JPH03207518A - Descaling method for hot rolled steel strip - Google Patents

Descaling method for hot rolled steel strip

Info

Publication number
JPH03207518A
JPH03207518A JP218090A JP218090A JPH03207518A JP H03207518 A JPH03207518 A JP H03207518A JP 218090 A JP218090 A JP 218090A JP 218090 A JP218090 A JP 218090A JP H03207518 A JPH03207518 A JP H03207518A
Authority
JP
Japan
Prior art keywords
steel strip
pickling
descaling
hot rolled
rolled steel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP218090A
Other languages
Japanese (ja)
Inventor
Satoshi Teshigawara
勅使河原 敏
Yukio Matsuda
行雄 松田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Sumitomo Metal Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Metal Industries Ltd filed Critical Sumitomo Metal Industries Ltd
Priority to JP218090A priority Critical patent/JPH03207518A/en
Publication of JPH03207518A publication Critical patent/JPH03207518A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B45/00Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills
    • B21B45/04Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for de-scaling, e.g. by brushing
    • B21B45/06Devices for surface or other treatment of work, specially combined with or arranged in, or specially adapted for use in connection with, metal-rolling mills for de-scaling, e.g. by brushing of strip material
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23GCLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G3/00Apparatus for cleaning or pickling metallic material
    • C23G3/02Apparatus for cleaning or pickling metallic material for cleaning wires, strips, filaments continuously
    • C23G3/027Associated apparatus, e.g. for pretreating or after-treating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B27/00Rolls, roll alloys or roll fabrication; Lubricating, cooling or heating rolls while in use
    • B21B27/005Rolls with a roughened or textured surface; Methods for making same

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)

Abstract

PURPOSE:To reduce the equipment cost, to decrease the occupied space for equipment and to improve the efficiency of descaling by specifying the center line mean roughness of the surface of steel strip by applying rolling reduction to the hot rolled steel strip, radiating the electric discharging arc to the surface and then pickling it. CONSTITUTION:The steel strip 1 is rolled with the roll 21 with dull incorporated in the rolling mill 2, the crack is generated on the surface of steel strip and fine ruggedness are simultaneously formed and the center line mean roughness Ra of the surface of steel strip is made to 0.5-5mum. Next, the steel strip 1 is irradiated with the electric discharging arc from the discharging electrode 4 during passing in the insulating liquid 5 and the crack number of surface is increased. At final, the steel strip 1 is subjected to pickling in the pickling tank. Therefore, the good descaling is executed and the time required for the descaling can be shortened.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は、普通鋼からステンレス鋼まで各種の熱間圧延
鋼帯を脱スケールする方法に関する。
DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a method for descaling various hot rolled steel strips from ordinary steel to stainless steel.

(従来の技術) 従来、熱間圧延鋼帯の脱スケールにおいては、鋼帯を酸
液に連続的に浸漬する方式の他に、酸浸漬の前処理とし
てメカニカル・デスケーリングを実施する方式が採用さ
れている。
(Conventional technology) Conventionally, in the descaling of hot rolled steel strips, in addition to the method of continuously immersing the steel strip in an acid solution, a method of performing mechanical descaling as a pretreatment for acid immersion has been adopted. has been done.

この方式の具体的な例としては、圧延曲げ等によりスケ
ールにクラックを生じさせ、あるいはショットブラスト
等によりスケールの付着した鋼帯表面を研掃した後酸浸
漬する方法をあげることができる。例えば、本出願人は
特開昭57−47519号公報で、熱間圧延鋼帯を圧下
率3〜10%で圧延した後テンション・レベラにより0
.5〜3.0%の引張曲げを加え、酸洗槽でスケールを
除去する方法を提案した。また、特開昭62−2801
9号公報では、圧下を加えた後、曲げ引張りではなく、
単なる曲げを加える方法を開示した。
Specific examples of this method include a method in which cracks are created in the scale by rolling and bending or the like, or the surface of the steel strip with scale adhering to it is polished by shot blasting or the like and then immersed in an acid. For example, in Japanese Unexamined Patent Publication No. 57-47519, the present applicant has disclosed that after rolling a hot rolled steel strip at a reduction ratio of 3 to 10%, a tension leveler is used to reduce the temperature to zero.
.. We proposed a method of applying tensile bending of 5 to 3.0% and removing scale in a pickling bath. Also, JP-A-62-2801
In Publication No. 9, after applying reduction, instead of bending and tension,
A method of adding simple bending was disclosed.

このように、メカニカル・デスケーリングを行うことに
より、脱スケール所要時間の短縮をはかることができる
By performing mechanical descaling in this manner, the time required for descaling can be shortened.

上記のように、熱間圧延鋼帯の脱スケールは酸洗により
なされているが、酸洗を実施するにあたり普通鋼とステ
ンレス鋼とでは酸液が異なり、前者では通常塩酸が用い
られ、後者では硝酸とぶつ酸の混酸(硝・ぶつ#1)が
用いられる。特に、難酸洗材であるステンレス鋼の脱ス
ケールにおいては、通常ショットブラスト処理を施した
後、硝・ぶつ酸に浸漬する方法が一般的である。そのた
め、普通鋼とステンレス鋼は別々の酸洗ラインで処理さ
れているのが現状である。
As mentioned above, hot-rolled steel strips are descaled by pickling, but the acid solution used for pickling differs between ordinary steel and stainless steel; hydrochloric acid is usually used for the former, while for the latter. A mixed acid of nitric acid and butsu acid (nitric acid/bututsu #1) is used. In particular, for descaling stainless steel, which is a material that is difficult to pickle, it is common to perform shot blasting and then immerse it in nitric acid. Therefore, ordinary steel and stainless steel are currently processed in separate pickling lines.

(発明が解決しようとする課題) 前記のように、熱間圧延網帯の酸洗において、普通鋼と
ステンレス鋼ではラインが異なり、そのため、ラインの
並列設置に伴う設備費および設備設置スペースの増大は
避け得なかった。
(Problems to be Solved by the Invention) As mentioned above, when pickling hot-rolled mesh strips, the lines are different for ordinary steel and stainless steel, and as a result, equipment costs and equipment installation space increase due to parallel installation of lines. was unavoidable.

また、酸洗うインに使用される個々の設備をみても、ス
テンレス鋼の酸洗前処理として一般に採用されているシ
ョットブラストは設備費、ランニングコスト共に高く、
また、前記の曲げ引張加工を施すために用いるテンショ
ン・レベラも設備費が高くなるとともに、大きな設備空
間を必要とする、等の問題がある。
In addition, looking at the individual equipment used for pickling, shot blasting, which is commonly used as a pre-treatment for pickling stainless steel, has high equipment costs and running costs.
Furthermore, the tension leveler used to perform the bending and tensioning process described above also has problems such as high equipment costs and a need for a large equipment space.

本発明は、普通鋼、ステンレス鋼に兼用が可能で、しか
も設備費の低減および設備占有空間の縮少ができるとと
もに、脱スケール効率を向上させ得る熱間圧延鋼帯の脱
スケール方法を提供することを目的とする。
The present invention provides a method for descaling hot rolled steel strip that can be used for common steel and stainless steel, and can reduce equipment costs and space occupied by the equipment, as well as improve descaling efficiency. The purpose is to

(課題を解決するための手段) 本発明の要旨は、「熱間圧延鋼帯に圧下を加えると共に
、鋼帯表面の中心線平均粗さRaを0.5〜5μmに調
整し、その鋼帯の表面に放電アークを照射した後、酸洗
することを特徴とする熱間圧延鋼帯の脱スケール方法」
にある。
(Means for Solving the Problems) The gist of the present invention is to apply rolling to a hot rolled steel strip, adjust the center line average roughness Ra of the steel strip surface to 0.5 to 5 μm, and ``A method for descaling hot rolled steel strip, which comprises irradiating the surface of the steel strip with a discharge arc and then pickling it.''
It is in.

前記の熱間圧延鋼帯は、普通鋼のみならず低合金鋼、ス
テンレス鋼など、いずれの網種であってもよい。
The hot rolled steel strip may be of any type, such as not only ordinary steel but also low alloy steel and stainless steel.

前記の鋼帯の表面とは、正確には鋼帯表面に形威された
スケールの表面であるが、鋼帯とスケールとは一体物と
みて、単に綱帯の表面と記載する。
The surface of the steel strip mentioned above is precisely the surface of the scale formed on the surface of the steel strip, but since the steel strip and the scale are considered to be one, it is simply referred to as the surface of the steel strip.

この鋼帯の表面粗さの調整には、ロールの表面に凹凸加
工(ダル加工)を施したダル付きロールを用いれば、圧
下を加えつつ鋼帯表面に微小凹凸をつけて所定の粗さと
することができるので好適である。
To adjust the surface roughness of this steel strip, if you use a dull roll that has been subjected to uneven processing (dull processing) on the surface of the roll, you can create minute irregularities on the surface of the steel strip while applying pressure to achieve the desired roughness. This is suitable because it allows

放電アークを照射するには、絶縁液中に放電電極を取り
4=Jけ、この電極と絶縁液中を通過する鋼帯との間で
放電アークを発止させればよい。電極は鋼帯の幅方向全
体に放電アークが照射されるように、鋼帯の幅方向に多
数設ける。
In order to irradiate a discharge arc, a discharge electrode is placed in an insulating liquid, and a discharge arc is started between this electrode and a steel strip passing through the insulating liquid. A large number of electrodes are provided in the width direction of the steel strip so that the entire width direction of the steel strip is irradiated with a discharge arc.

第1図は本発明を実施するための装置の一例の構或を示
す概略図である。
FIG. 1 is a schematic diagram showing the structure of an example of an apparatus for carrying out the present invention.

同図において、1ば鋼帯、2はダル付ロール2lが組み
込まれた圧延機、3は圧延機2の入側および出側に設け
られ、鋼帯lに必要な張力を与えるプライドルロール、
4は鋼帯の上面側および下面側に設けられ、絶縁液5中
を通過する鋼帯1との間で放電アークを発生させる放電
電極、6は酸洗槽である。
In the figure, 1 is a steel strip, 2 is a rolling mill incorporating a dull roll 2l, 3 is a priddle roll provided on the entry and exit sides of the rolling mill 2, and provides the necessary tension to the steel strip 1;
4 is a discharge electrode that is provided on the upper and lower surfaces of the steel strip and generates a discharge arc between the steel strip 1 passing through an insulating liquid 5; and 6 is a pickling tank.

この装置において、[F1は圧延m2に組み込まれたダ
ル付ロール21により圧下を受け、鋼帯表面にクランク
が発生すると同時に微小な凹凸が形威される.次いで鋼
帯1は絶縁液5中を通過する間に放電電極4により放電
アークの照射を受け、表面のクランク数が増加する。絶
縁液としては絶縁油が好適でであるが、水でもよい。
In this device, [F1 is rolled down by the dull roll 21 incorporated in the rolling m2, and at the same time a crank is generated on the surface of the steel strip, minute irregularities are formed. Next, the steel strip 1 is irradiated with a discharge arc by the discharge electrode 4 while passing through the insulating liquid 5, and the number of cranks on the surface increases. Insulating oil is suitable as the insulating liquid, but water may also be used.

最後に、綱帯1は酸洗槽で酸洗される。酸液としては、
通常の濃度の塩酸または硫酸が使用される。
Finally, the rope strap 1 is pickled in a pickling tank. As an acid solution,
Hydrochloric acid or sulfuric acid of normal concentration is used.

(作用) 一般に酸洗前にスケール層に微小なクラ・7クを形威さ
せると酸洗液がクラックに浸透し、酸洗速度が大きくな
る。しかし、圧延機のみによるクランクの形或(以下、
「スケールブレーキング」という)ではクランク数に限
度があり、酸洗速度をそれ以上に増大させることはでき
ない。本発明はこのクランクの数を増やしてやれば酸洗
速度はより大きくなることに着目してなされたもので、
放電アークによりスケール層に微小なクランクを形威さ
せ、酸洗速度を増大させるのである。
(Function) Generally, if minute cracks are formed in the scale layer before pickling, the pickling solution will penetrate into the cracks and the pickling speed will increase. However, the shape of the crank (hereinafter referred to as
(referred to as "scale breaking"), there is a limit to the number of cranks, and the pickling speed cannot be increased any further. The present invention was made based on the fact that increasing the number of cranks would increase the pickling speed.
The discharge arc creates minute cranks in the scale layer, increasing the pickling speed.

放電アークのみによりスケールブレーキングを行っても
放電アークが局部に集中しクラック数の増加とはならな
い。しかし、本発明方法においては、放電アークが綱帯
表面に均一に分散するように、放電前に圧延機により調
帯の全表面に微小凹凸を形成させているので、その凸部
に選択的にアークが発生し、均一に分散したクラックが
形成される。
Even if scale breaking is performed only by discharge arc, the discharge arc will be concentrated locally and the number of cracks will not increase. However, in the method of the present invention, minute irregularities are formed on the entire surface of the strap by a rolling machine before discharge, so that the discharge arc is uniformly distributed on the surface of the strap. Arcing occurs and uniformly distributed cracks form.

この微小凹凸の大きさ、すなわち、粗さと放電アークに
よるスケールブレーキング効果との間には一定の関係が
認められる。
A certain relationship is recognized between the size of these minute irregularities, that is, the roughness, and the scale breaking effect due to the discharge arc.

第2図は、普通網について表面粗さを変化させた場合の
放電時間とスケール断面のクラック数との関係を示すグ
ラフである。同図において、表面粗さはJIS B 0
601に規定される中心線平均粗さ(Ra)で表した。
FIG. 2 is a graph showing the relationship between the discharge time and the number of cracks in the cross section of the scale when the surface roughness of the ordinary mesh is changed. In the same figure, the surface roughness is JIS B 0.
It was expressed as center line average roughness (Ra) defined in 601.

縦軸の断面クランク数の単位はスケール7の断面におけ
る長さ10mm当たりのクランク8の数である(第3図
参照)。
The unit of the number of cross-sectional cranks on the vertical axis is the number of cranks 8 per 10 mm of length in the cross-section of the scale 7 (see FIG. 3).

第2図から明らかなように、鋼帯表面粗さ(Ra)が0
.5μm未満ではスケールブレーキング効果が少ない。
As is clear from Figure 2, the steel strip surface roughness (Ra) is 0.
.. When the thickness is less than 5 μm, the scale breaking effect is small.

また、Raが5μm超えると、面粗度の粗い製品となっ
てしまう。
Moreover, if Ra exceeds 5 μm, the product will have a rough surface.

第4図は、普通鋼についての断面クラック数と酸洗時間
との関係を示すグラフである。同図から、断面クラック
数が増すと酸洗時間は著しく減少ずることがわかる。
FIG. 4 is a graph showing the relationship between the number of cross-sectional cracks and pickling time for common steel. From the same figure, it can be seen that as the number of cross-sectional cracks increases, the pickling time decreases significantly.

以上より、鋼帯表面に形威させる微小凹凸は、Raが0
.5〜5μmの範囲になるように調整することとした。
From the above, the minute irregularities that form on the steel strip surface have an Ra of 0.
.. The thickness was adjusted to be in the range of 5 to 5 μm.

(実施例) 冷間圧延機の入側に前記第1に示した構戒の装置を設置
し、ライン速度10m/分で厚さ3 . 0mm、幅1
200mmのフェライ1〜系ステンレス鋼(sus 4
10)の熱間圧延鋼帯を通過させ、本発明方法を適用し
て脱スケールを行った。
(Example) The equipment shown in the first section above was installed on the entrance side of a cold rolling mill, and a line speed of 10 m/min was set to a thickness of 3.5 m/min. 0mm, width 1
200mm Ferrai 1~ series stainless steel (sus 4
10) was passed through the hot rolled steel strip, and descaling was performed by applying the method of the present invention.

スケールの厚さは約10μmであった。The thickness of the scale was approximately 10 μm.

用いたダル付圧延ロールは直径800mm、表面粗さ(
Ra)は3.5μmで、圧下率は1%とした。
The rolling roll with dullness used had a diameter of 800 mm and a surface roughness (
Ra) was 3.5 μm, and the rolling reduction was 1%.

放電電極は、1電極当たりIOOV・2A=200Wで
アーク照射面積は500cm”(幅5cmX長さ100
cm)、電極個数はコイル幅方向に24個、コイル長手
方向に10列とした。
The discharge electrode is IOOV・2A=200W per electrode, and the arc irradiation area is 500cm" (width 5cm x length 100cm).
cm), and the number of electrodes was 24 in the width direction of the coil and 10 rows in the longitudinal direction of the coil.

酸洗槽は長さ20mの槽を2槽直列に配置し、濃度10
%の塩酸(浴温85゜C)を用いた。
The pickling tank consists of two 20m long tanks arranged in series, with a concentration of 10
% hydrochloric acid (bath temperature 85°C) was used.

比較のため、同し熱間圧延鋼帯を対象として、ショット
ブラスト処理後酸洗処理する従来法を適用して脱スケー
ルを行った。酸洗槽は長さ20mの槽を4槽直列に配置
し、酸液には硝・ぶつ酸(10%硝酸+3%ふっ酸、浴
温60゜C)を用いた。
For comparison, the same hot rolled steel strip was descaled using the conventional method of shot blasting followed by pickling. Four pickling tanks each having a length of 20 m were arranged in series, and nitric acid (10% nitric acid + 3% hydrofluoric acid, bath temperature 60°C) was used as the acid solution.

本発明方法を適用した結果、良好な脱スケールがなされ
、冷間圧延後の鋼帯表面も従来の酸洗法を適用した場合
と変わらなかった。
As a result of applying the method of the present invention, good descaling was achieved, and the surface of the steel strip after cold rolling was no different from that when the conventional pickling method was applied.

また、脱スケールに要する時間は、従来法の1.5分に
対し、本発明方法では0.5分と著しく短縮された。
Further, the time required for descaling was significantly shortened to 0.5 minutes in the method of the present invention, compared to 1.5 minutes in the conventional method.

本発明方法によれば、ステンレス鋼も塩酸で処理するこ
とができ、しかも所要時間が著しく短縮する。
According to the method of the invention, stainless steel can also be treated with hydrochloric acid, and the time required is significantly reduced.

本発明方法は他のステンレス鋼や普通鋼、低合金鋼にも
適用可能であった。
The method of the present invention was also applicable to other stainless steels, ordinary steels, and low alloy steels.

(発明の効果) 本発明の脱スケール方法は、普通鋼からステンレス鋼ま
で各種の鋼に適用可能で、同一の脱スケルラインを兼用
することができ、しかも脱スケール効率が著しく向上ず
る。また、ショッi・ブラスト、テンション・レベラ等
の設備が不要のため、設備費および設備占有空間の削減
も可能である。
(Effects of the Invention) The descaling method of the present invention is applicable to various steels from ordinary steel to stainless steel, the same descaling line can be used for both, and the descaling efficiency is significantly improved. Furthermore, since equipment such as a shot blaster and a tension leveler is not required, it is possible to reduce the equipment cost and the space occupied by the equipment.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は、本発明方法を実施するための装置の一例の構
或を示す概略図である。 第2図は、鋼帯の表面粗さを変化させた場合の放電時間
とスケール断面のクランク数の関係を示す図である。 第3図は、スケール断面におけるクラック発生状況を示
す模式図である。 第4図は、スケール断面のクラック数と酸洗時間との関
係を示す図である。
FIG. 1 is a schematic diagram showing the structure of an example of an apparatus for carrying out the method of the present invention. FIG. 2 is a diagram showing the relationship between the discharge time and the crank number of the scale cross section when the surface roughness of the steel strip is changed. FIG. 3 is a schematic diagram showing the occurrence of cracks in a scale cross section. FIG. 4 is a diagram showing the relationship between the number of cracks in the scale cross section and the pickling time.

Claims (1)

【特許請求の範囲】[Claims] 熱間圧延鋼帯に圧下を加えると共に、鋼帯表面の中心線
平均粗さRaを0.5〜5μmに調整し、その鋼帯の表
面に放電アークを照射した後、酸洗することを特徴とす
る熱間圧延鋼帯の脱スケール方法。
It is characterized by applying pressure to the hot rolled steel strip, adjusting the center line average roughness Ra of the steel strip surface to 0.5 to 5 μm, irradiating the surface of the steel strip with a discharge arc, and then pickling. A method for descaling hot rolled steel strip.
JP218090A 1990-01-09 1990-01-09 Descaling method for hot rolled steel strip Pending JPH03207518A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP218090A JPH03207518A (en) 1990-01-09 1990-01-09 Descaling method for hot rolled steel strip

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP218090A JPH03207518A (en) 1990-01-09 1990-01-09 Descaling method for hot rolled steel strip

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Publication Number Publication Date
JPH03207518A true JPH03207518A (en) 1991-09-10

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JP218090A Pending JPH03207518A (en) 1990-01-09 1990-01-09 Descaling method for hot rolled steel strip

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JP (1) JPH03207518A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101271985B1 (en) * 2010-12-27 2013-06-05 주식회사 포스코 Method for Treating Surface of Hot strip

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101271985B1 (en) * 2010-12-27 2013-06-05 주식회사 포스코 Method for Treating Surface of Hot strip

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