansing material No. 1 was conducted and found to be fully satisfactory and well-balanced even when applied to sensitive skin. In addition, it does not create bubbles and can be easily washed off, and the emollients contained within remain clean on the skin, leaving the skin with a refreshing feel without peeling or drying. Moreover, it has the advantage that even small scratches, cracks, and spots can be effectively removed by the skin-friendly non-ionic detergent and wound cleanser (PIuronlc P-88) contained therein.

実施例2−ゲル状の洗顔用材料 下記範囲の量の下記構成成分を用いて、かつ総量を脱イ
オン水又は蒸留水で100%に合わせ、実施例1と同様
の方法を用いて処理を行った。
Example 2 - Facial cleansing material in gel form A treatment was carried out using the same method as in Example 1, using the following constituents in amounts in the following ranges and making the total amount to 100% with deionized or distilled water: Ta.

なお、下記表の3列目に記載された範囲内で、最適値と
思われる値が2列目に記載されている。
In addition, within the range described in the third column of the table below, the value considered to be the optimal value is described in the second column.

生成物を臨床評価したところ、実施例1で得られたとき
と同様の結果が得られた。
Clinical evaluation of the product gave similar results to those obtained in Example 1.

実施例3−ゲル状の洗顔用材料 さらに、本発明のゲル状の洗顔用材料の生産を実施例1
と同様の方法を用いて行った。なお、構成成分及びおお
よその量については下記の表のとおりであり、また、総
量は脱イオン水又は蒸留水を加えることによって100
重量%とした。
Example 3 - Gel-like facial cleansing material Furthermore, Example 1 produced the gel-like facial cleansing material of the present invention.
This was done using the same method. The components and approximate amounts are shown in the table below, and the total amount can be adjusted to 100% by adding deionized water or distilled water.
It was expressed as weight%.

この生産物を実施例1の場合と同様にして、臨床評価を
行ったところ、実施例1の生産物の時と同様の満足でき
る結果が得られた。
When this product was subjected to clinical evaluation in the same manner as in Example 1, satisfactory results similar to those of the product in Example 1 were obtained.

本発明のゲル状の洗顔用材料の必須成分は、以下に示す
通りであり、さらに詳細な定義については2列目に示さ
れているとおりである。なお、3列目には本発明のゲル
状の洗顔用材料の必須成分の重量%の範囲が示されてお
り、4列目には最適重量%が示されている。
The essential components of the gel-like facial cleansing material of the present invention are as shown below, and more detailed definitions are shown in the second column. Note that the third column shows the weight % range of the essential components of the gel-like facial cleansing material of the present invention, and the fourth column shows the optimum weight %.

なお、各成分に対する商品名及びCTFA(Cosme
tic.To11etry.and Fragranc
e Association )名に関する本発明の有
効成分の供給元については、以下の表のとおりである。
In addition, the product name and CTFA (Cosme
tic. To11try. and Fragrance
The table below shows the sources of the active ingredients of the present invention regarding the name of the Association.

また、同等の機能をもつ保湿剤、共溶媒、肌にやさしい
傷清浄剤、保湿剤兼湿潤剤、保湿剤兼皮膚軟化剤、透明
なゲル化剤、粘度安定剤、pH調整剤、独立した皮膚の
軟化剤、菌生育阻害剤、溶解剤、及びマスキング剤の代
替品は、本発明のゲル状の洗顔用材料の優れたかつ望ま
しい特性が代替品によって変化しなければ、必要又は望
まれる限り、使用することができる。
We also have moisturizers, co-solvents, skin-friendly wound cleansers, moisturizers and moisturizers, moisturizers and emollients, transparent gelling agents, viscosity stabilizers, pH regulators, and independent skin Substitutes for the emollients, fungal growth inhibitors, solubilizers, and masking agents may be used to the extent necessary or desired, provided that the substitutes do not alter the superior and desirable properties of the gel facial cleansing material of the present invention. can be used.

参考文献としては、米国特許 4,673,525が挙
げられる。この文献には、他の非イオン性界面活性剤の
代わりに本発明の構成成分として使用できる皮膚軟化剤
としての保湿剤、先に使用した肌にやさしい非イオン性
界面活性剤及び傷清浄剤を兼ねるものであるポロキサマ
ー188(Po1oxamcrl88)の代わりに使用
することができるポリマー等、及び目的の材料となって
いる本発明中の構成成分中に含まれている又は含まれて
いない他の至適な構成成分に関して、具体的に示されて
いる。さらに、本発明中に使用されている保湿剤兼湿潤
剤の代わりに、ポリプロピレングリコール、他のポリグ
リコール、グリセリンやソルビタールが、これらを基礎
単位とした他の保湿剤兼湿潤剤と同様、使用することが
できる。なお、ポリエチレングリコールは、室温で透明
な粘性のある液体で、ポリグリコール 200、300
、400、又は600が使用できるが、ポリグリコール
400がかなり好ましい。
References include US Pat. No. 4,673,525. This document describes moisturizers as emollients, skin-friendly nonionic surfactants and wound cleansers used previously, which can be used as constituents of the present invention in place of other nonionic surfactants. Polymers that can be used in place of poloxamcrl88, which also serves as a polymer, and other suitable materials that may or may not be included in the constituent components of the present invention, which are the target materials. The constituent components are specifically indicated. Furthermore, instead of the humectants and humectants used in the present invention, polypropylene glycol, other polyglycols, glycerin and sorbital can be used as well as other humectants and humectants based on these. be able to. Polyethylene glycol is a viscous liquid that is transparent at room temperature.
, 400, or 600 can be used, with polyglycol 400 being highly preferred.

中和やゲル化によって透明なゲルにする本発明のゲル化
剤又は濃化剤の代わりに、中和やゲル化によって透明に
なる限り、他のアクリル酸共重合体又は他の濃化剤又は
ゲル化剤が使用できる。さらに、ラウリルピロリドンの
代わりに又はこれに加えて使用できる粘度安定剤として
、メチルセルロース(Mathocel)やその他のセ
ルロース誘導体が数種ではあるが、挙げられる。本発明
のpHF1製剤、中和剤としてのトリエタノールアミン
の代わりに、他の第3級アミン又は類似物が同等に使用
できる。独立した皮膚軟化剤としてのクオーターニウム
−2 2 (quaternium=22 )の代わり
に、ポリ? − J R4 0 0 (polymer
 JR 400)  (−L二オン カーバイド(Ll
nion Carbide )より販売されている水溶
性のナトリウム塩である陽イオン性セルロースエーテル
で、CASの名がα−[2−ヒドロキシ−3−(トリメ
チルアミノ)プロピルコーω−ヒドロキシポリ(オキシ
ー1.2−エタンジイル)クロライドとのセルロースの
ω一エーテル(cat Iulosc,ω−ether
 with α−[2−hydroxy−3−(tri
mcthylammonio)propy I ]−ω
−hydroxypo I y (ox y−1 . 
2−cthancd1 y1)chlorideである
)が使用テキル。
Instead of the gelling agent or thickening agent of the present invention that becomes a transparent gel by neutralization or gelation, other acrylic acid copolymers or other thickening agents or Gelling agents can be used. Further, viscosity stabilizers that can be used in place of or in addition to laurylpyrrolidone include methylcellulose (Mathocel) and other cellulose derivatives, among others. Instead of triethanolamine as a neutralizing agent in the pHF1 formulations of the present invention, other tertiary amines or analogs can equally be used. Instead of quaternium-22 (quaternium=22) as an independent emollient, poly? - JR400 (polymer
JR 400) (-Lion carbide (Ll
CAS name is α-[2-hydroxy-3-(trimethylamino)propyl-ω-hydroxypoly(oxy-1.2 ω-ether of cellulose with (ethanediyl) chloride (cat Iulosc, ω-ether)
with α-[2-hydroxy-3-(tri
mcthylammonio) propy I]-ω
-hydroxypo I y (oxy y-1 .
2-cthancd1 y1) chloride) is used.

菌生育阻害剤又は防菌剤であるクオーターニウム−1 
5 (Quaternium−15 )の代わりとして
は、例えばメチル及びプロピルパラヒドロキシベンゾエ
ートが使用できる。また、先に示したが、PEG−40
ヒマシ油であり、マスキング剤の油を溶解するために使
用される非イオン性界面活性剤であるマスキング剤とし
ての溶解剤の代わりには、ポリオキシエチレン2 0 
(polyoxyethylene20)ないしはポリ
ソルベートート2 0 (polysorbate20
)であり、ソルビタンモノラウレートであるトゥイーン
2 0 (Tween20)のようなものが使用できる
Quaternium-1, a fungal growth inhibitor or antibacterial agent
As a substitute for 5 (Quaternium-15), for example, methyl and propyl parahydroxybenzoates can be used. In addition, as shown earlier, PEG-40
Instead of a solubilizer as a masking agent, which is castor oil and is a nonionic surfactant used to dissolve the oil in the masking agent, polyoxyethylene 20
(polyoxyethylene 20) or polysorbate 20 (polysorbate20)
) and sorbitan monolaurate, such as Tween 20, can be used.

トリエタノールアミンに関しては、水溶液の状態で調製
されており、トリエタノールアミンの他の水溶液はより
低い濃度で使用されているが、この実施例では99%濃
度を使用している。また、このようなトリエタノールア
ミン水溶液は、他の第3級アミンや類似の中和剤と同様
にして、トリエタノールアミンの代わりに同様の機能で
使用できる。
Regarding triethanolamine, it is prepared in an aqueous solution and is used at 99% concentration in this example, although other aqueous solutions of triethanolamine have been used at lower concentrations. Further, such an aqueous triethanolamine solution can be used in place of triethanolamine with the same function as other tertiary amines and similar neutralizing agents.

(発明の効果) 以上より示されるように、本発明は、敏感な肌にさえ合
う非常に良くバランスのとれた肌にやさしい洗顔剤から
なり、同時に独特な肌にやさしい傷ついた肌の清浄剤で
あり、泡立たず、すばやく洗い流せることを特徴とし、
pHがアルカリ性ではなく中性であり、独立した保湿剤
を−aし、保湿剤の洗剤又は界面活性剤に対する割合が
少なくとも2対1であり、最も敏感な肌にさえ使用でき
るほど効果的でかつ十分肌にやさしく、さらには洗浄の
面でも、顔を効果的に清潔に保ち、かつ肌にはやさしく
爽快で全体的に満足感があり、かつ特に従来の洗顔材料
に比べた場合、皮膚がはがれたり、肌が乾燥したりする
ことなく、清潔でさわやかで、また、非常に滑らかなし
っとり感のあるかなり好ましい優れた透明なゲル状の洗
顔材料を提供している。
(Effects of the Invention) As shown above, the present invention consists of a very well-balanced skin-friendly facial cleanser that is suitable even for sensitive skin, and at the same time is a unique skin-friendly cleanser for damaged skin. It is characterized by being non-foaming and quickly rinsing off.
The pH is neutral rather than alkaline, it has an independent humectant-a, the ratio of humectant to detergent or surfactant is at least 2:1, and it is effective and effective enough to be used on even the most sensitive skin. It is gentle enough on the skin, and even in terms of cleansing, it effectively keeps the face clean, yet gentle on the skin, refreshing and overall satisfying, and especially when compared to traditional face cleansing materials, it does not peel off the skin. The present invention provides an excellent transparent gel-like facial cleansing material that is clean, refreshing, and has a very smooth and moist feeling without drying or drying the skin.

なお、様々な修飾や変化が今後本発明の分野に精通して
いる当業者によって明らかにされてくることが予想され
るが、本発明は前記特許請求の範囲の記載にのみ限定さ
れていると解すべきであり、本発明は、実施例で示した
化合物、構成成分、方法又は材料に限定されるものでは
ない。
Although it is expected that various modifications and changes will be revealed by those skilled in the art in the field of the present invention in the future, it is understood that the present invention is limited only to the scope of the claims. It should be understood that this invention is not limited to the compounds, components, methods, or materials illustrated in the examples.

Claims (1)

【特許請求の範囲】 (1)pHが中性であり、泡が立たず、すばやく洗い流
せることを特徴とし、以下の成分から基本的になる澄ん
だ透明な良くバランスのとれたゲル状の洗顔用材料。 (2)肌にやさしい非イオン性洗剤兼傷清浄剤を2%〜
18%、(3)透明な粘性のあるポリエチレングリコー
ルからなる保湿剤兼湿潤剤を5%〜15%、(4)PP
Gエーテルからなる保湿剤兼皮膚軟化剤を5%〜10%
、(5)ゲル化剤を1%〜10%、(6)粘度安定剤を
0.2%〜2%、(7)pH調整剤を0.2%〜2%、
(8)クォーターニウム(quaternium)から
なる独立の皮膚軟化剤を0.1%〜2%、(9)防菌剤
又は菌生育阻害剤、及び(1)総量を100%とする脱
イオン水又は蒸留水 (なお、すべてのパーセント(%)は重量比であり、ま
た、(3)、(4)、(8)を加えたものの(2)に対
する割合は少なくとも2対1である。)(2)洗剤兼傷
清浄剤がポロキサマー188(Poloxamer18
8)からなり、保湿剤兼湿潤剤が室温で透明な粘性のあ
る液体であるポリエチレングリコールからなり、保湿剤
兼皮膚軟化剤がPPG−10メチルグルコースエーテル
からなり、ゲル化剤がアクリル酸共重合体からなり、粘
度安定剤がラウリルピロリドンからなり、pH調整剤が
トリエタノールアミンからなり、独立の皮膚軟化剤がク
オーターニウム−22(quaternium−22)
からなり、菌生育阻害剤がクオーターニウム−15(q
uaternium−15)からなる請求項1記載の洗
顔用材料。 (3)pHが中性であり、泡が立たず、すばやく洗い流
せることを特徴とし、以下の構成成分より基本的になる
請求項1に記載の澄んだ透明なよくバランスのとれたゲ
ル状の洗顔用材料。 (2)ポロキサマー188(Poloxamer188
)からなる肌にやさしい非イオン性洗剤兼傷清浄剤を2
%〜18%、(3)室温で透明な粘性のある液体である
ポリエチレングリコールからなる保湿剤兼湿潤剤を5%
〜15%、(4)PPG−10メチルグルコースエーテ
ルからなる保湿剤兼皮膚軟化剤を5%〜10%、(5)
アクリル酸共重合体からなるゲル化剤を1%〜10%、
(6)ラウリルピロリドンからなる粘度安定剤を0.2
%〜2%、(7)第3級アミンからなるpH調整剤を0
.2%〜2%、(8)クオーターニウム−22(qua
ternium−22)からなる独立の皮膚軟化剤を0
.1%〜2%、(9)菌生育阻害剤である防菌剤を0.
05%〜0.2%、(10)PEGヒマシ油からなる溶
解剤を0.01%〜0.1%、(11)精油からなるマ
スキング剤を0.01%〜0.1%、及び(1)総量を
100%とする脱イオン水又は蒸留水 (なお、これらのパーセント(%)はすべて重量比であ
り、また(3)、(4)、(8)を加えたものの(2)
に対する割合は少なくとも2対1である。) (4)ポロキサマー188(Poloxamer188
)が約5%量存在し、PEG−8からなるポリエチレン
グリコールが約5%量存在し、PPG−10メチルグル
コースエーテルが約5%量存在し、アクリル酸共重合体
が約2.5%量存在し、ラウリルピロリドンが約0.5
%量存在し、トリエタノールアミンからなる第3級アミ
ンが約0.5%量存在し、クオーターニウム−22(q
uaternium−22)が約0.1%量存在し、ク
オーターニウム−15(quaternium−15)
からなる防菌剤が約0.05%量存在し、PEG−40
ヒマシ油が約0.015%量存在し、精油が約0.01
5%量存在する請求項1記載の洗顔用材料。
[Claims] (1) A clear, well-balanced gel-like facial cleansing product that is characterized by having a neutral pH, no foaming, and can be washed off quickly, and which is basically composed of the following ingredients: material. (2) 2% ~ skin-friendly non-ionic detergent and wound cleanser
18%, (3) 5% to 15% moisturizing agent and humectant consisting of transparent viscous polyethylene glycol, (4) PP
5% to 10% moisturizer and emollient consisting of G ether
, (5) 1% to 10% gelling agent, (6) 0.2% to 2% viscosity stabilizer, (7) 0.2% to 2% pH adjuster,
(8) 0.1% to 2% of an independent emollient consisting of quaternium, (9) an antibacterial agent or fungal growth inhibitor, and (1) deionized water or Distilled water (all percentages are by weight and the ratio of (3), (4), and (8) plus (2) to (2) is at least 2:1) (2 ) The detergent and wound cleanser is Poloxamer 188 (Poloxamer 188).
8), the humectant and humectant consists of polyethylene glycol, which is a transparent viscous liquid at room temperature, the humectant and emollient consists of PPG-10 methyl glucose ether, and the gelling agent consists of acrylic acid copolymer. The viscosity stabilizer consists of laurylpyrrolidone, the pH adjuster consists of triethanolamine, and the independent emollient consists of quaternium-22.
The fungal growth inhibitor is quaternium-15 (q
2. The facial cleansing material according to claim 1, comprising: uaternium-15). (3) A clear, transparent, well-balanced gel face wash according to claim 1, characterized by having a neutral pH, non-foaming, and quick wash-off, and consisting essentially of the following components: Materials for use. (2) Poloxamer 188
) is a skin-friendly non-ionic detergent and wound cleanser.
% to 18%, (3) 5% humectant and humectant consisting of polyethylene glycol, which is a viscous liquid that is transparent at room temperature.
~15%, (4) 5% to 10% of a humectant and emollient consisting of PPG-10 methyl glucose ether, (5)
1% to 10% of a gelling agent consisting of an acrylic acid copolymer;
(6) 0.2 viscosity stabilizer consisting of laurylpyrrolidone
% to 2%, (7) pH adjuster consisting of tertiary amine to 0
.. 2% to 2%, (8) Quaternium-22 (qua
ternium-22) as an independent emollient.
.. 1% to 2%, and (9) 0.0% of a fungicide, which is a fungal growth inhibitor.
05% to 0.2%, (10) PEG castor oil dissolving agent 0.01% to 0.1%, (11) essential oil masking agent 0.01% to 0.1%, and ( 1) Deionized water or distilled water with the total amount being 100% (all percentages (%) are by weight, and (2) including (3), (4), and (8))
The ratio is at least 2:1. ) (4) Poloxamer 188 (Poloxamer188
) is present in an amount of approximately 5%, polyethylene glycol consisting of PEG-8 is present in an amount of approximately 5%, PPG-10 methyl glucose ether is present in an amount of approximately 5%, and acrylic acid copolymer is present in an amount of approximately 2.5%. present, and laurylpyrrolidone is about 0.5
% of quaternium-22 (q
uaternium-22) is present in an amount of about 0.1%, and quaternium-15 (quaternium-15) is present in an amount of about 0.1%.
An antibacterial agent consisting of PEG-40 is present in an amount of approximately 0.05%.
Castor oil is present in an amount of approximately 0.015%, and essential oil is approximately 0.01%.
A facial cleansing material according to claim 1, wherein the facial cleansing material is present in an amount of 5%.
JP2185467A 1989-07-17 1990-07-16 Material for face washing Pending JPH0352808A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US380,863 1989-07-17
US07/380,863 US5030374A (en) 1989-07-17 1989-07-17 Clear neutral non-foaming rapidly-rinsable gel facial cleanser formulation

Publications (1)

Publication Number Publication Date
JPH0352808A true JPH0352808A (en) 1991-03-07

Family

ID=23502748

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2185467A Pending JPH0352808A (en) 1989-07-17 1990-07-16 Material for face washing

Country Status (5)

Country Link
US (1) US5030374A (en)
JP (1) JPH0352808A (en)
KR (1) KR910002417A (en)
CA (1) CA2020990A1 (en)
FR (1) FR2649718B1 (en)

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US4400295A (en) * 1979-03-24 1983-08-23 Loire Cosmetics Co., Ltd. Emulsifier composition
GB2050825B (en) * 1979-06-14 1983-07-27 Kanebo Ltd Creamy or milky skin cosmetic compositions
DE3150653A1 (en) 1981-01-10 1982-09-02 Henri Gerhard Willem Bozeat Wellingborough Northamptonshire Pierson "HORIZONTAL VACUUM BAND FILTER"
GR76100B (en) * 1981-06-04 1984-08-03 Procter & Gamble
CA1232204A (en) * 1982-10-04 1988-02-02 Morris S. Herstein Reducing sebum spreading
IT1193614B (en) * 1983-01-24 1988-07-21 Crinos Industria Farmaco PREPARATION FOR THE HYGIENE AND CLEANING OF THE SKIN OF THE HAIR AND HAIR
US4495079A (en) * 1983-04-21 1985-01-22 Good Allen H Facial skin cleanser capable of softening and removing sebum plaque
FR2553660B1 (en) * 1983-10-25 1986-01-03 Oreal COSMETIC CLEANING COMPOSITION IN PARTICULAR FOR EYE MAKE-UP REMOVAL
US4673525A (en) * 1985-05-13 1987-06-16 The Procter & Gamble Company Ultra mild skin cleansing composition
US4708813A (en) * 1985-08-14 1987-11-24 The Procter & Gamble Company Nonlathering cleansing mousse with skin conditioning benefits

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7226860B2 (en) 2004-04-28 2007-06-05 Taiwan Semiconductor Manfacturing Co. Ltd. Method and apparatus for fabricating metal layer
JP2011526300A (en) * 2008-06-27 2011-10-06 ダウ グローバル テクノロジーズ エルエルシー Biocidal composition

Also Published As

Publication number Publication date
FR2649718A1 (en) 1991-01-18
FR2649718B1 (en) 1992-08-28
US5030374A (en) 1991-07-09
CA2020990A1 (en) 1991-01-18
KR910002417A (en) 1991-02-25

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