JPH03285878A - Production of lightweight concrete board - Google Patents

Production of lightweight concrete board

Info

Publication number
JPH03285878A
JPH03285878A JP8708990A JP8708990A JPH03285878A JP H03285878 A JPH03285878 A JP H03285878A JP 8708990 A JP8708990 A JP 8708990A JP 8708990 A JP8708990 A JP 8708990A JP H03285878 A JPH03285878 A JP H03285878A
Authority
JP
Japan
Prior art keywords
cement
granules
thermoplastic resin
lightweight concrete
foamed thermoplastic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP8708990A
Other languages
Japanese (ja)
Inventor
Yozo Mihara
三原 陽三
Takashi Terayama
隆司 寺山
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Chemical and Materials Co Ltd
Original Assignee
Nippon Steel Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Chemical Co Ltd filed Critical Nippon Steel Chemical Co Ltd
Priority to JP8708990A priority Critical patent/JPH03285878A/en
Publication of JPH03285878A publication Critical patent/JPH03285878A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To stably produce a lightweight inorg. material having internal cavities by blending a cement-based binder with granules of a foamed thermoplastic resin, hardening the blend in a molding flask and shrinking or subliming the resin by heating. CONSTITUTION:A cement-based binder is blended with a prescribed amt. of granules or chips of a foamed thermoplastic resin such as styrene foam and this blend is poured into a shallow tray-shaped molding flask and taken out of the molding flask in a hardened or semihardened state. Heat treatment is then carried out at a temp. at which the resin melts, shrinks or sublimes and the cement-based binder hardens properly and cavities are formed in the resulting concrete to obtain a lightweight concrete board. Since this board is not produced by foaming, the surface can be made smooth without any more treatment.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、軽量コンクリート板の製造方法に係り、特に
天井材や壁材及び床材など各種の建材或いは道路素材等
の建設資材としての用途に好適な軽量コンクリート板の
製造方法に関するものである。
[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a method for manufacturing lightweight concrete plates, particularly for use as construction materials such as various building materials such as ceiling materials, wall materials, and floor materials, or road materials. The present invention relates to a method for manufacturing lightweight concrete plates suitable for

〔従来の技術〕[Conventional technology]

マンションや住宅の外壁や床材等に用いる一般にALC
の名称で上市されている気泡コンクリートの製造方法の
概略は以下のようである。即ち、珪石、生石灰、アルミ
粉末、水のほか減水剤や遅延剤などの薬品等を必要に応
じて配合、混合した後型枠に流し込み発泡させる。次に
脱型の後、適当な大きさにスライスしてオートクレーブ
中で高温高圧蒸気養生して製造する。このALCは既に
多くのメーカーから上市されている。
ALC is generally used for exterior walls and flooring of condominiums and houses.
The outline of the manufacturing method of aerated concrete, which is marketed under the name of , is as follows. That is, silica stone, quicklime, aluminum powder, water, and chemicals such as water reducing agents and retardants are blended and mixed as necessary, and then poured into a mold and foamed. Next, after demolding, it is sliced into appropriate sizes and cured with high temperature and high pressure steam in an autoclave. This ALC is already on the market from many manufacturers.

コンクリートの軽量化という点では、別の方法として発
泡スチロールをセメントに混入する方法があり、その例
としては特開昭53−9825号がある。この方法は現
場打ちコンクリートに有効である。また、軽量コンクリ
ートブロックの製造方法としては特開昭62−4178
2号がある。
Another method for reducing the weight of concrete is to mix styrene foam into cement, an example of which is disclosed in Japanese Patent Laid-Open No. 53-9825. This method is effective for cast-in-place concrete. In addition, as a manufacturing method for lightweight concrete blocks, Japanese Patent Application Laid-Open No. 62-4178
There is number 2.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

従来の軽量コンクリートでは、上記のような製造方法に
よるため、表面に気泡が多く存在し、表面に平滑性がな
く、表面塗装をする場合には塗料の吸い込みが問題とな
る。軽量化のために気泡剤を用いる場合には、気泡の制
御に経験が必要であり、硬化もしくは半硬化後に成形の
ために手を加えなければならない。ALCでは、所定の
形状に加工の後にオートクレーブ処理するため最終製品
の仕上げに手間をかける場合がある。また、このような
製造工程をたどるため、製品の強度向上や仕上がり感の
向上を目的とした多層構造の板材の生産が難しい。多層
構造の板材の製造は発泡剤を用いると発泡後に複層化す
るため、硬化段階に差が生し、気泡のある層と気泡のな
い比較的密な層との界面の強度の低下がみられる。
Conventional lightweight concrete is produced using the above-mentioned manufacturing method, so there are many air bubbles on the surface, the surface is not smooth, and when the surface is painted, paint absorption becomes a problem. When using a foaming agent to reduce weight, experience is required to control the foam, and modifications must be made for molding after curing or semi-curing. In ALC, since autoclaving is performed after processing into a predetermined shape, it may take time and effort to finish the final product. Furthermore, since such a manufacturing process is followed, it is difficult to produce a multilayered plate material that aims to improve the strength and finish of the product. When manufacturing multilayer board materials, when a foaming agent is used, the material is multi-layered after foaming, resulting in a difference in the curing stage and a decrease in the strength of the interface between a layer with bubbles and a relatively dense layer without bubbles. It will be done.

これらの問題点を解消するために様々な研究が行われて
いるが、明確な有効手段は見出されていない。それ故、
本発明の目的とするところは、空隙を有する軽量無機材
料の製造において、これらに代わる有効な手段を提供す
ることにある。
Various studies have been conducted to solve these problems, but no clear effective means have been found. Therefore,
An object of the present invention is to provide an effective alternative means for producing lightweight inorganic materials having voids.

〔課題を解決するための手段〕[Means to solve the problem]

本発明者らは上記のような課題を解決するため研究を行
い、アルミ粉などの発泡剤を用いることなくより効果的
に安定した軽量無機材料を製造する方法を見出すにいた
った。
The present inventors conducted research to solve the above-mentioned problems and discovered a method for producing a stable lightweight inorganic material more effectively without using a foaming agent such as aluminum powder.

即ち本発明は、軽量コンクリート板の製造に際し、ボー
ドの全体積より少ない体積の発泡熱可塑性樹脂の粒状体
あるいは細片をセメント系結合材に投入充填し、浅いト
レイ状の型枠に流し込み、セメントの硬化過程において
該粒状体あるいは細片を拘束することなく自由に浮上さ
せて硬化もしくは半硬化させた後、加熱して前記樹脂を
溶解収縮もしくは昇華させ、空洞をコンクリート内部に
形成させることを特徴とする軽量コンクリート板の製造
方法に関し、加熱の方法として、乾燥空気、水蒸気、発
泡熱可塑性樹脂を溶解せしめる溶剤蒸気、もしくは こ
れらの混合蒸気を伴う加熱方法を用いた前記軽量コンク
リート板の製造方法である。以下、本発明の詳細な説明
する。
That is, in the production of lightweight concrete boards, the present invention involves filling a cement-based binder with granules or pieces of foamed thermoplastic resin having a volume smaller than the total volume of the board, pouring into a shallow tray-shaped formwork, and adding cement to the concrete. In the curing process, the granules or pieces are allowed to float freely without restraint, and after hardening or semi-hardening, the resin is melted, shrunk or sublimated by heating, and cavities are formed inside the concrete. Regarding the method for producing a lightweight concrete plate, the method uses a heating method involving dry air, water vapor, a solvent vapor for dissolving a foamed thermoplastic resin, or a mixed vapor thereof as a heating method. be. The present invention will be explained in detail below.

先ず、本発明の軽量コンクリート板とは板の厚さが5〜
20mmの範囲で、好ましくは8〜15胴の厚さのもの
をいう。板の製造にはセメント系結合材の組み合わせ、
例えば、セメントと水、珪砂と生石灰と水等の組み合わ
せを用意する。これに一定温度で融解する発泡熱可塑性
樹脂を所定量添加する。発泡熱可塑性樹脂の代表的な例
としては発泡スチロールがあげられる。発泡スチロール
を用いる場合には比重約0.02以上のものが好ましい
。粒状物の添加量は軽量化の要求度や製品の目的強度に
応じて決定されるが、水を含めたセメント系結合材の0
.5〜3%程度の添加が好ましい。
First, the lightweight concrete board of the present invention has a thickness of 5 to 5.
The thickness is in the range of 20 mm, preferably 8 to 15 mm. A combination of cement-based binding materials is used to manufacture the boards.
For example, combinations such as cement and water, silica sand, quicklime, and water are prepared. A predetermined amount of foamed thermoplastic resin that melts at a constant temperature is added to this. A typical example of foamed thermoplastic resin is styrene foam. If expanded polystyrene is used, it preferably has a specific gravity of about 0.02 or more. The amount of granules to be added is determined depending on the degree of weight reduction required and the intended strength of the product.
.. It is preferable to add about 5 to 3%.

空隙の量は添加する発泡熱可塑性樹脂の体積から容易に
計算可能である。また、粒子の形状は特に問わないが、
好ましくは2〜5IIIIn程度の径をもつものがよい
。空隙の大きさのコントロールは粒子の大きさを揃えれ
ばよいので、安定した形状の空隙が容易に管理できる。
The amount of voids can be easily calculated from the volume of foamed thermoplastic resin added. In addition, the shape of the particles is not particularly important, but
Preferably, it has a diameter of about 2 to 5 IIIn. The size of the voids can be controlled simply by making the sizes of the particles uniform, so that voids with a stable shape can be easily managed.

製造時には作業性や強度上の理由から減水剤や遅延剤等
を添加してもよい。
During production, water reducing agents, retardants, etc. may be added for reasons of workability and strength.

また、全体の強度向上のために配合の際に補強用の鋼材
や繊維材料を配合しても構わない。
Furthermore, reinforcing steel or fiber materials may be added during compounding in order to improve the overall strength.

各々を配合した後、浅いトレイ状の型枠に流し込み、硬
化もしくは半硬化の状態で型枠から取り出し、発泡熱可
塑性樹脂が溶解もしくは昇華する温度で且つセメント系
結合材が過不足なく硬化する温度で熱処理して目的とす
る製品を得る。一般に加熱温度は130〜220°Cの
範囲で任意に選択され、加圧を必要とする場合には2〜
12気圧をかける。加熱方法は乾燥空気によるもの、水
蒸気を伴うものに加え、発泡熱可塑性樹脂を溶解しうる
溶剤の蒸気を伴うもの、水蒸気と溶剤蒸気の混合蒸気に
よるもの等があり、何れを用いてもよい。処理時間は、
発泡熱可塑性樹脂が溶解もしくは昇華し且つセメント系
結合材が過不足なく硬化する時間であれば特に規定しな
い。粒状物は溶融温度に達した時、融解して粒状物があ
った部分は空隙となり、樹脂は空隙の周囲に薄い膜とな
るか、もしくは硬化したセメント材料の内部に入り込む
After mixing each, pour into a shallow tray-shaped mold and take it out from the mold in a hardened or semi-hardened state, at a temperature at which the foamed thermoplastic resin melts or sublimates, and a temperature at which the cementitious binder hardens in just the right amount. heat treatment to obtain the desired product. Generally, the heating temperature is arbitrarily selected within the range of 130 to 220°C, and if pressurization is required, the heating temperature is
Apply 12 atmospheres. Heating methods include those using dry air, those involving water vapor, those involving vapor of a solvent capable of dissolving the foamed thermoplastic resin, and those using mixed vapor of water vapor and solvent vapor, and any of them may be used. The processing time is
The time is not particularly specified as long as the foamed thermoplastic resin is dissolved or sublimated and the cementitious binder is cured in just the right amount. When the granules reach their melting temperature, they melt, leaving voids where the granules were, and the resin forms a thin film around the voids or penetrates into the hardened cement material.

本発明の軽量コンクリート板は発泡剤による発泡で製造
するものではないため始めから表面を平滑に仕上げるこ
とも容易である。
Since the lightweight concrete plate of the present invention is not manufactured by foaming with a foaming agent, it is easy to finish the surface smooth from the beginning.

板の片面を平滑にしたい場合、発泡熱可塑性樹脂とセメ
ント系結合材の配合物をトレイ状の型枠に流し込み静置
すると、硬化する前に発泡樹脂がその浮力により浮き上
がり、底部は発泡樹脂を含まない状態になり、型枠内の
底に当たる部分は気泡を含まず平滑になる。ここで、発
泡熱可塑性樹脂とセメント系結合材の配合物の流動性を
制御するなら、型枠内の底に当たる部分の気泡を含まな
い層の厚さを制御することができ、軽量セメント板の平
滑な面の硬さを調整することができる。
If you want to make one side of the board smooth, pour a mixture of foamed thermoplastic resin and cementitious binder into a tray-shaped mold and let it stand. The bottom of the formwork becomes smooth and contains no air bubbles. If the fluidity of the foamed thermoplastic resin and cementitious binder mixture is controlled, the thickness of the bubble-free layer at the bottom of the formwork can be controlled, and the thickness of the foamed thermoplastic resin and cementitious binder mixture can be controlled. The hardness of smooth surfaces can be adjusted.

本発明の方法の延長として、気泡の多い層と気泡を含ま
ない層とからなる多層構造の板も作ることができる。発
泡熱可塑性樹脂の粒状物を含まない配合と粒状物を含む
配合とを用意し、型の底に粒状物を含まない配合物を流
し込み、その上に粒状物を含む配合物を流し込み、更に
その上に粒状物を含まない配合物を流し込むなら、表面
の気泡を含まない層を厚くした3層構造の軽量気泡コン
クリート板を作ることができる。この考え方で更に多層
構造のものも作ることも可能である。
As an extension of the method of the invention, it is also possible to produce plates with a multilayer structure consisting of a cell-rich layer and a cell-free layer. Prepare a formulation without granules and a formulation with granules of foamed thermoplastic resin, pour the formulation without granules into the bottom of the mold, pour the formulation with granules on top, and then pour the formulation without granules into the bottom of the mold. If a particulate-free mix is poured on top, it is possible to create a three-layer lightweight cellular concrete slab with a thicker surface layer that does not contain air bubbles. Using this idea, it is also possible to create a multilayer structure.

[実施例] ポルトランドセメント100、砂150、水90、減水
剤1.5.2〜5IInn径の発泡スチロール3、の各
重量比で配合攪拌の後、3ocIn角、深さ1゜肛の型
枠に流し込む。硬化後型枠を外し、150°Cで5時間
加熱し、目的とする板の片面が平滑な軽量コンクリート
板を得た。
[Example] 100 parts of Portland cement, 150 parts of sand, 90 parts of water, 1 part of water reducing agent, and 3 parts of expanded polystyrene with a diameter of 5.2 to 5 II Inn were mixed in a weight ratio of 3. After stirring, the mixture was put into a mold of 3 ocIn square and 1 degree deep. Pour. After curing, the formwork was removed and heated at 150°C for 5 hours to obtain the desired lightweight concrete board with one side smooth.

得られた軽量コンクリート板は比重約0.8で市販の石
膏ボードの約1.0と比べて軽いこと、接着剤の塗布量
200g/r+(で壁用ビニールクロスを貼り両者に差
はなく接着剤が吸い込まれ易いことはないこと、更に 
市販の水性ペイントを塗布量300 g/rrfでスプ
レーガンを用いて平滑な面に均一に塗布し全体に色ムラ
を生じないことを確認し、建築材料として好適であるこ
とが判明した。
The resulting lightweight concrete board has a specific gravity of approximately 0.8, which is lighter than commercially available gypsum board's approximately 1.0, and a wall vinyl cloth was applied with an adhesive coating amount of 200g/r+ (there was no difference between the two). The agent should not be easily inhaled, and
A commercially available water-based paint was uniformly applied to a smooth surface using a spray gun at a coating amount of 300 g/rrf, and it was confirmed that no color unevenness occurred over the entire surface, proving that it is suitable as a building material.

〔発明の効果〕〔Effect of the invention〕

本発明は、表面の平滑性が良好で塗装などの仕上げが容
易、製品の最終仕上げに手間がかからない製造方法であ
る。製品の強度向上や仕上がり感の向上を目的とした多
層構造の板材の生産が容易等の利点を備えており、実用
上の効果は極めて顕著である。
The present invention is a manufacturing method that provides good surface smoothness, makes finishing such as painting easy, and does not require time and effort for the final finishing of the product. It has the advantage of being easy to produce multi-layered plate materials for the purpose of improving the strength and finish of products, and its practical effects are extremely significant.

Claims (2)

【特許請求の範囲】[Claims] (1)軽量コンクリート板の製造に際し、ボードの全体
積より少ない体積の発泡熱可塑性樹脂の粒状体あるいは
細片をセメント系結合材に投入充填し、浅いトレイ状の
型枠に流し込み、セメントの硬化過程において該粒状体
あるいは細片を拘束することなく自由に浮上させて硬化
もしくは半硬化させた後、加熱して前記樹脂を溶解収縮
もしくは昇華させ、空洞をコンクリート内部に形成させ
ることを特徴とする軽量コンクリート板の製造方法。
(1) When manufacturing lightweight concrete boards, granules or pieces of foamed thermoplastic resin with a volume smaller than the total volume of the board are charged into a cement-based binding material, poured into a shallow tray-shaped formwork, and the cement hardens. In the process, the granules or pieces are allowed to float freely without restraint, and after hardening or semi-hardening, the resin is melted, shrunk or sublimated by heating, and cavities are formed inside the concrete. Method of manufacturing lightweight concrete plates.
(2)加熱の方法として、乾燥空気、水蒸気、発泡熱可
塑性樹脂を溶解せしめる溶剤蒸気、もしくはこれらの混
合蒸気を伴う加熱方法を用いた請求項1記載の軽量コン
クリート板の製造方法。
(2) The method for manufacturing a lightweight concrete board according to claim 1, wherein the heating method involves dry air, water vapor, a solvent vapor for dissolving the foamed thermoplastic resin, or a mixed vapor thereof.
JP8708990A 1990-03-30 1990-03-30 Production of lightweight concrete board Pending JPH03285878A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP8708990A JPH03285878A (en) 1990-03-30 1990-03-30 Production of lightweight concrete board

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP8708990A JPH03285878A (en) 1990-03-30 1990-03-30 Production of lightweight concrete board

Publications (1)

Publication Number Publication Date
JPH03285878A true JPH03285878A (en) 1991-12-17

Family

ID=13905226

Family Applications (1)

Application Number Title Priority Date Filing Date
JP8708990A Pending JPH03285878A (en) 1990-03-30 1990-03-30 Production of lightweight concrete board

Country Status (1)

Country Link
JP (1) JPH03285878A (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7897801B2 (en) 2003-05-12 2011-03-01 Invista North America S.A R.L. Process for the preparation of dinitriles
US7919646B2 (en) 2006-07-14 2011-04-05 Invista North America S.A R.L. Hydrocyanation of 2-pentenenitrile
US7973174B2 (en) 2005-10-18 2011-07-05 Invista North America S.A.R.L. Process of making 3-aminopentanenitrile
US7977502B2 (en) 2008-01-15 2011-07-12 Invista North America S.A R.L. Process for making and refining 3-pentenenitrile, and for refining 2-methyl-3-butenenitrile
US8088943B2 (en) 2008-01-15 2012-01-03 Invista North America S.A R.L. Hydrocyanation of pentenenitriles
US8101790B2 (en) 2007-06-13 2012-01-24 Invista North America S.A.R.L. Process for improving adiponitrile quality
US8178711B2 (en) 2006-03-17 2012-05-15 Invista North America S.A R.L. Method for the purification of triorganophosphites by treatment with a basic additive
US8247621B2 (en) 2008-10-14 2012-08-21 Invista North America S.A.R.L. Process for making 2-secondary-alkyl-4,5-di-(normal-alkyl)phenols
US8338636B2 (en) 2009-08-07 2012-12-25 Invista North America S.A R.L. Hydrogenation and esterification to form diesters
US8373001B2 (en) 2003-02-10 2013-02-12 Invista North America S.A R.L. Method of producing dinitrile compounds

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8373001B2 (en) 2003-02-10 2013-02-12 Invista North America S.A R.L. Method of producing dinitrile compounds
US7897801B2 (en) 2003-05-12 2011-03-01 Invista North America S.A R.L. Process for the preparation of dinitriles
US7973174B2 (en) 2005-10-18 2011-07-05 Invista North America S.A.R.L. Process of making 3-aminopentanenitrile
US8178711B2 (en) 2006-03-17 2012-05-15 Invista North America S.A R.L. Method for the purification of triorganophosphites by treatment with a basic additive
US7919646B2 (en) 2006-07-14 2011-04-05 Invista North America S.A R.L. Hydrocyanation of 2-pentenenitrile
US8394981B2 (en) 2006-07-14 2013-03-12 Invista North America S.A R.L. Hydrocyanation of 2-pentenenitrile
US8101790B2 (en) 2007-06-13 2012-01-24 Invista North America S.A.R.L. Process for improving adiponitrile quality
US7977502B2 (en) 2008-01-15 2011-07-12 Invista North America S.A R.L. Process for making and refining 3-pentenenitrile, and for refining 2-methyl-3-butenenitrile
US8088943B2 (en) 2008-01-15 2012-01-03 Invista North America S.A R.L. Hydrocyanation of pentenenitriles
US8247621B2 (en) 2008-10-14 2012-08-21 Invista North America S.A.R.L. Process for making 2-secondary-alkyl-4,5-di-(normal-alkyl)phenols
US8338636B2 (en) 2009-08-07 2012-12-25 Invista North America S.A R.L. Hydrogenation and esterification to form diesters

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