JPH03234801A - Stocking - Google Patents
StockingInfo
- Publication number
- JPH03234801A JPH03234801A JP2736690A JP2736690A JPH03234801A JP H03234801 A JPH03234801 A JP H03234801A JP 2736690 A JP2736690 A JP 2736690A JP 2736690 A JP2736690 A JP 2736690A JP H03234801 A JPH03234801 A JP H03234801A
- Authority
- JP
- Japan
- Prior art keywords
- yarn
- yarns
- covering
- graft copolymer
- protein
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000835 fiber Substances 0.000 claims abstract description 23
- 229920000578 graft copolymer Polymers 0.000 claims abstract description 21
- 238000009940 knitting Methods 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 12
- 239000004952 Polyamide Substances 0.000 abstract description 5
- 229920002647 polyamide Polymers 0.000 abstract description 5
- 238000009835 boiling Methods 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 abstract description 2
- 238000010521 absorption reaction Methods 0.000 description 8
- 239000004677 Nylon Substances 0.000 description 6
- 229920001778 nylon Polymers 0.000 description 6
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 5
- 238000009792 diffusion process Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 102000004169 proteins and genes Human genes 0.000 description 5
- 108090000623 proteins and genes Proteins 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 239000002932 luster Substances 0.000 description 4
- 229920002635 polyurethane Polymers 0.000 description 4
- 239000004814 polyurethane Substances 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- 239000004744 fabric Substances 0.000 description 3
- 230000007423 decrease Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- NJYFRQQXXXRJHK-UHFFFAOYSA-N (4-aminophenyl) thiocyanate Chemical class NC1=CC=C(SC#N)C=C1 NJYFRQQXXXRJHK-UHFFFAOYSA-N 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 210000004177 elastic tissue Anatomy 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- -1 silk Polymers 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 230000035900 sweating Effects 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
Landscapes
- Socks And Pantyhose (AREA)
- Knitting Of Fabric (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、絹のような優雅な光沢のある外観品位に優れ
また、保温性、吸水拡散性が高く、べたつき感・ムレ感
のない肌触りに優れたストッキングに関する発明である
。[Detailed Description of the Invention] (Industrial Application Field) The present invention has an elegant, glossy appearance similar to silk, and has excellent heat retention, high water absorption and diffusion properties, and a texture that does not feel sticky or stuffy. This is an invention related to stockings that are excellent in quality.
ここでいう、ストッキングとは、パンティストッキング
、オーバーニーハイソックス等を総称する。Stockings herein refers to pantyhose, over-knee socks, etc.
（従来の技術）
従来、カバリングヤーン及び交編糸からなるストッキン
グまたは、カバリングヤーン１００％からなるストッキ
ングにおいて、そのカバリングヤーンの被覆糸及び／又
は交編糸にポリアミド系マルチフィラメント糸またはそ
の加工糸を使用した場合、光沢を与えるためには、糸断
面形状を異型化する方法、吸水性を高めるためには、糸
又は、製品加工糸に吸水加工を促す方法がある。(Prior Art) Conventionally, in stockings made of covering yarn and interwoven yarn, or stockings made of 100% covering yarn, polyamide multifilament yarn or processed yarn thereof is used as the covering yarn and/or interwoven yarn of the covering yarn. When used, in order to give gloss, there is a method of modifying the cross-sectional shape of the yarn, and in order to increase water absorption, there is a method of promoting water absorption processing to the yarn or product-processed yarn.
また、保温性を高めるためには、デニール数及びフィラ
メント数を高めるなど、種々の方法があるが、糸の断面
形状の異型化は、光沢は付与できてもギラツキ感があっ
たり、また、異型化によって製品着用時の肌触りが硬く
悪くなる欠点がある。In addition, there are various methods to improve heat retention, such as increasing the denier number and filament count, but changing the cross-sectional shape of the thread may give a glossy feel, This has the disadvantage that the product feels hard and uncomfortable when worn.
吸水加工は、繊維表面に吸水性をもたせる方法であり、
その性能の耐久性には乏しく、また、吸水性を長期的に
保持出来ても、拡散性能（乾燥性）をともなわないため
、製品着用時に、べたつき感、ムレ感が発生する欠点が
ある。また、デニール数、フィラメント数を上げること
により、保温性を高めても、透明感が低下し、絹地が厚
ぼったくなり、外観品位を悪くする欠点がある。Water absorption processing is a method of imparting water absorption properties to the fiber surface.
Its performance is poor in durability, and even if it can retain its water absorbency over a long period of time, it does not have diffusion performance (drying properties), so it has the disadvantage of causing a sticky or stuffy feeling when worn. Further, even if the heat retention property is improved by increasing the denier number and the number of filaments, there are disadvantages in that the transparency decreases, the silk fabric becomes thick and flimsy, and the appearance quality deteriorates.
いずれの方法においても、各性能を充分に満足し、外観
品位と着用性能を兼ね備えることは困難であった。In either method, it was difficult to fully satisfy each performance and to have both appearance quality and wearability.
その他、前記カバリングヤーンの被覆糸及び／又は交編
糸に、絹糸・綿糸などを使用したストッキングがあるが
、絹糸を使用したストッキングでは、優雅な光沢をもち
、外観品位に優れ、吸水性もあるが、拡散性能をともな
わないためムレ感が生じる欠点があり、また取り扱い性
もむずかしく、コスト面でも高くなる欠点がある。In addition, there are stockings that use silk thread, cotton thread, etc. as the covering thread and/or interwoven thread of the covering yarn, but stockings using silk thread have an elegant luster, excellent appearance quality, and are also water absorbent. However, since it does not have diffusion performance, it has the disadvantage of causing a stuffy feeling, is difficult to handle, and has the disadvantage of being expensive.
又、綿糸を使用したストッキングでは、吸水性は高いが
、これも拡散性能がともなわないため、ムレ感が生じる
。また、短繊維であるため糸ムラがあり、細デニール化
も困難で、外観品位も悪くなる欠点がある。In addition, stockings made of cotton yarn have high water absorption, but do not have good diffusion performance, resulting in a stuffy feeling. In addition, since they are short fibers, they have yarn unevenness, making it difficult to make them fine in denier, and the appearance quality is also poor.
このように、ポリアミド系合成繊維以外の、優れた外観
品位や機能性をもった天然繊維を用いた場合でも、外観
品位及び着用機能性を充分に満足し、兼ね備えたストッ
キングは得られないのが現状である。In this way, even when using natural fibers other than polyamide synthetic fibers that have excellent appearance quality and functionality, it is still not possible to obtain stockings that fully satisfy both appearance quality and wearing functionality. This is the current situation.
（発明が解決しようとする課題）
本発明は、絹のような優雅な光沢があり、また、保温性
、吸水拡散性が高く、ムレ感・へたつき感のない肌触り
にも優れた、外観品位及び製品の着用機能性を兼ね備え
たストッキングを得ることを目的とする。(Problems to be Solved by the Invention) The present invention has an appearance that has an elegant luster like silk, has high heat retention, water absorption and diffusion properties, and has an excellent texture without feeling stuffy or sticky. The purpose is to obtain stockings that have both elegance and product wearing functionality.
（課題を解決するための手段）
本発明は、芯糸及び被覆糸からなるカバリングヤーンと
交編糸とからなるストッキングにおいて、前記被覆糸及
び／又は交編糸が、蛋白アクリロニトリルグラフト共重
合体繊維糸であり、かつ、カバリングヤーンと交編糸が
１本交互に交編されているストッキング、及びカバリン
グヤーン１００％から編成されたストッキングにおいて
、前記被覆糸が、蛋白アクリロニトリルグラフト共重合
体繊維糸ぶあるストッキングである。(Means for Solving the Problems) The present invention provides a stocking comprising a covering yarn consisting of a core yarn and a covering yarn, and a cross-knit yarn, in which the covering yarn and/or the cross-knit yarn are made of protein acrylonitrile graft copolymer fibers. Stockings that are made of yarn and are alternately knitted with one covering yarn and one cross-knitted yarn, and stockings knitted from 100% covering yarn, wherein the covering yarn is a protein-acrylonitrile graft copolymer fiber yarn. These are some stockings.
ここでいう、カバリングヤーンとは、芯糸に弾性繊維糸
を配したＤＣＹ （ダブルカバリングヤーン）、５ＣＹ
（シングルカバリングヤーン）、ＡＣＹ（エアーカバリ
ングヤーン）など、あらゆるカバリングヤーンを示す。The covering yarn mentioned here refers to DCY (double covering yarn), 5CY, which has an elastic fiber yarn as the core yarn.
(single covering yarn), ACY (air covering yarn), etc.
また、前記カバリングヤーンに、蛋白アクリロニトリル
グラフト共重合体繊維を用いる場合、カバリングヤーン
の被覆糸に、蛋白アクリロニトリルグラフト共重合体繊
維糸が、少なくとも１本紀されておれば良い。Further, when protein-acrylonitrile graft copolymer fibers are used for the covering yarn, at least one protein-acrylonitrile graft copolymer fiber yarn may be included in the covering yarn of the covering yarn.
また、前記交編糸に、蛋白アクリロニトリルグラフト共
重合体繊維糸を用いた場合でも、蛋白アクリロニトリル
グラフト共重合体繊維糸が、少なくとも１本紀されてお
れば良い。Further, even when a protein-acrylonitrile graft copolymer fiber yarn is used as the cross-knitted yarn, at least one protein-acrylonitrile graft copolymer fiber yarn may be used.
次に本発明を詳述する。Next, the present invention will be explained in detail.
まず、本発明に使用する蛋白アクリロニトリルグラフト
共重合体繊維糸は、蛋白あるいは、その誘導体にアクリ
ロニトリルあるいはこれと他の共重合可能な不飽和化合
物とを、塩化亜鉛あるいはロダン塩を主成分とする溶媒
下で溶液重合して得られた蛋白−アクリロニトリルグラ
フト重合体溶液を湿式紡糸し、得られた湿潤繊維を該グ
ラフト重合体中の蛋白含を率に応じて乾燥することによ
り得られる。得られた繊維は破断強度２〜５．５ｇ／ｄ
Ｎ破断伸度１０〜４５％、沸水収縮率２〜６％であれ
ば良い。First, the protein-acrylonitrile graft copolymer fiber yarn used in the present invention is prepared by adding acrylonitrile or other unsaturated compounds copolymerizable with protein or its derivatives to a solvent containing zinc chloride or rhodan salt as a main component. The protein-acrylonitrile graft polymer solution obtained by the solution polymerization described below is wet-spun, and the resulting wet fibers are dried depending on the protein content in the graft polymer. The resulting fibers have a breaking strength of 2 to 5.5 g/d.
It is sufficient if the N-break elongation is 10 to 45% and the boiling water shrinkage is 2 to 6%.
また、前記蛋白アクリロニトリルグラフト共重合体繊維
糸は、トークルデニールが、１０〜５０デニールの範囲
内であること好ましい。これは、５０デニールを超える
と編地の厚みが増し、外観が悪くなり、また、肌触りが
硬くなるなど、本発明の目的とする外観品位及び着用機
能性を兼ね備えたストッキングになることが困難となり
、また、１０デニール未満であると、糸強力が低下し、
糸加工・編立等で糸切れ、フィラメント割れが発生し易
く操業性が不良となり、得られたストッキングも、欠点
が多くなるからである。Further, it is preferable that the protein-acrylonitrile graft copolymer fiber yarn has a torque denier in a range of 10 to 50 deniers. This is because if the knitted fabric exceeds 50 denier, the thickness of the knitted fabric increases, the appearance worsens, and the feel becomes hard, making it difficult to create stockings that have both the appearance quality and wearability that are the objectives of the present invention. Also, if it is less than 10 denier, the yarn strength will decrease,
This is because yarn breakage and filament cracking are likely to occur during yarn processing and knitting, resulting in poor operability and the resulting stockings having many defects.
（作用）
５−
本発明ストッキングは、絹のような優雅でやさしい光沢
を表現でき外観品位を高め、その」二、着用した時の機
能性を高める効果がある。(Function) 5- The stockings of the present invention have the effect of expressing an elegant and gentle luster like silk, enhancing the appearance quality, and secondly, enhancing functionality when worn.
前記、着用した時の機能性とは、快適な着用感を得ると
いうことであり、快適な着用感を得るためには、保温性
と、繊維が皮膚から水分を奪う吸水性と、それをすばや
く乾燥させる乾燥性が重要である。As mentioned above, functionality when worn means that it feels comfortable to wear.In order to achieve a comfortable wearing feeling, it is necessary to have heat retention, the ability of the fibers to absorb moisture from the skin, and to quickly absorb it. Drying performance is important.
本発明で使用する蛋白アクリロニトリルグラフト共重合
体繊維は保温性に優れ、ポリアミド系合成繊維や絹・綿
と比較して、水分を吸収拡散する性能に優れているため
、本発明によるストッキングにおいては、発汗時にもサ
ラッとした着用感で、従来のストッキングにあった汗に
よる不快なムレ感・べたつき感を解消する効果がある。The protein-acrylonitrile graft copolymer fiber used in the present invention has excellent heat retention properties and has excellent ability to absorb and diffuse moisture compared to polyamide synthetic fibers, silk, and cotton. They feel smooth to wear even when sweating, and are effective in eliminating the unpleasant stuffiness and stickiness caused by sweat that conventional stockings have.
また、カバリングヤーンの被覆糸及び／又は交編糸に、
蛋白アクリロニトリルグラフト共重合体繊維とポリアミ
ド系マルチフィラメント糸またはその加工糸とを混用す
ることにより、蛋白アクリロニトリルグラフト共重合体
繊維糸のみを使用するものより、強力を高めることがで
き、スト・ソキングの要求品質である耐久性も満たすこ
とが出来る。In addition, the covered yarn and/or the interlaced yarn of the covering yarn,
By mixing protein-acrylonitrile graft copolymer fiber with polyamide multifilament yarn or its processed yarn, it is possible to increase the strength compared to using only protein-acrylonitrile graft copolymer fiber yarn, making it possible to improve the strength of stretching and soaking. It can also meet the required quality of durability.
また、蛋白アクリロニトリルグラフト共重合体繊維糸を
使用する際は、無撚状態てはなく撚を１００〜４００
Ｔ／Ｍの範囲で付与することにより、糸加工時の操業性
及び組立性を高めることが出来る。In addition, when using protein acrylonitrile graft copolymer fiber yarn, the twist should be 100 to 400, rather than untwisted.
By applying it within the range of T/M, operability and assemblability during yarn processing can be improved.
（実施例）
以下実施例により、本発明を説明するが、本発明は実施
例に拘束されるものではない。(Examples) The present invention will be described below with reference to Examples, but the present invention is not limited to the Examples.
実施例 １゜
カバリングヤーンの芯糸として２０ｄのポリウレタン弾
性糸を用いて弾性糸ドラフトを約３倍に設定し、これに
被覆糸として蛋白アクリロニトリルグラフト共重合体マ
ルチフィラメント糸１５ｄ／８ｆに３８４Ｔ／Ｍの撚を
かけた糸を用いて、下撚２４００Ｔ／Ｍ。Example 1゜A 20 d polyurethane elastic yarn is used as the core yarn of the covering yarn, and the elastic yarn draft is set to about 3 times, and a protein acrylonitrile graft copolymer multifilament yarn 15 d/8 f of 384 T/M is used as the covering yarn. First twist 2400T/M using twisted yarn.
上撚１’８００Ｔ／Ｍでダブルカバードしたカバリング
ヤーンと、交編糸として、ナイロンマルチフィラメント
糸＋７ｄ／３ｆとを針本数４００本、日経４″の７ＮＩ
Ｌンスト編機で１コースごとに交編し、パンティストッ
キングを得た。Double-covered covering yarn with ply twist 1'800T/M and nylon multifilament yarn +7d/3f as interlaced yarn with 400 needles and Nikkei 4'' 7NI
Each course was alternately knitted using an L-st knitting machine to obtain pantyhose.
実施例 ２
カバリングヤーンの芯糸として２０ｄのポリウレタン弾
性糸を用いて弾性糸ドラフトを約３倍に設定し、これに
被覆糸として、蛋白アクリロニトリルグラフト共重合体
マルチフィラメント糸１５ｄ／８ｆに３８４Ｔ／Ｍのせ
撚をかけた糸を用いて、撚数ｌ７００Ｔ／Ｍでシングル
カバリングしたカバリングヤーンと交編糸として、ナイ
ロンマルチフィラメント糸１５ｄ／３ｆとを実施例１と
同様に交編してストッキングを得た。Example 2 A 20 d polyurethane elastic yarn was used as the core yarn of the covering yarn, and the elastic yarn draft was set to about 3 times, and a protein acrylonitrile graft copolymer multifilament yarn 15 d/8 f of 384 T/M was used as the covering yarn. Stockings were obtained by inter-knitting a single covering yarn with a twist number of 1700T/M and nylon multifilament yarn 15d/3f as an inter-knitting yarn in the same manner as in Example 1 using a twisted yarn. .
比較例 １゜
カバリングヤーンの芯糸として２０ｄのポリウレタン弾
性糸を用いて弾性糸ドラフトを約３倍に設定し、これに
被覆糸として、ナイロンマルチフィラメント糸１０ｄ１
５ｆを用いて、上撚２４００Ｔ／Ｍ 、上撚２１００Ｔ
／Ｍでダブルカバードしたカバリングヤーンと、交編糸
としてナイロンマルチフィラメント糸１５ｄ／３を実施
例１と同様に交編してストッキングを得た。Comparative Example 1゜A 20d polyurethane elastic yarn is used as the core yarn of the covering yarn, and the elastic yarn draft is set to about 3 times, and 10d1 of nylon multifilament yarn is used as the covering yarn.
Using 5f, ply twist 2400T/M, ply twist 2100T
/M double-covered covering yarn and nylon multifilament yarn 15d/3 as the interlacing yarn were inter-knitted in the same manner as in Example 1 to obtain stockings.
比較例 ２゜
カバリングヤーンの芯糸として２０ｄのポリウレタン弾
性糸を用いて弾性糸ドラフトを約３倍に設定し、これに
被覆糸として、ナイロンマルチフィラメント糸１２ｄ１
５ｆを用いて、撚数１７００７／Ｍでシングルカバリン
グしたカバリングヤーンと、交編糸として、ナイロンマ
ルチフィラメント糸１２ｄ／３ｆとを実施例１と同様に
交編してストッキングを得た。Comparative Example 2゜A 20d polyurethane elastic yarn was used as the core yarn of the covering yarn, and the elastic yarn draft was set to about 3 times, and a nylon multifilament yarn 12d1 was used as the covering yarn.
Stockings were obtained by inter-knitting a single covering yarn using 5f with a twist number of 17007/M and nylon multifilament yarn 12d/3f as an inter-knitting yarn in the same manner as in Example 1.
実施例１、実施例２、比較例１及び比較例２で得られた
ストッキングについて、外観品位および着用機能性につ
いて被験者２０名の着用テストにより評価した結果を第
１表に示す。Table 1 shows the results of evaluation of the appearance quality and wearability of the stockings obtained in Example 1, Example 2, Comparative Example 1, and Comparative Example 2 through a wearing test conducted by 20 test subjects.
９−
１０−
第
１
表
◎非常に優れている ○優れている △やや劣る
×劣る（発明の効果）
本発明によれば絹様の光沢感を有し、保温性、吸水性に
優れムレ感のない着用感良好なストッキングを得ること
が可能となった。9- 10- Table 1 ◎Very good ○Excellent △Slightly inferior
×Poor (Effect of the Invention) According to the present invention, it has become possible to obtain stockings that have a silk-like luster, are excellent in heat retention and water absorption, and are comfortable to wear without feeling stuffy.
Claims (2)
糸とからなるストッキングにおいて前記被覆糸及び／又
は交編糸が、蛋白アクリロニトリルグラフト共重合繊維
糸であり、かつ、カバリングヤーンと交編糸が１本交互
に交編されていることを特徴とするストッキング。(1) In a stocking made of a covering yarn consisting of a core yarn and a covering yarn, and a cross-knitting yarn, the covering yarn and/or the crossing-knitting yarn are protein-acrylonitrile graft copolymer fiber yarns, and the covering yarn and the crossing-knitting yarn are These stockings are characterized by being alternately knitted.
されたストッキングにおいて、前記被覆糸が蛋白アクリ
ロニトリルグラフト共重合体繊維糸であることを特徴と
するストッキング。(2) A stocking knitted with a covering yarn consisting of a core yarn and a covering yarn, wherein the covering yarn is a protein-acrylonitrile graft copolymer fiber yarn.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP02736690A JP3158409B2 (en) | 1990-02-07 | 1990-02-07 | stockings |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP02736690A JP3158409B2 (en) | 1990-02-07 | 1990-02-07 | stockings |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH03234801A true JPH03234801A (en) | 1991-10-18 |
| JP3158409B2 JP3158409B2 (en) | 2001-04-23 |
Family
ID=12219052
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP02736690A Expired - Fee Related JP3158409B2 (en) | 1990-02-07 | 1990-02-07 | stockings |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP3158409B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105926103A (en) * | 2016-06-20 | 2016-09-07 | 常州科旭纺织有限公司 | Siro core-spun yarn and process for producing same |
-
1990
- 1990-02-07 JP JP02736690A patent/JP3158409B2/en not_active Expired - Fee Related
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105926103A (en) * | 2016-06-20 | 2016-09-07 | 常州科旭纺织有限公司 | Siro core-spun yarn and process for producing same |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3158409B2 (en) | 2001-04-23 |
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