JPH03267335A - Corrosion resistant ti-based alloy - Google Patents
Corrosion resistant ti-based alloyInfo
- Publication number
- JPH03267335A JPH03267335A JP2069066A JP6906690A JPH03267335A JP H03267335 A JPH03267335 A JP H03267335A JP 2069066 A JP2069066 A JP 2069066A JP 6906690 A JP6906690 A JP 6906690A JP H03267335 A JPH03267335 A JP H03267335A
- Authority
- JP
- Japan
- Prior art keywords
- corrosion
- corrosion resistance
- based alloy
- resistant
- alloys
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000007797 corrosion Effects 0.000 title claims abstract description 68
- 238000005260 corrosion Methods 0.000 title claims abstract description 68
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 34
- 239000000956 alloy Substances 0.000 title claims abstract description 34
- 229910052707 ruthenium Inorganic materials 0.000 claims abstract description 8
- 239000012535 impurity Substances 0.000 claims abstract description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 229910052763 palladium Inorganic materials 0.000 abstract description 7
- 229910010977 Ti—Pd Inorganic materials 0.000 abstract description 4
- 229910052759 nickel Inorganic materials 0.000 abstract description 4
- 229910052709 silver Inorganic materials 0.000 abstract description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract description 2
- 230000002195 synergetic effect Effects 0.000 abstract description 2
- 239000010936 titanium Substances 0.000 description 33
- 238000012360 testing method Methods 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 9
- 238000007654 immersion Methods 0.000 description 8
- 230000001590 oxidative effect Effects 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- 238000005275 alloying Methods 0.000 description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910001069 Ti alloy Inorganic materials 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 229910003296 Ni-Mo Inorganic materials 0.000 description 2
- 229910001252 Pd alloy Inorganic materials 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000001737 promoting effect Effects 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Landscapes
- Materials For Medical Uses (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は耐蝕性Ｔｉ基合金に関し、さらに詳細には、耐
蝕性に優れており、かつ、加工性耐隙間腐蝕性に優れて
いる耐蝕性Ｔｉ基合金に関するものである。[Detailed Description of the Invention] [Field of Industrial Application] The present invention relates to a corrosion-resistant Ti-based alloy, and more particularly, to a corrosion-resistant Ti-based alloy that has excellent corrosion resistance and excellent crevice corrosion resistance in workability. This relates to Ti-based alloys.
「従来技術］
従来より、Ｔｉは耐蝕性の優れている金属として良く知
られており、化学プラント等の工業用の構造材料として
使用されているが、使用される環境によってはその耐蝕
性について疑問視される場合がある。"Prior Art" Ti has been well known as a metal with excellent corrosion resistance, and has been used as a structural material for industries such as chemical plants, but its corrosion resistance is questionable depending on the environment in which it is used. It may be seen.
Ｔｉは特に、硝酸等の酸化性の腐蝕環境、および海水や
その他の塩化物を含有する腐蝕環境においては優れた耐
蝕性を示すものである。Particularly, Ti exhibits excellent corrosion resistance in oxidizing corrosive environments such as nitric acid, and corrosive environments containing seawater and other chlorides.
しかし、塩酸および硫酸等の非酸化性の環境においては
、上記に説明した酸化性の環境等はど優れた耐蝕性を示
さない。However, in non-oxidizing environments such as hydrochloric acid and sulfuric acid, excellent corrosion resistance is not exhibited as in the oxidizing environments described above.
また、高温の塩化物溶液等の環境においては、その環境
におかれる物に隙間があると、その隙間に存在するＴｉ
が局部的に腐蝕を受けることはよく知られている。In addition, in environments such as high-temperature chloride solutions, if there are gaps in objects placed in that environment, Ti may be present in those gaps.
It is well known that corrosion occurs locally.
このようにＴｉが比較的に腐蝕を受は易い環境における
問題を解決するために、Ｔｉに種々の合金元素を含有さ
せて耐蝕性のＴｉ基合金が既に提案され、かつ、一般に
市販されている。In order to solve this problem in environments where Ti is relatively susceptible to corrosion, corrosion-resistant Ti-based alloys made by incorporating various alloying elements into Ti have already been proposed, and are generally commercially available. .
そして、このＴｉ基合金としては、Ｔｉ−Ｐｄ合金、Ｔ
ｉ−Ｎｉ−Ｍｏ合金等が挙げられるが、Ｔｊ−Ｐｄ合金
はＰｄは高価であり、経済的に問題があり、また、Ｔｉ
−Ｎｉ−Ｍｏ合金は加工性が悪いという問題があり、耐
蝕性が優れている割には広く使用されてしない。As this Ti-based alloy, Ti-Pd alloy, T
Examples include i-Ni-Mo alloys, but Tj-Pd alloys are economically problematic because Pd is expensive, and Ti
-Ni-Mo alloy has a problem of poor workability, and is not widely used despite its excellent corrosion resistance.
［発明が解決しようとする課題］
本発明は上記に説明したように、従来の耐蝕性が良好で
あると言われているＴｉ合金における種々の問題点に鑑
み、本発明者が鋭意研究を行い、検討を重ねた結果、加
工性が良好であり、かっ、Ｔｉ−Ｐｄ合金と同等または
それ以上の、特に、非酸化性等の環境において優れた耐
蝕性を示し、さらに、高温塩化物溶液等の環境における
耐隙間腐蝕性も実用上満足することができ、また、経済
的でもある耐蝕性Ｔｉ基合金を開発したのである。[Problems to be Solved by the Invention] As explained above, the present inventor has conducted extensive research in view of various problems with conventional Ti alloys that are said to have good corrosion resistance. As a result of repeated studies, we found that it has good workability and exhibits excellent corrosion resistance, equivalent to or better than that of Ti-Pd alloys, especially in non-oxidizing environments. We have developed a corrosion-resistant Ti-based alloy that has practically satisfactory crevice corrosion resistance in the environment of
［問題点を解決するための手段］
本発明に係る耐蝕性Ｔｉ基合金の特徴とするところは、
Ａｇ ０．ＯＱ５〜１ 、５ｗｔ％
を含有し、さらに、
Ｎｉ ０．００５〜２．ｈｔ％、Ｐｄ ０．００５〜２
．ｈｔ％、Ｒｕ ０．００５〜２．Ｏｗｔ％
の１種以上
を含有し、残部がＴｉおよび不可避不純物からなること
にある。[Means for Solving the Problems] The corrosion-resistant Ti-based alloy according to the present invention is characterized by: Ag 0. Contains OQ5-1, 5wt%, and further contains Ni 0.005-2. ht%, Pd 0.005-2
．． ht%, Ru 0.005-2. Owt%, and the remainder consists of Ti and unavoidable impurities.
本発明に係る耐蝕性Ｔｉ基合金について、以下詳細に説
明する。The corrosion-resistant Ti-based alloy according to the present invention will be explained in detail below.
合金元素として、従来使用されてきているＰｄにかえて
、より経済的であり、また、加工性に悪影響を与えない
元素を探すために多数の合金を製作して、耐蝕性および
耐隙間腐蝕性について研究を重ね、上記した特性が得ら
れる合金元素としてＡｇを見出した。In order to replace the conventionally used Pd as an alloying element, we created a number of alloys in search of elements that are more economical and do not have a negative effect on workability, and have improved corrosion resistance and crevice corrosion resistance. Through repeated research, Ag was discovered as an alloying element that provides the above properties.
しかして、ＴｉにＡｇ或いはＲｕのそれぞれ単独を含有
させることにより、耐蝕性の向上を図ることは特開昭５
３−１２３３２２号公報により提案されているが、これ
らＡｇおよびＲｕをそれぞれ単独に含有させても非酸化
性の環境下における耐蝕性の向上効果はない。このこと
は、これら貴金属の水素過電圧が比較的に大きいため、
Ｔ、の陽分極を速やかに促進させ、ＴｌＯ２の形成を促
進する作用が小さいためである。However, it has been proposed in Japanese Patent Application Laid-Open No. 5-11111 to improve corrosion resistance by incorporating Ag or Ru alone into Ti.
Although it is proposed in Japanese Patent No. 3-123322, even if each of Ag and Ru is contained alone, there is no effect of improving corrosion resistance in a non-oxidizing environment. This is because the hydrogen overvoltage of these precious metals is relatively large.
This is because the effect of rapidly promoting the anodic polarization of T and promoting the formation of TlO2 is small.
また、Ｔｉに対してＮｉ５Ｐｄ、Ｒｕのみを単独で０．
００５〜２．０ｗｔ％含有させても、非酸化性環境にお
いては従来のＴｉ−Ｐｄ合金と同等の耐蝕性は示さない
。In addition, Ni5Pd and Ru alone were added at 0.
Even if it is contained in an amount of 0.005 to 2.0 wt%, it does not exhibit corrosion resistance equivalent to that of conventional Ti-Pd alloys in a non-oxidizing environment.
しかし、ＴｉにＮｉ１Ｆｄ、Ｒｕを０．ＱＯ５−２，Ｑ
ｖｔ％含有させ、さらに、Ａｇを０．００５〜１．５ｗ
ｔ％含有させると、これらの合金元素の相乗効果によっ
て、耐蝕性は顕著に改善されてＴｉ−Ｐｄ合金と同等ま
たはそれ以上となる。However, Ti, Ni1Fd, and Ru were added to 0. QO5-2,Q
vt% and further contains 0.005 to 1.5 w of Ag.
When t% is contained, the synergistic effect of these alloying elements significantly improves the corrosion resistance to be equal to or higher than that of Ti--Pd alloy.
本発明に係る耐蝕性Ｔｉ合金の含有成分および成分割合
について説明する。The components and component ratios of the corrosion-resistant Ti alloy according to the present invention will be explained.
［実 施 例］
本発明に係る耐蝕性Ｔ１基合金の実施例を比較例と共に
説明する。[Example] Examples of the corrosion-resistant T1-based alloy according to the present invention will be described together with comparative examples.
実施例
第１表に示すＴｉ合金を、スポンジチタン（ＪＩＳｔ種
）に含有成分の金属粉末を各成分割合を変化させて含有
させ、真空アーク溶解炉において溶解して鋳塊を製造し
た。EXAMPLES The Ti alloys shown in Table 1 were mixed with titanium sponge (JISt type) and metal powders were mixed in varying proportions of each component, and the mixture was melted in a vacuum arc melting furnace to produce an ingot.
また、比較例として、スポンジチタン（ＪＩＳ１種）の
みの純Ｔｉ鋳塊を溶製した。Further, as a comparative example, a pure Ti ingot made of only sponge titanium (JIS Class 1) was melted.
これらの鋳塊を熱間鍛造および熱間圧延を行なって、１
、 Ｏｔｍｍの板を製作した。These ingots are hot forged and hot rolled to produce 1
, I made an Otmm board.
この板を真空焼鈍寝熱処理を行なった後、２０Ｄｎ＋ｎ
＋Ｘ １ ｔＩＩ＋ｍの腐蝕試験片を採取した。After performing vacuum annealing heat treatment on this plate, 20Dn+n
+X 1 tII+m corrosion test pieces were taken.
さらに、比較例として、市販の６２相当材（純Ｔｉ）、
Ｇ７相当材（Ｔｉ−０，１５Ｐｄ）、Ｇ１２相当材（Ｔ
ｉ−０，８Ｎｉ−０，３Ｍｏ）を併せて製作した。Furthermore, as a comparative example, a commercially available material equivalent to 62 (pure Ti),
G7 equivalent material (Ti-0,15Pd), G12 equivalent material (T
i-0,8Ni-0,3Mo) were also produced.
以下説明する試験により評価試験を行なった。Evaluation tests were conducted using the tests described below.
４２５ＭｇＣ１ｍ 隙間腐蝕浸漬試験この試験は、
第１図に示すＴｊボルト１、Ｔ、Ｐ３、マルチクレビス
φ２０帥（溝付き、テフロン）４、Ｔｉナツト２を組立
た治具を隙間腐蝕環境を模擬した４２％ＭｇＣＬｔ溶液
中に４８時間浸漬して、隙間腐蝕発生数により評価した
。425MgC1m Crevice corrosion immersion test This test is
A jig assembled with Tj bolts 1, T, P3, multi-clevis φ20 (grooved, Teflon) 4, and Ti nut 2 shown in Fig. 1 was immersed for 48 hours in a 42% MgCLt solution simulating a crevice corrosion environment. Evaluation was made based on the number of crevice corrosion occurrences.
第２表に耐隙間腐蝕性試験の結果を示す。Table 2 shows the results of the crevice corrosion resistance test.
第１表
第２表
○ ・・・ 隙間腐蝕発生なし
× ・・・ 隙間腐蝕発生あり
この第２表から明らかなように、本発明に係る耐蝕性Ｔ
ｉ基合金は、４２％ＭｇＣｌ、沸騰溶液中で２４時間浸
漬した場合の試験において、優れた耐隙間腐蝕性を示し
ていることかわかる。Table 1 Table 2 ○ ... No crevice corrosion occurred × ... Crevice corrosion occurred As is clear from this Table 2, the corrosion resistance T according to the present invention
It can be seen that the i-base alloy exhibits excellent crevice corrosion resistance in a test when immersed in a 42% MgCl boiling solution for 24 hours.
次に、本発明に係る耐蝕性Ｔｉ基合金の塩酸に対する全
面腐蝕性評価試験について第２図〜第５図により説明す
る。Next, a full-surface corrosion evaluation test against hydrochloric acid of the corrosion-resistant Ti-based alloy according to the present invention will be explained with reference to FIGS. 2 to 5.
第２図はＮｉ ０．４ｖｔ％、Ｐｄ ０．０１４ｖｔ％
、Ｒｕ０．０２６ｖｔ％と一定とし、Ａｇの含有量を変
化させた場合に、Ｔｉ基合金の２％ＨＣＩ沸騰溶液中に
おける２４時間の浸漬試験結果を示しである。Figure 2 shows Ni 0.4vt% and Pd 0.014vt%.
, the results of a 24-hour immersion test of a Ti-based alloy in a 2% HCI boiling solution when Ru is constant at 0.026 vt% and the Ag content is varied.
即ち、Ａｇ含有量を０．１ｗｔ％以上とすることにより
、耐蝕性が明らかに改善されていることかわかる。That is, it can be seen that the corrosion resistance is clearly improved by setting the Ag content to 0.1 wt% or more.
また、Ａｇ含有量を０．２ｖｔ％とすることにより、Ｇ
７相当材（Ｔｉ−０，１５Ｐｄ）より優れた耐蝕性を示
した。In addition, by setting the Ag content to 0.2vt%, G
It exhibited superior corrosion resistance to the material equivalent to No. 7 (Ti-0,15Pd).
第３図は、Ａｇ含有＠ ０．２ｗｔ％、Ｐｄ／Ｒｕ＝１
／２、Ｐｄ＋Ｒｕ＝０．（１４ｖｔ％と一定にし、Ｎｉ
含有量を変化させた場合に、本発明に係る耐蝕性Ｔｉ基
合金の２％ＨＣＩ沸騰溶液中における２４時間の浸漬結
果を示しである。Figure 3 shows Ag content @ 0.2wt%, Pd/Ru=1
/2, Pd+Ru=0. (Keep it constant at 14vt%, Ni
3 shows the results of immersion of the corrosion-resistant Ti-based alloy according to the present invention in a 2% HCI boiling solution for 24 hours when the content was varied.
即ち、Ｎ１含有重が増加するに従って腐蝕速度が減少し
ていることがわかる。That is, it can be seen that the corrosion rate decreases as the N1 content increases.
第４図はＡｇ含有量０．２ｔｖｔ％と一定とし、Ｎ１１
Ｐｄ、Ｒｕの含有量を変化させた場合の、本発明に係る
耐蝕性Ｔｉ基合金の２％ＨＣＩ沸騰溶液中において２時
間の浸漬結果を示しである。In Figure 4, the Ag content is constant at 0.2 tvt%, and N11
This figure shows the results of immersion of the corrosion-resistant Ti-based alloy according to the present invention in a 2% HCI boiling solution for 2 hours when the contents of Pd and Ru were varied.
即ち、Ｎｉ５Ｐｄ、Ｒｕの含有量が増加するに従って腐
蝕速度が減少しているが、ＮｉよりもＰｄ。That is, as the content of Ni5Pd and Ru increases, the corrosion rate decreases, but the corrosion rate decreases with Pd than with Ni.
ＲｕさらにＲｕよりＰｄの方が腐蝕速度か小さく優れて
いることがわかる。It can be seen that the corrosion rate of Pd is lower than that of Ru and is superior to Ru.
第５図は実施例の第１表に示しである、本発明に係る耐
蝕性Ｔ１基合金の■〜［株］の幾つかの例および比較例
■純Ｔｌ（Ｇ２相当材）、比較例■Ｔｉ０．８Ｎｉ−０
，３Ｍｏ（ＣＩ ２相当材）、比較例■Ｔｉ０．２Ａｇ
（０，２Ａｇ）、比較例■Ｔｉ−０，５Ｎｉ（０，５Ｎ
ｊ）等を２％沸！ＨＣＩ溶液中において２４時間浸漬し
た場合の浸漬結果を示しである。FIG. 5 shows some examples and comparative examples of corrosion-resistant T1-based alloys according to the present invention, which are shown in Table 1 of the Examples. ■ Pure Tl (G2 equivalent material), comparative example ■ Ti0.8Ni-0
, 3Mo (CI 2 equivalent material), comparative example ■Ti0.2Ag
(0,2Ag), Comparative example ■Ti-0,5Ni (0,5N
Boil j) etc. at 2%! This figure shows the results of immersion in an HCI solution for 24 hours.
即ち、本発明に係る耐蝕性Ｔｉ基合金は、比較例■〜■
のＴｌ−（ｐｄ、ＲＬＩ）材と同等かそれ以上に小さく
優れていることを示し、また、比較例■〜■のＴｉ基合
金より著しく腐蝕速度が小さいことを示している。That is, the corrosion-resistant Ti-based alloy according to the present invention is
The results show that the corrosion rate of the Ti-based alloys is significantly lower than that of the Ti-based alloys of Comparative Examples (1) to (2).
従って、本発明に係る耐蝕性Ｔｉ基合金は非酸化性環境
において優れた耐蝕性（腐蝕速度が極めて小さいこと。Therefore, the corrosion-resistant Ti-based alloy according to the present invention has excellent corrosion resistance (extremely low corrosion rate) in a non-oxidizing environment.
）を示していることがわかる。).
［発明の効果］
以上説明したように、本発明に係る耐蝕性Ｔｉ基合金は
上記の構成を有しているものであるから、非酸化性の環
境における耐蝕性に優れており、かつ、優れた耐隙間腐
蝕性をも併せて有しており、従来の耐蝕性Ｔｉ基合金の
問題点を著しく改善した極めて優れた高耐蝕性のＴｉ基
合金である。[Effects of the Invention] As explained above, since the corrosion-resistant Ti-based alloy according to the present invention has the above-mentioned structure, it has excellent corrosion resistance in a non-oxidizing environment. It also has crevice corrosion resistance, and is an extremely excellent highly corrosion-resistant Ti-based alloy that has significantly improved the problems of conventional corrosion-resistant Ti-based alloys.
第１図は耐隙間腐蝕性を試験するための治具、第２図は
Ａｇの含有量を変化させ、他の合金元素含有量は一定と
した場合の、ＨＣＩ浸漬試験におする腐蝕速度を示した
図、第３図はＮｉ含有量を変化させ、他の合金元素含有
量を一定とした場合の、ＨＣＩ浸漬試験における腐蝕速
度を示す図、第４図はＡｇ含有量を一定とした場合の、
ＨＣＩ浸漬試験における腐蝕速度を示した図、第５図は
本発明のに係る耐蝕性Ｔｉ基合金の実施例および比較例
のＨＣＩ浸漬試験における腐蝕速度を示した図である。
１−−−Ｔｉｂｏｌｔ、 ２−−−Ｔｉｎｕｔ、 ３
−・Ｔ、Ｐ、４・・・マルチクレビス。
才１図
４蝕Ｊ虚
（−−／Ｙつ
牙４
図
０．００１
１
〜）ＰｄＲυ（ｕ！ｔｚ）Figure 1 shows a jig for testing crevice corrosion resistance, and Figure 2 shows the corrosion rate in the HCI immersion test when the Ag content is varied and the other alloy element contents are constant. Figure 3 shows the corrosion rate in the HCI immersion test when the Ni content is changed and the other alloying element contents are constant, and Figure 4 is when the Ag content is constant. of,
FIG. 5 is a diagram showing the corrosion rate in the HCI immersion test of the corrosion-resistant Ti-based alloy according to the present invention and a comparative example. 1---Tibolt, 2---Tinut, 3
-・T, P, 4...Multi clevis. 1 figure 4 eclipse J imaginary (--/Ytsuga 4 figure 0.001 1 ~)PdRυ(u!tz)
Claims (1)
０ｗｔ％、Ｒｕ０．００５〜２．０ｗｔ％ の１種以上 を含有し、残部がＴｉおよび不可避不純物からなること
を特徴とする耐蝕性Ｔｉ基合金。[Claims] Contains 0.005 to 1.5 wt% of Ag, and further contains 0.005 to 2.0 wt% of Ni, and 0.005 to 2.0 wt% of Pd.
A corrosion-resistant Ti-based alloy, characterized in that it contains at least one of the following: 0 wt%, Ru: 0.005-2.0 wt%, and the remainder consisting of Ti and unavoidable impurities.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2069066A JPH03267335A (en) | 1990-03-19 | 1990-03-19 | Corrosion resistant ti-based alloy |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2069066A JPH03267335A (en) | 1990-03-19 | 1990-03-19 | Corrosion resistant ti-based alloy |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03267335A true JPH03267335A (en) | 1991-11-28 |
Family
ID=13391831
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2069066A Pending JPH03267335A (en) | 1990-03-19 | 1990-03-19 | Corrosion resistant ti-based alloy |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03267335A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100480934B1 (en) * | 2002-12-05 | 2005-04-07 | 주식회사 바이오머테리얼즈코리아 | Ti-Ag ALLOY FOR USE OF BIO-MATERIALS HAVING EXCELLENT STRENGTH AND CORROSION RESISTANCE |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50102982A (en) * | 1974-01-21 | 1975-08-14 | ||
| JPH02167644A (en) * | 1988-12-20 | 1990-06-28 | Olympus Optical Co Ltd | Transfer device for lens |
-
1990
- 1990-03-19 JP JP2069066A patent/JPH03267335A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50102982A (en) * | 1974-01-21 | 1975-08-14 | ||
| JPH02167644A (en) * | 1988-12-20 | 1990-06-28 | Olympus Optical Co Ltd | Transfer device for lens |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100480934B1 (en) * | 2002-12-05 | 2005-04-07 | 주식회사 바이오머테리얼즈코리아 | Ti-Ag ALLOY FOR USE OF BIO-MATERIALS HAVING EXCELLENT STRENGTH AND CORROSION RESISTANCE |
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