JPH03264636A - Forged member of al-si alloy powder reduced in attack on mating member - Google Patents

Forged member of al-si alloy powder reduced in attack on mating member

Info

Publication number
JPH03264636A
JPH03264636A JP6224890A JP6224890A JPH03264636A JP H03264636 A JPH03264636 A JP H03264636A JP 6224890 A JP6224890 A JP 6224890A JP 6224890 A JP6224890 A JP 6224890A JP H03264636 A JPH03264636 A JP H03264636A
Authority
JP
Japan
Prior art keywords
alloy powder
forged member
forged
alloy
mating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP6224890A
Other languages
Japanese (ja)
Inventor
Koichiro Morimoto
耕一郎 森本
Masaharu Kobayashi
小林 政春
Kazuyuki Hoshino
和之 星野
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Materials Corp
Original Assignee
Mitsubishi Materials Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Materials Corp filed Critical Mitsubishi Materials Corp
Priority to JP6224890A priority Critical patent/JPH03264636A/en
Publication of JPH03264636A publication Critical patent/JPH03264636A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To obtain a forged member of Al-Si alloy powder reduced in attacks on mating materials by uniformly dispersing specific amounts of multiple Al oxide into the matrix of a forged member of an Al-Si alloy powder having a specific composition containing Cu, Mg, Fe, Ni, and Mn. CONSTITUTION:A structure in which multiple Al oxide is uniformly dispersed by 5-20vol.% into the matrix of a forged member of an Al-Si alloy powder having a composition consisting of, by weight, 15-40% Si, 0.5-5% Cu, 0.5-3% Mg, 0.5-5% of one or more elements among Fe, Ni, and Mn, and the balance Al is formed. As the above multiple Al oxide, one or more kinds among cordierite, aluminum silicate, lithium aluminum silicate, and aluminum titanate are used. By this method, the forged member of Al-Si alloy excellent in wear resistance, having low coefficient of thermal expansion, and reduced in attacks on mating members can be obtained.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 この発明は、エンジン、コンプレッサー等の各種機械部
品、特に摺動機械部品として使用した場合に優れた特性
を発揮する低熱膨張係数を有し、耐摩耗性に優れ、かつ
相手部材に対する攻撃性(以下、相手攻撃性という)の
少ないAl−Si系合金粉末鍛造部材に関するものであ
る〔従来の技術〕 急冷凝固法により多量のSiを含有したAl5i系合金
粉末を原料粉末とし、粉末冶金法により得られるAN−
5i系合金部材は知られており、このAl2−Si系合
金部材を用いて各種機械部品を製造することは広く行わ
れている。このAl5i系合金部祠は、S i:12−
35%、Cu:10%以下、Mg:3%以下、残部:A
lおよび不可避不純物から成り(以上、%は、重量%)
、微細な初晶Siと平均粒径:3〜60turlのアル
ミナの硬質粒子二3〜25重量%が均一に分散した押出
部材の組織を有しく特開昭59−182242号公報参
照)、上記均一に分散しているアルミナの硬質粒子は、
耐摩耗性を向上せしめかつ低熱膨脹係数をもたらす作用
があることも知られている。
[Detailed Description of the Invention] [Field of Industrial Application] This invention has a low thermal expansion coefficient that exhibits excellent characteristics when used as various mechanical parts such as engines and compressors, especially sliding mechanical parts, This relates to an Al-Si alloy powder forged member that has excellent wear resistance and is less aggressive to mating members (hereinafter referred to as mating aggressiveness) [Prior art] Al5i containing a large amount of Si by rapid solidification. AN- series alloy powder is used as the raw material powder and obtained by powder metallurgy method.
BACKGROUND ART 5i alloy members are known, and various mechanical parts are widely manufactured using these Al2-Si alloy members. This Al5i alloy part shrine is S i:12-
35%, Cu: 10% or less, Mg: 3% or less, balance: A
1 and unavoidable impurities (% is weight %)
, the extruded member has a structure in which fine primary crystal Si and hard particles of alumina having an average particle size of 3 to 60 turl are uniformly dispersed in an amount of 23 to 25% by weight (see JP-A-59-182242), the above-mentioned uniform The hard particles of alumina dispersed in
It is also known to have the effect of improving wear resistance and providing a low coefficient of thermal expansion.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

しかしながら、上記従来のアルミナの硬質粒子が素地中
に均一に分散しているAI−Si系合金部材は、耐摩耗
性がすぐれかつ低熱膨脹係数を有するが、アルミナの硬
質粒子は素地から脱落しやすいために脱落した硬質粒子
が摺動する相手部材を摩耗し、相手攻撃性が高くなると
いう問題点があった。
However, although the conventional AI-Si alloy member in which hard alumina particles are uniformly dispersed in the base material has excellent wear resistance and a low coefficient of thermal expansion, the hard alumina particles easily fall off from the base material. Therefore, there was a problem in that the hard particles that fell off abraded the mating member on which it slid, increasing the ability to attack the mating member.

〔課題を解決するための手段〕[Means to solve the problem]

そこで、本発明者らは、アルミナの硬質粒子が素地から
脱落するのを防止すべく研究を行った結果、 硬質粒子をAIの複合酸化物の形でAI−Si系合金素
地中に均一に分散せしめると、素地から脱落するのを防
止することができるという知見を得たのである。
Therefore, the present inventors conducted research to prevent the hard particles of alumina from falling off the base material, and as a result, the hard particles were uniformly dispersed in the AI-Si alloy base in the form of an AI composite oxide. They found that if they were allowed to grow, it would be possible to prevent them from falling off the substrate.

この発明は、かかる知見にもとづいてなされたものであ
って、 S i:15〜40%、Cu:0.5〜5%、Mg:0
.5〜3%、Fe 、Ni 、Mnのうち1種または2
種以上:0.5〜5%(以上、%は、重量%)を含有し
、AI:残部から成るAI−Si系合金粉末鍛造部材の
素地中にアルミニウム複合酸化物の1種または2種以上
=5〜20容量%が均一に分散した組織を有する相手攻
撃性の少ないAl−Si系合金粉末鍛造部材に特徴を有
するものである。
This invention was made based on this knowledge, Si: 15-40%, Cu: 0.5-5%, Mg: 0
.. 5-3%, one or two of Fe, Ni, Mn
Species or more: 0.5 to 5% (or more, % is weight %), and AI: One or more types of aluminum composite oxide in the base material of an AI-Si alloy powder forged member consisting of the balance. It is characterized by an Al--Si based alloy powder forged member having a uniformly dispersed structure of 5 to 20% by volume and less aggressiveness to others.

上記アルミニウム複合酸化物は、コージェライ)   
(2MgO・ 2 Ap 2 03  ・ 5 S i
 O2) 、  アルミニウム・ケイ酸塩(Al203
・S iO2)、リチウム・アルミニウム・ケイ酸塩(
LiO・A I) 20 a Φ2SiO2)、チタン
酸アルミニウム(Al203ψT iO2)のうちのい
ずれかであることが好ましい。
The above aluminum composite oxide is
(2MgO・2Ap203・5Si
O2), aluminum silicate (Al203
・SiO2), lithium aluminum silicate (
It is preferably either LiO.A I) 20 a Φ2SiO2) or aluminum titanate (Al203ψT iO2).

つぎに、この発明のAI−Si系合金粉末鍛造部材の成
分組成およびアルミニウム複合酸化物の分散割合いを限
定した理由を説明する。
Next, the reason why the component composition and the dispersion ratio of the aluminum composite oxide of the AI-Si based alloy powder forged member of the present invention are limited will be explained.

(a)  5t St酸成分、初晶Stを析出させてAn)−Si系合金
の耐摩耗性を向上せしめ、熱膨脹係数を低下させる効果
があるが、その含有量が10重量%未満では十分な効果
は得られず、一方、40重量%を越えて含有すると脆化
するので好ましくない。したがって、Si成分含有量は
、10〜40重量%に定めた。
(a) 5t St acid component, which precipitates primary St crystals, has the effect of improving the wear resistance of the An)-Si alloy and lowering the coefficient of thermal expansion, but if its content is less than 10% by weight, it is not sufficient. On the other hand, if the content exceeds 40% by weight, it becomes brittle, which is not preferable. Therefore, the Si component content was set at 10 to 40% by weight.

(b)  CuおよびMg CuおよびMg成分は、共に、熱処理時に微細な金属間
化合物として析出し、AR−Si系合金に時効硬化性を
付与する成分であるが、その含有量がそれぞれCu:0
.5重量%未満、Mg:0゜5重量%未満では十分な時
効硬化が得られず、一方、Cuが5重量%を越えるかま
たはMgが3重量%を越えると脆化し、熱間加工性の低
下を来たすので好ましくない。したがって、Cuおよび
Mgの含有量は、それぞれCu:0.5〜5重量%、M
g:0.5〜3重量%に定めた。
(b) Cu and Mg Both Cu and Mg components precipitate as fine intermetallic compounds during heat treatment and are components that impart age hardenability to AR-Si alloys, but their content is Cu:0.
.. If Cu exceeds 5% by weight or Mg exceeds 3% by weight, sufficient age hardening will not be obtained. This is not preferable because it causes deterioration. Therefore, the contents of Cu and Mg are Cu: 0.5 to 5% by weight, Mg
g: determined at 0.5 to 3% by weight.

(c)  Fe 、 Ni 、 Mn Fe、NiおよびMn成分は、共に、Al5t系合金に
含まれて素地の熱膨脹係数を低下させかつ高温における
強度を向上させる効果があるが、それら含有量が0.5
重量%未満では所望の効果が得られず、一方、それら含
有量が5重量%を越えると脆化するので好ましくない。
(c) Fe, Ni, Mn Both Fe, Ni and Mn components are contained in the Al5t alloy and have the effect of lowering the coefficient of thermal expansion of the base material and improving the strength at high temperatures, but if their content is 0. 5
If the content is less than 5% by weight, the desired effect cannot be obtained, while if the content exceeds 5% by weight, it becomes brittle, which is not preferable.

したがって、Fe、NjおよびMnの含有量は0.5〜
5重量%に定めた。
Therefore, the content of Fe, Nj and Mn is 0.5~
It was set at 5% by weight.

(d)  アルミニウム複合酸化物 アルミニウム複合酸化物は、AI−Si系合金素地中に
分散して耐摩耗性を向上せしめ、熱膨脹係数を低下させ
る効果があるが、その含有量が5容量%未満では所望の
効果が得られず、一方、その含有量が20容量%を越え
ると脆化が著しく鍛造することが困難になるので好まし
くない。したがって、アルミナ複合酸化物の含有量は5
〜20容量%に定めた。
(d) Aluminum composite oxide Aluminum composite oxide is effective in improving wear resistance and lowering the coefficient of thermal expansion when dispersed in the AI-Si alloy matrix, but if its content is less than 5% by volume, On the other hand, if the content exceeds 20% by volume, the content will become extremely brittle and difficult to forge, which is not preferable. Therefore, the content of alumina composite oxide is 5
It was set at ~20% by volume.

ら 〔実 施 例〕 つぎに、この発明を実施例に基づいて具体的に説明する
[Examples] Next, the present invention will be specifically explained based on Examples.

第1表に示される成分組成を有するAl−Si系合金溶
湯を空気アトマイズして調製した平均粒径:45祠のA
p−Si系合金粉末、 平均粒径:13虜のコージェライト(2MgO・2Al
203・5SiO2)粉末、 平均粒径:10虜のアルミニウム・ケイ酸塩(Al20
3・5iO2)粉末、 平均粒径:15庫のリチウム・アルミニウム・ケイ酸塩
(LiO−Al 0 ・2 S iO2)粉末、3 平均粒径:12t1mのチタン酸アルミニウム(AF 
 O−T iO2)粉末、 3 平均粒径:iO廂のアルミナ(Al203)粉末、をそ
れぞれ原料粉末として用意し、これら原料粉末を所定の
割合いで配合し、室温において圧力=5ton/c−で
金型成形し、たて:8Bmms横:8mm5高さ: 1
7.4mmの寸法を有しかつ密度比:80%を有する成
形体を作製した。ついて、この成形体を窒素雰囲気中、
温度=400℃、1時間保持の条件で熱処理を施して脱
ガスしたのち、引続きこの成形体を窒素雰囲気中、温度
:500℃に15分間加熱保持したのち、8ton/c
Illの圧力で熱間鍛造を施し、密度比がほぼ100%
でたて: 40mm、横:iO祁、高さ:10mmの寸
法を有する熱間鍛造体を製造した。
Average particle size: A of 45 K, prepared by air atomizing a molten Al-Si alloy having the composition shown in Table 1.
p-Si alloy powder, average particle size: 13mm cordierite (2MgO・2Al
203.5SiO2) powder, average particle size: 10mm aluminum silicate (Al20
Lithium aluminum silicate (LiO-Al 0 ・2 SiO2) powder, average particle size: 15 tons, aluminum titanate (AF) powder, average particle size: 12t1m
O-T iO2) powder and alumina (Al203) powder with an average particle size of 3 iO were prepared as raw material powders, these raw material powders were blended in a predetermined ratio, and gold was heated at room temperature under a pressure of 5 ton/c-. Mold molded, length: 8Bmms width: 8mm5 height: 1
A molded body having a dimension of 7.4 mm and a density ratio of 80% was produced. Then, this molded body was placed in a nitrogen atmosphere.
After degassing by heat treatment at a temperature of 400°C and holding for 1 hour, the molded body was heated and held at a temperature of 500°C for 15 minutes in a nitrogen atmosphere, and then heated to 8 ton/c.
Hot forged under 100% pressure, density ratio is almost 100%
A hot forged body having dimensions of 40 mm in length, 10 mm in width and 10 mm in height was produced.

この熱間鍛造体は直ちに水冷の溶体化処理したのち、最
終的に温度170℃、6時間保持の時効処理し、第1表
に示される成分組成の素地にアルミニウム複合酸化物が
第1表に示される割合いで均一分散した本発明Aρ−s
i系合金粉末鍛造部材1〜20および比較Al−8t系 1〜8、並びにアルミナが第1表に示される割合いで均
一分散した従来Aρ−8j系合金粉末鍛造部材1を作製
した。
This hot forged body was immediately subjected to water-cooling solution treatment, and then finally aged at a temperature of 170°C for 6 hours. Aρ-s of the present invention uniformly dispersed in the indicated proportions
I-series alloy powder forged members 1 to 20, comparative Al-8t-series 1 to 8, and conventional Aρ-8j-series alloy powder forged member 1 in which alumina was uniformly dispersed in the proportions shown in Table 1 were produced.

これら本発明Al−3t系 1〜20、比較AN−8t系合金粉末鍛造部Jr11〜
8および従来A.l!−8j系合金粉末鍛造部材1を第
1図のブロック1として用い、一方、相手部材として外
径:40mAlls内径: 30mm5幅:l5mmの
寸法特開平3 264636 (5) を有し、545C(HRC: 3(1,焼入れ焼戻し)
鋼材で作製したリング2を用意し、第1図に示されるよ
うに、ブロック1をリング2の外周に接するように組合
わせ、ブロック1に荷重: 10kgをかけ、冷凍機油
を潤滑油3としてリング2の外周に供給しながらリング
2を周速度25m7秒、1時間回転せしめる試験法によ
りブロック1の耐摩耗性および相手攻撃性を測定した。
These invention Al-3t series 1 to 20, comparative AN-8t series alloy powder forged parts Jr11 to
8 and conventional A. l! A -8J alloy powder forged member 1 is used as the block 1 in Fig. 1, and a mating member has dimensions of JP-A-3 264636 (5), outer diameter: 40 mAll inner diameter: 30 mm, width: 15 mm, and 545C (HRC: 3 (1, quenching and tempering)
A ring 2 made of steel was prepared, and as shown in Fig. 1, a block 1 was assembled so as to be in contact with the outer circumference of the ring 2, a load of 10 kg was applied to the block 1, and the ring was assembled using refrigerating machine oil as a lubricating oil 3. The abrasion resistance and attack resistance of the block 1 were measured by a test method in which the ring 2 was rotated at a circumferential speed of 25 m for 7 seconds for 1 hour while being supplied to the outer circumference of the block 1.

耐摩耗性は、摺動回転するリング2によって第1図の点
線4で示されるようにブロック1が摩耗した時の摩耗幅
aを測定し、その測定結果を第1表に示して評価し、相
手攻撃性は、リング2の外周表面に形成された表面粗さ
R値を測定し、ax その測定結果を第1表に示して評価した。
Wear resistance was evaluated by measuring the wear width a when the block 1 was worn by the sliding and rotating ring 2 as shown by the dotted line 4 in FIG. 1, and the measurement results are shown in Table 1. The opponent aggressiveness was evaluated by measuring the R value of the surface roughness formed on the outer peripheral surface of the ring 2, and the measurement results are shown in Table 1.

第1表の結果から、本発明のAΩ−Si系合金粉末鍛造
部材1〜20は、従来AΩ−Si系合金粉末鍛造部材1
に比べて相手攻撃性が格段に小さく、また、この発明の
条件から外れている比較AΩ−81系合金粉末鍛造部材
1〜8(この発明の条件から外れている値に※印を付し
て第1表に示した)は、耐摩耗性が劣るかまたは相手攻
撃性が大きくなることがわかる。
From the results in Table 1, it can be seen that the AΩ-Si alloy powder forged members 1 to 20 of the present invention are different from the conventional AΩ-Si alloy powder forged members 1.
Comparative AΩ-81 series alloy powder forged members 1 to 8, which have much lower attack potential than those of the present invention, and which are outside the conditions of this invention (values outside the conditions of this invention are marked with *) (shown in Table 1) are found to have inferior abrasion resistance or to be more aggressive against opponents.

〔発明の効果〕〔Effect of the invention〕

この発明によると、従来のAl−8I系合金粉末鍛造部
材よりも特に相手攻撃性が格段に小さいAl−8I系合
金粉末鍛造部材を提供することができ、機械部品などの
寿命を延ばすことができるなどの優れた効果を奏するも
のである。
According to the present invention, it is possible to provide an Al-8I alloy powder forged member that is much less aggressive than conventional Al-8I alloy powder forged members, and the life of mechanical parts can be extended. It has excellent effects such as:

【図面の簡単な説明】[Brief explanation of drawings]

第1図は、All−8I系合金粉末鍛造部祠の耐摩耗性
および相手攻撃性をハIlj定するための装置の概略図
である。
FIG. 1 is a schematic diagram of an apparatus for determining the wear resistance and attack resistance of an All-8I alloy powder forged part.

Claims (2)

【特許請求の範囲】[Claims] (1)Si:15〜40%、Cu:0.5〜5%、Mg
:0.5〜3%、Fe、Ni、Mnのうち1種または2
種以上:0.5〜5%(以上、%は、重量%)を含有し
、Al:残部から成るAl−Si系合金粉末鍛造部材の
素地中にアルミニウム複合酸化物:5〜20容量%が均
一に分散した組織を有することを特徴とする相手部材に
対する攻撃性の少ないAl−Si系合金粉末鍛造部材。
(1) Si: 15-40%, Cu: 0.5-5%, Mg
:0.5-3%, one or two of Fe, Ni, Mn
Aluminum composite oxide: 5 to 20% by volume in the base material of an Al-Si alloy powder forged member consisting of 0.5 to 5% (or more, % is weight %) of seeds or more, and the balance being Al. An Al-Si alloy powder forged member having a uniformly dispersed structure and less aggressive against mating members.
(2)上記アルミニウム複合酸化物は、コージェライト
、アルミニウムケイ酸塩、リチウムアルミニウムケイ酸
塩、チタン酸アルミニウムのうちの1種または2種以上
であることを特徴とする請求項1記載の相手部材に対す
る攻撃性の少ないAl−Si系合金粉末鍛造部材。
(2) The mating member according to claim 1, wherein the aluminum composite oxide is one or more of cordierite, aluminum silicate, lithium aluminum silicate, and aluminum titanate. An Al-Si alloy powder forged member that is less aggressive against.
JP6224890A 1990-03-13 1990-03-13 Forged member of al-si alloy powder reduced in attack on mating member Pending JPH03264636A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP6224890A JPH03264636A (en) 1990-03-13 1990-03-13 Forged member of al-si alloy powder reduced in attack on mating member

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6224890A JPH03264636A (en) 1990-03-13 1990-03-13 Forged member of al-si alloy powder reduced in attack on mating member

Publications (1)

Publication Number Publication Date
JPH03264636A true JPH03264636A (en) 1991-11-25

Family

ID=13194652

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6224890A Pending JPH03264636A (en) 1990-03-13 1990-03-13 Forged member of al-si alloy powder reduced in attack on mating member

Country Status (1)

Country Link
JP (1) JPH03264636A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013227658A (en) * 2012-03-30 2013-11-07 Sumitomo Electric Sintered Alloy Ltd Sliding member and manufacturing method of sliding member
CN103540810A (en) * 2013-10-17 2014-01-29 常熟市良益金属材料有限公司 Aluminum-silicon alloy

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013227658A (en) * 2012-03-30 2013-11-07 Sumitomo Electric Sintered Alloy Ltd Sliding member and manufacturing method of sliding member
CN103540810A (en) * 2013-10-17 2014-01-29 常熟市良益金属材料有限公司 Aluminum-silicon alloy

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