JPH0338281A - Preparation of precoated metal plate - Google Patents

Preparation of precoated metal plate

Info

Publication number
JPH0338281A
JPH0338281A JP17113089A JP17113089A JPH0338281A JP H0338281 A JPH0338281 A JP H0338281A JP 17113089 A JP17113089 A JP 17113089A JP 17113089 A JP17113089 A JP 17113089A JP H0338281 A JPH0338281 A JP H0338281A
Authority
JP
Japan
Prior art keywords
slurry
metal plate
roll
paint
powder
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP17113089A
Other languages
Japanese (ja)
Inventor
Kenjiro Kaneko
金子 堅次郎
Satoshi Oonuma
大沼 理志
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Metal Products Co Ltd
Original Assignee
Nippon Steel Metal Products Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Metal Products Co Ltd filed Critical Nippon Steel Metal Products Co Ltd
Priority to JP17113089A priority Critical patent/JPH0338281A/en
Publication of JPH0338281A publication Critical patent/JPH0338281A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To enhance paint fixing efficiency by supplying a powder paint slurry to a pickup roll and applying the same to a metal plate through an applicator roll to apply heat treatment to the coated metal plate. CONSTITUTION:About 20-60 pts. of powder paint of an epoxy type, an acrylic type or a polyethylene type and about 80-40 pts. of a dispersing medium are mixed to prepare a slurry 8. This slurry 8 is allowed to flow down on a paint supply inclined plate 9 inclined downwardly and a pickup roll 1 is allowed to approach the paint supply inclined plate 9 from above and brought into contact with the slurry 8 flowing down to pick up the slurry 8. The film on the pickup roll 1 is controlled in its thickness by a thickness controller 10 and the slurry is applied to a metal plate 5 through an applicator roll 4. Subsequently, the coated metal plate is heat-treated to cure the film on the metal plate. By this method, the coated metal plate can be prepared on a high speed line.

Description

【発明の詳細な説明】 産業上の利用分野 本発明は粉体塗料をロール塗装してプレコート金属板を
製造する方法に関する。
DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to a method for manufacturing precoated metal sheets by roll coating a powder coating.

従来の技術 近年環境問題や省資源の点から溶剤を含まない塗料によ
る塗装が種々の形で実用化されて来ている。この一つが
いわゆる粉体塗装であり、塗装方式としては静電粉体吹
付法が最も代表的に用いられて来た。
BACKGROUND OF THE INVENTION In recent years, various forms of painting using paints that do not contain solvents have been put into practical use from the viewpoint of environmental issues and resource conservation. One of these is so-called powder coating, and electrostatic powder spraying has been most commonly used as the coating method.

静電粉体吹付法は粉体塗料に空気を混ぜて流動化させ、
これを圧縮空気でガンの先端から噴出させ、この時ガン
の先端部に設けた電極によって噴出粉体を高電圧に荷電
させることにより、アースされた被覆物に均一な塗着を
効率よく行なわせるというものである。
Electrostatic powder spraying mixes air with powder paint to make it fluid.
This powder is ejected from the tip of the gun using compressed air, and at this time, the ejected powder is charged to a high voltage by an electrode installed at the tip of the gun, allowing for efficient and uniform application of the powder to the grounded coating. That is what it is.

この方式の最大の利点は対象物の形を問わずに利用でき
ることであり、又普及が進んでいることによる利用のし
易さも挙げられる。しかし次の様に限界も多い。
The biggest advantage of this method is that it can be used regardless of the shape of the object, and it is also easy to use due to its increasing popularity. However, there are many limitations as follows.

先ず圧縮空気の力で粉体を吹付けるため、被塗物に届い
た粉体が未だ速度を有しており、静電吸引力の方向と異
なる速度成分は粉体の塗着効率を減する。
First, the powder is sprayed using the force of compressed air, so the powder that reaches the object still has some velocity, and a velocity component that differs from the direction of the electrostatic attraction force reduces the powder coating efficiency. .

又圧縮空気流が被塗物に折角塗着した粉体を再び吹飛ば
すことによる塗着効率の低下もある。この結果静電粉体
吹付法による一次塗着効率は高々80%に留まり、又膜
厚もつけ難い。
In addition, the compressed air flow blows off the powder that has been applied to the object again, resulting in a decrease in the application efficiency. As a result, the primary coating efficiency by electrostatic powder spraying is only 80% at most, and it is difficult to increase the film thickness.

更には大容量の塗装が必要な時に吹付は量を増大させる
のに、静電ガンの数を増して対処しなければならない。
Furthermore, when a large amount of coating is required, the amount of spraying increases, and the number of electrostatic guns must be increased.

更に大きい欠点は粉塵の発生が大なることである0発生
粉塵は集塵回収すればよいが、設備の膨大さ、或いは回
収粉の再利用歩留を考慮すれば、高価な粉体塗血に対し
て更に経済的な不利を加えることになる。
An even bigger disadvantage is that a large amount of dust is generated.Although the generated dust can be collected and collected, considering the huge amount of equipment or the reuse rate of the collected powder, it is not recommended to use expensive powder blood coating. This will add to the economic disadvantage.

一方、工程省略、コストダウンの要求に応えて、アルミ
板、冷延鋼板、溶融亜鉛めっき鋼板等を工場であらかじ
め塗装し、加工1組立または施工後に塗装をしなくても
良いようにしたプレコート金属板の使用が益々盛んであ
る。
On the other hand, in response to demands for process omissions and cost reductions, pre-coated metals such as aluminum plates, cold-rolled steel plates, hot-dip galvanized steel plates, etc. are coated in advance at the factory, eliminating the need for painting after processing, assembly, or construction. Boards are increasingly being used.

しかしながら、上記静電粉体吹付法によりコイルから連
続塗装ラインでプレコート金属板を製造しようとすると
、多数(たとえば数十台)の静電塗装機を、一定間隔毎
に配置せざるを得なくなると共に、現溶剤系塗料を用い
るラインに比し数倍の塗装スペースを要し、設備費の増
大となる。また塗布量を確保するために、生産速度も思
うように上げられない。
However, when trying to manufacture precoated metal sheets from coils on a continuous coating line using the electrostatic powder spraying method described above, it is necessary to arrange a large number of electrostatic coating machines (for example, several dozen units) at regular intervals. Compared to lines that use current solvent-based paints, this method requires several times more painting space and increases equipment costs. In addition, in order to ensure the amount of coating, production speed cannot be increased as desired.

そこで、上記の様な不利の克服を意図して被塗物への粉
体塗料の供給を重力方向によって行う粉体塗装装置も開
発されている(特公昭81−14871号)。
In order to overcome the above-mentioned disadvantages, a powder coating apparatus has been developed in which the powder coating is supplied to the object to be coated in the direction of gravity (Japanese Patent Publication No. 81-14871).

発明が解決しようとする課題 本発明の目的は塗着効率もよく、短いラインで高速で粉
体塗料を塗装してプレコート金属板を提供しようとする
ことである。
Problems to be Solved by the Invention An object of the present invention is to provide a precoated metal plate by applying powder coating at high speed in a short line with good coating efficiency.

課題を解決するための手段 本発明は粉体塗料に分散媒を加えてスラリーとし、該ス
ラリーをピックアップロールに供給し。
Means for Solving the Problems In the present invention, a dispersion medium is added to a powder coating material to form a slurry, and the slurry is supplied to a pickup roll.

アプリケータロールを介して金属板にスラリーを塗装し
、次いで加熱処理することを特徴とするプレコート金属
板の製造方法である。
This is a method for producing a pre-coated metal plate, which is characterized in that a slurry is applied to a metal plate via an applicator roll, and then heat treatment is performed.

作用(発明の詳細な説明) 本発明は粉体塗料をロール塗装することを特徴とする。Effect (detailed description of the invention) The present invention is characterized in that the powder coating is applied by roll coating.

たとえば第3図に示すようにピックアップロールl上に
ホー、パー2から粉体塗料3を流下し、これをアプリケ
ーター4を介して金属板5上に塗装する方法が考えられ
る。
For example, as shown in FIG. 3, a method may be considered in which a powder coating material 3 is poured down from a hoe and a par 2 onto a pickup roll 1, and is applied onto a metal plate 5 through an applicator 4.

しかしながら、このような方法では粉体塗料が均一にロ
ール上に塗着せず結果として均一な塗装金属板は得られ
ない。
However, in such a method, the powder coating is not uniformly applied onto the roll, and as a result, a uniformly coated metal plate cannot be obtained.

そこで粉体塗料に分散媒を加えてスラリーとし、たとえ
ば第4図に示すごとく塗料容器7に収容したスラリー8
をピックアップロールlでピックアップし、これをアプ
リケーター4を介して金属板5上に転着する方法が考え
られる。
Therefore, a dispersion medium is added to the powder paint to form a slurry, and the slurry 8 is stored in a paint container 7 as shown in FIG.
A conceivable method is to pick up the liquid with a pick-up roll l and transfer it onto the metal plate 5 via the applicator 4.

しかしながら粉体塗料の場合粒度分布があり、スラリー
中のある粒子は容器中に沈降する傾向がある。又ピック
アップロールとアプリケータの間隙で細粒子はど間隙を
通り易い、従って、塗装工程前半と工程後半では塗装さ
れる塗料の質が変る恐れもある。
However, powder coatings have a particle size distribution and some particles in the slurry tend to settle in the container. Furthermore, fine particles easily pass through the gap between the pick-up roll and the applicator, so there is a risk that the quality of the paint applied will change between the first half of the coating process and the second half of the process.

そこで本発明においては第1図及び第2図にその一例を
示すごとく、スラリーの沈降がなく、又塗料の質を変え
ることなくピックアップロールに供給する方法として、
先ず第1図では、スラリー8を下方に傾斜する塗料供給
傾斜板9上を流下させ、上方よりピックアップロールl
を塗料供給傾斜板9に近ずけ、流下するスラリー8と接
触させピックアップし、厚みコントローラーlOで膜厚
調整(併せて、塗料表面の平滑化)を行って、次いでア
プリケーターロール4を介して金属板5にスラリーを塗
装する。
Therefore, in the present invention, as shown in FIG. 1 and FIG. 2 as an example, as a method of supplying the slurry to the pickup roll without sedimentation and without changing the quality of the paint,
First, in FIG. 1, the slurry 8 is made to flow down on a paint supply inclined plate 9 which is inclined downward, and a pick-up roll l is applied from above.
is brought close to the paint supply inclined plate 9, brought into contact with the flowing slurry 8, and is picked up.The thickness controller 10 adjusts the film thickness (and smooths the paint surface), and then the metal is passed through the applicator roll 4. Paint the slurry on board 5.

次に第2図では、ピックアップロール1に、その幅に均
一にスラリー8を供給できる塗料供給ノズル1Bから直
接スラリー8を供給しピー2クアツプさせ、以下上記第
1図の方法と同様にして金属板5にスラリー8を塗装す
る。
Next, in FIG. 2, the slurry 8 is directly supplied to the pick-up roll 1 from the paint supply nozzle 1B that can uniformly supply the slurry 8 over its width, and the slurry 8 is peaked up. The slurry 8 is applied to the board 5.

尚、厚みコントローラー10の代わりに他の手段、例え
ばドクターブレードの如き手段でもよい。
Note that other means such as a doctor blade may be used instead of the thickness controller 10.

また、ピックアップされずに、または、金属板5上に塗
布されなかったスラリー8は、ロール下部に設置した塗
料受は皿12により回収され、塗料供給タンク15で攪
拌及び分散された後再びピックアップロールlに供給さ
れる。
In addition, the slurry 8 that was not picked up or not coated on the metal plate 5 is collected by a tray 12 in the paint receiver installed at the bottom of the roll, stirred and dispersed in a paint supply tank 15, and then rolled again to be picked up. l is supplied.

この方法で塗料の枕降が防止でき、より均一な塗装が達
成できる。
This method prevents paint build-up and achieves a more uniform coating.

ここで分散媒としては、粉体塗料を溶解したり、膨潤も
させたりしないものが好ましく、粉体塗料を溶解したり
1N潤したりするものでは、塗装加熱処理後に粉体塗料
独特の表面外観及び、塗膜性能が得られない場合がある
0例えば、粉体塗料としてポリエステル系のものを用い
た場合、分散媒としては、水、アルコールの混合系が良
好な結果を示した。
Here, it is preferable that the dispersion medium is one that does not dissolve or swell the powder coating.If the dispersion medium dissolves the powder coating or moistens the powder coating by 1N, the dispersion medium may have a surface appearance unique to the powder coating after the heat treatment. For example, when a polyester-based powder coating was used, a mixed system of water and alcohol as a dispersion medium showed good results.

粉体塗料としては、この他、エポキシ系、アクリル系、
ポリエチレン系、ポリアミド系、塩化ビニル系等も市販
されており、各々分散媒を選択して使用可能である。ま
た、粉体塗料のスラリー化の方法は、特に限定されるも
のではなく、公知の方法でよい、また必要ならば、界面
活性剤等の助剤を使用してもよい、一般に、粉体塗料2
0〜80部に対して分散媒80〜40部が好ましいが、
これに限定されない。
In addition to this, powder coatings include epoxy, acrylic,
Polyethylene-based, polyamide-based, vinyl chloride-based, etc. are also commercially available, and a dispersion medium for each can be selected and used. In addition, the method of slurryizing the powder coating is not particularly limited, and any known method may be used.If necessary, auxiliary agents such as surfactants may be used.Generally, powder coating 2
Preferably, 80 to 40 parts of dispersion medium to 0 to 80 parts,
It is not limited to this.

尚、基材金属板(被塗物)としては、熱延鋼板、冷延鋼
板、電気亜鉛メツキ鋼板、溶融亜鉛メツキ鋼板、ステン
レス鋼板、アルミニウム板等であり、これらをそのまま
用いるか又は必要に応じて、鋼板表面に化成処理等の表
面処理を施して使用すればよい。
In addition, the base metal plate (substrate to be coated) includes hot-rolled steel plate, cold-rolled steel plate, electrolytic galvanized steel plate, hot-dip galvanized steel plate, stainless steel plate, aluminum plate, etc., and these can be used as is or as necessary. Therefore, the steel plate may be used after surface treatment such as chemical conversion treatment.

塗装後、粉体塗料の種類に応じた加熱処理を行い、分散
媒の蒸発と共に塗膜の硬化を行う。
After coating, heat treatment is performed depending on the type of powder coating to evaporate the dispersion medium and harden the coating.

実施例1 (1)スラリー塗料 粉体塗料:用上塗料■製、ポーセラツク3ooopcx
ポリエステル粉体塗料 50重量部 分散媒1:エクソン化学■製、アイソパー020重量部 分散媒2:エクンン化学■製、エクンゾールD−402
9重量部 分散助剤:サンノプコ■製、 SNデイスパーサント9
228 1重量部 以上の組成のものをデイスパーを用いて攪拌分散しスラ
リー塗料とした。
Example 1 (1) Slurry paint Powder paint: Made by Top Paint ■, Porcelac 3ooopcx
Polyester powder coating 50 parts by weight Dispersion 1: Manufactured by Exxon Chemical ■, ISOPAR 020 Part by weight dispersion 2: Manufactured by Ekun Chemical ■, Ekunsol D-402
9 parts by weight Dispersant: SN Dispersant 9 manufactured by San Nopco■
A composition containing 1 part by weight or more of 228 was stirred and dispersed using a disper to obtain a slurry paint.

(2) fi装条件及び塗装結果 塗装方式:塗装方式は、第1図の方式に従う。(2) FI mounting conditions and painting results Painting method: The painting method follows the method shown in Figure 1.

また、塗装設備の概略を第5図に示す、すなわち、ペイ
オフリール17から鋼帯5を供給し、パスロール18を
経由してアプリケーターロール4を介して鋼帯5に塗装
し、加熱装N13で近赤外加熱を行い、冷却後、コイリ
ングリール22でプレコート鋼帯の巻取りを行う。
The outline of the coating equipment is shown in FIG. After infrared heating and cooling, the precoated steel strip is wound up with a coiling reel 22.

塗装条件及び塗装結果については、第1表に示した。The coating conditions and coating results are shown in Table 1.

実施例2 (1)スラリー塗料 粉体塗料:用上塗料■製、ポーセラツク3000PCM
ポリエステル粉体塗料 50重量部 分故媒l:水、30重量部 分散媒2:メタノール、8重量部 分散助剤l:信越化学■製、メトローズ90SH300
00の1%水溶液 11重量部 分散助剤2:花王■製、エマルゲン L−400,8重
量部 消泡剤:旭電化工業■製、7デカネートB−13400
,2重量部 以上の組成のものをデイスパーを用いて攪拌し、スラリ
ー塗料とした。
Example 2 (1) Slurry paint powder paint: Made by Top Paint ■, Porcelac 3000PCM
Polyester powder coating 50 parts by weight Medium: Water, 30 parts by weight Dispersing medium 2: Methanol, 8 parts by weight Dispersing agent: Shin-Etsu Chemical ■, Metrose 90SH300
00 1% aqueous solution 11 parts by weight Dispersing agent 2: Kao ■, Emulgen L-400, 8 parts by weight Antifoaming agent: Asahi Denka Kogyo ■, 7 Decanate B-13400
, 2 parts by weight or more was stirred using a disper to obtain a slurry paint.

(2)塗装条件及び塗装結果 塗装方式:塗装方式は、第2図に従う。(2) Painting conditions and results Painting method: The painting method is as shown in Figure 2.

(また、塗装設備の概略を第5図 に示す、) 塗装条件及び塗装結果については、第1表に示す。(Also, Figure 5 shows an outline of the painting equipment. ) The coating conditions and coating results are shown in Table 1.

(以下余白) 第1表 金属板   ; 板厚:0」■ 板幅:4o■ロール周
速比;  LS:AR:PR:MRで表示LS=通板速
度 ARニアプリケータ−ロール周速 PR:ピックアップロール周速 MR:膜厚コントローラー周速 ロール間距離; ピックアップロールと膜厚コントロー
ラー間の距離密着性   ; 基盤目エリクセン試験耐
薬品性  ; 5%硫酸及び5%水酸化ナトリウム水溶
液中に24時間浸浸漬塗膜表面を観察する。
(Leaving space below) Table 1 Metal plate; Plate thickness: 0'' ■ Plate width: 4o ■ Roll circumferential speed ratio; Displayed as LS: AR: PR: MR LS = Threading speed AR Near applicator - Roll circumferential speed PR: Pick up roll Peripheral speed MR: Film thickness controller peripheral speed distance between rolls; Distance between pickup roll and film thickness controller Adhesion; Substrate Erichsen test chemical resistance; 24 hour immersion coating in 5% sulfuric acid and 5% sodium hydroxide aqueous solution Observe the membrane surface.

耐汚染性  : マジック(赤、昆りで汚染し、2偶佃
後にエタノールで拭き取る 発明の効果 本発明により、表面性状及び塗膜性能の良好なプレコー
ト金属板が、塗着効率もよく、ロールコータ−を使用し
た高速ラインで製造できた。
Stain resistance: Effect of the invention: staining with magic marker (red, kelp and wiping it off with ethanol) - could be manufactured on a high-speed line using

【図面の簡単な説明】[Brief explanation of drawings]

第1〜5図は立面図である。 l・・・ピックアップロール、2・・・ホッパー、3・
・・粉体塗料、4・・・アプリケーターロール、5・・
・金属板、6・・・バックアップロール、7・・・塗料
容器、8・・・スラリー、9・・・塗料供給傾斜板、1
0・・・厚みコントローラー、11・・・かさとり板、
12・・・塗料量は皿、 13・・◆撹拌機、14・・
・ロータリーポンプ、15・・・塗料供給タンク、IB
・・・塗料供給ノズル、17・・・ペイオフリール、1
8・・・パスロール、18・・・加熱装置、20・・・
冷却装置、21・・・プライドルロール、22・・・コ
イリングリール。
Figures 1-5 are elevational views. l...Pickup roll, 2...Hopper, 3.
...Powder coating, 4...Applicator roll, 5...
・Metal plate, 6... Backup roll, 7... Paint container, 8... Slurry, 9... Paint supply inclined plate, 1
0...thickness controller, 11...bulk board,
12...The amount of paint is on a plate, 13...◆Agitator, 14...
・Rotary pump, 15...Paint supply tank, IB
...Paint supply nozzle, 17...Payoff reel, 1
8... Pass roll, 18... Heating device, 20...
Cooling device, 21...Pridle roll, 22... Coiling reel.

Claims (3)

【特許請求の範囲】[Claims] (1)粉体塗料に分散媒を加えてスラリーとし、該スラ
リーをピックアップロールに供給し、アプリケータロー
ルを介して金属板にスラリーを塗装し、ついで加熱処理
することを特徴とするプレコート金属板の製造方法。
(1) A pre-coated metal plate characterized in that a dispersion medium is added to a powder coating to form a slurry, the slurry is supplied to a pick-up roll, the slurry is applied to a metal plate via an applicator roll, and then heat-treated. manufacturing method.
(2)粉体塗料に分散媒を加えてスラリーとし、該スラ
リーを傾斜する板上を流下させながらピックアップロー
ルに供給しピックアップし、アプリケーターロールを介
して金属板にスラリーを塗装し、ついで加熱処理するこ
とを特徴とするプレコート金属板の製造方法。
(2) Add a dispersion medium to the powder coating to make a slurry, supply the slurry to a pick-up roll while flowing down on an inclined plate, and pick it up. Apply the slurry to the metal plate via an applicator roll, and then heat treat it. A method for producing a precoated metal plate, characterized by:
(3)前記ピックアップロールへの供給方法が、ピック
アップロールに近接するノズルから直接行われることを
特徴とする、特許請求の範囲第一項記載のプレコート金
属板の製造方法。
(3) The method for manufacturing a precoated metal sheet according to claim 1, characterized in that the method of supplying to the pickup roll is performed directly from a nozzle adjacent to the pickup roll.
JP17113089A 1989-07-04 1989-07-04 Preparation of precoated metal plate Pending JPH0338281A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP17113089A JPH0338281A (en) 1989-07-04 1989-07-04 Preparation of precoated metal plate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP17113089A JPH0338281A (en) 1989-07-04 1989-07-04 Preparation of precoated metal plate

Publications (1)

Publication Number Publication Date
JPH0338281A true JPH0338281A (en) 1991-02-19

Family

ID=15917538

Family Applications (1)

Application Number Title Priority Date Filing Date
JP17113089A Pending JPH0338281A (en) 1989-07-04 1989-07-04 Preparation of precoated metal plate

Country Status (1)

Country Link
JP (1) JPH0338281A (en)

Cited By (11)

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JP2002235040A (en) * 2001-02-08 2002-08-23 Mitsubishi Electric Corp Method for coating substrate
JP2007029675A (en) * 2005-07-21 2007-02-08 Kenichiro Yasuno Caring diaper replacement assisting implement
JP2012517500A (en) * 2009-02-06 2012-08-02 イーストマン ケミカル カンパニー Thermosetting polyester coating composition containing tetramethylcyclobutanediol
JP2012517498A (en) * 2009-02-06 2012-08-02 イーストマン ケミカル カンパニー Coating composition containing a blend of acrylic and aliphatic polyester
JP2012517499A (en) * 2009-02-06 2012-08-02 イーストマン ケミカル カンパニー Coating composition containing tetramethylcyclobutanediol
US9029461B2 (en) 2009-02-06 2015-05-12 Eastman Chemical Company Aliphatic polyester coating compositions containing tetramethyl cyclobutanediol
US9650539B2 (en) 2014-10-27 2017-05-16 Eastman Chemical Company Thermosetting compositions based on unsaturated polyesters and phenolic resins
US9988553B2 (en) 2016-02-22 2018-06-05 Eastman Chemical Company Thermosetting coating compositions
US10011737B2 (en) 2016-03-23 2018-07-03 Eastman Chemical Company Curable polyester polyols and their use in thermosetting soft feel coating formulations
US10526444B2 (en) 2015-09-25 2020-01-07 Eastman Chemical Company Polymers containing cyclobutanediol and 2,2-bis(hydroxymethyl)alkylcarboxylic acid
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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6051572A (en) * 1983-06-30 1985-03-23 アキユメ−タ−・ラボラトリ−ズ・インコ−ポレ−テツド Roll coating machine used for applying adhesive and applyingmethod
JPS6325536B2 (en) * 1980-10-31 1988-05-25 Nippon Denki Hoomu Erekutoronikusu Kk

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6325536B2 (en) * 1980-10-31 1988-05-25 Nippon Denki Hoomu Erekutoronikusu Kk
JPS6051572A (en) * 1983-06-30 1985-03-23 アキユメ−タ−・ラボラトリ−ズ・インコ−ポレ−テツド Roll coating machine used for applying adhesive and applyingmethod

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JP2002235040A (en) * 2001-02-08 2002-08-23 Mitsubishi Electric Corp Method for coating substrate
JP2007029675A (en) * 2005-07-21 2007-02-08 Kenichiro Yasuno Caring diaper replacement assisting implement
JP4719845B2 (en) * 2005-07-21 2011-07-06 賢一郎 安野 Assembled nursing diaper changing aid
US9029461B2 (en) 2009-02-06 2015-05-12 Eastman Chemical Company Aliphatic polyester coating compositions containing tetramethyl cyclobutanediol
JP2012517498A (en) * 2009-02-06 2012-08-02 イーストマン ケミカル カンパニー Coating composition containing a blend of acrylic and aliphatic polyester
JP2012517499A (en) * 2009-02-06 2012-08-02 イーストマン ケミカル カンパニー Coating composition containing tetramethylcyclobutanediol
JP2012517500A (en) * 2009-02-06 2012-08-02 イーストマン ケミカル カンパニー Thermosetting polyester coating composition containing tetramethylcyclobutanediol
US9029460B2 (en) 2009-02-06 2015-05-12 Stacey James Marsh Coating compositions containing acrylic and aliphatic polyester blends
JP2016047915A (en) * 2009-02-06 2016-04-07 イーストマン ケミカル カンパニー Coating compositions containing tetramethyl cyclobutanediol
US9650539B2 (en) 2014-10-27 2017-05-16 Eastman Chemical Company Thermosetting compositions based on unsaturated polyesters and phenolic resins
US10676565B2 (en) 2015-05-19 2020-06-09 Eastman Chemical Company Aliphatic polyester coating compositions containing tetramethyl cyclobutanediol
US10526444B2 (en) 2015-09-25 2020-01-07 Eastman Chemical Company Polymers containing cyclobutanediol and 2,2-bis(hydroxymethyl)alkylcarboxylic acid
US9988553B2 (en) 2016-02-22 2018-06-05 Eastman Chemical Company Thermosetting coating compositions
US10011737B2 (en) 2016-03-23 2018-07-03 Eastman Chemical Company Curable polyester polyols and their use in thermosetting soft feel coating formulations

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