JPH03221196A - Apparatus for making ozonized water - Google Patents
Apparatus for making ozonized waterInfo
- Publication number
- JPH03221196A JPH03221196A JP2016159A JP1615990A JPH03221196A JP H03221196 A JPH03221196 A JP H03221196A JP 2016159 A JP2016159 A JP 2016159A JP 1615990 A JP1615990 A JP 1615990A JP H03221196 A JPH03221196 A JP H03221196A
- Authority
- JP
- Japan
- Prior art keywords
- water
- ozone
- storage tank
- ozone gas
- reaction tube
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 168
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims abstract description 128
- 239000007921 spray Substances 0.000 claims abstract description 19
- 239000007788 liquid Substances 0.000 claims abstract description 4
- 238000004519 manufacturing process Methods 0.000 claims description 9
- 239000010419 fine particle Substances 0.000 abstract description 3
- 238000007599 discharging Methods 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 13
- 238000004090 dissolution Methods 0.000 description 5
- 239000007791 liquid phase Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 238000005273 aeration Methods 0.000 description 1
- 235000013361 beverage Nutrition 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
Landscapes
- Treating Waste Gases (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野：
本発明はオゾン殺菌、オゾン４白、脱臭等に使用される
オゾン水を供給するためのオゾン反応装置に関する。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application: The present invention relates to an ozone reaction device for supplying ozonated water used for ozone sterilization, ozone 4 whitening, deodorization, etc.
〔従来の技術１
オゾンガスをオゾン水に変換するために最ら良く用いら
れている方法は、例えば第２図に示す「オゾン利用の新
技術」（三 置所発行〉の第１０６頁に記載されている
よづな散気板を用いてオゾンガスを水中に吹き込み、気
泡を分散させることからなる散気板型オゾン接触筒を使
用する方法である。[Conventional technology 1 The most commonly used method for converting ozone gas into ozonated water is described, for example, on page 106 of "New technology for the use of ozone" (published by San Okisho), as shown in Figure 2. This method uses a diffuser plate-type ozone contact cylinder, which uses a diffuser plate to blow ozone gas into the water to disperse air bubbles.
二の方法によれば、オゾンガスと水との接触面積を比較
的大きくとれ、簡単にオゾン水を得ることかできるか、
オゾンガスの気泡か浮上した後はオゾンガスと水との接
触か断たれるため接触時間か非常に短く、オゾンガスは
充分に溶けず、高濃度のオゾン水を短時間に得ることは
て′きない。According to the second method, the contact area between ozone gas and water can be made relatively large, and ozonated water can be easily obtained.
After the ozone gas bubbles float to the surface, the contact between the ozone gas and water is broken, so the contact time is very short, and the ozone gas does not dissolve sufficiently, making it impossible to obtain highly concentrated ozone water in a short time.
この欠点を改善する方法ヒして、「飲料製造におけるオ
ゾンの利用法ｊ１ヒハリンジ、ジャパンＮ ｏ 、 ４
５ （１９８５）’、には、水中タービシ法、循環プロ
ペラ法、高速接触型タービン法、複合エシェクターフ去
、超音波デイスパージャ−法等か開示されている。A method to improve this drawback is described in ``Using Ozone in Beverage Production'', published by Haringi, Japan No. 4.
5 (1985)', discloses an underwater turbidity method, a circulating propeller method, a high-speed contact turbine method, a composite eschectaf evacuation method, an ultrasonic disperger method, etc.
また、特開昭６２−２２５２４２号公報には、高速噴射
ｌ去によるオゾン反応装置か、特開昭６２．−２２６８
０１号公報には、１放細気泡圧入、去によるオゾン反応
装置かそれぞれ開示されている。In addition, Japanese Patent Application Laid-open No. 62-225242 describes an ozone reaction device using high-speed injection and removal. -2268
The No. 01 publication discloses an ozone reaction apparatus using one fine bubble injection and one discharge.
更に、特開昭６３−１６６４９３号公報には、オゾンガ
スを混合室に圧送し、微粒子化した水と接触させてオゾ
ン水を得る装置か開示されているか、これによるヒオゾ
ンガスを圧送する手段か必要てあり、大掛かりな装置か
必要となる大点かある。Furthermore, JP-A-63-166493 discloses an apparatus for obtaining ozone water by force-feeding ozone gas into a mixing chamber and bringing it into contact with atomized water. Yes, there are large-scale equipment or major points required.
「発明か解決しようとする課題１
上述の方法はいずれも短時間に高濃度のオゾン水を得る
ことはできるが、オゾン反応装置は高価で大形のｂ力か
・２・要となる。``Problem to be solved by the invention 1 All of the above-mentioned methods can obtain highly concentrated ozonated water in a short time, but the ozone reaction equipment is expensive and requires a large power source.
一般に、オゾンガスを水に溶解する場合、溶解律則から
オシ〉′濃度の高い方が早く高濃度に達し易いので、高
濃度のオゾンガス発生装置を用いる二とが好ましい。こ
の場合、投入エネルキーに対する発生オゾン量はほぼ一
定となる力で、高濃度のオゾン発生装置はど、発生ガス
量は少なくなるので、多量の発生ガス量を必要とする上
述の方法を用いると溶解効率か低下する。Generally, when dissolving ozone gas in water, it is preferable to use a high-concentration ozone gas generator, because according to the law of dissolution, the higher the ozone concentration, the faster the concentration can be reached. In this case, the amount of ozone generated relative to the input energy key is approximately constant, and the amount of gas generated is smaller than that of a high-concentration ozone generator. Efficiency decreases.
更に、オゾン水を貯留するためには、上述の方法ではオ
ゾン反応装置全体を大きくするか、貯留槽を別に設置す
ることになり、オゾン水製造装置としてとりまとめる場
合、形状、寸法の規制に対処できず、いたずらに大きな
装置となっていた。Furthermore, in order to store ozonated water, the above method requires either increasing the size of the entire ozone reaction device or installing a separate storage tank, which makes it impossible to deal with regulations regarding shape and size when combining it as an ozonated water production device. It turned out to be an unnecessarily large device.
従って、本発明の目的はこれらの欠点を改善し、安く短
時間にオゾン水か得られ且つ小型化することができるオ
ゾン水貯留槽を備えたオゾン水製造装置を提供すること
にある。SUMMARY OF THE INVENTION Therefore, an object of the present invention is to improve these drawbacks and provide an ozonated water production apparatus equipped with an ozonated water storage tank that can obtain ozonated water cheaply and in a short time and that can be downsized.
「課題を解決するための手段］
即ち、本発明は反応筒（５）と、反応筒（５）に設けら
れた噴霧ノズル（４〉と、水を電気分解してオゾンガス
を得るためのオゾナイザ（１７）と、オゾナイザ（１７
）からのオゾンガスを前記反応筒（５）内に放出する敗
気具（２）と、反応筒（５）の下部に接続されたオゾン
水貯留槽（１１）と、得られたオゾン水を放出する。夜
体ポンプ（１８）と、得られたオゾン水を前記噴霧ノズ
ル（４）へ戻すための循環管路（１５）を備えてなり、
上記オゾン水貯留槽を反応筒（５）より大形と１．たこ
とを特徴とするオゾン水％！遣装置にｆ系 る 。"Means for Solving the Problems" That is, the present invention comprises a reaction tube (5), a spray nozzle (4) provided in the reaction tube (5), and an ozonizer (4) for electrolyzing water to obtain ozone gas. 17) and ozonizer (17)
) into the reaction tube (5); an ozone water storage tank (11) connected to the lower part of the reaction tube (5); do. It is equipped with a night body pump (18) and a circulation pipe (15) for returning the obtained ozonated water to the spray nozzle (4),
1. The ozone water storage tank is larger than the reaction tube (5). Ozonated water% characterized by! The f system is connected to the sending device.
また、本発明のオゾン水製造装置は反応筒（５）内に空
気を送り込むためのエアーポンプ（１９〉と、前記反応
筒（５）、７１上部に接続し、オゾンガスを汁解裏害化
するオゾンキラ＝（２０）とを設ける二ともである。In addition, the ozone water production apparatus of the present invention is connected to an air pump (19) for feeding air into the reaction cylinder (5) and the upper part of the reaction cylinder (5) and 71 to decompose ozone gas and turn it into a poison. In both cases, ozone killer=(20) is provided.
「作 用１
本発明力オゾン反応装置は、オシ〉′カスと水との接触
反応を受は持つ反応筒と、オ゛ノン水の貯留を受は持つ
オゾン水貯留槽との役割＝Ｓ−離しているために、次力
ように二つ力部分が好適な性能を示すことかできる。``Function 1'' The ozone reaction device of the present invention has the following functions: a reaction cylinder that receives the contact reaction between the gas and water, and an ozone water storage tank that stores the ozone water. Because of the separation, the two force parts can exhibit favorable performance as shown in the following figure.
即ち、本発明のオシ〉反応装置はオゾンガスを充満させ
た反応筒内に、−液相の噴霧ノスルを用いて７ｋを噴霧
させるのて゛、オゾンガスと水ヒ力接触面績かＲ躍的（
こ大きて−°るのて 短時間に高濃度Ｊ）すりン水り・
１等！二、れる。That is, the ozone reaction apparatus of the present invention uses a -liquid phase spray nostle to spray 7K into a reaction cylinder filled with ozone gas, so that the contact surface between ozone gas and water is dramatically improved.
High concentration in a short time J) Surin water
1st prize! Second, I can do it.
更に、流量あるいは水圧を変えてｒ＃ｉ霧氷の流速を制
御することにより溶解時間を充分にとることかでき、従
って高濃度のオゾン水が得られる。Furthermore, by controlling the flow rate of the r#i hoarfrost by changing the flow rate or water pressure, sufficient melting time can be obtained, and highly concentrated ozonated water can therefore be obtained.
また、−７夜用の噴貴ノズルから噴霧された水は落下す
る際にオゾンを溶解し、その一部は反応筒の内壁に当た
った後、内壁に沿って落下し、その他は直接落下し２反
応筒の下部に設置されているオゾン水貯留槽に溜まる。In addition, the water sprayed from the nozzle for -7 night dissolves ozone as it falls, and some of it hits the inner wall of the reaction tube and falls along the inner wall, while the rest falls directly. 2. The ozone water accumulates in the ozone water storage tank installed at the bottom of the reaction tube.
この時に、オゾン水の水面に噴霧水の落下による波打ち
現象か現れ、反応筒内に充満しているオゾンガスと水面
との接触面積が広かり、且つオゾン水の波によるオゾン
ガスの巻き込み現象によってオゾンガスとの接触面積が
更に太きくなってオゾンの溶解効率を更に向上させるこ
とかできる。At this time, a rippling phenomenon appears on the surface of the ozonated water due to the falling of the sprayed water, and the contact area between the ozone gas filling the reaction cylinder and the water surface is wide, and the ozone gas is mixed with the ozone gas due to the entrainment phenomenon of the ozone gas by the waves of the ozonated water. The contact area becomes larger, and the ozone dissolution efficiency can be further improved.
更に、反応筒下部に設置されているオゾン水貯留槽のオ
ゾン水の水位を一定に渫っことにより、噴霧水とオゾン
ガスの接触面積を一定に保持することかてき、それによ
ってオゾン水の濃度を一定とすることかできる。Furthermore, by keeping the water level of the ozonated water in the ozonated water storage tank installed at the bottom of the reaction tube constant, the contact area between the spray water and the ozone gas can be kept constant, thereby reducing the concentration of the ozonated water. It can be kept constant.
また オゾン水貯留槽に溜ま１ｆＳオ゛ｌ゛ン水は貯留
槽内で停留することによって未溶解のオゾンガスか抜け
、安定したオゾンガス水りａ度となる。Further, the 1 fS oil water accumulated in the ozone water storage tank remains in the storage tank, and undissolved ozone gas escapes, resulting in a stable ozone gas level of a degree.
一方、オゾン水の間尺使用に応；二るためには、・ピ・
要なオゾン水の貯留１に応にたオ゛ノン水貯留槽力容積
を確保することによりてオゾン水濃度の安定したオゾン
水を多量に得ることかできる。On the other hand, in order to respond to the use of ozonated water,
By securing the capacity of the ozonated water storage tank corresponding to the required ozonated water storage 1, it is possible to obtain a large amount of ozonated water with a stable ozonated water concentration.
また 反応筒とオゾン水貯留槽とにｌｔ！能か分離され
ているので、上述のように反応筒はオゾンガスの溶解効
率か最適て、オゾン水濃度の立ち上がり時間か短てなる
ように、δ芯筒の形状を小形にて゛きると共にオゾン水
貯留槽は反応筒より大形の円：笥あるいは箱形等の任意
の形状か採用できるので、オゾン反応装置を用いたシス
テム全体の形状かｔ：、 、Ａ要求に適合することかで
きる。Also, it is included in the reaction tube and ozone water storage tank! As mentioned above, the reaction tube is designed to have a small shape for the δ-core tube and an ozone water storage tank to optimize the ozone gas dissolution efficiency and shorten the rise time of the ozone water concentration. can be of any shape, such as a circle larger than the reaction tube, a box or a box, so that the shape of the entire system using the ozone reactor can meet the requirements of t:, ,A.
史に、オ゛ｌンカスの溶解度は水温か低いはと高い力で
オゾン水貯留検力形状を例えは箱形にするヒ、冷却用平
板用フィンを叶けて空冷する二ともてき、希望のオゾン
水濃度を炙定して得ることかできる。Historically, the solubility of ozone gas is very low at water temperature, and the ozone water storage detection force has been made into a box shape, for example, and air-cooled with fins for a flat plate for cooling. It can be obtained by measuring the ozone water concentration.
また、−度オシン水貯留槽に貯留したオゾン水をポンプ
等を用いて再循環することにより間欠的てはあるがより
高濃度のオシ〉水を得ることかできる。In addition, by recirculating the ozone water stored in the ozone water storage tank using a pump or the like, it is possible to obtain ozone water with a higher concentration, albeit intermittently.
［実 施 例］
以下、本発明のオゾン水製造装置の１実施解揉を添付第
１図を用いて説明する。[Example] Hereinafter, one implementation of the ozone water production apparatus of the present invention will be explained using the attached FIG. 1.
ます、オゾナイザ−（１７）により水を電気分解したオ
ゾンガスをオゾンガス装入パイプ（１）より反応筒（５
）に導入し、反応筒（５）内にオゾンガスを充満させる
。なお、反応筒（５）内にオゾンガスを迅速且つ均一に
拡散させるために、オゾン・ガス装入バイブ（１）の先
端に散気具（２）を設置することが好ましい。First, the ozone gas obtained by electrolyzing water by the ozonizer (17) is introduced into the reaction tube (5) from the ozone gas charging pipe (1).
), and the reaction column (5) is filled with ozone gas. In addition, in order to quickly and uniformly diffuse ozone gas into the reaction tube (5), it is preferable to install an aeration tool (2) at the tip of the ozone gas charging vibe (1).
次に２反応筒（５）の上部に設置された噴霧ノズル取付
バイブ（３）に導入された水は、噴霧ノズル取ｆ寸パイ
プの先端に取り付けされた一湾用の噴霧ノズル（４）か
ら前記オゾン充満気体中に微粒子として噴霧し、オゾン
ガスと水とを反応させてオゾン水を得る。Next, the water introduced into the spray nozzle-mounted vibrator (3) installed at the top of the second reaction tube (5) is supplied from the one-bay spray nozzle (4) attached to the tip of the spray nozzle diameter pipe. Fine particles are sprayed into the ozone-filled gas, and the ozone gas and water are reacted to obtain ozonated water.
この時、−液相の噴霧ノズル（４）から噴霧されろ水の
微粒３力噴霧範囲角度（θ）は水の微粒子力）内壁に当
たるたけ充分に大きい、二とか好ましし）。At this time, the spray range angle (θ) of the fine particles of filtrate sprayed from the liquid phase spray nozzle (4) is sufficiently large to hit the inner wall (preferably 2).
こいオソ〉水の一部は反応筒の内壁に当たった俺、内壁
に沿１て落下し、ａｉか多い場合、内壁に水膜を形ｌｔ
して流れ、残りは直接落下し、反応筒内下部に設置され
ているオゾン水貯留槽に溜まる。この時、オゾン水力水
面に噴霧水の落下による波打ち現象か現れ、反応筒（５
）及びオゾン水貯留槽（１１）内に充満しているオゾン
ガスと水面との接触面積か広かり且つオゾン水の波によ
るオゾンガスの巻き込み現象によってオゾンガスとの接
触面積か更に大きくなってオゾン溶解効率か向上する。A part of the water hits the inner wall of the reaction tube and falls along the inner wall, forming a water film on the inner wall if there is too much water.
The remainder falls directly and collects in the ozone water storage tank installed at the bottom of the reaction cylinder. At this time, a rippling phenomenon appeared on the ozone hydraulic water surface due to the falling spray water, and the reaction tube (5
) and the contact area between the ozone gas filling the ozone water storage tank (11) and the water surface is large, and due to the entrainment phenomenon of the ozone gas by the waves of ozonated water, the contact area with the ozone gas becomes even larger, which reduces the ozone dissolution efficiency. improves.
また、￥底筒内壁に形成されたオゾン水流の膜を通Ｌ、
オゾンガスか拡散されていくのて、（寸り目的効果ニし
てオ゛′）ホＪ度か高＜をる。In addition, the ozone water flow passes through the membrane formed on the inner wall of the bottom cylinder.
As the ozone gas is diffused, the temperature increases (depending on the intended effect).
上」、りようにｊ−て得；）ｉ″したオシ；水はオゾン
水貯留槽（１１）底部に設は毛れたオ゛ｌ′）＋Ｃ放出
パイプ（８）そ浦して液体ポンプ＜１：３）によりオゾ
ン水貯留槽（：１）外に放出される。The water is supplied from the ozone water storage tank (11), which is installed at the bottom, and the C discharge pipe (8) from which the liquid pump is placed. <1:3), the ozone water is released outside the ozone water storage tank (:1).
なお、オゾン水貯留槽（１１）内のオゾン水の水位を一
定とすると、それによって噴霧水とオゾンガスの接触面
積を一定とすることかでき、更に、オゾン水の濃度ら一
定となるのて水位計（９）及び（１０）によって供給量
を制御することかてきる。In addition, if the water level of the ozonated water in the ozonated water storage tank (11) is kept constant, the contact area between the spray water and the ozone gas can be kept constant.Furthermore, since the concentration of the ozonated water is kept constant, the water level can be kept constant. The supply amount can be controlled by the totals (9) and (10).
ここで、本発明のオシ〉・反応装置は水位計（９〉及び
（１０）の作用により連続式または間欠式に運転する二
！かてきる。Here, the reactor of the present invention can be operated continuously or intermittently by the action of the water level gauges (9) and (10).
ます、連続式の運転においては、オゾン水貯留槽（１１
）内のオゾン水の水位が一定になると、水位計（９）及
び（■０）からの信号によってオゾン水放出バイブ（８
〉から液体ポンプ（■８）によりオゾン水をオゾン水貯
留槽（１１）外に放出する。この場斤には、給水しなか
ら放出する二とによって連続的に高濃度力オソ′シ水を
得るニヒかできる。In continuous operation, ozone water storage tank (11
) When the ozonated water level in ) becomes constant, the ozonated water release vibrator (8
> from the liquid pump (■8) to discharge ozonated water to the outside of the ozonated water storage tank (11). In this case, it is possible to continuously obtain highly concentrated water by supplying and discharging water.
更に、間欠式の運転においては、オゾン水貯留槽（１１
）内の水位か一定になると、水位計（９）及び（１０）
からの信号により給水を止め、即時またはオゾン水貯留
槽〈ＩＩ）内のオゾン水を循環ポンプ（１６〉及び循環
管路〈１５）によりｉＩ￥厖環させて、上り高濃魔力オ
ゾン水としてオゾン水放出パイプ（８〉から７夜体ボニ
プ〈１８）によりオゾン水をオゾン水貯留槽（１１）外
に間欠的に放出する二とかできる。。Furthermore, in intermittent operation, the ozone water storage tank (11
) When the water level becomes constant, the water level gauges (9) and (10)
The water supply is stopped immediately or the ozonated water in the ozonated water storage tank (II) is circulated by the circulation pump (16) and the circulation pipe (15), and the ozonated water is turned into high-concentration magic ozonated water. It is possible to intermittently release ozonated water to the outside of the ozonated water storage tank (11) by using the water release pipe (8) to the water discharge pipe (18). .
また、反に筒下部にオゾン水貯留槽（１１，）ｅ設け’
Ａ Ｓとら 反応筒（５）かオゾン水山間欠使用に応し
るため、必要なオゾン水を貯留できる程充分大きければ
上記の間欠式の運転かできるか、反応筒内に残留するオ
ゾン量か本発明装置より多てなる。In addition, an ozone water storage tank (11,) is provided at the bottom of the cylinder.
A S Tora If the reaction tube (5) is large enough to store the necessary ozone water in order to meet the intermittent use of the ozone water mountain, can it be operated intermittently as described above, or is the amount of ozone remaining in the reaction tube? This is more than the device of the present invention.
オゾンガスを連続的に反応筒に装入する場合は、反応筒
内に残留するオゾンガス量の多少により、初期のオゾン
水濃度か異なり、また、一定濃度力オゾン水を得るまで
に時間も掛かる。When ozone gas is continuously charged into the reaction column, the initial ozone water concentration varies depending on the amount of ozone gas remaining in the reaction column, and it takes time to obtain ozone water at a constant concentration.
本発明装置は、反応筒よりら大形のオゾン水貯留槽を備
えることにより、オゾンガスか残留する空間を少なくし
、上述の影響を最小限にまたち力である。The apparatus of the present invention is equipped with an ozone water storage tank larger than the reaction tube, thereby reducing the space in which ozone gas remains and minimizing the above-mentioned effects.
史に、オゾン水濃度が短時間で一定になるように速続式
てオゾン水を製造する場合は、給水前にオソ〉′水貯留
槽（■１）外にオゾン水を放出した後、エアーポンプ（
１９〉を用いてエアーパイプ（７）かｔ）反応筒（５）
及びオゾン水貯留槽（１１〉内に空気を送り込み、未反
応のオゾンガスを排カスバイブ〈６）を通し、オゾンキ
ラー（２０）を介して反応筒（５）及びオゾン水貯留槽
（１１）外へ排出し、反応筒（５）及びオゾン水貯留槽
（１１）の残留オゾンガス量を一定に維持することがで
きる。これにより一定濃度の安定したオゾン水をより短
時間で得ることができる。Historically, when producing ozonated water using a rapid succession method so that the ozonated water concentration becomes constant in a short period of time, the ozonated water was released outside the ozone water storage tank (■1) before water supply, and then the air was pump(
19〉 using air pipe (7) or reaction tube (5)
Air is sent into the ozone water storage tank (11), and unreacted ozone gas is passed through the exhaust vibrator (6) and out of the reaction column (5) and the ozone water storage tank (11) via the ozone killer (20). The amount of residual ozone gas in the reaction tube (5) and the ozone water storage tank (11) can be maintained constant. This makes it possible to obtain stable ozonated water with a constant concentration in a shorter time.
更に、−液相の噴霧ノズルとしては反応筒の形状によっ
て１つまたは数個の充円錐ノズルまたは充角錐ノズルを
用いることによ１て反応筒内のオゾンガスと水の微粒子
との接触面積を大きくすることかできる。Furthermore, by using one or several full cone nozzles or full pyramidal nozzles as the liquid phase spray nozzle depending on the shape of the reaction tube, the contact area between the ozone gas and water particles in the reaction tube can be increased. I can do something.
更に、オゾン水貯留槽（１１）に溜まったオゾン水は貯
留槽内で停留することによって未溶解のオゾンガスか抜
けるので吐出されたオゾン水からのオゾンガスの放出が
少なくなる。Further, since the ozonated water accumulated in the ozonated water storage tank (11) remains in the storage tank, undissolved ozone gas escapes, so that the amount of ozone gas released from the discharged ozonated water is reduced.
更に、反応筒とオゾン水貯留槽とに機能か分離されてい
るので、−液相の噴霧ノズル（４〉からの給水の圧力及
びオゾンガスの流量、圧力及び濃度によ１で反応筒及び
貯留槽の最適な形状を選択することかできる。Furthermore, since the functions are separated into the reaction column and the ozone water storage tank, the reaction column and the storage tank can be separated at 1 depending on the pressure of the water supplied from the liquid phase spray nozzle (4) and the flow rate, pressure and concentration of ozone gas. You can choose the most suitable shape.
即ち、溶解効Ｔか最適て、しからオゾン水の濃度の立ち
上かり時間か短てなるように、反応筒の形状を小形にて
きると共にオゾン水貯留槽の形状は円筒あるいは箱形等
の任意力形状か選択できるのてオゾン反応装置を用いた
システム全体の形状かｉ）の要求にＪきすることかでき
、システム全体力形状を容易に小形にすることができる
。That is, in order to optimize the dissolution efficiency T and shorten the rise time of the ozonated water concentration, the shape of the reaction cylinder is made small, and the shape of the ozonated water storage tank is made into a cylinder or box shape. Since an arbitrary force shape can be selected, the shape of the entire system using the ozone reactor can be adjusted to meet the requirements of i), and the overall force shape of the system can be easily made small.
更に、オゾン水貯留槽の上部には、反応筒の接続の池に
、水位計力取り付は場所を設定することがて′きるのて
゛、オゾン水貯留槽内の水位力コ〉・ドローＩＬ ｆｌ
ｌの水位計はオゾン水貯留槽の上面及び下面に設置でき
るため、ストロークの短い安価な水位計そ用いることが
てきる。Furthermore, at the top of the ozone water storage tank, a water level gauge can be installed in the pond connected to the reaction cylinder, so the water level power cord in the ozone water storage tank can be adjusted.
Since the water level gauge 1 can be installed on the upper and lower surfaces of the ozone water storage tank, an inexpensive water level gauge with a short stroke can be used.
オゾン水製造例１
オシ〉水貯留槽を備えたオゾン反応装置反応筒（５）の
寸法 内径１００Ｉ 高さ１００ｍｍオゾシ水オゾ
ン水貯留槽法 縦１２０ ｍ ｍ横１６０１帥
高さ１：’１０ｍＩＩｌ
上述の寸法をらつ装置を用いて濃度６０，０００ｐｐｍ
のオゾンガスを１２０ｃｃ、１分で送入し、２１．、．
１分の水を連続的に給水したところ濃度６ ｐｐｍのオ
シ〉・水を得た。また、濃度６ ｐｐｍの安定したオシ
〉水を得るまでにかかった時間は約１０分間であった。Ozone water production example 1 Ozone reactor equipped with a water storage tank Dimensions of reaction cylinder (5) Inner diameter 100 mm Height 100 mm Ozone water Ozone water storage tank method Length 120 mm Width 160 mm Height 1: 10 m IIl As described above Concentration 60,000 ppm using a device with large dimensions
Inject 120cc of ozone gas in 1 minute, 21. ,．
When water was continuously supplied for 1 minute, water with a concentration of 6 ppm was obtained. Further, it took about 10 minutes to obtain stable osseous water with a concentration of 6 ppm.
オゾン水製造例２（比較例）。Ozonated water production example 2 (comparative example).
反応筒を大きくし、上述と同量のオゾン水を貯留できる
反応筒（内径１００ｍｍ 、高さ４００１）を用いて上
述と同条件でオゾン水を作ったが、連続的に濃度６ ｐ
ｐｍの安定したオゾン水を得るまでに約４０分間かかっ
た。Ozonated water was made under the same conditions as above using a reaction cylinder (inner diameter 100 mm, height 400 mm) that could store the same amount of ozonated water as above, but with a continuous concentration of 6 p.
It took about 40 minutes to obtain ozonated water with a stable pm.
これは反応筒より大型カオゾン水貯留槽を備えずに単に
反応筒のみを大きくした場合の例であり、上述の本発明
装置より劣ることか判る。This is an example in which only the reaction tube is made larger without providing a larger caozone water storage tank than the reaction tube, and it can be seen that it is inferior to the apparatus of the present invention described above.
「発明の効果］
以上の説明から明らかなように、本発明によれば反応筒
とオゾン水貯留槽とに機能が分離しているために、上述
のような簡単なオゾン反応装置により、一定濃魔力所望
の高濃度のオゾン水を連続的に得られ、丘つ間Ｘ的な使
用に耐えるような多量力オゾン水看で、更に高ＩＡ度の
オゾン水を短時間に得ることかできると共にオゾン反応
装置そ用いたシステム全体の形状をコンパクトにする二
とかできる。“Effects of the Invention” As is clear from the above explanation, according to the present invention, the functions are separated into the reaction column and the ozone water storage tank, so that a constant concentration can be achieved using the simple ozone reaction device as described above. It is possible to continuously obtain ozonated water with the desired high concentration of magical power, and with a large amount of ozonated water that can withstand long-term use, it is possible to obtain ozonated water with a high IA degree in a short time, and also ozone water. The shape of the entire system using the reactor can be made more compact.
Claims (1)
ズル（４）と、水を電気分解してオゾンガスを得るため
のオゾナイザ（１７）と、オゾナイザ（１７）からのオ
ゾンガスを前記反応筒（５）内に放出する散気具（２）
と、反応筒（５）の下部に接続されたオゾン水貯留槽（
１１）と、得られたオゾン水を放出する液体ポンプ（１
８）と、得られたオゾン水を前記噴霧ノズル（４）へ戻
すための循環管路（１５）を備えてなり、上記オゾン水
貯留槽を反応筒（５）より大形としたことを特徴とする
オゾン水製造装置。 ２、反応筒（５）内に空気を送り込むためのエアーポン
プ（１９）と、前記反応筒（５）の上部に接続し、オゾ
ンガスを分解無害化するオゾンキラー（２０）とを備え
てなる請求項１記載のオゾン水製造装置。[Claims] 1. A reaction tube (5), a spray nozzle (4) provided in the reaction tube (5), an ozonizer (17) for electrolyzing water to obtain ozone gas, and an ozonizer ( 17) a diffuser (2) that releases ozone gas from the reactor into the reaction tube (5);
and an ozone water storage tank (
11) and a liquid pump (1) that releases the obtained ozonated water.
8) and a circulation pipe (15) for returning the obtained ozonated water to the spray nozzle (4), and the ozonated water storage tank is larger than the reaction tube (5). Ozone water production equipment. 2. A claim comprising an air pump (19) for feeding air into the reaction tube (5), and an ozone killer (20) connected to the upper part of the reaction tube (5) to decompose ozone gas and render it harmless. Item 1. The ozonated water production device according to item 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2016159A JPH03221196A (en) | 1990-01-29 | 1990-01-29 | Apparatus for making ozonized water |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2016159A JPH03221196A (en) | 1990-01-29 | 1990-01-29 | Apparatus for making ozonized water |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03221196A true JPH03221196A (en) | 1991-09-30 |
Family
ID=11908731
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2016159A Pending JPH03221196A (en) | 1990-01-29 | 1990-01-29 | Apparatus for making ozonized water |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03221196A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20050066881A (en) * | 2003-12-27 | 2005-06-30 | 동부아남반도체 주식회사 | Device for making o3 water |
| JP2009262028A (en) * | 2008-04-23 | 2009-11-12 | Toyota Motor Corp | Treatment method and device for ozone solution |
| KR101000779B1 (en) * | 2010-05-28 | 2011-01-04 | 주식회사 지케이옥시 | The apparatus for development of an oxygen water |
| WO2012029906A1 (en) * | 2010-09-01 | 2012-03-08 | シャープ株式会社 | Medical device washing method and medical device washing device |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63171694A (en) * | 1986-12-29 | 1988-07-15 | Katsumi Takao | Ozonized water feeder |
-
1990
- 1990-01-29 JP JP2016159A patent/JPH03221196A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63171694A (en) * | 1986-12-29 | 1988-07-15 | Katsumi Takao | Ozonized water feeder |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20050066881A (en) * | 2003-12-27 | 2005-06-30 | 동부아남반도체 주식회사 | Device for making o3 water |
| JP2009262028A (en) * | 2008-04-23 | 2009-11-12 | Toyota Motor Corp | Treatment method and device for ozone solution |
| KR101000779B1 (en) * | 2010-05-28 | 2011-01-04 | 주식회사 지케이옥시 | The apparatus for development of an oxygen water |
| WO2012029906A1 (en) * | 2010-09-01 | 2012-03-08 | シャープ株式会社 | Medical device washing method and medical device washing device |
| CN102985026A (en) * | 2010-09-01 | 2013-03-20 | 夏普株式会社 | Medical device washing method and medical device washing device |
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