JPH03239542A - Highly weatherable lysing sheet - Google Patents
Highly weatherable lysing sheetInfo
- Publication number
- JPH03239542A JPH03239542A JP3557090A JP3557090A JPH03239542A JP H03239542 A JPH03239542 A JP H03239542A JP 3557090 A JP3557090 A JP 3557090A JP 3557090 A JP3557090 A JP 3557090A JP H03239542 A JPH03239542 A JP H03239542A
- Authority
- JP
- Japan
- Prior art keywords
- sheet
- aggregate
- coating
- fluoro
- stain resistance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 230000002934 lysing effect Effects 0.000 title 1
- 239000011248 coating agent Substances 0.000 claims abstract description 12
- 238000000576 coating method Methods 0.000 claims abstract description 12
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 8
- 239000011737 fluorine Substances 0.000 claims description 8
- 229910052731 fluorine Inorganic materials 0.000 claims description 8
- 108010039491 Ricin Proteins 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 9
- 239000004576 sand Substances 0.000 abstract description 3
- 239000000377 silicon dioxide Substances 0.000 abstract description 3
- KDXKERNSBIXSRK-UHFFFAOYSA-N Lysine Natural products NCCCCC(N)C(O)=O KDXKERNSBIXSRK-UHFFFAOYSA-N 0.000 abstract description 2
- 239000004472 Lysine Substances 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
- 239000000463 material Substances 0.000 description 14
- 230000000694 effects Effects 0.000 description 6
- 239000003973 paint Substances 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000002655 kraft paper Substances 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- -1 shirasu balloon Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical class FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
- 102100027262 Electron transfer flavoprotein subunit beta Human genes 0.000 description 1
- 101001057122 Homo sapiens Electron transfer flavoprotein subunit beta Proteins 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000004049 embossing Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920002493 poly(chlorotrifluoroethylene) Polymers 0.000 description 1
- 239000005023 polychlorotrifluoroethylene (PCTFE) polymer Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 238000009958 sewing Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 239000010455 vermiculite Substances 0.000 description 1
- 229910052902 vermiculite Inorganic materials 0.000 description 1
- 235000019354 vermiculite Nutrition 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 235000015099 wheat brans Nutrition 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は内、外壁材の化粧材、被覆材として有用な高耐
候性リシンシートに関するものである。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a highly weather-resistant ricin sheet useful as a decorative material or coating material for interior and exterior wall materials.
一般にシート材に化粧を付加するには、エンボス加工か
、別途に縫うか、あるいは模様を貼着するかのいずれか
であった。Generally, decorative decorations have been applied to sheet materials by either embossing, sewing separately, or pasting patterns.
しかしながら、上記シート材では凹凸模様が小さく立体
感に欠ける不利があった。また、この種シートは主に内
装材に使用されるため、耐候性に欠け、しかも防火性、
防水性、耐汚染性、防カビ性にも劣る不利があった。However, the above-mentioned sheet material has a disadvantage in that the uneven pattern is small and lacks a three-dimensional effect. In addition, since this type of sheet is mainly used as an interior material, it lacks weather resistance, and is not fire retardant.
It also had the disadvantage of being inferior in waterproofness, stain resistance, and mold resistance.
本発明はこのような欠点を除去するため、可撓性のある
シート状物の表面に骨材を固着し、さらにこの表面をフ
ッソ塗膜で被覆して、立体感を醸し出すと共に、耐候性
、防火性、防水性、防カビ性、耐汚染性に富み、しかも
不燃シートを使用した際は防火性と外装材の化粧材とし
ても有用な高耐候性リシンシートを提案するものである
。In order to eliminate these drawbacks, the present invention fixes aggregate to the surface of a flexible sheet and further coats this surface with a fluorine coating to create a three-dimensional effect and improve weather resistance. We propose a highly weather-resistant ricin sheet that is rich in fire retardancy, waterproofness, mold resistance, and stain resistance, and is also useful as a fire retardant and decorative material for exterior materials when a noncombustible sheet is used.
以下に、図面を用いて本発明に係る高耐候性リシンシー
トの一実施例について詳細に説明する。DESCRIPTION OF THE PREFERRED EMBODIMENTS An embodiment of the highly weather resistant ricin sheet according to the present invention will be described in detail below with reference to the drawings.
すなわち、第１図は上記発明に係る高耐候性リシンシー
）Ａの一部を示す説明図であり、１はシート、２は骨材
、３はフッソ塗膜、４は基材である。That is, FIG. 1 is an explanatory diagram showing a part of the highly weather resistant resin sheet A according to the above invention, in which 1 is a sheet, 2 is an aggregate, 3 is a fluorine coating film, and 4 is a base material.
さらに説明すると、シート１はクラフト紙、ステンレス
シート、鉄シート、クラフト紙にアルミニウム箔をラミ
ネート、もしくは蒸着したもの、アクリル、ポリエステ
ルシート等のプラスチックシート、このシートに金属箔
をう果ネート、発泡シ−トしたもの等の１種から形成し
たものである。To explain further, sheet 1 can be made of kraft paper, stainless steel sheet, iron sheet, kraft paper laminated or vapor-deposited with aluminum foil, plastic sheet such as acrylic or polyester sheet, metal foil on this sheet, or foamed sheet. - It is formed from one type of material such as
勿論、エンボスシート、あるいは接着剤付きのシートも
含むものであり、特にフッソ塗膜３と接着性のよいもの
が好ましく、かつ可撓性のあるものである。骨材２は珪
砂、岩石、鉱物粉、ゼオライト、バーミキュライト、雲
母、アルξす、シラスバルーン、パーライト、ガラス粒
、金属粉の１種以上からなり、その大きさは約１〜２５
０メツシユ位の１種、あるいは混合物からなるものであ
る。勿論、骨材２は粒径、隔片状等の１種以上からなり
、その分布はまばら、高密度、縞状の塊、線状、模様状
等、その目的に応じて分布したものである。Of course, it includes an embossed sheet or a sheet with an adhesive, and in particular, a sheet that has good adhesion to the fluorine coating film 3 and is flexible is preferred. The aggregate 2 consists of one or more of silica sand, rock, mineral powder, zeolite, vermiculite, mica, aluminum, shirasu balloon, perlite, glass particles, and metal powder, and its size is about 1 to 25 mm.
It consists of one type or a mixture of 0 meshes. Of course, the aggregate 2 is composed of one or more types of grain size, septum shape, etc., and its distribution can be sparse, high density, striped lumps, linear, patterned, etc. depending on the purpose. .
さらにフッソ塗膜３は骨材２の露出面の被覆と耐候性の
改善に寄与するものであり、主成分としてはフッソ塗料
を用いる。このフッソ塗膜３はフッソ樹脂を主成分とし
、これにアクリル樹脂、溶剤、顔料を添加したものであ
る。上記フッソ樹脂としては（略称） ＰＴＦＥ、 Ｆ
ＥＰ 、、ＰＦＡ 、 ＥＰＢ 、 ＰＣＴＦＥ、ＰＶ
ＤＦ、 ＥＴＦＢ、 ＰＶＦ等をビヒクルの約１０〜５
０％位を含有するものである。具体的な一例を示せば、
■フルオロオレフィンービニル糸上ツマ−共重合体８０
〜４０重量部と炭素数２〜５で分子量がｉｓ、ｏｏｏ〜
４０．０００のアルキル（メタ）アクリレートを８５％
以上を含むアクリル樹脂を２０〜６０重量部、顔料、及
び硬化剤を配合した組成の塗料、アクリル変性フッ化ビ
ニリデン樹脂を主成分とし、これに紫外線吸収剤を添加
した塗料等であって、塗布時の粘度は３０〜５ｏｏｃｐ
ｓ位である。基材４としては金属板（Ｆｅ、 Ａ Ｉ
ＸＣｕ、ステンレス、チタン）、紙（ダンボール、クラ
フト紙）等の１種以上を直接、もしくは図示しない接着
剤を介して一体に固着するものである。Further, the fluorinated paint film 3 contributes to covering the exposed surface of the aggregate 2 and improving weather resistance, and a fluorinated paint is used as the main component. This fluorinated coating film 3 has a fluorinated resin as a main component, to which an acrylic resin, a solvent, and a pigment are added. The above fluorine resins (abbreviation) are PTFE, F
EP, PFA, EPB, PCTFE, PV
DF, ETFB, PVF, etc. in the vehicle about 10-5
It contains about 0%. To give a specific example,
■Fluoroolefin-vinyl yarn thread copolymer 80
~40 parts by weight and 2 to 5 carbon atoms, molecular weight is, ooo~
85% of 40.000 alkyl (meth)acrylates
Paints with compositions containing 20 to 60 parts by weight of acrylic resins containing the above, pigments, and curing agents, paints with acrylic-modified vinylidene fluoride resin as the main component and an ultraviolet absorber added thereto, etc. The viscosity is 30~5oocp
He is in s position. The base material 4 is a metal plate (Fe, AI
XCu, stainless steel, titanium), paper (cardboard, kraft paper), etc., are fixed together directly or via an adhesive (not shown).
次に製造法について簡単に説明すると、エンボス加工し
たクラフト紙（シートｌ）上に接着剤（図示せず）を介
して珪砂（骨材２）２をまばらに散布、固着し、次にフ
ッソ塗料（フッソ塗膜３）を全化粧面に塗布し、シート
１、骨材２の化粧面をフッソ塗１１３で被覆した後、乾
燥硬化する。この高耐候性リシンシー１−Ａを戸のフス
マ紙として使用した。その結果、防水性、耐汚染性にす
ぐれ、収縮もなく、立体感があり、しかも極めて美しい
外観となった。勿論、可撓性があるため、作業性、加工
性が非常によかった。Next, to briefly explain the manufacturing method, silica sand (aggregate 2) 2 is sparsely spread and fixed on embossed kraft paper (sheet 1) via an adhesive (not shown), and then fluorinated paint is applied. (Fluorine coating film 3) is applied to all decorative surfaces, and the decorative surfaces of the sheet 1 and aggregate 2 are coated with fluorine coating 113, which is then dried and hardened. This highly weather resistant Rishinshi 1-A was used as wheat bran paper for doors. As a result, it has excellent waterproofness and stain resistance, has no shrinkage, has a three-dimensional effect, and has an extremely beautiful appearance. Of course, due to its flexibility, workability and processability were very good.
以上説明したのは本発明に係る高耐候性リシンシートの
一実施例にすぎず、内、外壁材の片面、もしくは両面に
高耐候性リシンシートＡを一体に貼着することもできる
。さらに第２図（ａ）、（ｂ）に示すようにサンドイン
チ板の両面、あるいは片面にこの種の高耐候性リシンシ
ー）Ａを一体に形成することもできる。What has been described above is only one embodiment of the highly weather resistant ricin sheet according to the present invention, and the highly weather resistant ricin sheet A can also be integrally attached to one or both sides of the inner and outer wall materials. Furthermore, as shown in FIGS. 2(a) and 2(b), this type of highly weather resistant resin sheet A can be integrally formed on both sides or one side of the sandwich board.
（発明の効果〕
上述したように本発明に係る高耐候性リシンシートによ
れば、新規、既存の内外壁に貼着、もしくは装着するだ
けで立体感、耐候性、耐汚染性に富む外観を任意に形成
できる特徴がある。また、内、外装材の表面に貼着した
際は金属板のイメージを一新した板材とすることもでき
る。等の特徴、効果がある。(Effects of the Invention) As described above, the highly weather-resistant ricin sheet of the present invention can create an appearance with a three-dimensional effect, weather resistance, and stain resistance simply by attaching or attaching it to new or existing interior and exterior walls. It has the feature that it can be formed arbitrarily.Furthermore, when it is attached to the surface of an interior or exterior material, it can be used as a board material with a completely new image of a metal plate.It has the following characteristics and effects.
第１図は本発明に係る高耐候性リシンシートの一実施例
を示す拡大説明図、第２図（ａ）、（ロ）はその他の実
施例を示す説明図である。
１・・・シート、２・・・骨材、３・・・フッソ塗膜。FIG. 1 is an enlarged explanatory view showing one embodiment of a highly weather-resistant lysine sheet according to the present invention, and FIGS. 2(a) and (b) are explanatory views showing other embodiments. 1... Sheet, 2... Aggregate, 3... Fluorine coating film.
Claims (1)
して上記表面を被覆すると共に、一体に形成したことを
特徴とする高耐候性リシンシート。(1) A highly weather-resistant ricin sheet, characterized in that a fluorine coating film is applied to the surface of the sheet on which aggregate is fixed to cover the surface, and the sheet is integrally formed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3557090A JPH03239542A (en) | 1990-02-15 | 1990-02-15 | Highly weatherable lysing sheet |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3557090A JPH03239542A (en) | 1990-02-15 | 1990-02-15 | Highly weatherable lysing sheet |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03239542A true JPH03239542A (en) | 1991-10-25 |
Family
ID=12445418
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3557090A Pending JPH03239542A (en) | 1990-02-15 | 1990-02-15 | Highly weatherable lysing sheet |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03239542A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6485781B2 (en) | 1999-05-26 | 2002-11-26 | Basf Corporation | Metal roofing shingle stock and method for making it |
-
1990
- 1990-02-15 JP JP3557090A patent/JPH03239542A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6485781B2 (en) | 1999-05-26 | 2002-11-26 | Basf Corporation | Metal roofing shingle stock and method for making it |
| US6540829B2 (en) | 1999-05-26 | 2003-04-01 | Basf Corporation | Metal roofing shingle stock and method for making it |
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