JPH03227337A - Flame retardant composition and flame retardant cable - Google Patents
Flame retardant composition and flame retardant cableInfo
- Publication number
- JPH03227337A JPH03227337A JP2021101A JP2110190A JPH03227337A JP H03227337 A JPH03227337 A JP H03227337A JP 2021101 A JP2021101 A JP 2021101A JP 2110190 A JP2110190 A JP 2110190A JP H03227337 A JPH03227337 A JP H03227337A
- Authority
- JP
- Japan
- Prior art keywords
- flame retardant
- flame
- ethylene
- composition
- copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 25
- 239000003063 flame retardant Substances 0.000 title claims description 27
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims description 25
- 229920001577 copolymer Polymers 0.000 claims abstract description 10
- 229910000000 metal hydroxide Inorganic materials 0.000 claims abstract description 10
- 150000004692 metal hydroxides Chemical class 0.000 claims abstract description 10
- 229920000098 polyolefin Polymers 0.000 claims abstract description 9
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000005977 Ethylene Substances 0.000 claims abstract description 8
- 239000000178 monomer Substances 0.000 claims abstract description 8
- 239000012212 insulator Substances 0.000 claims description 4
- 125000005439 maleimidyl group Chemical class C1(C=CC(N1*)=O)=O 0.000 claims 1
- 230000000704 physical effect Effects 0.000 abstract description 4
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 abstract description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 abstract description 3
- 150000001875 compounds Chemical class 0.000 abstract description 3
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 abstract description 3
- 239000000347 magnesium hydroxide Substances 0.000 abstract description 3
- 229910001862 magnesium hydroxide Inorganic materials 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract description 3
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 abstract description 2
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 abstract 1
- 239000005038 ethylene vinyl acetate Substances 0.000 abstract 1
- -1 maleimide compound Chemical class 0.000 description 8
- 230000000694 effects Effects 0.000 description 6
- 238000002844 melting Methods 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 4
- 229910052736 halogen Inorganic materials 0.000 description 3
- 150000002367 halogens Chemical class 0.000 description 3
- 150000003923 2,5-pyrrolediones Chemical class 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 2
- 229920006244 ethylene-ethyl acrylate Polymers 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- KPQOXMCRYWDRSB-UHFFFAOYSA-N 1-(2-chlorophenyl)pyrrole-2,5-dione Chemical compound ClC1=CC=CC=C1N1C(=O)C=CC1=O KPQOXMCRYWDRSB-UHFFFAOYSA-N 0.000 description 1
- QYOJZFBQEAZNEW-UHFFFAOYSA-N 1-(2-methylphenyl)pyrrole-2,5-dione Chemical compound CC1=CC=CC=C1N1C(=O)C=CC1=O QYOJZFBQEAZNEW-UHFFFAOYSA-N 0.000 description 1
- BQTPKSBXMONSJI-UHFFFAOYSA-N 1-cyclohexylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1CCCCC1 BQTPKSBXMONSJI-UHFFFAOYSA-N 0.000 description 1
- SJLLJZNSZJHXQN-UHFFFAOYSA-N 1-dodecylpyrrole-2,5-dione Chemical compound CCCCCCCCCCCCN1C(=O)C=CC1=O SJLLJZNSZJHXQN-UHFFFAOYSA-N 0.000 description 1
- HIDBROSJWZYGSZ-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC=C1 HIDBROSJWZYGSZ-UHFFFAOYSA-N 0.000 description 1
- 229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 239000005042 ethylene-ethyl acrylate Substances 0.000 description 1
- 238000007765 extrusion coating Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920006163 vinyl copolymer Polymers 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
- Insulated Conductors (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野〕
この発明はポリオレフィン系樹脂を主体とした難燃性組
成物、特に電線やケーブル被覆材料、接続材料として高
い難燃化を達成できる難燃性組成物およびこれを用いた
ケーブルに関する。[Detailed Description of the Invention] [Field of Industrial Application] This invention relates to a flame-retardant composition based on a polyolefin resin, particularly a flame-retardant composition that can achieve high flame retardancy as an electric wire or cable covering material, or as a connection material. The present invention relates to a composition and a cable using the same.
′従来の技術）
ポリオレフィンまたはエチレンと他のモノマーとの共重
合体は電気特性および加工性もよいことから電線ケーブ
ルの分野では広く用いられているか、従来これを難燃化
するにはハロゲン系難燃剤や水酸化アルミニウム、水酸
化マグネシウム等の難燃剤を配合したものか知られてい
る。'Prior art) Polyolefins or copolymers of ethylene and other monomers have good electrical properties and processability, so they are widely used in the field of electric wires and cables. It is known that it contains flame retardants such as flame retardants and aluminum hydroxide and magnesium hydroxide.
組成物にハロゲン系難燃化剤を添加する場合は、火災時
に機器を腐食し、健康にも有害なハロゲンガスの発生が
あり、水酸化アルミニウム、水酸化マグネシウム等の難
燃剤を配合したものでは、これらの水酸化物が比較的難
燃効果か低いために多量に添加する必要があり、組成物
は引張特性、耐寒性の劣化か大きく改良が求められてい
た。If a halogen-based flame retardant is added to the composition, it may corrode equipment in the event of a fire and generate halogen gas, which is harmful to health. Since these hydroxides have a relatively low flame retardant effect, it is necessary to add them in large amounts, and the composition has been in need of significant improvement in terms of deterioration in tensile properties and cold resistance.
本発明は上記の問題を解決することを目的とするもので
ある。The present invention aims to solve the above problems.
この発明においては、マレイミド系化合物と金属水酸化
物との併用によって、上記課題を解決するように１ｆ−
〔作用〕
マレイミド系化合物と金属水酸化物との併用により、そ
の相乗効果によって高い難燃性が得られ、このため金属
水酸化物の配合量を低めることか可能となって、組成物
の引張特性や耐寒性の低下を抑えることができる。In this invention, the above problem is solved by using a maleimide compound and a metal hydroxide in combination. 1f- [Function] By using a maleimide compound and a metal hydroxide in combination, the synergistic effect results in high flame retardancy. This makes it possible to reduce the amount of metal hydroxide added, thereby suppressing deterioration in the tensile properties and cold resistance of the composition.
以下、この発明の詳細な説明する。The present invention will be explained in detail below.
この発明の難燃性組成物は、ポリオレフィンまたはエチ
レンと他のモノマーとの共重合体１００重量部に対し、
マレイミド系化合物０．１〜５０重量部、金属水酸化物
１０〜１５０重量部を配合したものであり、また難燃性
ケーブルは、この難燃性組成物からなる絶縁体あるいは
シースもしくはその両者を有するものである。The flame retardant composition of the present invention contains 100 parts by weight of a polyolefin or a copolymer of ethylene and other monomers.
It contains 0.1 to 50 parts by weight of a maleimide compound and 10 to 150 parts by weight of a metal hydroxide, and the flame-retardant cable is made of an insulator or a sheath made of this flame-retardant composition, or both. It is something that you have.
この発明で用いられるポリオレフィンまたはエチレンと
他のモノマーとの共重合体としては、高Ｅ［ポリエチレ
ン（ＨＤＰＥ）、低密度ポリエチレン（ＬＤＰＥ）、直
鎖状低密度ポリエチレン（ＬＬＤＰＥ）なとのポリエチ
レン、ポリプロピレン、エチレン−プロピレン共電＝体
、ｘｔし７−４１：Ｉｌｌビニル共重合体（ＥＶＡ）、
エチレン−エチルアクリレート共重合体（ＥＥＡ）、エ
チレン−アクリル酸共重合体（ＥＡＡ）、エチレン−プ
ロピレン−ジエン共重合体（ＥＰＤＭ）などが用いられ
、これらポリマーの単独もしくは２種以上のブレンドポ
リマーが用いられる。ブレンドポリマーにおけるブレン
ド比は任意である。The polyolefins or copolymers of ethylene and other monomers used in this invention include polyethylenes with high E [polyethylene (HDPE), low density polyethylene (LDPE), linear low density polyethylene (LLDPE), polypropylenes] , ethylene-propylene coelectronic body, xt 7-41: Ill vinyl copolymer (EVA),
Ethylene-ethyl acrylate copolymer (EEA), ethylene-acrylic acid copolymer (EAA), ethylene-propylene-diene copolymer (EPDM), etc. are used, and single or blended polymers of two or more of these polymers are used. used. The blend ratio in the blend polymer is arbitrary.
また、ここで使用されるマレイミド系化合物としては、
次の一般式（１）〜（ＩＩＩ）で表わされる化合物であ
り、その融点が４０〜２００°Ｃの範囲にあるものが用
いられる。In addition, the maleimide compounds used here include:
Compounds represented by the following general formulas (1) to (III) and having a melting point in the range of 40 to 200°C are used.
たはアルキル基もしくはハロゲンを示す。〕これらのマ
レイミド系化合物の具体例としては、Ｎ−フェニルマレ
イミド（１点８７〜９０℃）、Ｎ−（２−メチルフェニ
ル）マレイミド（融点７３〜７６℃）、Ｎ−（２，６−
ジニチルフエニル）マレイミド（融点７３〜７６°Ｃ）
、Ｎ−（２−クロロフェニル）マレイミド（Ｍ点７２
〜７５℃）、Ｎ−シクロへキシルマレイミド（融点８７
°Ｃ）、Ｎ−ラウリルマレイミド（融点５１〜５６°Ｃ
）などが挙げられる。このマレイミド系化合物はマイク
ロカプセル化したものを使用することもでき、成形加工
時のマレイミド系化合物の揮散を防止できて好ましい。or an alkyl group or a halogen. ] Specific examples of these maleimide compounds include N-phenylmaleimide (1 point 87-90°C), N-(2-methylphenyl)maleimide (melting point 73-76°C), N-(2,6-
(dinitylphenyl)maleimide (melting point 73-76°C)
, N-(2-chlorophenyl)maleimide (M point 72
~75°C), N-cyclohexylmaleimide (melting point 87
°C), N-laurylmaleimide (melting point 51-56 °C)
), etc. The maleimide compound may be microencapsulated, which is preferable since volatilization of the maleimide compound can be prevented during molding.
このマレイミド系化合物の配合量は、上記ポリオレフィ
ンまたはエチレンと他のモノマーとの共重合体１００重
量部に対してＯ，１〜５０重量部とされる。０．１重量
部未満では難燃効果か不十分であり、５０重量部を越え
ると引張特性、耐寒性等の物性が低下して好ましくない
。The blending amount of the maleimide compound is 1 to 50 parts by weight based on 100 parts by weight of the polyolefin or copolymer of ethylene and other monomer. If it is less than 0.1 parts by weight, the flame retardant effect will be insufficient, and if it exceeds 50 parts by weight, physical properties such as tensile properties and cold resistance will deteriorate, which is not preferable.
さらに、金属水酸化物としては、水酸化マグネシウム（
Ｍｇ（○Ｈ）？）、水酸化アルミニウム（Ａ Ｃ（ＯＨ
）３） 、水酸化カルシウム（Ｃａ（○Ｈ）２）などが
挙げられる。この金属水酸化物の配合量はポリオレフィ
ンまたはエチレンと他のモノマーとの共重合体１００重
量部に対して１０〜１５０重量部とされ、１０重量部未
満では難燃効果が不十分であり、１５０重量部を越える
と物性低下が大きくなって不都合となる。Furthermore, as a metal hydroxide, magnesium hydroxide (
Mg(○H)? ), aluminum hydroxide (AC(OH
)3), calcium hydroxide (Ca(○H)2), and the like. The amount of metal hydroxide blended is 10 to 150 parts by weight per 100 parts by weight of the polyolefin or copolymer of ethylene and other monomers, and if it is less than 10 parts by weight, the flame retardant effect is insufficient; If the amount exceeds 1 part by weight, the physical properties will deteriorate significantly, which is disadvantageous.
この難燃性組成物の難燃化機構は、ペースポリマーを構
成するポリオレフィンまたはエチレンと他のモノマーと
の共重合体が燃焼する際の低分子量化をマレイミド系化
合物が抑制し、さらに金属水酸化物の発水分解（吸熱反
応）が複合して起り、それぞれか単独で用いられたとき
に生じる効果を上回る相乗効果を奏する。The flame retardant mechanism of this flame retardant composition is that the maleimide compound suppresses the reduction in molecular weight when the polyolefin or copolymer of ethylene and other monomers constituting the pace polymer burns, and the Hydrolytic decomposition (endothermic reaction) of substances occurs in combination, producing a synergistic effect that exceeds the effect produced when each is used alone.
また、この難燃性組成物には、必要に応じて、リン系難
燃剤、老化防止剤、カーボンブラック、顔料などを添加
することかできる。さらに、有機過酸化物を添加して架
橋型組成物としてもよい。Further, a phosphorus-based flame retardant, an anti-aging agent, carbon black, a pigment, etc. can be added to this flame-retardant composition, if necessary. Furthermore, an organic peroxide may be added to form a crosslinked composition.
この発明の難燃性ケーブルは、上述の難燃性組成物をそ
の絶縁体または／−スあるいはその両者に用いたもので
ある。高い電気絶縁性を求められるケーブルでは／−ス
にのみこの難燃性組成物を用いることか好ましい。この
難燃性組成物は良好な加工性を有しているので、通常の
押出被覆法によって絶縁体あるいはソースとすることか
できる。The flame-retardant cable of the present invention uses the above-mentioned flame-retardant composition for its insulator and/or base. In cables that require high electrical insulation, it is preferable to use this flame retardant composition only in the base. Since this flame retardant composition has good processability, it can be made into an insulator or source by conventional extrusion coating methods.
以下、具体例を示して作用効果を明確にする。Hereinafter, specific examples will be shown to clarify the effects.
（実施例）
第１表に示す配合組成の組成物を調製し、押出成形して
／−ト状の試験片を得た。この試験片について、酸素指
数および耐寒性を測定した。耐寒性は、Ｊ Ｉｓ−に−
６７６０により、−４０’Ｃにおいて試験片が破壊しな
いものを○とし、破壊したものを×として表わした。(Example) A composition having the composition shown in Table 1 was prepared and extruded to obtain a plate-shaped test piece. The oxygen index and cold resistance of this test piece were measured. Cold resistance is J Is-
6760, those in which the test piece did not break at -40'C were marked ○, and those in which it was broken were marked x.
結果を第１表に併せて示した。The results are also shown in Table 1.
第１表の結果から明らかように、この発明の難燃性組成
物は、高い難燃性を有するとともに金属水酸化物の配合
量を削減できるので、機械的特性、耐寒性も良好である
ことがわかる。As is clear from the results in Table 1, the flame retardant composition of the present invention has high flame retardancy and can reduce the amount of metal hydroxide, so it has good mechanical properties and cold resistance. I understand.
以上の説明から明らかなように、この発明の難燃性組成
物は、高い難燃性と良好な物理的性質を併せて有するも
のであり、難燃性ケーブルも良好な難燃性および機械的
特性を有するものとなる。As is clear from the above description, the flame-retardant composition of the present invention has both high flame retardancy and good physical properties, and the flame-retardant cable also has good flame retardancy and mechanical properties. It becomes something with characteristics.
Claims (2)
の共重合体１００重量部に対し、マレイミド系化合物０
．１〜５０重量部、金属水酸化物１０〜１５０重量部を
配合してなることを特徴とする難燃性組成物。(1) 0 maleimide compounds per 100 parts by weight of polyolefin or copolymer of ethylene and other monomers
．． 1. A flame retardant composition comprising 1 to 50 parts by weight and 10 to 150 parts by weight of a metal hydroxide.
／あるいはシースもしくは両者を有することを特徴とす
る難燃性ケーブル。(2) A flame-retardant cable comprising an insulator and/or a sheath made of the flame-retardant composition according to claim (1).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2021101A JPH03227337A (en) | 1990-01-31 | 1990-01-31 | Flame retardant composition and flame retardant cable |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2021101A JPH03227337A (en) | 1990-01-31 | 1990-01-31 | Flame retardant composition and flame retardant cable |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03227337A true JPH03227337A (en) | 1991-10-08 |
Family
ID=12045482
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2021101A Pending JPH03227337A (en) | 1990-01-31 | 1990-01-31 | Flame retardant composition and flame retardant cable |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03227337A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0794028A (en) * | 1993-09-24 | 1995-04-07 | Hitachi Cable Ltd | Polypropylene-insulated electric wire |
| CN103524844A (en) * | 2013-09-30 | 2014-01-22 | 芜湖航天特种电缆厂 | High-temperature-resistant cable sheath material and preparation method thereof |
| CN106750947A (en) * | 2016-12-23 | 2017-05-31 | 安徽天元电缆有限公司 | A kind of novel environment friendly anti-electrostatic fire retardant cable material |
-
1990
- 1990-01-31 JP JP2021101A patent/JPH03227337A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0794028A (en) * | 1993-09-24 | 1995-04-07 | Hitachi Cable Ltd | Polypropylene-insulated electric wire |
| CN103524844A (en) * | 2013-09-30 | 2014-01-22 | 芜湖航天特种电缆厂 | High-temperature-resistant cable sheath material and preparation method thereof |
| CN103524844B (en) * | 2013-09-30 | 2016-05-04 | 芜湖航天特种电缆厂 | A kind of high temperature resistant protective cover material and preparation method thereof for cable |
| CN106750947A (en) * | 2016-12-23 | 2017-05-31 | 安徽天元电缆有限公司 | A kind of novel environment friendly anti-electrostatic fire retardant cable material |
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