JPH0339838B2 - - Google Patents
Info
- Publication number
- JPH0339838B2 JPH0339838B2 JP60066436A JP6643685A JPH0339838B2 JP H0339838 B2 JPH0339838 B2 JP H0339838B2 JP 60066436 A JP60066436 A JP 60066436A JP 6643685 A JP6643685 A JP 6643685A JP H0339838 B2 JPH0339838 B2 JP H0339838B2
- Authority
- JP
- Japan
- Prior art keywords
- thin film
- film layer
- transparent thin
- iris
- laminate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000010409 thin film Substances 0.000 claims description 91
- 208000016339 iris pattern Diseases 0.000 claims description 46
- 239000010408 film Substances 0.000 claims description 33
- 230000001747 exhibiting effect Effects 0.000 claims description 23
- 238000002834 transmittance Methods 0.000 claims description 13
- 239000000463 material Substances 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- 229910010272 inorganic material Inorganic materials 0.000 claims description 10
- 239000011147 inorganic material Substances 0.000 claims description 10
- 239000010419 fine particle Substances 0.000 claims description 6
- 239000011368 organic material Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 4
- 150000002736 metal compounds Chemical class 0.000 claims description 4
- 229920003002 synthetic resin Polymers 0.000 claims description 3
- 239000000057 synthetic resin Substances 0.000 claims description 3
- 238000010030 laminating Methods 0.000 claims description 2
- 229920000620 organic polymer Polymers 0.000 claims 4
- 239000002861 polymer material Substances 0.000 claims 4
- 239000010410 layer Substances 0.000 description 93
- -1 polyethylene terephthalate Polymers 0.000 description 15
- 238000000034 method Methods 0.000 description 14
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 12
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- 239000005083 Zinc sulfide Substances 0.000 description 8
- 229910052984 zinc sulfide Inorganic materials 0.000 description 8
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 8
- 239000000020 Nitrocellulose Substances 0.000 description 7
- 238000007756 gravure coating Methods 0.000 description 7
- 229920001220 nitrocellulos Polymers 0.000 description 7
- 239000003973 paint Substances 0.000 description 7
- 229920000139 polyethylene terephthalate Polymers 0.000 description 7
- 239000005020 polyethylene terephthalate Substances 0.000 description 7
- 229920001577 copolymer Polymers 0.000 description 6
- 239000000243 solution Substances 0.000 description 6
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 5
- 239000004793 Polystyrene Substances 0.000 description 4
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 4
- 229920002678 cellulose Polymers 0.000 description 4
- 239000001913 cellulose Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 229920001225 polyester resin Polymers 0.000 description 4
- 239000004645 polyester resin Substances 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 229920002223 polystyrene Polymers 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920006163 vinyl copolymer Polymers 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 229920000877 Melamine resin Polymers 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 229920006397 acrylic thermoplastic Polymers 0.000 description 3
- 239000012790 adhesive layer Substances 0.000 description 3
- 239000002390 adhesive tape Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000008119 colloidal silica Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000004417 polycarbonate Substances 0.000 description 3
- 229920000515 polycarbonate Polymers 0.000 description 3
- 239000011241 protective layer Substances 0.000 description 3
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 3
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 2
- BDSSZTXPZHIYHM-UHFFFAOYSA-N 2-phenoxypropanoyl chloride Chemical compound ClC(=O)C(C)OC1=CC=CC=C1 BDSSZTXPZHIYHM-UHFFFAOYSA-N 0.000 description 2
- IMROMDMJAWUWLK-UHFFFAOYSA-N Ethenol Chemical compound OC=C IMROMDMJAWUWLK-UHFFFAOYSA-N 0.000 description 2
- 239000004640 Melamine resin Substances 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- WDJHALXBUFZDSR-UHFFFAOYSA-M acetoacetate Chemical compound CC(=O)CC([O-])=O WDJHALXBUFZDSR-UHFFFAOYSA-M 0.000 description 2
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- JPUHCPXFQIXLMW-UHFFFAOYSA-N aluminium triethoxide Chemical compound CCO[Al](OCC)OCC JPUHCPXFQIXLMW-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000000149 argon plasma sintering Methods 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- BSDOQSMQCZQLDV-UHFFFAOYSA-N butan-1-olate;zirconium(4+) Chemical compound [Zr+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] BSDOQSMQCZQLDV-UHFFFAOYSA-N 0.000 description 2
- 239000013522 chelant Substances 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 229920000592 inorganic polymer Polymers 0.000 description 2
- 238000007733 ion plating Methods 0.000 description 2
- ORUIBWPALBXDOA-UHFFFAOYSA-L magnesium fluoride Chemical compound [F-].[F-].[Mg+2] ORUIBWPALBXDOA-UHFFFAOYSA-L 0.000 description 2
- 229910001635 magnesium fluoride Inorganic materials 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 2
- 229920001568 phenolic resin Polymers 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000004926 polymethyl methacrylate Substances 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 229920000915 polyvinyl chloride Polymers 0.000 description 2
- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Chemical compound [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 description 2
- JTQPTNQXCUMDRK-UHFFFAOYSA-N propan-2-olate;titanium(2+) Chemical compound CC(C)O[Ti]OC(C)C JTQPTNQXCUMDRK-UHFFFAOYSA-N 0.000 description 2
- 238000007763 reverse roll coating Methods 0.000 description 2
- 150000003377 silicon compounds Chemical class 0.000 description 2
- 229920005573 silicon-containing polymer Polymers 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- JMXKSZRRTHPKDL-UHFFFAOYSA-N titanium ethoxide Chemical compound [Ti+4].CC[O-].CC[O-].CC[O-].CC[O-] JMXKSZRRTHPKDL-UHFFFAOYSA-N 0.000 description 2
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 2
- 238000001771 vacuum deposition Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- 229910001928 zirconium oxide Inorganic materials 0.000 description 2
- ODFUONPPRRIIIB-UHFFFAOYSA-N 5-azido-2-benzofuran-1,3-dione Chemical compound [N-]=[N+]=NC1=CC=C2C(=O)OC(=O)C2=C1 ODFUONPPRRIIIB-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
- 229920000299 Nylon 12 Polymers 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 238000010009 beating Methods 0.000 description 1
- SPJUYZFDLKHDIJ-UHFFFAOYSA-N buta-1,3-dienylbenzene hydrochloride Chemical compound C=CC=CC1=CC=CC=C1.Cl SPJUYZFDLKHDIJ-UHFFFAOYSA-N 0.000 description 1
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- GBRBMTNGQBKBQE-UHFFFAOYSA-L copper;diiodide Chemical compound I[Cu]I GBRBMTNGQBKBQE-UHFFFAOYSA-L 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 229910001610 cryolite Inorganic materials 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 229920006334 epoxy coating Polymers 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000002648 laminated material Substances 0.000 description 1
- 239000002650 laminated plastic Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 239000011698 potassium fluoride Substances 0.000 description 1
- 235000003270 potassium fluoride Nutrition 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Chemical compound [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、新規な虹彩色を呈し主として装飾用
に用いる虹彩模様を呈する積層体に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a laminate exhibiting a novel iris color and an iris pattern used primarily for decoration.
従来から虹彩模様を表面に呈するプラスチツク
積層体として色々なものが提案されており、例え
ば、下記(ア)〜(ウ)によつて例示される。
Various plastic laminates exhibiting an iris pattern on the surface have been proposed in the past, and are exemplified by (a) to (c) below.
(ア) 硫化亜鉛、酸化チタン、酸化錫、フツカ化マ
グネシウムおよびヨウ化銅のごとき特殊な化合
物を複層蒸着する方法による積層体。(a) A laminate made by depositing multiple layers of special compounds such as zinc sulfide, titanium oxide, tin oxide, magnesium fluoride, and copper iodide.
(イ) 特公昭37−8731号公報に記載されたごとき酸
化チタン薄膜層を積層した積層体。(a) A laminate in which titanium oxide thin film layers are laminated as described in Japanese Patent Publication No. 37-8731.
(ウ) 特公昭45−39958号公報に記載されているよ
うな、プラスチツクフイルム上に薄い金属層、
透明ワニス、別の金属層を積層したもの、特公
昭51−33589号公報のような、光線反射膜、干
渉樹脂膜、半透明金属膜を積層したもの、さら
に特公昭52−1413号公報のような、光線反射
膜、凹凸状の干渉樹脂膜、半透明金属膜を積層
した虹彩模様を呈する積層体。(c) A thin metal layer on a plastic film as described in Japanese Patent Publication No. 45-39958,
Transparent varnish, laminated with another metal layer, laminated with light reflecting film, interference resin film, semi-transparent metal film as in Japanese Patent Publication No. 51-33589, and also as in Japanese Patent Publication No. 52-1413 A laminate that exhibits an iris pattern by laminating a light reflecting film, an uneven interference resin film, and a translucent metal film.
しかし、これら従来の積層体およびそれらの製
造方法には、それぞれ欠点がある。例えば、(ア)の
方法によるものでは積層物質が特殊で一般に高価
であり、これら物質を約1000Å以上の光学的厚み
に凹凸に蒸着する必要があるので大量生産に不向
きであり、得られる虹彩の模様を随意のパターン
に調整することが困難である。 However, each of these conventional laminates and methods of manufacturing them has drawbacks. For example, in method (a), the laminated materials are special and generally expensive, and these materials need to be deposited unevenly to an optical thickness of about 1000 Å or more, making it unsuitable for mass production. It is difficult to adjust the pattern to any desired pattern.
また(イ)によるものは、四塩化チタンガスを使用
するために塩酸ガスの発生があり、製造時の作業
者の健康、製造設備の腐食、環境に対する公害等
の問題がある。 In addition, in the case of (a), since titanium tetrachloride gas is used, hydrochloric acid gas is generated, which poses problems such as the health of workers during production, corrosion of production equipment, and environmental pollution.
さらに(ウ)によるものでは、光線反射膜としてア
ルミニウム等を中心とする金属蒸着や金属箔であ
ることから、透過率が１％以下の不透明な膜であ
り、従つて、不透明な虹彩模様を呈する積層体と
なる。これらの積層体はそれを種々の被装飾物等
に貼着した場合、その表面の外観を遮断するよう
になるため、貼着する物の表面が透明なものや模
様を有するごときのもの、すなわち、その外観を
生かしたりする場合は適用できないという欠点が
あつた。 Furthermore, in the case of (c), since the light reflecting film is a vapor-deposited metal mainly made of aluminum or a metal foil, it is an opaque film with a transmittance of 1% or less, and therefore exhibits an opaque iris pattern. It becomes a laminate. When these laminates are attached to various objects to be decorated, etc., they will block the appearance of the surface of the object, so if the surface of the object is transparent or has a pattern, i.e. However, it has the disadvantage that it cannot be applied when making the most of its appearance.
（本発明が解決しようとする問題点〕
本発明は、上記に述べた従来の虹彩発現技術の
欠点を改良し、基材の成型体の外観状態を損なわ
ずに、任意の多彩で美麗な虹彩模様を呈する積層
体を得ることを目的とする。(Problems to be Solved by the Present Invention) The present invention improves the drawbacks of the conventional iris expression technology described above, and produces any desired variety of beautiful iris without impairing the appearance of the molded body of the base material. The purpose is to obtain a laminate exhibiting a pattern.
本発明は成型体の上に透明な下引き層を介し虹
彩薄膜層を設けてなる積層体において、
該紅虹薄膜層が、可視光線透過率が50％以上で
ある透明な薄膜層Ａと可視光線透過率が50％以上
である凹凸のある透明な薄膜層Ｂとから成り、か
つ該透明な薄膜層ＡとＢとの屈折率の差が0.05以
上であることを特徴とする虹彩模様を呈する積層
体を提供するものである。
The present invention provides a laminate in which an iris thin film layer is provided on a molded body through a transparent undercoat layer, in which the iris thin film layer is a transparent thin film layer A having a visible light transmittance of 50% or more and a visible iris thin film layer. The iris pattern is composed of a transparent thin film layer B having irregularities and a light transmittance of 50% or more, and the difference in refractive index between the transparent thin film layers A and B is 0.05 or more. The present invention provides a laminate.
以下、本発明における虹彩模様を呈する積層体
を第１〜３図において説明する。 Hereinafter, a laminate exhibiting an iris pattern according to the present invention will be explained with reference to FIGS. 1 to 3.
ここで薄膜層の積層順は、第１図がＡ／Ｂ／
Ａ、第２図がＡ／Ｂ、第３図がＢ／Ａのものを表
している。なお、本発明が下記説明により限定さ
れるものでないことは言うまでもない。 Here, the stacking order of the thin film layers is A/B/
A, Fig. 2 shows A/B, and Fig. 3 shows B/A. It goes without saying that the present invention is not limited to the following explanation.
本発明における成型体１とは、合成樹脂、紙、
木材、ガラス等のフイルム状、シート状、板状、
ブロツク状の他各種形状の成型体があげられる。 The molded body 1 in the present invention is made of synthetic resin, paper,
Film, sheet, plate, etc. of wood, glass, etc.
Examples include molded bodies of various shapes other than block shapes.
該成型体１は着色されていてもよいし、透明体
であつてもよい。着色されている場合には、その
上に積層される虹彩模様を付与する層が透明なた
めに該成型体基材の生地の外観と融合した美麗な
虹彩模様を呈する積層体となる。また、透明体で
ある場合には、その上に積層される虹彩模様を付
与する層が透明なために全体として透明で美しい
虹彩模様を呈する積層体となる。 The molded body 1 may be colored or transparent. When colored, the iris pattern imparting layer laminated thereon is transparent, resulting in a laminate that exhibits a beautiful iris pattern that blends with the appearance of the fabric of the molded body base material. In addition, in the case of a transparent body, since the layer that provides the iris pattern that is laminated thereon is transparent, the laminate as a whole exhibits a transparent and beautiful iris pattern.
該成型体１としては表面への虹彩模様付与のし
やすさ、および生産性の点で可塑性のあるシート
状物が好ましい。中でも合成樹脂フイルム、例え
ばポリエチレンテレフタレート、ポリブチレンテ
レフタレートで代表されるポリエステル系、ポリ
エチレン、ポリプロピレンで代表されるポリオレ
フイン系、ナイロン６、ナイロ66、ナイロン12で
代表されるポリアミド系、ポリニトロセルロー
ス、ポリ酢酸セルロースで代表されるセルロース
系、ポリビニルアルコール、３フツ化ポリエチレ
ン、ポリカーボネート、ポリメチルメタクリレー
ト、ポリイミド、塩化ビニル、塩化ビニリデン等
の有機樹脂からなるフイルムで例示されるものが
具体例としてあげられ、これは単層でも２枚以上
の貼り合されたものであつてもよい。さらに表面
にマツト加工、ヘアーライン加工、スピン加工等
をあらかじめ施しておいたものでも可能である。 As the molded body 1, a plastic sheet-like body is preferable from the viewpoint of ease of imparting an iris pattern to the surface and productivity. Among them, synthetic resin films, such as polyester films such as polyethylene terephthalate and polybutylene terephthalate, polyolefin films such as polyethylene and polypropylene, polyamide films such as nylon 6, nylon 66, and nylon 12, polynitrocellulose, and polyacetic acid. Specific examples include films made of organic resins such as cellulose typified by cellulose, polyvinyl alcohol, trifluorinated polyethylene, polycarbonate, polymethyl methacrylate, polyimide, vinyl chloride, and vinylidene chloride. It may be a single layer or two or more layers bonded together. Furthermore, it is also possible to use a material whose surface has been subjected to matte processing, hairline processing, spin processing, etc. in advance.
本発明における透明な下引き層２とは成型体１
上に下記(エ)、(オ)によつて例示されるものであり、
通常0.005〜5.0μの膜厚が好ましい。 The transparent undercoat layer 2 in the present invention refers to the molded body 1
These are exemplified by (d) and (e) below,
Usually, a film thickness of 0.005 to 5.0μ is preferred.
該下引き層２は密着性、耐摩耗性、帯電防止
性、耐水性、耐薬品性等の向上のためにもうけら
れる。 The undercoat layer 2 is provided to improve adhesion, abrasion resistance, antistatic properties, water resistance, chemical resistance, and the like.
(エ) グラビアコート法やリバースロールコート法
等の各種既知の方法でポリエステル樹脂、アク
リル樹脂、ウレタン樹脂、メラミン樹脂、エポ
キシ樹脂などを単独または混合し必要に応じて
硬化剤を添加して得られた薄膜。(iv) Polyester resins, acrylic resins, urethane resins, melamine resins, epoxy resins, etc. may be used alone or in combination, and a curing agent may be added if necessary, using various known methods such as gravure coating and reverse roll coating. thin film.
(オ) 抵抗加熱法もしくは高周波加熱蒸着法、スパ
ツタリング法、イオンプレーテイング法等いわ
ゆる真空蒸着法および化学蒸着法、湿式メツキ
法等の既知の方法で、Al、Ni、Cu、Fe等の金
属の格付け法等により透明化したもの、または
Al2O3、SiO等の金属化合物単独、または混合
してコーテイングして得られた薄膜。(e) Metals such as Al, Ni, Cu, Fe, etc. can be coated using known methods such as resistance heating method, high frequency heating evaporation method, sputtering method, ion plating method, etc., so-called vacuum evaporation method, chemical vapor deposition method, and wet plating method. Those made transparent by grading laws, etc., or
A thin film obtained by coating a metal compound such as Al 2 O 3 or SiO alone or in combination.
本発明における虹彩薄膜層３は透明な薄膜層Ａ
と凹凸のある透明な薄膜層Ｂで構成されている。
透明な薄膜層Ａとは下記(カ)〜（ケ）によつて例示
されるものであり、薄膜層Ｂの屈折率と0.05以上
の差があり、かつ可視光線透過率が50％以上であ
る未着色または着色透明な薄膜層Ａであり、その
表面や内部において微粒子等により光散乱があつ
てもよい。 The iris thin film layer 3 in the present invention is a transparent thin film layer A.
It is composed of a transparent thin film layer B with irregularities.
Transparent thin film layer A is exemplified by (f) to (k) below, and has a refractive index different from that of thin film layer B by 0.05 or more, and has a visible light transmittance of 50% or more. The thin film layer A is uncolored or colored and transparent, and there may be light scattering on the surface or inside thereof due to fine particles or the like.
(カ) 酸化チタン、酸化ケイ素、酸化亜鉛、酸化ア
ンチモン、硫化亜鉛、フツ化マグネシウム、フ
ツ化カリウム、氷晶石等で例示される金属化合
物薄膜層。(f) A metal compound thin film layer exemplified by titanium oxide, silicon oxide, zinc oxide, antimony oxide, zinc sulfide, magnesium fluoride, potassium fluoride, cryolite, etc.
(キ) 塩化ビニリデンと塩化ビニル、酢酸ビニル、
ビニルアルコール等との共重合体あるいはポリ
塩化ビニル、ポリ塩化ビニリデン、ポリスチレ
ンのいずれかと塩化ビニル、スチレンとの共重
合体等の熱可塑性樹脂に光、熱等各種方法で分
解されて生じたガスによる微細な気泡を有する
薄膜層。(g) Vinylidene chloride, vinyl chloride, vinyl acetate,
Gas generated by decomposition of thermoplastic resins such as copolymers with vinyl alcohol, etc., or copolymers of polyvinyl chloride, polyvinylidene chloride, or polystyrene with vinyl chloride or styrene using various methods such as light or heat. A thin film layer with fine air bubbles.
(ク) ポリスチレン、ポリカーボネート、メラミン
樹脂、フエノール樹脂、アクリル系を含むビニ
ル系共重合体、繊維素系共重合体、ウレタン系
共重合体とこれを硬化する各種の硬化剤、硬化
性官能基を有する組成物、さらに有機置換され
たケイ素系化合物よりなる薄膜層および上記有
機材料と酸化チタン、酸化アルミニウム、酸化
ジルコニウム等の無機系微粒子よりなる薄膜
層。(H) Polystyrene, polycarbonate, melamine resin, phenolic resin, vinyl copolymers including acrylics, cellulose copolymers, urethane copolymers, various curing agents for curing them, and curable functional groups. a thin film layer made of an organically substituted silicon compound, and a thin film layer made of the organic material and inorganic fine particles such as titanium oxide, aluminum oxide, and zirconium oxide.
（ケ） チタンテトラエトキシド、チタンテトラ
ーｎ−プロポキシド、アルミニウムトリエトキ
シド、ジルコニウムテトラ−ｎ−ブトキシドな
どの金属アルコレート化合物、ジ−イソプロポ
キシチタニウムビスアセチルアセトネート、ト
リ−ｎ−ブトキシドジルコニウムモノエチルア
セトアセテート等のキレート化合物、さらに炭
酸ジルコニールアンモニウム、あるいはジルコ
ニウムを主成分とする活性無機ポリマー等の液
状被膜形成性のある無機系材料、または上記無
機系材料とアルキルシリケート類もしくはその
加水分解物、さらにコロイド状シリカゾルの混
合物およびアクリル系を含むビニル系共重合
体、フツ素置換された各種ポリマー、芳香環を
含まないポリエステル系重合体、シリコーン系
ポリマー等の有機材料と上記無機材料との混合
物よりなる薄膜層。(ke) Metal alcoholate compounds such as titanium tetraethoxide, titanium tetra-n-propoxide, aluminum triethoxide, zirconium tetra-n-butoxide, di-isopropoxytitanium bisacetylacetonate, tri-n-butoxide zirconium monoethyl A chelate compound such as acetoacetate, an inorganic material capable of forming a liquid film such as zirconyl ammonium carbonate, or an active inorganic polymer containing zirconium as a main component, or the above inorganic material and an alkyl silicate or a hydrolyzate thereof, Furthermore, mixtures of colloidal silica sol, vinyl copolymers including acrylics, various fluorine-substituted polymers, polyester polymers containing no aromatic rings, silicone polymers, and other organic materials and mixtures of the above inorganic materials. A thin film layer.
該薄膜層Ａが、薄膜層Ｂと屈折率の差が0.05未
満の場合には虹彩模様が不鮮明となる。該薄膜層
Ａは単一物質からなるものである必要は必ずしも
なく、２種以上の物質の混合物でもよい。さらに
薄膜層Ｂの屈折率と0.05以上の差があれば異なる
物質の２層以上の積層であつてもよい。 If the difference in refractive index between the thin film layer A and the thin film layer B is less than 0.05, the iris pattern will be unclear. The thin film layer A does not necessarily have to be made of a single substance, but may be a mixture of two or more substances. Furthermore, it may be a stack of two or more layers of different materials as long as there is a difference in refractive index from the thin film layer B by 0.05 or more.
(カ)による金属化合物からなる透明な薄膜層Ａ
は、抵抗加熱法もしくは高周波加熱蒸着法、スパ
ツタリング法、イオンプレーテイング法等いわゆ
る真空蒸着法および化学蒸着法により、成型体１
の上に下引き層２を介して薄く蒸着させて積層す
る。 Transparent thin film layer A consisting of a metal compound according to (F)
The molded body 1 is formed by a resistance heating method, a high frequency heating evaporation method, a sputtering method, an ion plating method, or a so-called vacuum evaporation method or a chemical vapor deposition method.
A thin layer is deposited on top of the undercoat layer 2 with an undercoat layer 2 interposed therebetween.
(キ)〜（ケ）による透明な薄膜層Ａはグラビアコ
ート法やリバースロールコート法、ツーロールビ
ート法の各種既知の方法により、成型体１の上に
下引き層２を介して薄く塗布、乾燥して積層す
る。薄膜層Ａの厚みは50〜2000Åの範囲の均一な
厚みのものであることが特に好ましい。この厚み
が50Å未満あるいは2000Åを越えると最終的に美
麗な虹彩薄膜層を得るに至らない。 The transparent thin film layer A according to (g) to (k) is thinly applied onto the molded body 1 via the undercoat layer 2 by various known methods such as gravure coating, reverse roll coating, and two-roll beating. Dry and laminate. It is particularly preferable that the thin film layer A has a uniform thickness in the range of 50 to 2000 Å. If this thickness is less than 50 Å or more than 2000 Å, it will not be possible to obtain a beautiful iris thin film layer.
該薄膜層Ａとしては上記の各種材料からなるも
のに限定されるものではなく、薄膜層Ｂと屈折率
の差が0.05以上あれば、これらの限りではない。 The thin film layer A is not limited to those made of the various materials mentioned above, as long as the difference in refractive index from the thin film layer B is 0.05 or more.
凹凸のある透明な薄膜層Ｂとは、下記（コ）〜
（シ）によつて例示されるものであり、薄膜層
（Ａ）と屈折率の差が0.05以上の差があり、かつ
可視光線透過率が50％以上である未着色または着
色透明な薄膜層であり、その表面や内部において
微粒子等により光散乱があつてもよい。 Transparent thin film layer B with unevenness refers to the following (c) ~
(C) is an uncolored or colored transparent thin film layer that has a refractive index difference of 0.05 or more from the thin film layer (A) and a visible light transmittance of 50% or more. , and there may be light scattering due to fine particles on the surface or inside.
（コ） 塩化ビニリデンと塩化ビニル、酢酸ビニ
ル、ビニルアルコール等との共重合体あるいは
ポリ塩化ビニル、塩化ビニリデン、ポリスチレ
ンのいずれかと塩化ビニルスチレンとの共重合
体等の熱可塑性樹脂に光、熱等各種方法で分解
されて生じたガスによる微細な気泡を有する薄
膜層。(c) Light, heat, etc. are applied to thermoplastic resins such as copolymers of vinylidene chloride and vinyl chloride, vinyl acetate, vinyl alcohol, etc., or copolymers of polyvinyl chloride, vinylidene chloride, or polystyrene and vinylstyrene chloride. A thin film layer with fine bubbles created by gases generated by decomposition using various methods.
（サ） ポリスチレン、ポリカーボネート、メラ
ミン樹脂、フエノール樹脂、アクリル系を含む
ビニル系共重合体、繊維素系共重合体、ウレタ
ン系共重合体とこれを硬化する各種の硬化剤、
硬化性官能基を有する組成物、さらに有機置換
されたケイ素系化合物によりなる薄膜層、およ
び上記有機材料と酸化チタン、酸化アルミニウ
ム、酸化ジルコニウム等の無機系微粒子よりな
る薄膜層。(Sa) Polystyrene, polycarbonate, melamine resin, phenolic resin, vinyl copolymers including acrylics, cellulose copolymers, urethane copolymers and various curing agents for curing them,
A thin film layer comprising a composition having a curable functional group, an organically substituted silicon compound, and a thin film layer comprising the organic material and inorganic fine particles such as titanium oxide, aluminum oxide, zirconium oxide, etc.
（シ） チタンテトラエトキシド、チタンテトラ
ーｎ−プロポキシド、アルミニウムトリエトキ
シド、ジルコニウムテトラ−ｎ−ブトキシドな
どの金属アルコレート化合物、ジ−イソプロポ
キシチタニウムビスアセチルアセトネート、ト
リ−ｎ−ブトキシドジルコニウムモノエチルア
セトアセテートなどのキレート化合物、さらに
炭酸ジルコニールアンモニウム、あるいはジル
コニウムを主成分とする活性無機ポリマー等の
液状被膜形成性のある無機系材料、または上記
無機系材料とアルキルシリケート類、もしくは
その加水分解物、さらにコロイド状シリカゾル
の混合物、およびアクリル系を含むビニル系共
重合体、フツ素置換された各種ポリマー、芳香
環を含まないポリエステル系重合体、シリコー
ン系ポリマー等の有機材料と上記無機材料との
混合物よりなる薄膜層。(C) Metal alcoholate compounds such as titanium tetraethoxide, titanium tetra-n-propoxide, aluminum triethoxide, zirconium tetra-n-butoxide, di-isopropoxytitanium bisacetylacetonate, tri-n-butoxide zirconium monoethyl Chelate compounds such as acetoacetate, inorganic materials capable of forming liquid films such as zirconyl ammonium carbonate, or active inorganic polymers mainly composed of zirconium, or the above inorganic materials and alkyl silicates, or hydrolysates thereof. Furthermore, a mixture of colloidal silica sol, and organic materials such as vinyl copolymers including acrylic copolymers, various fluorine-substituted polymers, polyester polymers containing no aromatic rings, and silicone polymers, and the above inorganic materials. A thin film layer consisting of a mixture.
該凹凸のある透明な薄膜層Ｂが、薄膜層Ａと屈
折率の差が0.05未満の場合には虹彩模様が不鮮明
となる。該凹凸のある透明な薄膜層Ｂは単一物質
からなるものである必要は必ずしもなく、２種以
上の物質の混合物でもよい。 If the difference in refractive index between the uneven transparent thin film layer B and the thin film layer A is less than 0.05, the iris pattern will be unclear. The transparent thin film layer B having irregularities does not necessarily need to be made of a single substance, and may be a mixture of two or more substances.
さらに薄膜層Ａの屈折率と0.05以上の差があれ
ば異なる物質の２層以上の積層であつてもよい。 Furthermore, as long as there is a difference in refractive index from the thin film layer A by 0.05 or more, it may be a stack of two or more layers of different materials.
該凹凸のある透明な薄膜層Ｂは均一な厚みの塗
膜でなく、表面が凹凸不均一な厚みのものである
必要があり、その厚みの範囲は100〜10000Åの範
囲が特に好ましい。また、凹凸の程度は美麗な虹
彩模様を得るために凹部と凸部の厚みの差が200
〜2000Å程度あることが好ましい。この範囲を逸
脱すると虹彩模様が発現せず全体が無彩色の色調
を呈するようになる。なお、凹凸の周期（一定と
は限らない。）は、虹彩模様の密度に対応するの
で、通常は0.5〜10cm程度が好ましいが、必ずし
もこの範囲に限定されるものではない。該凹凸の
ある透明な薄膜層Ｂはロールコーテイング、グラ
ビアコーテイング等の一般的樹脂コーテイング法
および印刷法およびスプレー法等により塗布でき
る。 The uneven transparent thin film layer B is not a coating film with a uniform thickness, but must have an uneven surface with uneven thickness, and the thickness is particularly preferably in the range of 100 to 10,000 Å. In addition, in order to obtain a beautiful iris pattern, the difference in thickness between the concave and convex portions is 200 mm.
The thickness is preferably about 2000 Å. If it deviates from this range, no iris pattern will appear and the entire color will appear achromatic. Note that the period of the unevenness (not necessarily constant) corresponds to the density of the iris pattern, so it is usually preferably about 0.5 to 10 cm, but it is not necessarily limited to this range. The uneven transparent thin film layer B can be applied by a general resin coating method such as roll coating or gravure coating, a printing method, a spray method, or the like.
該薄膜層Ｂとしては上記の各種材料からなるも
のに限定されるものではなく、薄膜層Ａと屈折率
の差が0.05以上あれば、これらの限りではない。 The thin film layer B is not limited to those made of the various materials mentioned above, as long as the difference in refractive index from the thin film layer A is 0.05 or more.
該透明な薄膜層Ａと該凹凸のある透明な薄膜層
Ｂは積層したときに、その屈折率の差と層Ｂの表
面の凹凸により虹彩模様を呈する積層体に使用で
きる虹彩薄膜層となる。 When laminated, the transparent thin film layer A and the uneven transparent thin film layer B become an iris thin film layer that can be used in a laminate exhibiting an iris pattern due to the difference in refractive index and the unevenness of the surface of layer B.
該虹彩薄膜層３がＡ／Ｂ／Ａ、Ａ／Ｂ、Ｂ／Ａ
の積層構成の時、美麗な虹彩模様が得られる。ま
た、Ｂ／Ａ／Ｂの時も美麗な虹彩模様が得られる
が、第２層目のＢを設けることによる生産コスト
上昇の割に虹彩効果の向上がすくない。なお、使
用の目的に応じて、虹彩薄膜層３の上に保護層を
設けて耐水性等の向上をはかることができる。ま
た、該虹彩模様を呈する積層体を他の成型体と積
層するために接着層を設けることもできる。Ａ／
Ｂ／Ａ、Ｂ／Ａ構成の虹彩薄膜層３上に接着層ま
たは保護層等を設ける時これらの屈折率の大小に
にかかわらず美麗な虹彩はなくならない。しかし
Ａ／Ｂ構成の虹彩薄膜層３はＢの屈折率との差が
0.05以上の接着層、保護層等を設けた時のみ美麗
な虹彩はなくならない。 The iris thin film layer 3 is A/B/A, A/B, B/A.
When using this laminated structure, a beautiful iris pattern can be obtained. Also, a beautiful iris pattern can be obtained in the case of B/A/B, but the improvement in the iris effect is not so great considering the increase in production cost due to the provision of the second layer of B. Note that, depending on the purpose of use, a protective layer may be provided on the iris thin film layer 3 to improve water resistance and the like. Further, an adhesive layer may be provided in order to laminate the iris-patterned laminate with another molded product. A/
When an adhesive layer or a protective layer is provided on the iris thin film layer 3 having a B/A or B/A configuration, a beautiful iris will not be lost regardless of the refractive index of these layers. However, the iris thin film layer 3 with the A/B configuration has a difference in refractive index from B.
Beautiful iris will not disappear only if an adhesive layer of 0.05 or higher and a protective layer are provided.
次に本発明を実施例により詳しく説明する。 Next, the present invention will be explained in detail with reference to examples.
実施例 １
可視光線透過率93％の透明なポリメチルメタア
クリレートキヤスト板（屈折率1.50）の両面に片
面づつ交互にベルジヤー型真空蒸着機を使用し、
５×10-2パスカルの真空度中で硫化亜鉛（屈折率
2.35）の蒸着膜をそれぞれ450Åづつ得た。Example 1 A Bergier type vacuum evaporation machine was used to alternately deposit one side on both sides of a transparent polymethyl methacrylate cast plate (refractive index 1.50) with a visible light transmittance of 93%.
Zinc sulfide (refractive index
2.35) were obtained, each having a thickness of 450 Å.
次に上記積層アクリルキヤスト板の片面にニト
ロセルロース（屈折率1.51）の10％濃度のトルエ
ン溶液をロールコーターにより横パターン状に塗
布、95℃の熱風乾燥機中で10分間乾燥した。さら
に、もう一方の片面に同様に上記片面とは横パタ
ーンが直交するようにニトロセルロースを塗布乾
燥した。得られたアクリルキヤスト板は格子状の
虹彩模様の鮮かな透明な化粧板となつた。 Next, a 10% toluene solution of nitrocellulose (refractive index 1.51) was applied in a horizontal pattern on one side of the laminated acrylic cast board using a roll coater, and dried for 10 minutes in a hot air dryer at 95°C. Furthermore, nitrocellulose was similarly applied to the other side and dried so that the horizontal pattern was perpendicular to that of the above-mentioned one side. The obtained acrylic cast board became a bright transparent decorative board with a grid-like iris pattern.
実施例 ２
25μの厚みの可視光線透過率87％の二軸延伸ポ
リエチレンフタレートフイルム（屈折率1.65）の
片面にポリエステル樹脂（屈折率1.65）の10％濃
度のメチルエチルケトン溶液を＃３のバーコータ
ーで塗布し120℃で乾燥して厚さ約0.5μの下引き
層を形成した。Example 2 A 10% concentration methyl ethyl ketone solution of polyester resin (refractive index 1.65) was coated on one side of a 25μ thick biaxially stretched polyethylene phthalate film (refractive index 1.65) with a visible light transmittance of 87% using a #3 bar coater. It was dried at 120°C to form a subbing layer with a thickness of about 0.5μ.
そのうえベルジヤー型蒸着機を使用し５×10-2
パスカルの真空度中で硫化亜鉛（屈折率2.35）を
真空蒸着した。付着した硫化亜鉛層の厚みは400
Åで、得られた蒸着フイルムの可視光線透過率は
76％であつた。この硫化亜鉛を積層したポリエチ
レンテレフタレートフイルムの硫化亜鉛薄膜層の
上にニトロセルロース（屈折率1.51）の10％濃度
のメチルエチルケトン溶液を＃８のバーコーター
を約３cm周期で間欠的に動かすことにより、横パ
ターン状に不均一に塗布し、150℃の熱風循環式
オーブン中で30秒間乾燥した。 Furthermore, using a Bergier type vapor deposition machine, 5×10 -2
Zinc sulfide (refractive index 2.35) was vacuum deposited in a Pascal vacuum. The thickness of the deposited zinc sulfide layer is 400
In Å, the visible light transmittance of the vapor-deposited film is
It was 76%. A 10% methyl ethyl ketone solution of nitrocellulose (refractive index 1.51) was applied horizontally to the zinc sulfide thin film layer of the polyethylene terephthalate film laminated with zinc sulfide by intermittently moving a #8 bar coater at approximately 3 cm intervals. It was applied unevenly in a pattern and dried for 30 seconds in a hot air circulation oven at 150°C.
得られた積層ポリエチレンテレフタレートフイ
ルムは青味がかかつた横パターンの美しい透明な
虹彩模様を呈していた。しかし、このフイルムの
ニトロセルロース塗工面上に透明な粘着テープを
貼り付けると虹彩模様は消滅した。この虹彩模様
はこの粘着テープをはがすことにより元の状態の
虹彩模様になつた。さらに上記虹彩模様のフイル
ムの片面積層側のニトロセルロース塗膜の上から
ベルジヤー型蒸着機中５×10-2パスカルの真空度
中で、上記と同様に硫化亜鉛を400Åの厚みにな
るように真空蒸着した。得られた積層ポリエチレ
ンテレフタレートフイルムの横パターンの虹彩模
様は一段と濃色で美麗となつた。このフイルムの
蒸着面側に透明な粘着テープを貼り付けた場合に
も、この美麗な虹彩模様は消滅することはなかつ
た。 The obtained laminated polyethylene terephthalate film had a beautiful transparent iris pattern with a bluish horizontal pattern. However, when transparent adhesive tape was pasted on the nitrocellulose-coated side of this film, the iris pattern disappeared. This iris pattern returned to its original state by peeling off this adhesive tape. Furthermore, zinc sulfide was applied to the nitrocellulose coating on one side of the iris-patterned film to a thickness of 400 Å in the same manner as above in a Bergier type evaporator in a vacuum of 5 × 10 -2 Pascals. Deposited. The iris pattern of the horizontal pattern of the obtained laminated polyethylene terephthalate film became even darker and more beautiful. Even when a transparent adhesive tape was attached to the vapor-deposited side of this film, this beautiful iris pattern did not disappear.
実施例 ３
厚さ18μ、幅1mの二軸延伸ポリエチレンテレフ
タレートフイルムの片面にポリエステル樹脂（屈
折率1.65）の10％濃度のメチルエチルケトン溶液
をグラビアコート法で塗布し、120℃で乾燥して
厚さ約0.5μの下引き層を形成した。この下引き層
上に下記塗料Ａ（屈折率1.70）をグラビアコート
法で塗布し、150℃で乾燥400Åの薄膜を得た。Example 3 A 10% methyl ethyl ketone solution of polyester resin (refractive index 1.65) was coated on one side of a biaxially stretched polyethylene terephthalate film with a thickness of 18μ and a width of 1m using a gravure coating method, and dried at 120°C to a thickness of approx. A 0.5 μm subbing layer was formed. On this undercoat layer, the following paint A (refractive index: 1.70) was applied by gravure coating to obtain a thin film of 400 Å after drying at 150°C.
塗料Ａ：アセチルアセトン162ｇに攪拌下でテ
トラ−ｎ−ブチルチタネート32.2ｇ、メタノール
分散コロイド状シリカ10ｇ、シリコーン系界面活
性剤0.11ｇを添加し混合した。 Paint A: To 162 g of acetylacetone, 32.2 g of tetra-n-butyl titanate, 10 g of methanol-dispersed colloidal silica, and 0.11 g of silicone surfactant were added and mixed with stirring.
この塗料層の上にニトロセルロース（屈折率
1.51）95ｇ、エポキシ樹脂（屈折率1.55）5.5ｇの
メチルエチルケトン10％溶液をグラビアコート法
で塗布し150℃で乾燥し、200〜2000Åの凹凸膜を
得た。得られた積層ポリエチレンテレフタレート
フイルムは青から赤までの各色の色彩がある美し
い透明な虹彩模様を呈していた。 On top of this paint layer, nitrocellulose (refractive index
1.51) A 10% solution of methyl ethyl ketone containing 95 g and 5.5 g of an epoxy resin (refractive index 1.55) was coated using a gravure coating method and dried at 150°C to obtain an uneven film of 200 to 2000 Å. The obtained laminated polyethylene terephthalate film exhibited a beautiful transparent iris pattern with various colors ranging from blue to red.
上記虹彩模様のフイルムの片面積層側のニトロ
セルロースエポキシ塗膜の上から再度塗料Ａをグ
ラビアコート法で塗布し、400Åの薄膜を得ると、
さらに高輝度の透明で美麗な虹彩模様を呈する積
層体となつた。 Paint A is again applied using the gravure coating method over the nitrocellulose epoxy coating on one side of the iris-patterned film to obtain a 400 Å thin film.
Furthermore, the resulting laminate exhibits a high-luminance, transparent, and beautiful iris pattern.
実施例 ４
厚さ18μ、幅1mの二軸延伸ポリエチレンテレフ
タレートフイルムの片面に実施例２に準拠して下
引き層（屈折率1.65）0.5μを形成した。この下引
き層の上に、下記塗料Ｂをスプレー塗布、乾燥し
約0.6μ厚さの薄膜を得た。この薄膜に200Wの石
英水銀灯を室温下で25秒露光し露光後約80℃、30
秒加熱し薄膜（屈折率1.4）を得た。Example 4 A 0.5 μm undercoat layer (refractive index: 1.65) was formed on one side of a biaxially stretched polyethylene terephthalate film having a thickness of 18 μm and a width of 1 m according to Example 2. On top of this undercoat layer, the following paint B was applied by spraying and dried to obtain a thin film with a thickness of about 0.6 μm. This thin film was exposed to a 200W quartz mercury lamp for 25 seconds at room temperature.
A thin film (refractive index 1.4) was obtained by heating for seconds.
塗料Ｂ：４−アジド無水フタル酸12ｇを10％濃
度クエン酸水溶液120ｇに溶解させ、さらに50％
濃度ポリビニルアルコール水溶液144ｇと50％濃
度塩化ビニリデン溶液72ｇ、エチレングリコール
72ｇを混合する。 Paint B: Dissolve 12g of 4-azidophthalic anhydride in 120g of 10% citric acid aqueous solution, and then dissolve 50%
144 g of concentrated polyvinyl alcohol aqueous solution, 72 g of 50% concentrated vinylidene chloride solution, ethylene glycol
Mix 72g.
この塗料層の上に、10％濃度の水溶性ポリエス
テル樹脂（屈折率1.65）を＃８のバーコーターで
約３cm周期に間欠的に動かすことにより、横パタ
ーン状でかつ微小気泡による幻想的な虹彩模様を
呈する積層体となつた。 By intermittently moving 10% water-soluble polyester resin (refractive index 1.65) on this paint layer with a #8 bar coater at approximately 3 cm intervals, a fantastic iris with horizontal patterns and microbubbles is created. The result was a laminate with a pattern.
〔発明の効果〕
本発明の虹彩模様を呈する積層体は、成型体の
上に下引き層を介し虹彩薄膜層を設けてなる積層
体において、該虹彩薄膜層が、可視光線透過率が
50％以上である透明な薄膜層Ａと可視光線透過率
が50％以上である凹凸のある透明な薄膜層Ｂとか
ら成り、かつ該透明な薄膜層ＡとＢとの屈折率の
差が0.05以上であることを特徴とする虹彩模様を
呈する積層体であるために、（ス）透明な薄膜層
Ａと凹凸のある透明な薄膜層Ｂの織りなす多彩で
且つ透明であり、美麗な虹彩模様を呈する積層体
を提供する。本発明による虹彩模様を呈する積層
体は、その美しい外観特性を生かして糸、包装材
料、壁紙、ポスター、ラベル、女性の衣料やベル
トおよび釣竿、ボタン、イヤリング、ペンダント
等に使われる。[Effects of the Invention] The laminate exhibiting an iris pattern of the present invention is a laminate in which an iris thin film layer is provided on a molded body via an undercoat layer, and the iris thin film layer has a visible light transmittance.
It consists of a transparent thin film layer A having a visible light transmittance of 50% or more and a transparent thin film layer B having irregularities having a visible light transmittance of 50% or more, and the difference in refractive index between the transparent thin film layers A and B is 0.05. Since this is a laminate exhibiting an iris pattern characterized by the above, (S) the transparent thin film layer A and the uneven transparent thin film layer B are woven together to produce a colorful, transparent, and beautiful iris pattern. The present invention provides a laminate that exhibits the following properties. The laminate exhibiting an iris pattern according to the present invention can be used for threads, packaging materials, wallpapers, posters, labels, women's clothing, belts, fishing rods, buttons, earrings, pendants, etc. by taking advantage of its beautiful appearance characteristics.
（セ） 該凹凸のある透明な薄膜層Ｂの厚みを調
整することにより、任意の図柄の虹彩模様を有
する虹彩模様を呈する積層体を大量生産でき
る。(C) By adjusting the thickness of the uneven transparent thin film layer B, a laminate exhibiting an iris pattern having an arbitrary design can be mass-produced.
（ソ） 該成型体、該下引き層、該薄膜層Ａ該凹
凸のある透明な薄膜層Ｂに染料、顔料を混入す
ることにより着色と虹彩の織りなす多彩で美麗
な虹彩模様を呈する積層体を提供する。(X) By mixing dyes and pigments into the molded body, the undercoat layer, the thin film layer A and the uneven transparent thin film layer B, a laminate exhibiting a colorful and beautiful iris pattern created by coloring and iris is produced. provide.
（タ） 該成型物に透明体を採用することによ
り、透明な虹彩模様を呈する積層体を提供す
る。(t) By employing a transparent body in the molded product, a laminate exhibiting a transparent iris pattern is provided.
第１，２，３図は本発明に係る虹彩模様を呈す
る積層体の実施例を示す拡大断面図である。薄膜
の積層順序は、第１図がＡ／Ｂ／Ａを、第２図が
Ａ／Ｂを、第３図がＢ／Ａのものをそれぞれ表し
ている。
１……シート状の成型体、２……下引き層、３
……虹彩薄膜層、Ａ……透明な薄膜層、Ｂ……凹
凸のある透明な薄膜層。
1, 2, and 3 are enlarged cross-sectional views showing an embodiment of a laminate exhibiting an iris pattern according to the present invention. Regarding the stacking order of the thin films, FIG. 1 shows A/B/A, FIG. 2 shows A/B, and FIG. 3 shows B/A. 1...Sheet-like molded body, 2...Undercoat layer, 3
...Iris thin film layer, A...Transparent thin film layer, B...Transparent thin film layer with unevenness.
Claims (1)
層を設けてなる積層体において、 該虹彩薄膜層が、可視光線透過率が50％以上で
ある透明な薄膜層Ａと可視光線透過率が50％以上
である凹凸のある透明な薄膜層Ｂとから成り、か
つ該透明な薄膜層ＡとＢとの屈折率の差が0.05以
上であることを特徴とする虹彩模様を呈する積層
体。 ２ 透明な薄膜層Ａの厚みが50〜2000Å、凹凸の
ある透明な薄膜層Ｂの厚みが100〜10000Åの特許
請求の範囲第１項記載の虹彩模様を呈する積層
体。 ３ 透明な薄膜層Ａが１種または２種以上の異な
る金属化合物からなる特許請求の範囲第１項記載
の虹彩模様を呈する積層体。 ４ 透明な薄膜層Ａが内部に微細な気泡を有する
高分子材料からなる特許請求の範囲第１項記載の
虹彩模様を呈する積層体。 ５ 透明な薄膜層Ａが有機高分子材料または無機
系微粒子を含有する有機高分子材料からなる特許
請求の範囲第１項記載の虹彩模様を呈する積層
体。 ６ 透明な薄膜層Ａが液状被膜形成性のある無機
系材料または該無機系材料と有機系材料の混合物
からなる特許請求の範囲第１項記載の虹彩模様を
呈する積層体。 ７ 透明な薄膜層Ａまたは凹凸のある透明な薄膜
層Ｂが異なる物質の２層以上積層からなる特許請
求の範囲第１項記載の虹彩模様を呈する積層体。 ８ 凹凸のある透明な薄膜層Ｂが内部に微細な気
泡を有する高分子材料からなる特許請求の範囲第
１項記載の虹彩模様を呈する積層体。 ９ 凹凸のある透明な薄膜層Ｂが有機高分子材料
または無機系微粒子を含有する有機高分子材料か
らなる特許請求の範囲第１項記載の虹彩模様を呈
する積層体。 １０ 凹凸のある透明な薄膜層Ｂが液状被膜形成
性のある無機系材料または該無機系材料と有機係
材料の混合物からなる特許請求の範囲第１項記載
の虹彩模様を呈する積層体。 １１ 透明な薄膜層Ａと凹凸のある透明薄膜層Ｂ
が、Ａ／Ｂ／Ａ、Ａ／Ｂ、Ｂ／Ａの順に積層して
なる特許請求の範囲第１項記載の虹彩模様を呈す
る積層体。 １２ 成型体が合成樹脂フイルムである特許請求
の範囲第１項記載の虹彩模様を呈する積層体。[Scope of Claims] 1. A laminate in which an iris thin film layer is provided on a molded body via a transparent undercoat layer, wherein the iris thin film layer is a transparent thin film layer having a visible light transmittance of 50% or more. An iris comprising A and a transparent thin film layer B with irregularities having a visible light transmittance of 50% or more, and wherein the difference in refractive index between the transparent thin film layers A and B is 0.05 or more. A laminate that exhibits a pattern. 2. A laminate exhibiting an iris pattern according to claim 1, wherein the transparent thin film layer A has a thickness of 50 to 2000 Å, and the uneven transparent thin film layer B has a thickness of 100 to 10000 Å. 3. A laminate exhibiting an iris pattern according to claim 1, wherein the transparent thin film layer A is made of one or more different metal compounds. 4. A laminate exhibiting an iris pattern according to claim 1, wherein the transparent thin film layer A is made of a polymeric material having fine bubbles inside. 5. A laminate exhibiting an iris pattern according to claim 1, wherein the transparent thin film layer A is made of an organic polymer material or an organic polymer material containing inorganic fine particles. 6. A laminate exhibiting an iris pattern according to claim 1, wherein the transparent thin film layer A is made of an inorganic material capable of forming a liquid film or a mixture of the inorganic material and an organic material. 7. A laminate exhibiting an iris pattern according to claim 1, wherein the transparent thin film layer A or the uneven transparent thin film layer B is a laminate of two or more layers of different materials. 8. A laminate exhibiting an iris pattern according to claim 1, wherein the uneven transparent thin film layer B is made of a polymeric material having fine bubbles inside. 9. A laminate exhibiting an iris pattern according to claim 1, wherein the uneven transparent thin film layer B is made of an organic polymer material or an organic polymer material containing inorganic fine particles. 10. A laminate exhibiting an iris pattern according to claim 1, wherein the uneven transparent thin film layer B is made of an inorganic material capable of forming a liquid film or a mixture of the inorganic material and an organic material. 11 Transparent thin film layer A and uneven transparent thin film layer B
A laminate exhibiting an iris pattern according to claim 1, which is formed by laminating A/B/A, A/B, and B/A in the order of A/B/A, A/B, and B/A. 12. A laminate exhibiting an iris pattern according to claim 1, wherein the molded product is a synthetic resin film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6643685A JPS61227098A (en) | 1985-04-01 | 1985-04-01 | Laminate displaying iris pattern |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP6643685A JPS61227098A (en) | 1985-04-01 | 1985-04-01 | Laminate displaying iris pattern |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61227098A JPS61227098A (en) | 1986-10-09 |
| JPH0339838B2 true JPH0339838B2 (en) | 1991-06-17 |
Family
ID=13315725
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6643685A Granted JPS61227098A (en) | 1985-04-01 | 1985-04-01 | Laminate displaying iris pattern |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61227098A (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4026696B2 (en) * | 1998-02-27 | 2007-12-26 | パイロットインキ株式会社 | Magnetic display device |
| US8586158B2 (en) | 2003-05-14 | 2013-11-19 | Toyo Seikan Kaisha, Ltd. | Decorated plastic package |
| JP4539129B2 (en) * | 2003-05-14 | 2010-09-08 | 東洋製罐株式会社 | Plastic package and its decoration method |
| JP5615567B2 (en) * | 2010-02-25 | 2014-10-29 | 三光合成株式会社 | Thin decoration |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5133589A (en) * | 1974-09-17 | 1976-03-22 | Torio Kk | EKISHOHYOJISOCHI |
| JPS521413A (en) * | 1975-06-24 | 1977-01-07 | Suzuki Motor Co Ltd | Variable reluctance motor |
-
1985
- 1985-04-01 JP JP6643685A patent/JPS61227098A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5133589A (en) * | 1974-09-17 | 1976-03-22 | Torio Kk | EKISHOHYOJISOCHI |
| JPS521413A (en) * | 1975-06-24 | 1977-01-07 | Suzuki Motor Co Ltd | Variable reluctance motor |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61227098A (en) | 1986-10-09 |
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