JPH03218789A - Blade body applied with coating treatment - Google Patents

Blade body applied with coating treatment

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Publication number
JPH03218789A
JPH03218789A JP1534290A JP1534290A JPH03218789A JP H03218789 A JPH03218789 A JP H03218789A JP 1534290 A JP1534290 A JP 1534290A JP 1534290 A JP1534290 A JP 1534290A JP H03218789 A JPH03218789 A JP H03218789A
Authority
JP
Japan
Prior art keywords
layer
high hardness
stress relaxation
blade
coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP1534290A
Other languages
Japanese (ja)
Inventor
Hiroaki Miyazaki
宮崎 宏明
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kaijirushi Hamono Center KK
Original Assignee
Kaijirushi Hamono Center KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kaijirushi Hamono Center KK filed Critical Kaijirushi Hamono Center KK
Priority to JP1534290A priority Critical patent/JPH03218789A/en
Publication of JPH03218789A publication Critical patent/JPH03218789A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:Not only to improve the non-cohesiveness but also to improve the cutting quality and the durability in the blade body to which fluororesin coating is performed by performing the coating of three layers of a stress relaxation layer, a high hardness layer and a non-cohesive resin layer to a blade part of a stock. CONSTITUTION:To the blade body, the coating treatment of three layers consisting of a stress relaxation layer 3 formed by executing directly coating to the outside surface of a blade part 2 of a stock 1, a high hardness layer 4 formed by executing coating to the outside surface of this stress relaxation layer 3, and a non-cohesive resin layer 5 formed by executing coating to the outside surface of this high hardness layer 4 and the outside surface of the stock 1 is performed. The high hardness layer 4 further coated with the non-cohesive resin layer, and this high hardness layer 4 becomes a blade tip 4a and the cutting quality and the durability can be improved. Also, the stock 1 and the high hardness layer 4 are inferior in adhesion because various characteristics are different, but since the stress relaxation layer 3 is interposed between them, adhesion of the stock 1 and the stress relaxation layer 3, and adhesion of the stress relaxation layer 3 and the high hardness layer 4 are improved, respectively, and as a result, adhesion of the stock 1 and the high hardness layer 4 can be made firm.

Description

【発明の詳細な説明】 発明の目的 [産業上の利用分野] この発明はコーティング処理を施した鋏等の刃物の刃体
において、そのコーティング層の改良に関するものであ
る. [従来の技術] 従来、このような刃体としては、ステンレス鋼等からな
る素材の外面にふっ素樹脂コーティングを施したものが
ある.このようなふっ素樹脂コ−ティングにより、刃体
への粘着性が低下し、被切断物が付着し難くなる. [発明が解決しようとする課題] このような刃体においては、素材の刃先を露出させて使
用するが、素材を加工する必要上、素材の材質を高硬度
のものにすることが難しく、切れ味や耐久性が悪くなる
. 本発明はこのようなふっ素樹脂コーティングを施した刃
体において、非粘着性の向上ばかりではなく、切れ味や
耐久性をも向上させることを目的としている. 発明の構成 [課題を解決するための手段〕 この目的に鑑み本発明は、後記する各実施例の図面に示
すように、素材1の刃部2にコーティングした応力緩和
層3と、この応力緩和層3にコーティングした高硬度層
4と、この高硬度層4にコーティングした非粘着性樹脂
層5とからなる三層のコーティング処理を施したもので
ある。
DETAILED DESCRIPTION OF THE INVENTION Purpose of the Invention [Industrial Field of Application] The present invention relates to improving the coating layer of a coated blade body of a cutlery such as scissors. [Prior Art] Conventionally, such blade bodies have been made of a material such as stainless steel with a fluororesin coating applied to the outer surface. Such a fluororesin coating reduces the adhesion to the blade, making it difficult for objects to be cut to adhere to it. [Problem to be solved by the invention] In such a blade, the cutting edge of the material is exposed, but due to the necessity of processing the material, it is difficult to make the material of the material highly hard, and the sharpness is poor. and durability deteriorates. The purpose of the present invention is to improve not only the non-stick properties but also the sharpness and durability of blades coated with fluororesin. Structure of the Invention [Means for Solving the Problems] In view of this object, the present invention provides a stress relaxation layer 3 coated on a blade portion 2 of a material 1, and a stress relaxation layer 3 coated on a blade portion 2 of a material 1, as shown in the drawings of each embodiment described later. A three-layer coating process consisting of a high hardness layer 4 coated on layer 3 and a non-adhesive resin layer 5 coated on this high hardness layer 4 is performed.

[作用] このように構成された刃体においては、高硬度層4の刃
先4aにより被切断物が切断され、この切17i後非粘
着性樹脂層5に被切断物が接触してもこれに付着しにく
い. 又、素材1と高硬度層4とは各種特性が異なるため、密
着性に劣るが、それらの間に応力緩和層3を介在させて
いるので、素材1と応力緩和層3との密着性及び応力緩
和層3と高硬度層4との密着性がそれぞれ向上する. 「第一実施例] まず、本発明を鋏の刃体に具体化した第一実施例を第1
図(a)〜(h)に従って説明する.第1図(g)(h
)示すように、本実施例に係る刃体には素材1の刃部2
の外面に直接コーティングした応力緩和層3と、この応
力緩和層3の外面にコーティングした高硬度層4と、こ
の高硬度層4の外面及び素材1の外面にコーティングし
た非粘着性樹脂層5とからなる三層のコーティング処理
が施されている. この刃体の製造手順を詳述する. 第1図(a)に示す素材1はステンレス鋼や炭素工具鋼
等からなる.このような素材1の一端縁に対し第1図(
b)に示すような斜状の刃付面2aを素材1の一端面1
aに連続するように形成する.さらに、素材1の一端面
1aを除去して第1図(C)に示すような斜状の小刃付
面2bを刃付面2aに連続するように形成する.この刃
付面2aと小刃付面2bとにより素材1に刃部2が形成
される. 次に、前記刃部2の外面に第1図(d)に示すような応
力緩和層3をコーティングする.この応力緩和層3はT
i(チタン)からなり、その厚みAは約0.1μである
.なお、この応力緩和層3の材質としては、Zr(ジル
コニウム)、Hf(ハフニウム)、■(バナジウム)、
Nb(ニオブ)、Ta(タンタル)、Cr(クロム)、
MO(モリブデン》、W《タングステン》等、周期律表
IVa族、Va族、Vla族の金属を使用する.次に、
前記応力緩和層3の外面に第1図(e)に示すような高
硬度層4をコーティングする.この高硬度層4はビッカ
ース硬さHv2000以上のTiN(窒化チタン》又は
Tic(炭化チタン》又はTiCN(炭窒化チタン)か
らなり、その厚みBは1〜10μである,なお、この高
硬度層4としては、前記のもの以外に、前記各族の金属
の窒化物又は炭化物又は炭窒化物を使用する.次に、前
記高硬度層4の外面を含む素材1の外面全体に第1図(
f)に示すような非粘着性樹脂層(5)をコーティング
する。この非粘着性樹脂層5はふっ素樹脂からなり、そ
の厚みCは3〜15μである。ふっ素樹脂としては、ボ
リ四フッ化エチレン(PTFE)+ボリフッ化ビニル(
PVF》、ボリフッ化ビニリデン(PVdF)、ポリ塩
化三フッ化エチレン(PCTFE) 、四フッ化エチレ
ン六フッ化プロピレン共重合体(FEP)、エチレンー
四フッ化エチレン共重合体(ETFE)、エチレンー塩
化三フッ化工犬レン共重合体ECTFE)、四フッ化エ
チレンーパーフルオロアルキルビニルエーテル共重合体
(PFA)等を使用し、このようなふっ素樹脂を単体と
して又は混合して使用する場合と、このようなふっ素樹
脂をノ《インダー樹脂に混合してバインダー樹脂内にふ
っ素樹脂を分散したコーティング液を使用する場合とが
考えられる.バインダー樹脂を利用すれば、より強い密
着性を得る。バインダー樹脂としては、フェノール樹脂
、アクリル樹脂、エポキシ樹脂、ポリアミドイミド樹脂
、ウレタン樹脂、シリコン樹脂などがある. 次に、第1図(g)に示すようなカッティングを行う.
このカッティングにより、刃部2の小刃付面2b上の高
硬度層4に沿って非粘着性樹脂層5が除去され、高硬度
層4が露出する.このような刃体を有する一対の鉄片を
互いに開閉可能に支持し、両刃体を互いに摺り合わせる
と、第1図(g)に示すような摩耗線Wまで非粘着性樹
脂層5が摺り減り、第1図(h)に示すように高硬度層
4の刃先4aが露出する. このように本実施例の鋏の刃体は、応力緩和層3と高硬
度層4と非粘着性樹脂層5とにより三層のコーティング
が施されている.非粘着性樹脂層5は被切断物の付着を
防止する.この点は前述した従来技術のものと同様であ
るが、素材1の刃部2において高硬度層4がコーティン
グされ、この高硬度層4に非粘着性樹脂層5がさらにコ
ーティングされている点で、本実施例は従来技術のもの
と異なる.従って、この高硬度層4が刃先4aとなって
切れ昧及び耐久性を向上させることができる。又、素材
1と高硬度層4とは各種特性が異なるため、密着性に劣
るが、それらの間に応力緩和層3を介在させているので
、素材1と応力緩和層3との密着性及び応力緩和層3と
高硬度層4との密着性がそれぞれ向上し、ひいては素材
1と高硬度層4との密着性を強固なものとすることがで
きる。
[Function] In the blade body configured in this way, the object to be cut is cut by the cutting edge 4a of the high hardness layer 4, and even if the object to be cut comes into contact with the non-adhesive resin layer 5 after cutting 17i, the object will not be cut. Difficult to adhere. Furthermore, since the material 1 and the high-hardness layer 4 have different properties, their adhesion is poor, but since the stress relaxation layer 3 is interposed between them, the adhesion between the material 1 and the stress relaxation layer 3 is improved. The adhesion between the stress relaxation layer 3 and the high hardness layer 4 is improved. “First Example” First, the first example in which the present invention is embodied in a scissors blade body is described in the first example.
This will be explained according to figures (a) to (h). Figure 1 (g) (h
) As shown, the blade according to this embodiment has a blade portion 2 of a material 1.
a stress relaxation layer 3 coated directly on the outer surface of the material 1; a high hardness layer 4 coated on the outer surface of the stress relaxation layer 3; and a non-adhesive resin layer 5 coated on the outer surface of the high hardness layer 4 and the outer surface of the material 1. A three-layer coating process is applied. The manufacturing procedure for this blade will be explained in detail. The material 1 shown in Fig. 1(a) is made of stainless steel, carbon tool steel, etc. For one end edge of such material 1 as shown in FIG.
The oblique bladed surface 2a as shown in b) is attached to one end surface 1 of the material 1.
Form so that it is continuous with a. Furthermore, one end surface 1a of the material 1 is removed to form a diagonal small blade surface 2b continuous with the blade surface 2a as shown in FIG. 1(C). A blade portion 2 is formed on the material 1 by the blade surface 2a and the small blade surface 2b. Next, the outer surface of the blade portion 2 is coated with a stress relaxation layer 3 as shown in FIG. 1(d). This stress relaxation layer 3 is T
It is made of titanium (titanium) and its thickness A is approximately 0.1μ. Note that the materials of this stress relaxation layer 3 include Zr (zirconium), Hf (hafnium), ■ (vanadium),
Nb (niobium), Ta (tantalum), Cr (chromium),
Use metals from the IVa group, Va group, and Vla group of the periodic table, such as MO (molybdenum) and W (tungsten).Next,
The outer surface of the stress relaxation layer 3 is coated with a high hardness layer 4 as shown in FIG. 1(e). This high hardness layer 4 is made of TiN (titanium nitride), Tic (titanium carbide), or TiCN (titanium carbonitride) with a Vickers hardness of Hv2000 or more, and its thickness B is 1 to 10μ. In addition to the above-mentioned materials, nitrides, carbides, or carbonitrides of metals of the above-mentioned groups are used.Next, the entire outer surface of the material 1 including the outer surface of the high-hardness layer 4 is coated as shown in FIG.
Coat with a non-stick resin layer (5) as shown in f). This non-adhesive resin layer 5 is made of fluororesin and has a thickness C of 3 to 15 microns. As a fluororesin, polytetrafluoroethylene (PTFE) + polyfluorinated vinyl (
PVF》, polyvinylidene fluoride (PVdF), polychlorinated trifluoroethylene (PCTFE), tetrafluoroethylene hexafluoropropylene copolymer (FEP), ethylene-tetrafluoroethylene copolymer (ETFE), ethylene-trifluoroethylene copolymer (ETFE), Fluorinated polyurethane copolymer (ECTFE), tetrafluoroethylene-perfluoroalkyl vinyl ether copolymer (PFA), etc. are used, and such fluororesins are used alone or in combination; One possibility is to mix fluororesin with binder resin and use a coating liquid in which fluororesin is dispersed within the binder resin. By using a binder resin, stronger adhesion can be obtained. Binder resins include phenol resin, acrylic resin, epoxy resin, polyamideimide resin, urethane resin, and silicone resin. Next, perform cutting as shown in Figure 1 (g).
By this cutting, the non-adhesive resin layer 5 is removed along the high hardness layer 4 on the small edged surface 2b of the blade part 2, and the high hardness layer 4 is exposed. When a pair of iron pieces having such blade bodies are supported so as to be openable and closable, and both blade bodies are rubbed against each other, the non-adhesive resin layer 5 is rubbed down to a wear line W as shown in FIG. 1(g). As shown in FIG. 1(h), the cutting edge 4a of the high hardness layer 4 is exposed. As described above, the scissor blade of this embodiment is coated with three layers: the stress relaxation layer 3, the high hardness layer 4, and the non-adhesive resin layer 5. The non-adhesive resin layer 5 prevents objects to be cut from sticking. This point is similar to that of the prior art described above, except that the blade portion 2 of the material 1 is coated with a high hardness layer 4, and this high hardness layer 4 is further coated with a non-adhesive resin layer 5. , this embodiment is different from the prior art. Therefore, this high hardness layer 4 becomes the cutting edge 4a, and can improve sharpness and durability. Furthermore, since the material 1 and the high-hardness layer 4 have different properties, their adhesion is poor, but since the stress relaxation layer 3 is interposed between them, the adhesion between the material 1 and the stress relaxation layer 3 is improved. The adhesion between the stress relaxation layer 3 and the high-hardness layer 4 is improved, and as a result, the adhesion between the material 1 and the high-hardness layer 4 can be strengthened.

[第二実施例] 次に、本発明の第二実施例を第2図(a)〜(g)に従
って説明する. 前記第一実施例では第1図(g)(h)に示すごとく素
材1の刃部2の小刃付面2bに高硬度層4がコーティン
グされたままの状態となるように非粘着性樹脂層5のみ
が第1図(f)の状態からカッティングされているが、
この第二実施例では第2図(f>(g)に示すごとく小
刃付面2bが露出するように高硬度層4もカッティング
されている. この第二実施例では第一実施例と比較して小刃付面2b
の露出の有無の他に、製造手順が異なる.すなわち、第
2図(a)に示す素材1から第2図(b)に示す刃付を
行う点は、第一実施例の第1図(a)(b)に示す場合
と同様であるが、第一実施例では第1図(b)に示す刃
付からさらに第1図(C)に示す小刃付を行っているの
に対し、この第二実施例ではこのような小刃付は省略さ
れ、第2図(b)に示す刃付状態のまま第2図(c)(
d)に示すような応力緩和層3及び高硬度層4のコーテ
ィングを第一実施例の第1図(d)(e)に示す場合と
同様にして行っている. 次に、この第二実施例では第2図(e)に示すような非
粘着性樹脂層5のコーティングを第一実施例の第1図(
f)に示す場合と同様にして行う。
[Second Embodiment] Next, a second embodiment of the present invention will be described with reference to FIGS. 2(a) to 2(g). In the first embodiment, the non-adhesive resin is applied so that the high hardness layer 4 remains coated on the cutter surface 2b of the blade portion 2 of the material 1 as shown in FIGS. 1(g) and 1(h). Only layer 5 is cut from the state shown in FIG. 1(f), but
In this second embodiment, the high hardness layer 4 is also cut so that the small edged surface 2b is exposed as shown in Fig. 2 (f>(g)). Small blade surface 2b
The manufacturing procedure differs in addition to the presence or absence of exposure. That is, the point that the cutting edge shown in FIG. 2(b) is performed from the material 1 shown in FIG. 2(a) is the same as that shown in FIGS. 1(a) and (b) of the first embodiment. In the first embodiment, a small blade shown in FIG. 1(C) is added to the blade shown in FIG. 1(b), whereas in this second embodiment, such a small blade is added. This is omitted, and the blade shown in FIG. 2(c) remains in the state shown in FIG. 2(b).
Coating of the stress relaxation layer 3 and high hardness layer 4 as shown in d) was carried out in the same manner as in the case shown in FIGS. 1(d) and 1(e) of the first embodiment. Next, in this second embodiment, the coating of the non-adhesive resin layer 5 as shown in FIG. 2(e) is applied as shown in FIG.
It is carried out in the same manner as in the case shown in f).

第二実施例の第2図(e)に示す場合と,第一実施例の
第1図(f)に示す場合とを比較すると、第二実施例が
小刃付を行っていない点で第一実施例と異なる. 次に、この第二実施例では第2図(f)に示すように非
粘着性樹脂層5及び高硬度層4をカッティングすると同
時に、素材1の刃部2に小刃付を行い、刃部2の小刃付
面2bを露出させる.そして、鋏の刃体を互いに摺り合
わせると、第2図(g)に示すように非粘着性樹脂層5
が摺り減って高硬度層4の刃先4aが露出する。
Comparing the case shown in FIG. 2(e) of the second embodiment and the case shown in FIG. 1(f) of the first embodiment, the second embodiment is the second embodiment in that it does not have a small blade. This is different from one embodiment. Next, in this second embodiment, as shown in FIG. 2(f), the non-adhesive resin layer 5 and the high hardness layer 4 are cut, and at the same time, a small blade is attached to the blade part 2 of the material 1. 2.Expose the small blade surface 2b. Then, when the blades of the scissors are rubbed together, a non-adhesive resin layer 5 is formed as shown in FIG. 2(g).
is worn away and the cutting edge 4a of the high hardness layer 4 is exposed.

この第二実施例においても、応力緩和層3と高硬度層4
と非粘着性樹脂層5とにより三層構造とした利点は、前
記第一実施例の場合と同様である。
Also in this second embodiment, the stress relaxation layer 3 and the high hardness layer 4
The advantage of having a three-layer structure consisting of the non-adhesive resin layer 5 and the non-adhesive resin layer 5 is the same as that of the first embodiment.

[第三実施例] 次に、第3図(a)〜(C)に示す第三実施例を説明す
る. 第3図(b)(c)に示すようにこの第三実施例では素
材1の刃部2の小刃付面2bに非粘着性樹脂層5がコー
ティングされている点で、第二実施例の第2図(f)(
g)に示す場合と興なる.この第三実施例に係る鋏の刃
体の製造手順は、第二実施例の第2図(a>(b)(c
)(d)に示すまでは同様であるが、第二実施例では第
2図(d)に示す状態から第2図(e)に示すように非
粘着性樹脂層5をコーティングしているのに対し、この
第三実施例では第3図(a)に示すように第2図(d)
に示す状態から素材1の刃部2に小刃付を行い、応力緩
和層3及び高硬度層4をカッティングするとともに小刃
付面2bを露出させている。
[Third Embodiment] Next, a third embodiment shown in FIGS. 3(a) to (C) will be described. As shown in FIGS. 3(b) and 3(c), this third embodiment is different from the second embodiment in that the small blade surface 2b of the blade portion 2 of the material 1 is coated with a non-adhesive resin layer 5. Figure 2 (f) (
The case shown in g) is interesting. The manufacturing procedure of the scissors blade according to the third embodiment is as shown in FIG. 2 (a>(b)(c) of the second embodiment).
) (d), but in the second embodiment, the non-adhesive resin layer 5 is coated from the state shown in FIG. 2(d) to the state shown in FIG. 2(e). On the other hand, in this third embodiment, as shown in FIG. 3(a), FIG. 2(d)
From the state shown in FIG. 1, a small blade is applied to the blade portion 2 of the material 1, and the stress relaxation layer 3 and high hardness layer 4 are cut, and the small blade surface 2b is exposed.

そして、第3図(a)に示す状態から非粘着性樹脂層5
を第3図(b)に示すようにコーティングする.この第
三実施例に係る鋏の刃体を互いに摺り合わせると、高硬
度層4の刃先4aが第3図(c)に示すように露出する
. この第三実施例においても、応力緩和層3と高硬度層4
と非粘着性樹脂層5とにより三層槽遣とした利点は、前
記第一実施例の場合と同様である.発明の効果 本発明によれば、非粘着性樹脂層5が被切断物の付着を
防止するばかりではなく、高硬度層4が刃先4aとなっ
て切れ味及び耐久性を向上させることができるとともに
、素材1と高硬度層4との密着性を強固なものとするこ
とができる.
Then, from the state shown in FIG. 3(a), the non-adhesive resin layer 5
Coat as shown in Figure 3(b). When the blade bodies of the scissors according to the third embodiment are rubbed together, the cutting edge 4a of the high hardness layer 4 is exposed as shown in FIG. 3(c). Also in this third embodiment, the stress relaxation layer 3 and the high hardness layer 4
The advantage of having a three-layered tank structure with the non-adhesive resin layer 5 and the non-adhesive resin layer 5 is the same as in the first embodiment. Effects of the Invention According to the present invention, the non-adhesive resin layer 5 not only prevents the object to be cut from sticking, but also the high hardness layer 4 serves as the cutting edge 4a to improve sharpness and durability. The adhesion between the material 1 and the high hardness layer 4 can be made strong.

【図面の簡単な説明】[Brief explanation of drawings]

第1図(a)〜(h)は第一実施例に係る鋏の刃体の製
造手順を示すために刃体の断面梢遣を表した説明図、第
2図(a)〜(g)は第二実施例に係る同様な説明図、
第3図(a)〜(c)は第三実施例に係る同様な説明図
である。 1・・・素材、2・・・刃部、2a・・・刃付面、2b
・・・小刃付面、3・・・応力緩和層、4・・・高硬度
層、4a・・・刃先、5・・・非粘着性樹脂層.
FIGS. 1(a) to (h) are explanatory views showing the cross-section of the scissor blade according to the first embodiment, and FIGS. 2(a) to (g) is a similar explanatory diagram according to the second embodiment,
FIGS. 3(a) to 3(c) are similar explanatory diagrams according to the third embodiment. 1...Material, 2...Blade portion, 2a...Blade surface, 2b
... small blade surface, 3 ... stress relaxation layer, 4 ... high hardness layer, 4a ... cutting edge, 5 ... non-adhesive resin layer.

Claims (1)

【特許請求の範囲】[Claims] 1、素材(1)の刃部(2)にコーティングした応力緩
和層(3)と、この応力緩和層(3)にコーティングし
た高硬度層(4)と、この高硬度層(4)にコーティン
グした非粘着性樹脂層(5)とからなる三層のコーティ
ング処理を施したことを特徴とする刃体。
1. A stress relaxation layer (3) coated on the blade part (2) of the material (1), a high hardness layer (4) coated on this stress relaxation layer (3), and a coating on this high hardness layer (4). A blade body characterized by being subjected to a three-layer coating treatment consisting of a non-adhesive resin layer (5).
JP1534290A 1990-01-25 1990-01-25 Blade body applied with coating treatment Pending JPH03218789A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1534290A JPH03218789A (en) 1990-01-25 1990-01-25 Blade body applied with coating treatment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1534290A JPH03218789A (en) 1990-01-25 1990-01-25 Blade body applied with coating treatment

Publications (1)

Publication Number Publication Date
JPH03218789A true JPH03218789A (en) 1991-09-26

Family

ID=11886118

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1534290A Pending JPH03218789A (en) 1990-01-25 1990-01-25 Blade body applied with coating treatment

Country Status (1)

Country Link
JP (1) JPH03218789A (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6342378B2 (en) * 1980-04-04 1988-08-23 Nippon Telegraph & Telephone
JPS6447849A (en) * 1987-08-11 1989-02-22 Sekisui Chemical Co Ltd Ceramic coating product and ceramic coating cutting tool

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6342378B2 (en) * 1980-04-04 1988-08-23 Nippon Telegraph & Telephone
JPS6447849A (en) * 1987-08-11 1989-02-22 Sekisui Chemical Co Ltd Ceramic coating product and ceramic coating cutting tool

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