JPH0352797B2 - - Google Patents

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Publication number
JPH0352797B2
JPH0352797B2 JP60164830A JP16483085A JPH0352797B2 JP H0352797 B2 JPH0352797 B2 JP H0352797B2 JP 60164830 A JP60164830 A JP 60164830A JP 16483085 A JP16483085 A JP 16483085A JP H0352797 B2 JPH0352797 B2 JP H0352797B2
Authority
JP
Japan
Prior art keywords
water
present
bleach
cleaning
composition
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP60164830A
Other languages
Japanese (ja)
Other versions
JPS6225198A (en
Inventor
Tadashi Gomi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Yuho Chemicals Inc
Original Assignee
Yuho Chemicals Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Yuho Chemicals Inc filed Critical Yuho Chemicals Inc
Priority to JP60164830A priority Critical patent/JPS6225198A/en
Publication of JPS6225198A publication Critical patent/JPS6225198A/en
Publication of JPH0352797B2 publication Critical patent/JPH0352797B2/ja
Granted legal-status Critical Current

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Description

【発明の詳細な説明】[Detailed description of the invention]

本発明は漂白剤と保水性物質とからなる新規な
漂白洗浄剤組成物に関し、更に詳しくは敷物及び
衣服をそれらの裏打あるいは裏地を濡らすことな
く、かつ強力に洗浄漂白することができる漂白洗
浄剤組成物に関する。 〔従来技術〕 従来からの衣服の洗浄には、衣服の裏地を取除
いた後に丸洗いする方法が取られてきた。しかし
このような方法は、縫つた個所を解き、洗浄後縫
い合せる作業が必要であることから作業性が悪
く、また衣服の縮み繊維の損傷等を生じるという
欠点を有していた。 また、敷物の洗浄方法にも同様に丸洗いする方
法が採用されてきたが、縮みあるいは損傷を生じ
ることがあるとともに、床に敷き込んだ敷物は、
剥すことができず、その結果丸洗いができない場
合もあつた。 そこで従来の丸洗いに代えて、以下のような方
法が提案されている。すなわち、漂白剤を汚れた
衣服又は敷物に散布し、次いで水を吹き掛ける
か、あるいは漂白剤に水を加えたものを衣服等の
汚れ部分に塗布して、一定時間湿布した後、ブラ
ツシング等して、最後に湿つたウエス等でぬぐい
取り、仕上げる方法である。しかるに該方法で
は、水の使用量の調節が難しく、水の使用量が少
ないと漂白洗浄力が十分に発揮されずに洗浄が不
十分となり、他方水の使用量が多い場合には、洗
浄力は十分だが衣服の裏地、敷物の裏打ちまでに
水分が浸み込み、洗浄液の広がり、すなわち輪じ
みを生じる欠点があつた。それ故この方法も、家
庭等で簡易に汚れを落す方法としては不向きなも
のであつた。 そこで本発明者らは、上記のような従来の方法
の欠点を改良、改善すべく研究した結果、漂白剤
とともに保水性を有する物質を有することで輪じ
み等を生じることなく衣服、敷物を良好に洗浄で
きることを見出し、本発明を完成したのである。 〔発明の構成〕 すなわち本発明は、漂白剤と保水性物質とから
なる漂白洗浄剤組成物に関するものである。 本発明において「漂白剤」としては、過炭酸ソ
ーダ、過ホウ素酸ソーダ、過酸化水素水、過酸化
ナトリウム等の酸化漂白剤を使用することができ
る。 本発明においては市販され、容易に入手できる
漂白剤はいずれも良好に使用することができる。 また上記漂白剤に加えて、ヒドロキシ酢酸、シ
ユウ酸、エチレンジアミンテトラ酢酸塩、ニトリ
ロ酢酸又はそれらの塩等のキレート剤の1種又は
2種以上を組合せて使用することができる。該キ
レート剤の併用は、鉄錆、水あか等の汚れない対
し特に効果的である。 一方、本発明において「保水性物質」として
は、ポリビニルアルコール、ビドロキシエチルセ
ルロース、ポリアクリル酸ソーダ、アルギン酸ナ
トリウム、ポリビニルメチルエーテル−無水マレ
イン酸共重合体、ポリビニルピロリドン、ビニル
ピロリドンと水不溶性樹脂とからなるポリマー誘
導体(例えばアンタラ・エマルジヨン、GAF社
製)、特殊アクリル酸系の粉粒状吸水樹脂、水溶
性熱可塑性樹脂(ポリエチレンオキサイド)等の
高分子ポリマーを使用することができる。 本発明の漂白洗浄組成物は、前記「漂白剤」の
一種または二種以上及び前記「保水性物質」の一
種又は二種以上からなるものである。尚、漂白剤
と保水性物質との配合割合は、漂白剤及び保水性
物質の種類によつて異なるが、漂白剤/保水性物
質=(80〜95)/(20〜5)の範囲である。 また、本発明の漂白洗浄組成物には、さらに必
要により (1) 界面活性剤(汚れに対し浸透、乳化、分散効
果等)、 (2) 溶剤(例えばグリコール系、アルコール系、
石油系等)、 (3) 酵素(たとえばたんぱく、デンプン分解酵素
等)、 を添加せしめることもできる。 以上説明した本発明の組成物は、以下のように
して使用することができる。 すなわち、本発明の組成物を汚れた衣服や敷物
等に均一にばらまき一定量の水を散布するか、又
は本発明組成物に一定量の水を加えて混合したも
のを、衣服等に均一に散布し、汚れと状態に応じ
て一定時間湿布する。次いでブラツシングした
後、乾式掃除機又は軽く水で湿らしたウエスでぬ
ぐい取り、仕上げる。 本発明の組成物は、固形化又はペースト状とす
ることによつて、汚染した衣服あるいは壁面等と
の密着性を増すことができるため、特に優れた性
能を発揮することができる。尚、ポリエチレング
リコール(分子量1500〜20000)又は、高級脂肪
酸ソーダ塩(たとえば、ステリアン酸ソーダ塩)
等を溶融し、本発明組成物に対し、5〜60%の範
囲内において加え、冷却することにより固形化す
ることが可能である。 尚、本発明の組成物使用時の水の使用量は、
(漂白剤+保水性物質)/水(重量比)=(5〜
90)/(95〜10)の範囲であることが好ましい。 本発明の組成物は、衣服や敷物等への洗浄液の
広がり、すなわち輪じみを生じることなく、かつ
裏打ちや裏地を濡らすことなく衣服等を簡単かつ
十分に洗浄できるものであり、衣服、敷物等の全
面漂白洗浄、部分漂白洗浄等のあらゆる洗浄に使
用可能である。 以下本発明を実施例によりさらに詳細に説明す
る。 実施例1〜4及び比較例1〜5 表1に示す水を除く各成分を表1に示す配合量
でV型ドライブレンダー中にて混合し、実施例1
〜4及び比較例1〜5の各組成物を得た。次いで
各組成物は、漂白洗浄試験に供した。 尚、漂白洗浄試験の結果、本願発明の組成物に
おいては、洗浄液の広がり、すなわち輪じみの広
がりは観察されなかつた。一方、比較例1〜5の
組成物では洗浄液の広がりが観察された。
The present invention relates to a novel bleaching detergent composition comprising a bleaching agent and a water-retaining substance, and more particularly to a bleaching detergent composition capable of powerfully cleaning and bleaching rugs and clothing without wetting their linings or linings. Regarding the composition. [Prior Art] Conventionally, clothing has been washed by removing the lining of the clothing and then washing the clothing. However, such a method has disadvantages in that it is difficult to work because it requires the work of untying the sewn parts, washing and sewing them together, and also causes damage to the shrunk fibers of the clothing. In addition, a similar method of washing rugs has been adopted, but this may cause shrinkage or damage, and the rugs placed on the floor may
In some cases, it could not be removed and, as a result, it could not be washed completely. Therefore, the following methods have been proposed in place of conventional washing. In other words, spray bleach on dirty clothes or rugs, then spray water on them, or apply a mixture of bleach and water to the dirty parts of clothes, apply a compress to the soiled parts of the clothes for a certain period of time, and then brush the area. Then, finish by wiping it off with a damp cloth. However, with this method, it is difficult to adjust the amount of water used; if the amount of water used is small, the bleaching and cleaning power will not be fully demonstrated, resulting in insufficient cleaning; on the other hand, if the amount of water used is large, the cleaning power will be insufficient. Although it is sufficient, there is a drawback that moisture seeps into the lining of clothes and the lining of rugs, causing the cleaning solution to spread, that is, to cause bleeding. Therefore, this method was also unsuitable as a simple method for removing dirt at home. Therefore, the present inventors conducted research to improve and improve the shortcomings of the conventional methods as described above, and found that by using a water-retaining substance together with bleach, clothes and rugs can be left in good condition without causing blemishes. They discovered that it can be cleaned easily and completed the present invention. [Structure of the Invention] That is, the present invention relates to a bleach cleaning composition comprising a bleaching agent and a water-retaining substance. In the present invention, as the "bleaching agent", oxidizing bleaching agents such as sodium percarbonate, sodium perborate, hydrogen peroxide, and sodium peroxide can be used. In the present invention, any commercially available and easily available bleaching agent can be used successfully. In addition to the above bleaching agents, one or more chelating agents such as hydroxyacetic acid, oxalic acid, ethylenediaminetetraacetate, nitriloacetic acid or salts thereof can be used in combination. The combined use of the chelating agent is particularly effective in preventing stains such as iron rust and water scale. On the other hand, in the present invention, the "water-retaining substance" includes polyvinyl alcohol, bidroxyethyl cellulose, sodium polyacrylate, sodium alginate, polyvinyl methyl ether-maleic anhydride copolymer, polyvinylpyrrolidone, vinylpyrrolidone and water-insoluble resin. High molecular polymers such as polymer derivatives (for example, Antara Emulsion, manufactured by GAF), special acrylic acid-based powdery water-absorbing resins, and water-soluble thermoplastic resins (polyethylene oxide) can be used. The bleach cleaning composition of the present invention comprises one or more of the above-mentioned "bleaching agents" and one or more of the above-mentioned "water-retentive substances". The blending ratio of bleach and water-retaining substance varies depending on the type of bleach and water-retaining substance, but is in the range of bleach/water-retaining substance = (80-95)/(20-5). . In addition, the bleach cleaning composition of the present invention may further contain (1) a surfactant (penetrating, emulsifying, dispersing effect on dirt, etc.), (2) a solvent (for example, glycol-based, alcohol-based,
(3) Enzymes (e.g. protein, starch degrading enzymes, etc.) can also be added. The composition of the present invention explained above can be used as follows. That is, the composition of the present invention is uniformly spread over dirty clothes, rugs, etc. and a certain amount of water is sprinkled on the same, or the composition of the present invention is mixed with a certain amount of water and the mixture is uniformly spread on clothes, etc. Spray and apply a compress for a certain period of time depending on the dirt and condition. Then, after brushing, finish by wiping with a dry vacuum cleaner or a rag lightly dampened with water. When the composition of the present invention is solidified or made into a paste form, it can increase its adhesion to contaminated clothing or walls, so it can exhibit particularly excellent performance. In addition, polyethylene glycol (molecular weight 1500-20000) or higher fatty acid sodium salt (for example, stearic acid sodium salt)
It is possible to melt the compound, add it to the composition of the present invention in a range of 5 to 60%, and solidify by cooling. The amount of water used when using the composition of the present invention is:
(Bleach + water-retaining substance)/water (weight ratio) = (5~
90)/(95-10). The composition of the present invention can easily and thoroughly clean clothes, etc. without spreading the cleaning liquid onto clothes, rugs, etc., that is, without causing any bleeding, and without wetting the lining or lining. It can be used for all types of cleaning such as full bleach cleaning and partial bleach cleaning. The present invention will be explained in more detail below with reference to Examples. Examples 1 to 4 and Comparative Examples 1 to 5 Each component other than water shown in Table 1 was mixed in a V-type dry blender in the amount shown in Table 1, and Example 1
4 and Comparative Examples 1 to 5 were obtained. Each composition was then subjected to a bleach wash test. As a result of the bleach cleaning test, no spreading of the cleaning solution, that is, no spreading of rings was observed in the composition of the present invention. On the other hand, in the compositions of Comparative Examples 1 to 5, spreading of the cleaning liquid was observed.

【表】 漂白洗浄試験方法 東レ株式会社製、パイル長11mm、ナイロン素材
100%のCSカーペツト(商品名・マイライフMY
−6)に直径50mm径の円を描き、円内にコーヒー
(20%インスタントコーヒー水溶液)を10mlづつ
均一に3回に渡つて塗布した後、30日間室温に放
置し、コーヒーのしみをカーペツトに固着させ
る。コーラ、オレンジジユースのしみも同様に固
着させる。カーペツトに固着させたしみに、表1
に示す実施例1〜4の本発明の組成物と比較例1
〜4の本発明以外の組成物の水を除いた成分、す
なわち粉末組成物を5gづつ均一に散布し直ち
に、表1に各実施例及び比較例ごとに示した所定
量の水をスプレーにて均一に塗布する。 また形状が液状を呈する比較例5の本発明以外
の組成物も、しみの部分に均一に塗布する。 その後各実施例及び比較例ともに3時間室温に
て放置した後、水で濡らしたウエスにて拭き取り
漂白洗浄率を測定する。
[Table] Bleach cleaning test method Manufactured by Toray Industries, pile length 11mm, nylon material
100% CS Carpet (Product name: My Life MY
-6) Draw a circle with a diameter of 50 mm, apply 10 ml of coffee (20% instant coffee aqueous solution) evenly within the circle three times, and leave it at room temperature for 30 days to remove the coffee stains from the carpet. Make it stick. It also fixes cola and orange juice stains in the same way. For stains fixed on the carpet, use Table 1.
Compositions of the present invention of Examples 1 to 4 and Comparative Example 1 shown in
The components of the compositions other than the present invention in ~4, excluding water, i.e., 5 g of the powder composition, were uniformly dispersed, and immediately the predetermined amount of water shown in Table 1 for each Example and Comparative Example was sprayed. Apply evenly. Moreover, the composition other than the present invention of Comparative Example 5, which has a liquid shape, is also applied uniformly to the stained area. After that, each Example and Comparative Example were left at room temperature for 3 hours, and then wiped with a cloth dampened with water to measure the bleaching and cleaning efficiency.

【表】 漂白洗浄率の算出式
漂白洗浄後の汚染布の反射
率−汚染布の反射率
漂白洗浄率(%)
[Table] Calculation formula for bleach cleaning rate
Reflectance of contaminated cloth after bleach cleaning - Reflectance of contaminated cloth
Bleach cleaning rate (%)

Claims (1)

【特許請求の範囲】[Claims] 1 酸化漂白剤及び高分子ポリマー保水性物質を
含み、該漂白剤/該保水物質(重量比)が(80〜
95)/(20〜5)の範囲である漂白洗浄組成物。
1 Contains an oxidative bleaching agent and a polymeric water-retaining substance, and the bleaching agent/the water-retaining substance (weight ratio) is (80~
95)/(20-5).
JP60164830A 1985-07-25 1985-07-25 Bleaching detergent composition Granted JPS6225198A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP60164830A JPS6225198A (en) 1985-07-25 1985-07-25 Bleaching detergent composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP60164830A JPS6225198A (en) 1985-07-25 1985-07-25 Bleaching detergent composition

Publications (2)

Publication Number Publication Date
JPS6225198A JPS6225198A (en) 1987-02-03
JPH0352797B2 true JPH0352797B2 (en) 1991-08-13

Family

ID=15800735

Family Applications (1)

Application Number Title Priority Date Filing Date
JP60164830A Granted JPS6225198A (en) 1985-07-25 1985-07-25 Bleaching detergent composition

Country Status (1)

Country Link
JP (1) JPS6225198A (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0639665A1 (en) * 1993-08-20 1995-02-22 Ciba-Geigy Ag Phosphate-free reducing and bleaching agent
US6300299B1 (en) 2001-02-06 2001-10-09 E. I. Du Pont De Nemours And Company Process for cleaning turmeric stains
JP5379963B2 (en) * 2007-08-24 2013-12-25 ライオン株式会社 Cleaning composition for wiping and cleaning method

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5527333A (en) * 1978-08-16 1980-02-27 Kao Corp Bleaching agent composition
JPS56139595A (en) * 1979-11-03 1981-10-31 Procter & Gamble Particulate detergent composition
JPS57145300A (en) * 1981-03-04 1982-09-08 Hitachi Ltd Plasma controller for nucler fusion reactor
JPS58101199A (en) * 1981-12-11 1983-06-16 花王株式会社 Stabilizing composition for powder chlorine bleaching agent
JPS59105100A (en) * 1982-12-07 1984-06-18 ユ−ホ−ケミカル株式会社 Dry sweeping agent

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5527333A (en) * 1978-08-16 1980-02-27 Kao Corp Bleaching agent composition
JPS56139595A (en) * 1979-11-03 1981-10-31 Procter & Gamble Particulate detergent composition
JPS57145300A (en) * 1981-03-04 1982-09-08 Hitachi Ltd Plasma controller for nucler fusion reactor
JPS58101199A (en) * 1981-12-11 1983-06-16 花王株式会社 Stabilizing composition for powder chlorine bleaching agent
JPS59105100A (en) * 1982-12-07 1984-06-18 ユ−ホ−ケミカル株式会社 Dry sweeping agent

Also Published As

Publication number Publication date
JPS6225198A (en) 1987-02-03

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