JPH03203948A - Composition for forming light shielding part of color filter - Google Patents
Composition for forming light shielding part of color filterInfo
- Publication number
- JPH03203948A JPH03203948A JP34336689A JP34336689A JPH03203948A JP H03203948 A JPH03203948 A JP H03203948A JP 34336689 A JP34336689 A JP 34336689A JP 34336689 A JP34336689 A JP 34336689A JP H03203948 A JPH03203948 A JP H03203948A
- Authority
- JP
- Japan
- Prior art keywords
- composition
- color filter
- forming
- shielding part
- light shielding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 22
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 7
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 7
- 239000006229 carbon black Substances 0.000 claims abstract description 7
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 4
- 125000005647 linker group Chemical group 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 239000000975 dye Substances 0.000 abstract description 11
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 abstract description 6
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 abstract description 6
- 239000002904 solvent Substances 0.000 abstract description 5
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 abstract description 4
- 239000002245 particle Substances 0.000 abstract description 4
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 abstract description 3
- 229920001577 copolymer Polymers 0.000 abstract description 3
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 abstract description 2
- 230000001588 bifunctional effect Effects 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000004973 liquid crystal related substance Substances 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001875 compounds Chemical group 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000011049 pearl Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- WBYWAXJHAXSJNI-VOTSOKGWSA-M .beta-Phenylacrylic acid Natural products [O-]C(=O)\C=C\C1=CC=CC=C1 WBYWAXJHAXSJNI-VOTSOKGWSA-M 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 1
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- WBYWAXJHAXSJNI-SREVYHEPSA-N Cinnamic acid Chemical compound OC(=O)\C=C/C1=CC=CC=C1 WBYWAXJHAXSJNI-SREVYHEPSA-N 0.000 description 1
- 241000557626 Corvus corax Species 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229920005822 acrylic binder Polymers 0.000 description 1
- 229920006243 acrylic copolymer Polymers 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
- 150000004056 anthraquinones Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 150000001540 azides Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229930016911 cinnamic acid Natural products 0.000 description 1
- 235000013985 cinnamic acid Nutrition 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 description 1
- 210000002858 crystal cell Anatomy 0.000 description 1
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 description 1
- PPSZHCXTGRHULJ-UHFFFAOYSA-N dioxazine Chemical compound O1ON=CC=C1 PPSZHCXTGRHULJ-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- RBTKNAXYKSUFRK-UHFFFAOYSA-N heliogen blue Chemical group [Cu].[N-]1C2=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=NC([N-]1)=C(C=CC=C3)C3=C1N=C([N-]1)C3=CC=CC=C3C1=N2 RBTKNAXYKSUFRK-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- WBYWAXJHAXSJNI-UHFFFAOYSA-N methyl p-hydroxycinnamate Natural products OC(=O)C=CC1=CC=CC=C1 WBYWAXJHAXSJNI-UHFFFAOYSA-N 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- DGBWPZSGHAXYGK-UHFFFAOYSA-N perinone Chemical compound C12=NC3=CC=CC=C3N2C(=O)C2=CC=C3C4=C2C1=CC=C4C(=O)N1C2=CC=CC=C2N=C13 DGBWPZSGHAXYGK-UHFFFAOYSA-N 0.000 description 1
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
[産業上の利用分野コ
本発明は、遮光性、平滑性に優れたカラーフィルター遮
光部形成用組成物に関し、さらに詳しくは。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a composition for forming a light-shielding portion of a color filter that has excellent light-shielding properties and smoothness, and more particularly.
カラー液晶表示装置、カラーファクシミリ、小型ビデオ
カメラ、プロジェクタ−などに装着されるカラーフィル
ターを形成するためのカラーフィルター遮光部形成用組
成物に関する。The present invention relates to a composition for forming a light-shielding part of a color filter for forming a color filter mounted on a color liquid crystal display device, a color facsimile, a small video camera, a projector, etc.
[従来の技術]
近年、液晶表示装置におけるフルカラー化はすでに実用
化されており1色再現性も陰極線管(CRT)に対し遜
色ないまでに改良されている。色再現性に優れたフルカ
ラー液晶表示装置としては、液晶セル内部または外部に
カラーフィルターを設は液を光学的シャッターとして利
用したカラーフィルター方式がある。レッド、グリーン
、ブルーの三原色カラーモザイクパターンを基板上に配
しフィルターを形成するが、カラートッドの周辺に遮光
部を設ける事により、コントラストが高くなり鮮明性の
高い画質が得られる。遮光用顔料としてカーボンを用い
る例は多いものの分散性、平滑性の点で要求品質を満足
するものは少ない。[Prior Art] In recent years, full-color liquid crystal display devices have already been put to practical use, and the reproducibility of one color has been improved to the point that it is comparable to that of a cathode ray tube (CRT). As a full-color liquid crystal display device with excellent color reproducibility, there is a color filter method in which a color filter is provided inside or outside a liquid crystal cell and the liquid is used as an optical shutter. A color mosaic pattern of the three primary colors of red, green, and blue is arranged on a substrate to form a filter, and by providing a light shielding area around the color tod, contrast is increased and image quality with high clarity is obtained. Although there are many examples of using carbon as a light-shielding pigment, there are few that satisfy the required quality in terms of dispersibility and smoothness.
[発明が解決しようとする課題]
本発明は2以上の状況に鑑み、遮光性、平滑性に優れた
カラーフィルター遮光部形成用組成物を開発すべく鋭意
研究を重ねた結果、実現したものであり。[Problems to be Solved by the Invention] In view of two or more circumstances, the present invention was realized as a result of intensive research to develop a composition for forming a color filter light-shielding part that has excellent light-shielding properties and smoothness. can be.
遮光性、平滑性に優れたカラーフィルター遮光部形成用
組成物を提供するものである。The present invention provides a composition for forming a light-shielding part of a color filter that has excellent light-shielding properties and smoothness.
[発明が解決しようとする課題]
本発明は上記目的を達成するために次のような構成を有
する。即ち、カーボンブランク100重量部に対しアク
リル樹脂が20〜200重量部、下記−般式で示される
色素誘導体が0.1〜30重量部を含有することを特徴
とするカラーフィルター透光部形成用組成物である。[Problems to be Solved by the Invention] The present invention has the following configuration to achieve the above object. That is, a color filter for forming a light-transmitting part, which contains 20 to 200 parts by weight of an acrylic resin and 0.1 to 30 parts by weight of a dye derivative represented by the following general formula based on 100 parts by weight of a carbon blank. It is a composition.
\
Rz
(式中、Dは有機色素残基、Xは直接結合または二価の
結合基、R+ 、Rzはアルキル基2mは1〜4の整数
、nは1〜4の整数をそれぞれ示す。)Dは、アゾ系、
フタロシアニン系、キナクリドン系、アントラキノン系
、ジオキサジン系、ペリレン系、ペリノン系等の有機色
素、Xは直接結合または二価の結合基であり、この結合
としては、−0−NR,−、−3−、−Co−、−3o
□−1−CR3(R4)、 SO□NR8−、−C
ONR。\Rz (In the formula, D is an organic dye residue, X is a direct bond or a divalent bonding group, R+ and Rz are alkyl groups, 2m is an integer of 1 to 4, and n is an integer of 1 to 4, respectively.) D is azo type,
Phthalocyanine-based, quinacridone-based, anthraquinone-based, dioxazine-based, perylene-based, perinone-based organic dyes, X is a direct bond or a divalent bonding group, and this bond is -0-NR, -, -3- , -Co-, -3o
□-1-CR3(R4), SO□NR8-, -C
ONR.
R3,R,は水素原子、アルキル基、またはアリール基
を示す。R3, R, represents a hydrogen atom, an alkyl group, or an aryl group.
本発明におけるカーボンブラックは粒子径40μm以下
でストラフチャーレベルが低く、シかも比表面積400
rrr/g以下のものが望ましく、具体例として、三菱
化成工業#100.50.40,30゜MA−100,
MA−8,キャボント社製す−ガル400.500,6
00.ブランクパールズ1000.1020.2000
等がある。The carbon black used in the present invention has a particle size of 40 μm or less, a low stracture level, and a specific surface area of 400 μm or less.
rrr/g or less, specific examples include Mitsubishi Chemical #100.50.40, 30° MA-100,
MA-8, Cavonto Su-Gal 400.500,6
00. Blank Pearls 1000.1020.2000
etc.
本発明におけるアクリル系バインダー樹脂としては、ア
クリル樹脂およびそのエステル、アクリルアミド、アク
リロニトリル、メタクリル酸およびそのエステル、スチ
レンなどからなる共重合体9例えば。Examples of the acrylic binder resin in the present invention include copolymers 9 made of acrylic resin and its esters, acrylamide, acrylonitrile, methacrylic acid and its esters, styrene, and the like.
ブチルメタクリレート30〜50重置%、ブチルアクリ
レート30〜50重量%、メタクリル酸10〜30重量
%の組成よりなる共重合体が好ましい。溶剤としてはア
クリル樹脂を溶解する溶剤であれば良く2例えばトルエ
ン、キシレン、酢酸ブチル、酢酸セロソルブ、メチルセ
ロソルブ、エチルセロソルブ。A copolymer having a composition of 30 to 50% by weight of butyl methacrylate, 30 to 50% by weight of butyl acrylate, and 10 to 30% by weight of methacrylic acid is preferred. The solvent may be any solvent that dissolves the acrylic resin, such as toluene, xylene, butyl acetate, cellosolve acetate, methyl cellosolve, and ethyl cellosolve.
シクロヘキサノン等がある。Examples include cyclohexanone.
本発明に基づきカラーフィルター透光部形成用組成物を
作るには、アクリル樹脂、溶剤、カーボンブランクおよ
び色素誘導体をボールミル、サンドミル。In order to make a composition for forming a color filter transparent part based on the present invention, an acrylic resin, a solvent, a carbon blank, and a dye derivative are mixed in a ball mill or a sand mill.
アトライター、その他の分散、混合装置によって分散、
混合する。また、カーボンブラックおよび色素誘導体を
混合し1次のフェス等と混合9分散させることができる
。尚、混合2分散の順序はこれだけに限るものではなく
、適宜行うことができる。Dispersion by attritor, other dispersion and mixing equipment,
Mix. Further, carbon black and a pigment derivative can be mixed and dispersed with a primary festival. Note that the order of mixing and dispersion is not limited to this, and can be performed as appropriate.
遮光部の形成には、該組成物と光重合系、アジド系、ジ
アゾ系、ケイ皮酸系の感光性樹脂との組み合わせ、該組
成物と光架橋剤との組み合わせ、該組成物とモノマーま
たはオリゴマーおよび開始剤との組み合わせ等により、
適宜、調整された塗液を用いることができる。上記組み
合わせにより調整された塗液をガラス基板等の支持体上
にスピナー、ロールコータ−、デイツプコーター、ホイ
ルコーター、バーコーターなどの塗布装置により、乾燥
時の膜厚が0゜1〜10μmになるように塗布する。乾
燥後、パターン露光し、アルカリエツチングする。かく
して得られたカラーフィルター遮光部は遮光性、平滑性
において極めて優れていた。The formation of the light-shielding part can be achieved by combining the composition with a photopolymerizable, azide, diazo, or cinnamic acid photosensitive resin, by combining the composition with a photocrosslinking agent, by combining the composition with a monomer or By combining with oligomers and initiators, etc.
A suitably adjusted coating liquid can be used. The coating liquid prepared by the above combination is applied onto a support such as a glass substrate using a coating device such as a spinner, roll coater, dip coater, foil coater, or bar coater, so that the film thickness when dried becomes 0.1 to 10 μm. Apply to. After drying, pattern exposure and alkali etching are performed. The color filter light-shielding portion thus obtained was extremely excellent in light-shielding properties and smoothness.
(実施例1)
ブチルメタクリレート 50重量%、ブチルアクリレー
ト 30重量%、メタクリル酸 20重量%。(Example 1) Butyl methacrylate 50% by weight, butyl acrylate 30% by weight, methacrylic acid 20% by weight.
からなるアクリル共重合体10g、 シクロへキサノ
ン78.9g、プラソクパールズ800 (キャボット
社製)10.3gおよび下記一般式で示される色素誘導
体0.8gをアトライターで十分に分散し透光部形成用
組成物を得た。10 g of an acrylic copolymer consisting of 78.9 g of cyclohexanone, 10.3 g of Prasok Pearls 800 (manufactured by Cabot), and 0.8 g of a dye derivative represented by the following general formula were sufficiently dispersed with an attritor to form a transparent area. A forming composition was obtained.
t Hs
(CuPc:銅フタロシアニン残基)
(実施例2)
実施例1においてカーボンブラックをMA−100(三
菱化成工業■社製)に代えて透光部形成用組成物を得た
。t Hs (CuPc: Copper phthalocyanine residue) (Example 2) A composition for forming a transparent part was obtained in Example 1 except that carbon black was replaced with MA-100 (manufactured by Mitsubishi Chemical Corporation).
(実施例3)
実施例1においてカーボンブラックをラーベン1020
(コロンビアカーボン社製)に代えて透光部形成用組成
物を得た。(Example 3) In Example 1, carbon black was replaced with Raven 1020.
(manufactured by Columbia Carbon), a composition for forming a transparent part was obtained.
(実施例4)
実施例1において色素誘導体を下記一般式で示される化
合物に代えて透光部形成用組成物を得た。(Example 4) A composition for forming a transparent part was obtained in Example 1 except that the dye derivative was replaced with a compound represented by the following general formula.
\ CH。\ CH.
(実施例5)
実施例1において色素誘導体を下記一般式で示される化
合物に代えて遮光部形成用組成物を得た。(Example 5) A composition for forming a light-shielding part was obtained by replacing the dye derivative in Example 1 with a compound represented by the following general formula.
\
CH3
(Q:キナクリドン残基)
(比較例1〜3)
実施例1〜3において色素誘導体を添加せずに遮光部形
成用組成物を得た。\CH3 (Q: Quinacridone residue) (Comparative Examples 1 to 3) In Examples 1 to 3, compositions for forming light shielding portions were obtained without adding the dye derivative.
実施例1〜5.比較例1〜3により得た遮光部形成用組
成物の流動性2粒度分布の測定およびドクターブレード
を用いて塗布し光沢の測定を行い品質を比較した結果を
下表にまとめた。Examples 1-5. The results of comparing the quality of the compositions for forming light-shielding parts obtained in Comparative Examples 1 to 3 by measuring the fluidity 2 particle size distribution and measuring the gloss after coating with a doctor blade are summarized in the table below.
TI値:5rpm値/60rpm値
平均粒子径:p、。値 CAPA−700(堀場製作所
製、遠心沈降式)
東洋インキ製造株式会社TI value: 5 rpm value/60 rpm value Average particle diameter: p. Value CAPA-700 (manufactured by Horiba, centrifugal sedimentation type) Toyo Ink Mfg. Co., Ltd.
Claims (1)
20〜200重量部、下記一般式で示される色素誘導体
0.1〜30重量部を含んでなるカラーフィルター遮光
部形成用組成物。 ▲数式、化学式、表等があります▼ (式中、Dは有機色素残基、Xは直接結合または二価の
結合基、R_1、R_2はアルキル基、mは1〜4の整
数、nは1〜4の整数をそれぞれ示す。)[Claims] 1. A composition for forming a light-shielding part of a color filter, which contains 20 to 200 parts by weight of an acrylic resin and 0.1 to 30 parts by weight of a dye derivative represented by the following general formula, based on 100 parts by weight of carbon black. . ▲There are mathematical formulas, chemical formulas, tables, etc.▼ (In the formula, D is an organic dye residue, X is a direct bond or a divalent bonding group, R_1, R_2 are an alkyl group, m is an integer from 1 to 4, n is 1 (Indicates each integer from ~4.)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1343366A JP2694036B2 (en) | 1989-12-29 | 1989-12-29 | Color filter light-shielding part forming composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1343366A JP2694036B2 (en) | 1989-12-29 | 1989-12-29 | Color filter light-shielding part forming composition |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH03203948A true JPH03203948A (en) | 1991-09-05 |
JP2694036B2 JP2694036B2 (en) | 1997-12-24 |
Family
ID=18360962
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1343366A Expired - Fee Related JP2694036B2 (en) | 1989-12-29 | 1989-12-29 | Color filter light-shielding part forming composition |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2694036B2 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0519423A2 (en) * | 1991-06-19 | 1992-12-23 | MITSUI TOATSU CHEMICALS, Inc. | Phthalocyanine compounds and usage thereof |
US5380842A (en) * | 1991-06-20 | 1995-01-10 | Mitsui Toatsu Chemicals, Incorporated | Phthalocyanine compounds and usage thereof |
JP2002311232A (en) * | 2002-02-12 | 2002-10-23 | Seiko Epson Corp | Liquid crystal display device, color filter and substrate with color filter |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0238440A (en) * | 1988-07-28 | 1990-02-07 | Toppan Printing Co Ltd | Colored acrylic resin composition |
-
1989
- 1989-12-29 JP JP1343366A patent/JP2694036B2/en not_active Expired - Fee Related
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0238440A (en) * | 1988-07-28 | 1990-02-07 | Toppan Printing Co Ltd | Colored acrylic resin composition |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0519423A2 (en) * | 1991-06-19 | 1992-12-23 | MITSUI TOATSU CHEMICALS, Inc. | Phthalocyanine compounds and usage thereof |
EP0519423A3 (en) * | 1991-06-19 | 1994-03-09 | Mitsui Toatsu Chemicals | |
US5380842A (en) * | 1991-06-20 | 1995-01-10 | Mitsui Toatsu Chemicals, Incorporated | Phthalocyanine compounds and usage thereof |
JP2002311232A (en) * | 2002-02-12 | 2002-10-23 | Seiko Epson Corp | Liquid crystal display device, color filter and substrate with color filter |
Also Published As
Publication number | Publication date |
---|---|
JP2694036B2 (en) | 1997-12-24 |
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