JPH0344546A - Detection of internal abnormality of gas insulated electric device - Google Patents
Detection of internal abnormality of gas insulated electric deviceInfo
- Publication number
- JPH0344546A JPH0344546A JP17901589A JP17901589A JPH0344546A JP H0344546 A JPH0344546 A JP H0344546A JP 17901589 A JP17901589 A JP 17901589A JP 17901589 A JP17901589 A JP 17901589A JP H0344546 A JPH0344546 A JP H0344546A
- Authority
- JP
- Japan
- Prior art keywords
- gas
- sensor
- transformer
- bad smell
- substance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000005856 abnormality Effects 0.000 title claims abstract description 20
- 238000001514 detection method Methods 0.000 title description 7
- 239000000126 substance Substances 0.000 claims abstract description 13
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000011810 insulating material Substances 0.000 claims abstract description 7
- 239000007787 solid Substances 0.000 claims abstract description 7
- 239000007789 gas Substances 0.000 claims description 35
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 6
- WQOXQRCZOLPYPM-UHFFFAOYSA-N dimethyl disulfide Chemical compound CSSC WQOXQRCZOLPYPM-UHFFFAOYSA-N 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- QMMFVYPAHWMCMS-UHFFFAOYSA-N Dimethyl sulfide Chemical compound CSC QMMFVYPAHWMCMS-UHFFFAOYSA-N 0.000 claims description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 2
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 claims 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 claims 1
- 235000019645 odor Nutrition 0.000 claims 1
- 238000005979 thermal decomposition reaction Methods 0.000 claims 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 abstract description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract description 3
- 239000003574 free electron Substances 0.000 abstract description 2
- 229910044991 metal oxide Inorganic materials 0.000 abstract description 2
- 238000005245 sintering Methods 0.000 abstract description 2
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract 2
- 230000003247 decreasing effect Effects 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
- 238000004227 thermal cracking Methods 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 description 7
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 4
- 150000001299 aldehydes Chemical class 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- -1 polyethylene terephthalate Polymers 0.000 description 3
- 239000005020 polyethylene terephthalate Substances 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 238000010891 electric arc Methods 0.000 description 2
- 238000004817 gas chromatography Methods 0.000 description 2
- 238000013021 overheating Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 230000035945 sensitivity Effects 0.000 description 2
- 125000003011 styrenyl group Chemical group [H]\C(*)=C(/[H])C1=C([H])C([H])=C([H])C([H])=C1[H] 0.000 description 2
- 230000033228 biological regulation Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- 238000004949 mass spectrometry Methods 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
この発明は、SF、ガス封入変圧器等のガス絶縁電気機
器における例えばアーク放電や過熱などの内部異常の有
無を検出する方法に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a method for detecting the presence or absence of internal abnormalities, such as arc discharge or overheating, in gas-insulated electrical equipment such as SFs and gas-filled transformers.
変圧器内にアーク放電や過熱等の異常が発生すると、異
常発生周辺部のSF、ガスや固体絶縁材料が過熱され、
分解生成ガスが発生する。この分解生成ガスを極力早期
に検出することができれば、事故の拡大を未然に防止す
ることができる。When an abnormality such as arc discharge or overheating occurs in a transformer, the SF, gas, and solid insulating material around the abnormality will become overheated.
Decomposition gas is generated. If this decomposition gas can be detected as early as possible, the spread of the accident can be prevented.
以上のような観点から、変圧器の円滑な運用を目的とし
て、変圧器から定期的に採取したSF。From the above point of view, SF is periodically collected from the transformer for the purpose of smooth operation of the transformer.
ガスを分析し、内部異常に起因して生成する分解生成ガ
スの存在を調べ、内部異常の有無を判断する方法が一般
に行われている。このような分析には、ガスクロマトグ
ラフィや質量分析器などの装置が使用されている。A commonly used method is to analyze gas and check for the presence of decomposed gas produced due to internal abnormalities to determine the presence or absence of internal abnormalities. Devices such as gas chromatography and mass spectrometry are used for such analysis.
従来の内部異常の検出は、以上のような高級な分析装置
を用いて行われるので、分析には専門の知識を必要とし
、また分析には時間がかがるという問題点があった。Conventional detection of internal abnormalities is carried out using the above-mentioned high-grade analysis equipment, which has the problem of requiring specialized knowledge and time-consuming analysis.
この発明は、以上のような従来の問題点を解消するため
になされたもので、専門知識を必要とせず、短時間でガ
ス絶縁変圧器の内部異常を検出する方法を得ることにあ
る。The present invention was made to solve the above-mentioned conventional problems, and an object of the present invention is to provide a method for detecting internal abnormalities in a gas insulated transformer in a short time without requiring specialized knowledge.
この発明にかかる内部異常検出方法は、変圧器の内部異
常によってSF、ガスや固体絶縁材料が過熱された場合
に生ずる悪臭物質に起因した臭気を測定するものである
。The internal abnormality detection method according to the present invention measures the odor caused by malodorous substances that occur when SF, gas, or solid insulating material is overheated due to an internal abnormality in a transformer.
一般にガス絶縁変圧器には、絶縁ガスとしてSF6ガス
、また固体絶縁材料として、例えばコイル絶縁紙、ブレ
スポードおよび木材のようなセルロース系材料やポリエ
チレンテレフタレート樹脂などが使用されている。In general, gas insulated transformers use SF6 gas as an insulating gas, and solid insulating materials such as cellulose materials such as coil insulating paper, breath pods and wood, and polyethylene terephthalate resin.
硫化水素(H2S)、メチルメルカプタン(CH,SH
)、硫化メチル[(CH3)2 S 〕および二硫化メ
チル(C14y S−S CH3]は、SF、と有機材
料との複合分解、アセトアルデヒド
(CH,Cl−10)はセルロース系材料あるいはポリ
エチレンテレフタレート樹脂の分解、スチレンの分解に
起因して生成する物質である。これらの物質は法律の°
″悪臭防止法”において指定されているものであり、極
めて微量の存在でも臭いを発する1例えば、人が楽に検
知できる臭いの場合、メチルメルカプタンで0.004
ppm、アセトアルデヒドで0 、1 ppm程度であ
るといわれている。Hydrogen sulfide (H2S), methyl mercaptan (CH, SH
), methyl sulfide [(CH3)2S] and methyl disulfide (C14y S-S CH3) are complex decomposition of SF and organic materials, and acetaldehyde (CH, Cl-10) is a cellulose-based material or polyethylene terephthalate resin. These substances are produced due to the decomposition of styrene and the decomposition of styrene.These substances are subject to legal regulations.
It is specified in the ``Offensive Odor Prevention Act,'' and even in extremely small amounts it emits an odor.For example, in the case of an odor that can be easily detected by humans, methyl mercaptan is 0.004
ppm, and is said to be about 0.1 ppm for acetaldehyde.
第1図は、この発明の根拠を示す実験結果の一例であり
、変圧器に使用されているセルロース系の材料を190
℃〜335℃の温度で加熱した場合のアルデヒド類の生
成量を示している。Figure 1 shows an example of experimental results showing the basis of this invention.
It shows the amount of aldehydes produced when heated at a temperature of 335°C to 335°C.
第1図から、材料の分解に伴ってアルデヒド類が生威し
、生成量は高温度で高くなることがわかる。From FIG. 1, it can be seen that aldehydes grow as the material decomposes, and the amount produced increases at high temperatures.
また別の試験では、ガス絶縁変圧器のコイル絶縁材料に
使用されているポリエチレンテレフタレートフィルム約
101111?をN2ガス中で400℃、30分間保持
し、生成ガスをガスクロマトグラフィー質量分析装置で
調べ、悪臭物質の−っであるスチレンが生成することを
確認している。このような実験から、SF、ガス中の悪
臭物質を検出することによって変圧器内部異常を発見で
きることがわかる。In another test, polyethylene terephthalate film, which is used as a coil insulation material for gas-insulated transformers, was found to have an approximately 101,111? was maintained at 400° C. for 30 minutes in N2 gas, and the resulting gas was examined using a gas chromatography mass spectrometer to confirm that styrene, a malodorous substance, was produced. These experiments show that an abnormality inside a transformer can be discovered by detecting foul-smelling substances in SF and gas.
第2図は、この発明の一実施例におけるガス絶縁電気機
器内部異常検出装置を示す断面図である。FIG. 2 is a sectional view showing an internal abnormality detection device for gas-insulated electrical equipment in one embodiment of the present invention.
図において、(1)は変圧器タンク、く2)は前記タン
クに封入されたSF、ガス、(3)は前記タンク(1)
内と連通ずるガス入口流路、(4)はガス循環流路上に
配置されたガス循環ポンプ、(5a)〜(5b)はガス
循環流路上に配置されたバルブ、(6n)〜(6b)は
ガス循環流路上に配置されたフランジ、(7)はガス出
口流路に配置されたセンサ、(8〉は前記タンク(]〉
内と連通ずるガス出口流路である。In the figure, (1) is the transformer tank, 2) is the SF and gas sealed in the tank, and (3) is the tank (1).
(4) is a gas circulation pump disposed on the gas circulation passage; (5a) to (5b) are valves disposed on the gas circulation passage; (6n) to (6b) is a flange placed on the gas circulation flow path, (7) is a sensor placed on the gas outlet flow path, and (8> is the tank ()).
This is a gas outlet flow path that communicates with the inside.
次に動作について説明する。変圧器タンク(1〉内のS
F、ガス(2)は、ガス循環ポンプ(4)によって、ガ
ス入口流N(3)→ガス循環ポンプ(4)→バルブ(5
a)→フランジ(6)→センサ(7)→フランジ(6b
)→バルブ(5b)→ガス出力流路(8)の経路で循環
している。Next, the operation will be explained. S in the transformer tank (1)
F, gas (2) is transferred by gas circulation pump (4) to gas inlet flow N (3) → gas circulation pump (4) → valve (5
a) → Flange (6) → Sensor (7) → Flange (6b
)→valve (5b)→gas output channel (8).
変圧器タンク内に異常が発生すると、SF、や固体絶縁
材料が分解して、分解生成成分を生成する。変圧器タン
ク(1)内のSF、ガス〈2〉は、前述の経路で循環し
ているので、分解生成成分はS F sガスと共にセン
サ(7)に流入して検出される。When an abnormality occurs in a transformer tank, SF or solid insulating material decomposes and generates decomposition products. Since the SF gas <2> in the transformer tank (1) circulates through the aforementioned path, the decomposition product components flow into the sensor (7) together with the SF s gas and are detected.
センサく7)は、例えば白金線コイル上にSnO2、Z
nO等の金属酸化物を焼結させたような素子であり、ア
ルデヒドやメチルメルカプタン等の悪臭物質に感応し、
素子に電子が注入され、自由電子濃度が増加するために
抵抗が低下する。Sensor 7) is, for example, a platinum wire coil coated with SnO2, Z
It is an element made by sintering metal oxides such as nO, and is sensitive to malodorous substances such as aldehydes and methyl mercaptan.
Electrons are injected into the device, and the resistance decreases because the free electron concentration increases.
ところで、上記説明では、この発明をSF、ガスを封入
したガス絶縁変圧器に適用した場合について述べたが、
その他のガス絶縁電気機器でも、内部異常によって71
!臭物質を生成するようなケースについては、本法を適
用できることはいうまでもない。By the way, in the above explanation, the present invention was applied to SF, a gas insulated transformer filled with gas.
Other gas-insulated electrical equipment also suffered 71% due to internal abnormalities.
! It goes without saying that this law can be applied to cases where odor substances are generated.
以上のようにこの発明では、検出感度の高い悪臭物質を
異常検出の対象成分としたので、ガス絶縁電気機器の内
部異常を、簡単かつ高感度で検出できる。As described above, in this invention, malodorous substances with high detection sensitivity are used as the target components for abnormality detection, so that internal abnormalities in gas-insulated electrical equipment can be detected easily and with high sensitivity.
第1図は、この発明の根拠を示す実験結果の一例、第2
図は、ガス絶縁変圧器内部異常検出装置の一例を示す断
面図である。
第2図において、(1ンは変圧器タンク、(4)はガス
循環ポンプ、(7)はセンサである。Figure 1 shows an example of experimental results showing the basis of this invention.
The figure is a sectional view showing an example of a gas insulated transformer internal abnormality detection device. In FIG. 2, (1) is a transformer tank, (4) is a gas circulation pump, and (7) is a sensor.
Claims (1)
発生する硫化水素、メチルメルカプタン、硫化メチル、
二硫化メチル、アセトアルデヒドあるいはスチレン等の
悪臭物質に起因する臭気を、悪臭物質に感応するセンサ
をガス絶縁電気機器の本体と連通するガス循環流路に配
置し、検出することを特徴とする、ガス絶縁電気機器内
部異常検出方法。(1) Hydrogen sulfide, methyl mercaptan, methyl sulfide generated by thermal decomposition of SF_6 gas and solid insulating materials,
A gas insulated electric appliance, characterized in that odors caused by malodorous substances such as methyl disulfide, acetaldehyde, or styrene are detected by disposing a sensor sensitive to malodorous substances in a gas circulation flow path that communicates with the main body of the gas-insulated electrical equipment. Method for detecting internal abnormalities in insulated electrical equipment.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP17901589A JPH0344546A (en) | 1989-07-13 | 1989-07-13 | Detection of internal abnormality of gas insulated electric device |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP17901589A JPH0344546A (en) | 1989-07-13 | 1989-07-13 | Detection of internal abnormality of gas insulated electric device |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH0344546A true JPH0344546A (en) | 1991-02-26 |
Family
ID=16058626
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP17901589A Pending JPH0344546A (en) | 1989-07-13 | 1989-07-13 | Detection of internal abnormality of gas insulated electric device |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0344546A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101975806A (en) * | 2010-08-20 | 2011-02-16 | 郑州炜盛电子科技有限公司 | Combined type gas sensor and gas detection method thereof |
JP2011121102A (en) * | 2009-12-14 | 2011-06-23 | Mitsubishi Electric Corp | Solder joining apparatus |
CN109540970A (en) * | 2018-12-06 | 2019-03-29 | 五邑大学 | One kind being based on novel ZnO nano column/SnO2Thin film detector and preparation method |
US20230148728A1 (en) * | 2021-11-12 | 2023-05-18 | Shenzhen Yumi Info. Co., Ltd | Hair remover |
-
1989
- 1989-07-13 JP JP17901589A patent/JPH0344546A/en active Pending
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011121102A (en) * | 2009-12-14 | 2011-06-23 | Mitsubishi Electric Corp | Solder joining apparatus |
CN101975806A (en) * | 2010-08-20 | 2011-02-16 | 郑州炜盛电子科技有限公司 | Combined type gas sensor and gas detection method thereof |
CN109540970A (en) * | 2018-12-06 | 2019-03-29 | 五邑大学 | One kind being based on novel ZnO nano column/SnO2Thin film detector and preparation method |
CN109540970B (en) * | 2018-12-06 | 2024-03-19 | 中建八局检测科技有限公司 | ZnO nano-column/SnO 2 Thin film detector and preparation method thereof |
US20230148728A1 (en) * | 2021-11-12 | 2023-05-18 | Shenzhen Yumi Info. Co., Ltd | Hair remover |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR101260566B1 (en) | Chemical ionization reaction or proton transfer reaction mass spectrometry with a quadrupole or time-of-flight mass spectrometer | |
US20130203180A1 (en) | Chemical Ionization Reaction or Proton Transfer Reaction Mass Spectrometry | |
DE2446918A1 (en) | DEVICE FOR DETECTION OF TRACES OF A SPECIFIC VAPOR IN AN AIR SAMPLE | |
US6291821B1 (en) | Method of monitoring the status of the gas drying system in an ion mobility spectrometer | |
JPH0344546A (en) | Detection of internal abnormality of gas insulated electric device | |
Takhar et al. | Characterization of secondary organic aerosol from heated-cooking-oil emissions: evolution in composition and volatility | |
KR20170008784A (en) | Chemical calibration process, system and device | |
US2414363A (en) | Means for generating radiant energy for spectrum analysis | |
Yankelevich et al. | High-power short-pulsed corona: investigation of electrical performance, SO/sub 2/removal, and ozone generation | |
Rubloff | Photoemission studies of time-resolved surface reactions: Isothermal desorption of CO from Ni (111) | |
GB2534460A (en) | Process and system for facilitating chemical identification in a detector | |
Michel et al. | A selected ion flow tube study of the reactions of H3O+, NO+ and O2+ with methyl vinyl ketone and some atmospherically important aldehydes | |
CN110431411A (en) | Method and apparatus | |
EP0421100B1 (en) | Procedure and equipment for recognizing dangerous conditions in a room | |
CA1147810A (en) | Device and method for detecting alkali metals | |
Tanaka et al. | High field dissipation current waveform of polyethylene film obtained by new method | |
SU728067A1 (en) | Method of determining of ultratracing impurities of organic compounds | |
JPH08298955A (en) | Reduction of odor of garlic | |
JPS5818446Y2 (en) | Abnormality detection device for electrical equipment | |
Felger et al. | Analysis of thermal breakdown products of electrical insulation | |
Sekii et al. | Analysis of deterioration by partial discharge of XLPE using GCMS and FTIR | |
Ji et al. | Design and experiment of a laser ionization source for ion mobility spectrometer | |
JPH11354333A (en) | Inside abnormality diagnostic method for gas insulated electric device | |
JPS5324783A (en) | Breakdown voltage goodness or not analyzing method | |
Van Brunt et al. | Production of S2F10, S2OF10, and S2O2F10 from spark and negative-corona discharges in SF6 and SF6/O2 gas mixtures |