JPS6342378B2 - - Google Patents

Info

Publication number
JPS6342378B2
JPS6342378B2 JP55044449A JP4444980A JPS6342378B2 JP S6342378 B2 JPS6342378 B2 JP S6342378B2 JP 55044449 A JP55044449 A JP 55044449A JP 4444980 A JP4444980 A JP 4444980A JP S6342378 B2 JPS6342378 B2 JP S6342378B2
Authority
JP
Japan
Prior art keywords
catalyst
plug
container
outer container
storage battery
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP55044449A
Other languages
Japanese (ja)
Other versions
JPS56141181A (en
Inventor
Toshio Matsushima
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Telegraph and Telephone Corp
Original Assignee
Nippon Telegraph and Telephone Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Telegraph and Telephone Corp filed Critical Nippon Telegraph and Telephone Corp
Priority to JP4444980A priority Critical patent/JPS56141181A/en
Publication of JPS56141181A publication Critical patent/JPS56141181A/en
Publication of JPS6342378B2 publication Critical patent/JPS6342378B2/ja
Granted legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/52Removing gases inside the secondary cell, e.g. by absorption
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Landscapes

  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Secondary Cells (AREA)

Description

【発明の詳細な説明】 本発明は蓄電池から発生する酸素、水素、混合
ガスを触媒反応によつて再結合させる熱放散、生
成水蒸気の凝縮を妨げない蓄電池用触媒栓に関す
るものである。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a catalyst plug for a storage battery that does not hinder heat dissipation that recombines oxygen, hydrogen, and a mixed gas generated from a storage battery through a catalytic reaction, and condensation of the generated water vapor.

従来の触媒栓の構造を第1図に示した。 The structure of a conventional catalyst plug is shown in FIG.

触媒栓では、下部の還水口6より内部に流入し
た酸素・水素混合ガスは、多孔質のアルミナ焼結
体から成る触媒容器1を通過して触媒2に到達
し、反応する。この反応によつて水蒸気が生成
し、この水蒸気は外器3の内壁で潜熱を放出して
凝縮する。また、この反応は発熱反応であり、多
量の熱が発生するが、この熱も外器3を通して外
部に放出されている。このように、外器3は触媒
栓で発生した熱を触媒栓外へ放出する役割りと、
生成した水蒸気を凝縮させる役割りを果たしてい
る。従つて外器3の熱放散が妨げられた場合には
外器温度が上昇し、水蒸気の凝縮が妨げられてし
まう。しかしながら従来の型の触媒栓では外器3
の頂部に排気孔4があり、防爆フイルタ5も外器
3の上面をおおうため、放熱抵抗となり、放熱に
有効な面積が減少し、生成水蒸気の凝縮が妨げら
れ触媒栓の性能が低下する欠点があつた。
In the catalyst plug, the oxygen/hydrogen mixed gas that has flowed into the interior through the lower water return port 6 passes through the catalyst container 1 made of a porous alumina sintered body, reaches the catalyst 2, and reacts therewith. Water vapor is generated by this reaction, and this water vapor releases latent heat and condenses on the inner wall of the outer vessel 3. Further, this reaction is an exothermic reaction, and a large amount of heat is generated, but this heat is also released to the outside through the outer container 3. In this way, the outer container 3 has the role of discharging the heat generated in the catalyst plug to the outside of the catalyst plug.
It plays the role of condensing the generated water vapor. Therefore, if the heat dissipation of the outer container 3 is hindered, the temperature of the outer container will rise, and the condensation of water vapor will be prevented. However, in the conventional catalyst plug, the outer container 3
There is an exhaust hole 4 at the top of the casing, and the explosion-proof filter 5 also covers the top surface of the outer container 3, which creates resistance to heat radiation, reduces the effective area for heat radiation, and prevents condensation of generated steam, resulting in a reduction in the performance of the catalyst plug. It was hot.

この欠点を除くため、蓄電池に使用するフイル
タの形状を小さくすることも考えられる。しかし
蓄電池を浮動充電状態で負荷に電力を供給する場
合において、フイルタが小型になると充電用整流
器の故障などによつて、大きな充電電流が流れ、
多量のガスが発生し、これが未反応ガスとして排
出される場合には防爆性能を保証し得ない恐れも
ある。
In order to eliminate this drawback, it may be possible to reduce the size of the filter used in the storage battery. However, when supplying power to a load with a storage battery in a floating charging state, if the filter becomes small, a large charging current will flow due to a failure of the charging rectifier, etc.
If a large amount of gas is generated and is discharged as unreacted gas, there is a possibility that explosion-proof performance cannot be guaranteed.

本発明は従来のかかる欠点を克服し、外器表面
を反応熱の放散と水蒸気の凝縮に有効に利用して
触媒栓の還水効率の向上を図るため、上部を密封
した円筒体と中央部に開口した還水口に向かつて
下向きに傾斜する環状傾斜面を有する底部とを一
体に構成した外器内に、触媒材を収納したセラミ
ツク製触媒容器を配設し、蓄電池から発生する酸
素と水素ガスを再結合し、電解液中に水分を還流
させる蓄電池用触媒栓において、前記外器内中央
部の温度より低い温度にある外器側壁面に近接し
て排気管を設け、前記排気管は前記環状傾斜面に
穿たれた孔を貫通し、その一端が前記触媒容器の
上端の高さに開口し、他端は前記環状傾斜面の外
壁面に接着した断面が略コ字形状をなす環状の防
爆フイルタ内に開口していることを特徴とする。
The present invention overcomes such drawbacks of the conventional art and effectively uses the surface of the outer vessel for dissipating reaction heat and condensing water vapor to improve the return water efficiency of the catalyst plug. A ceramic catalyst container containing catalyst material is placed inside the outer container, which is integrated with a bottom part that has an annular slope that slopes downward toward the water return port that opens to the water return port. In a catalyst plug for a storage battery that recombines gas and refluxes water into an electrolytic solution, an exhaust pipe is provided in close proximity to a side wall surface of the outer container whose temperature is lower than the temperature of the central part of the outer container, and the exhaust pipe is An annular shape having a substantially U-shaped cross section, which passes through a hole bored in the annular inclined surface, has one end opening at the height of the upper end of the catalyst container, and has the other end adhered to the outer wall surface of the annular inclined surface. It is characterized by an opening inside the explosion-proof filter.

本発明の説明に先立つて、本発明を想起する基
礎となつた従来の触媒栓の動作状態について、触
媒栓内の水蒸気凝縮面及び温度分布に関し、触媒
栓のモデル実験による検討結果を述べる。
Prior to explaining the present invention, we will discuss the operating conditions of a conventional catalyst plug, which was the basis for conceiving the present invention, and the results of a study conducted on a catalyst plug model experiment regarding the water vapor condensation surface and temperature distribution within the catalyst plug.

第2図はモデル触媒栓における水蒸気の凝縮面
図、第3図は同じく温度分布図を示す。
FIG. 2 shows a water vapor condensation surface diagram in a model catalyst plug, and FIG. 3 similarly shows a temperature distribution diagram.

その結果、水蒸気が凝縮しない面は、第2図に
示した通り外器3の上部Aおよび下方のCにおい
て認められた。またこの時の栓内の温度分布の測
定によれば、第3図の通り、栓内の上部に温度の
高い部分が存在し、栓内の底部に近づくにつれて
低くなつている。この現象から温度の高い部分
に、外部との放熱抵抗となるものは設けず、むし
ろこの部分からの放熱を促進する構造とすること
が望ましいと判断される。
As a result, surfaces on which water vapor did not condense were found at the upper part A and the lower part C of the outer container 3, as shown in FIG. Furthermore, according to the measurement of the temperature distribution inside the stopper at this time, as shown in FIG. 3, there is a high temperature part at the top of the stopper, and the temperature decreases as it approaches the bottom of the stopper. From this phenomenon, it is judged that it is desirable not to provide a heat dissipation resistance to the outside in a high temperature part, but rather to have a structure that promotes heat dissipation from this part.

そこで本発明では、排気孔の設置位置として
は、温度の高い外器3の上部をさけ、温度が低く
放熱にはそれほど関係しない外器の底面を選ん
だ。第2図、第3図において、Xはφ150mm、Y
は250mm、Pは触媒容器を示す。
Therefore, in the present invention, as the installation position of the exhaust hole, we avoided the upper part of the outer case 3 where the temperature is high, and chose the bottom surface of the outer case where the temperature is low and does not have much effect on heat radiation. In Figures 2 and 3, X is φ150mm, Y
is 250mm, P indicates the catalyst container.

つぎに本発明を図面にもとづいて説明する。 Next, the present invention will be explained based on the drawings.

本発明の一実施例を第4図に示す。外器をドー
ム型に形成した。この構造は凝縮した水滴が流下
し易い構造であれば良く、必ずしもこの型に限る
ものではない。
An embodiment of the present invention is shown in FIG. The outer vessel was formed into a dome shape. This structure may be any structure that allows condensed water droplets to easily flow down, and is not necessarily limited to this type.

外器3の底部の円筒状の還水口部6の周縁に還
水口部6に向かつて下方に傾斜する環状傾斜面1
3−1を貫通する孔13−2を温度の低い外器1
3の内壁13Aに近接して穿ち、孔13−2を貫
通し、環状傾斜面13−1の底部より外器内部に
挿通し、一端が触媒容器1の高さに達する位置に
開口部14−1を有する排気管14を設ける。こ
の排気管14の内径や長さを変えることで、栓内
での排気抵抗または開口部14−1の位置を自由
に変えることができる。
At the periphery of the cylindrical water return port 6 at the bottom of the outer container 3, there is an annular inclined surface 1 that slopes downward toward the water return port 6.
The hole 13-2 passing through 3-1 is connected to the outer container 1 with a low temperature.
An opening 14- is bored close to the inner wall 13A of the catalyst container 1, passes through the hole 13-2, and is inserted into the outer container from the bottom of the annular inclined surface 13-1, with one end reaching the height of the catalyst container 1. 1 is provided. By changing the inner diameter and length of the exhaust pipe 14, the exhaust resistance within the plug or the position of the opening 14-1 can be freely changed.

また防爆フイルタ15は、排気管14の下部開
口部14−2をおおう形で、外器13の下部の環
状傾斜面13−1の下面外壁部に取付けられる。
防爆フイルタ15の平面図は第5図のとおりであ
る。還水口部6には上下に半円形状のじやま板7
を設ける。
The explosion-proof filter 15 is attached to the lower outer wall of the annular inclined surface 13-1 at the lower part of the outer case 13 so as to cover the lower opening 14-2 of the exhaust pipe 14.
A plan view of the explosion-proof filter 15 is shown in FIG. The water return port 6 has a semicircular top and bottom board 7.
will be established.

次に本発明の触媒栓における動作を説明する。 Next, the operation of the catalyst plug of the present invention will be explained.

本発明の触媒栓では、還水口部6から導かれた
酸素・水素ガスは触媒材2に到達して反応する。
反応で生成した水蒸気は外器13において潜熱を
放出して速やかに凝縮し、内壁面を伝わつて還流
する。また外器13の上部には放熱効果を妨げる
付属物は何等設けられていないので反応による生
成熱も容易に外気と熱交換することができる。
In the catalyst plug of the present invention, the oxygen/hydrogen gas led from the water return port 6 reaches the catalyst material 2 and reacts therewith.
The water vapor generated by the reaction releases latent heat in the outer vessel 13, quickly condenses, and refluxes through the inner wall surface. Further, since no attachments are provided on the upper part of the outer container 13 to impede the heat dissipation effect, the heat produced by the reaction can be easily exchanged with the outside air.

さらに本発明では排気孔と防爆フイルタは外器
の下部に設置されているが、この部分は外器の他
の部分と比較しても温度が低い部分なので、防爆
フイルタを設置しても熱抵抗にはなりにくい。
Furthermore, in the present invention, the exhaust hole and the explosion-proof filter are installed at the bottom of the outer case, but since this part has a lower temperature compared to other parts of the outer case, even if the explosion-proof filter is installed, there will be no thermal resistance. It is difficult to become.

ところで排気孔が外器の底面に単なる小孔で設
けられた場合には、酸素・水素ガスは触媒栓の内
部に十分浸入する前に排気孔から外部に排出され
てしまう恐れがある。
However, if the exhaust hole is simply a small hole provided on the bottom surface of the outer container, there is a risk that the oxygen/hydrogen gas may be discharged to the outside from the exhaust hole before it has sufficiently penetrated into the inside of the catalyst plug.

この問題を本発明の触媒栓では、排気孔に連通
するパイプを設ける手段により流通抵抗とガス流
路を変化させて解決している。つまり、本発明で
はパイプの径を変えればガスの排出の際の流通抵
抗が変わり、また外器の底面から触媒栓内部へ向
う排気管を設ける際に使用するパイプの長さを変
えることで触媒容器と排気管の開口端14−1の
相対的な位置を変えることができる。この結果、
酸素・水素ガスは触媒容器の近傍を通過してから
排気管の開口部14−1に向うことになり、その
間に触媒材で反応することができる。したがつ
て、本発明の排気管によれば、触媒栓内の開口部
の位置を変えることで、酸素・水素ガスの導入か
ら排出までの流通抵抗と流れを変化させ、触媒と
酸素・水素ガスの接触まで操作することができ
る。
In the catalyst plug of the present invention, this problem is solved by changing the flow resistance and gas flow path by providing a pipe communicating with the exhaust hole. In other words, in the present invention, by changing the diameter of the pipe, the flow resistance during gas discharge changes, and by changing the length of the pipe used when providing the exhaust pipe from the bottom of the outer container to the inside of the catalyst plug. The relative position of the container and the open end 14-1 of the exhaust pipe can be changed. As a result,
The oxygen/hydrogen gas passes near the catalyst container and then heads toward the opening 14-1 of the exhaust pipe, during which time it can react with the catalyst material. Therefore, according to the exhaust pipe of the present invention, by changing the position of the opening in the catalyst plug, the flow resistance and flow from the introduction of the oxygen/hydrogen gas to the exhaust can be changed, and the flow between the catalyst and the oxygen/hydrogen gas can be changed. It can be operated up to the point of contact.

また排気管のパイプを外器の温度の低い壁13
A近傍に設置することで、外器で冷却された温度
の低い流体(生成水蒸気と未反応ガスの混合物)
が排出される。一般に気体中に含まれる水量と温
度については、関係湿度が一定の場合には、温度
が低いほど含まれる水分量も低くなる関係にあ
る。したがつて、この場合も単位時間あたりに排
出される流体の量が同一なら、温度の低い流体を
排出する方が外部に排出される水分量も少なく、
本発明のように壁近くの温度の低い流体を排出す
る方式の方が、従来の触媒栓に比べて生成水蒸気
の損失も少ない。
In addition, the pipe of the exhaust pipe is connected to the low temperature wall 13 of the outer vessel.
By installing it near A, a low temperature fluid (mixture of generated water vapor and unreacted gas) cooled by the outer vessel
is discharged. In general, regarding the amount of water contained in a gas and its temperature, if the relative humidity is constant, the lower the temperature, the lower the amount of water contained in the gas. Therefore, in this case as well, if the amount of fluid discharged per unit time is the same, the amount of water discharged to the outside will be smaller if the fluid with a lower temperature is discharged.
The method of the present invention, which discharges the low-temperature fluid near the wall, causes less loss of generated water vapor than the conventional catalyst plug.

なお、本発明の実施例では外器形状はドーム型
となつているが、本発明はこれに限るものではな
く、水滴の流下を促進し、放熱を効果的にすすめ
るために、外器に放熱用のフインを設けること、
あるいは冷却効果の向上を図るため、蛇腹構造と
すること等、本発明の意図を逸脱しない範囲内で
の変更を含んでいる。
In the embodiments of the present invention, the shape of the outer container is dome-shaped, but the present invention is not limited to this.In order to promote the flow of water droplets and to effectively dissipate heat, the outer container has a heat dissipation structure. providing fins for
Alternatively, in order to improve the cooling effect, changes may be made without departing from the spirit of the present invention, such as a bellows structure.

本発明の外器は底面を除いて全て発生熱の放熱
と水蒸気の凝縮にあずかることができる。従つて
発生した熱も容易に外部に放出され、水蒸気の凝
縮も促進される。
The entire outer container of the present invention, except for the bottom surface, can participate in the radiation of generated heat and the condensation of water vapor. Therefore, the generated heat is also easily released to the outside, and the condensation of water vapor is also promoted.

このため本発明にかかる触媒栓における、生成
水蒸気の凝縮・還流の効果は同一容積の従来型触
媒栓に比べて極めて大きい。
Therefore, the effect of condensing and refluxing the generated water vapor in the catalyst plug according to the present invention is extremely large compared to a conventional catalyst plug having the same volume.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は従来の触媒栓の断面図、第2図は触媒
栓における水蒸気の凝縮面図、第3図は触媒栓内
の温度分布図、第4図は本発明の触媒栓の断面
図、第5図は本発明の防爆フイルタの平面図を示
す。 1……触媒容器、2……触媒材、6……還水口
部、13……容器、13−1……環状傾斜面、1
3−2……貫通孔、14……排気管、14−1…
…開口端、15……防爆フイルタ。
FIG. 1 is a sectional view of a conventional catalyst plug, FIG. 2 is a surface view of water vapor condensation in the catalyst plug, FIG. 3 is a temperature distribution diagram inside the catalyst plug, and FIG. 4 is a sectional view of the catalyst plug of the present invention. FIG. 5 shows a plan view of the explosion-proof filter of the present invention. DESCRIPTION OF SYMBOLS 1... Catalyst container, 2... Catalyst material, 6... Water return port, 13... Container, 13-1... Annular inclined surface, 1
3-2...Through hole, 14...Exhaust pipe, 14-1...
...Open end, 15...Explosion-proof filter.

Claims (1)

【特許請求の範囲】[Claims] 1 上部を密封した円筒体と中央部に開口した還
水口に向つて下向きに傾斜する環状傾斜面を有す
る底部とを一体に構成した外器内に、触媒材を収
納したセラミツク製触媒容器を配設し、蓄電池か
ら発生する酸素と水素ガスを再結合し、電解液中
に水分を還流させる蓄電池用触媒栓において、前
記外器内中央部の温度より低い温度にある外器側
壁面に近接して排気管を設け、前記排気管は前記
環状傾斜面に穿たれた孔を貫通し、その一端が前
記触媒容器の上端の高さに開口し、他端は前記環
状傾斜面の外壁面に接着した断面が略コ字形状を
なす環状の防爆フイルタ内に開口していることを
特徴とする蓄電池用触媒栓。
1. A ceramic catalyst container containing a catalyst material is placed in an outer container that is integrally composed of a cylindrical body with a sealed upper part and a bottom part having an annular inclined surface that slopes downward toward a water return port opened in the center. In a catalyst plug for a storage battery that recombines oxygen and hydrogen gas generated from the storage battery and refluxes water into the electrolyte, the plug is placed close to the side wall surface of the outer container, which is at a temperature lower than the temperature of the central part of the outer container. an exhaust pipe is provided, the exhaust pipe passing through a hole bored in the annular inclined surface, one end of which opens at the height of the upper end of the catalyst container, and the other end adhered to the outer wall surface of the annular inclined surface; A catalyst plug for a storage battery, characterized in that it opens in an annular explosion-proof filter having a substantially U-shaped cross section.
JP4444980A 1980-04-04 1980-04-04 Catalyst plug for storage battery Granted JPS56141181A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP4444980A JPS56141181A (en) 1980-04-04 1980-04-04 Catalyst plug for storage battery

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4444980A JPS56141181A (en) 1980-04-04 1980-04-04 Catalyst plug for storage battery

Publications (2)

Publication Number Publication Date
JPS56141181A JPS56141181A (en) 1981-11-04
JPS6342378B2 true JPS6342378B2 (en) 1988-08-23

Family

ID=12691792

Family Applications (1)

Application Number Title Priority Date Filing Date
JP4444980A Granted JPS56141181A (en) 1980-04-04 1980-04-04 Catalyst plug for storage battery

Country Status (1)

Country Link
JP (1) JPS56141181A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03218789A (en) * 1990-01-25 1991-09-26 Kaijirushi Hamono Kaihatsu Center:Kk Blade body applied with coating treatment

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE267463T1 (en) 1998-04-20 2004-06-15 Hoppecke Zoellner Sohn Accu RECOMBINATION DEVICE FOR THE CATALYTIC RECOMBINATION OF HYDROGEN AND OXYGEN PRODUCED IN ACCUMULATORS TO WATER
JP6576297B2 (en) * 2016-05-02 2019-09-18 日本ゴア株式会社 Catalyst parts and vent filters, vent plugs and lead-acid batteries including the same

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS54107024U (en) * 1978-01-13 1979-07-27

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03218789A (en) * 1990-01-25 1991-09-26 Kaijirushi Hamono Kaihatsu Center:Kk Blade body applied with coating treatment

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JPS56141181A (en) 1981-11-04

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