JPH03194322A - Wall surface material for cooking utensil - Google Patents
Wall surface material for cooking utensilInfo
- Publication number
- JPH03194322A JPH03194322A JP33442589A JP33442589A JPH03194322A JP H03194322 A JPH03194322 A JP H03194322A JP 33442589 A JP33442589 A JP 33442589A JP 33442589 A JP33442589 A JP 33442589A JP H03194322 A JPH03194322 A JP H03194322A
- Authority
- JP
- Japan
- Prior art keywords
- oxide
- aluminum
- covering film
- catalyst
- composite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 title claims abstract description 25
- 238000010411 cooking Methods 0.000 title description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 14
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000000835 fiber Substances 0.000 claims abstract description 14
- 239000000919 ceramic Substances 0.000 claims abstract description 12
- 239000002131 composite material Substances 0.000 claims abstract description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052742 iron Inorganic materials 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims abstract description 7
- 229910052684 Cerium Inorganic materials 0.000 claims abstract description 6
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052802 copper Inorganic materials 0.000 claims abstract description 5
- 239000010949 copper Substances 0.000 claims abstract description 5
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 4
- 239000010941 cobalt Substances 0.000 claims abstract description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 4
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims abstract description 4
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 3
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052814 silicon oxide Inorganic materials 0.000 claims abstract description 3
- 238000007743 anodising Methods 0.000 claims description 4
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 2
- 239000004917 carbon fiber Substances 0.000 claims description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical group C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 2
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 2
- 239000003054 catalyst Substances 0.000 abstract description 12
- 238000000576 coating method Methods 0.000 abstract description 9
- 239000011248 coating agent Substances 0.000 abstract description 8
- 238000004140 cleaning Methods 0.000 abstract description 5
- 229910044991 metal oxide Inorganic materials 0.000 abstract description 4
- 150000004706 metal oxides Chemical group 0.000 abstract description 4
- 229910001220 stainless steel Inorganic materials 0.000 abstract description 3
- 239000010935 stainless steel Substances 0.000 abstract description 3
- 239000011230 binding agent Substances 0.000 abstract description 2
- 230000003647 oxidation Effects 0.000 abstract description 2
- 238000007254 oxidation reaction Methods 0.000 abstract description 2
- 238000010276 construction Methods 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- 240000008415 Lactuca sativa Species 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000000635 electron micrograph Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 235000012045 salad Nutrition 0.000 description 1
- 239000013585 weight reducing agent Substances 0.000 description 1
Landscapes
- Catalysts (AREA)
- Cookers (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は、調理器の庫内壁面用の軽量で自己浄化能をも
つ調理器用壁面材に関する。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to a lightweight and self-purifying wall material for the interior wall of a cooking appliance.
従来の技術
従来、調理器の庫内壁面は鉄、アルミニウムメツキ鋼板
、ステンレスで構成されている。さらに一部には触媒を
含有した多孔質コーティングあるいはフッ素樹脂コーテ
ィングを施し、自己浄化能や非粘着性を付与しているも
のがある。BACKGROUND OF THE INVENTION Conventionally, the interior walls of cooking appliances have been made of iron, aluminum-plated steel, or stainless steel. Furthermore, some of them are coated with a porous coating containing a catalyst or a fluororesin coating, giving them self-cleaning ability and non-stick properties.
発明が解決しようとする課題
しかし、上記の構成では庫内壁面材が鉄、アルミニウム
メツキ鋼板またはステンレスであるために１重量が重い
という課題があった。Problems to be Solved by the Invention However, in the above configuration, there was a problem in that the interior wall material was made of iron, aluminum-plated steel plate, or stainless steel, and the weight was heavy.
本発明は上記従来の課題を解決するもので、軽量、高強
度で自己浄化能をもつ庫内材を提供するものである。The present invention solves the above-mentioned conventional problems and provides a refrigerator interior material that is lightweight, has high strength, and has self-cleaning ability.
課題を解決するための手段
上記課題を解決するために１本発明の調理器用壁面材は
セラミック線維とアルミニウムの複合体の表面に陽極酸
化法で酸化物被膜を形成し、さらに酸化物被膜表面に金
属酸化物を担持して庫内壁面の構成材とするものである
。Means for Solving the Problems In order to solve the above problems, the wall material for cooking utensils of the present invention is produced by forming an oxide film on the surface of a composite of ceramic fibers and aluminum by an anodizing method, and further forming an oxide film on the surface of the oxide film. It supports metal oxides and serves as a constituent material for the inner wall surface of the refrigerator.
作用
上記の構成で、セラミック繊維とアルミニウムの複合体
の比重は鉄の約％であるので、庫内壁面材としての使用
量が体積で同じならは約％の軽量化となる、また、セラ
ミック繊維とアルミニウムの複合体の引張シ強さは炭素
繊維強化アルミニウムで６７ ｋｇｆ−ｔｘ−２であり
、ステアＬ／Ｌの６０にぎｆ−ＭＭ−２と同等もしくは
それ以上である。Effect With the above configuration, the specific gravity of the ceramic fiber and aluminum composite is about % of that of iron, so if the amount used as the interior wall material is the same in terms of volume, the weight will be reduced by about %. The tensile strength of the carbon fiber-reinforced aluminum composite is 67 kgf-tx-2, which is equal to or higher than 60 kgf-mm-2 of steer L/L.
一方、自己浄化能の付与はコーティング方式の場合には
触媒が結合剤に覆われてしまうために。On the other hand, in the case of a coating method, the self-purification ability is imparted because the catalyst is covered with a binder.
本発明は繊維強化アルミニウムの表面に陽極酸化法で酸
化けい素（Ｓｉｎ２）や酸化アルミニウム（Ａｇ２Ｏ３
）の酸化物被膜を形成後、この被膜表面に金属酸化物触
媒を直接担持することで触媒を露出させ、高い浄化能力
を得る。陽極酸化法で得られる５ｉｎ２．ムｅ２０５被
膜は数μｍの孔径をもつ多孔体で、触媒担体として適し
ている。In the present invention, silicon oxide (Sin2) and aluminum oxide (Ag2O3) are added to the surface of fiber-reinforced aluminum using an anodizing method.
) After forming the oxide film, a metal oxide catalyst is directly supported on the surface of this film to expose the catalyst and obtain high purification ability. 5in2. obtained by anodic oxidation method. The Mu-e205 film is a porous material with a pore diameter of several micrometers, and is suitable as a catalyst carrier.
実施例 以下５本発明の実施例を図面を参照しながら説明する。Example Hereinafter, five embodiments of the present invention will be described with reference to the drawings.
第１図は本発明の一実施例による調理器用壁面材の断面
図であり、１はセラミック繊維２でアルミニウム３を強
化した複合体基材、４は陽極酸化法で形成した５ｉｎ２
被膜、６は担持した酸化物であり、第２図は５ｉｏ２被
膜４の拡大写真である。FIG. 1 is a cross-sectional view of a wall material for a cooker according to an embodiment of the present invention, in which 1 is a composite base material in which aluminum 3 is reinforced with ceramic fibers 2, and 4 is a 5in2
The coating 6 is a supported oxide, and FIG. 2 is an enlarged photograph of the 5io2 coating 4.
上記の構成において、セラミック繊維２およびアルミニ
ウム３で軽量、高強度の庫内壁面基材１を構成し、その
表面に５１０２被膜４および酸化物６（以下、触媒とい
う）で自己浄化能を発揮する。In the above configuration, the ceramic fiber 2 and aluminum 3 constitute a lightweight, high-strength interior wall base material 1, and the 5102 coating 4 and oxide 6 (hereinafter referred to as catalyst) on the surface exhibit self-purifying ability. .
セラミック繊維２には炭素繊維または炭化けい素繊維を
用いた。また５１０２被膜４の代わシにムｅ２０５でも
よい。陽極酸化は繊維強化アルミニウムを陽極として、
シリケートなどの金属溶液中で通電して形成した。For the ceramic fiber 2, carbon fiber or silicon carbide fiber was used. Further, instead of the 5102 coating 4, Mue205 may be used. Anodizing uses fiber-reinforced aluminum as the anode.
It was formed by applying electricity in a metal solution such as silicate.
この方法で形成した酸化物被膜は硬く、密着性も良好で
あった。膜厚は約１０μ１以上が好ましく、特に５μ箇
以下では下地になっているアルミニウムが部分的に露出
することがあり、触媒担持に適していない。The oxide film formed by this method was hard and had good adhesion. The film thickness is preferably about 10 μl or more; in particular, if the film thickness is less than 5 μm, the underlying aluminum may be partially exposed, making it unsuitable for supporting a catalyst.
触媒担持は、マンガン、鉄、コバルト、ニッケル、銅、
セリウムなどを含む金属溶液１＆：５ｉｎ２被Ｍ４に含
浸させた後、焼成するという工程で行った。上記金属の
中でセリウムは触媒の比表面積を大きくする効果があり
２例えばマンガン：銅絢１：１の酸化物の場合、セリウ
ムをマンガン：銅：セリウム＝１：１：２で混合したと
きに比表面積は２倍以上になった。またマンガン、鉄、
コバルト。Catalyst support is manganese, iron, cobalt, nickel, copper,
The process was performed by impregnating the metal solution 1&:5in2 with M4 containing cerium, etc., and then firing it. Among the above metals, cerium has the effect of increasing the specific surface area of the catalyst.2 For example, in the case of a manganese:copper oxide of 1:1, when cerium is mixed at a ratio of manganese:copper:cerium=1:1:2. The specific surface area has more than doubled. Also manganese, iron,
cobalt.
ニッケル、銅の酸化物は調理物から発生する油脂を主成
分とする汚れの分解作用をもつことは知られており、第
１図に示した構成でサラダオイル６金分解することがで
きた。It is known that oxides of nickel and copper have the ability to decompose dirt mainly composed of fats and oils generated from cooking, and the configuration shown in Figure 1 was able to decompose six-metal salad oil.
以上の壁面材で、従来にない軽量の調理器が実現できる
ことは既に明らかであり、軽量化だけでなく自己浄化能
を従来と異なった構成で実現できた。It is already clear that it is possible to create a lighter weight cooker than ever before using the wall material described above, and we were able to achieve not only weight reduction but also self-cleaning ability with a configuration different from conventional ones.
発明の効果
以上のように本発明の調理器用壁面材は、セラミック繊
維とアルミニウムの複合体基材で構成するので軽量で高
強度の壁面材ができるとともに基材表面に油脂分解能の
高い被膜を形成しているので庫内汚れのない調理器がで
きる。Effects of the Invention As described above, the wall material for cooking appliances of the present invention is composed of a composite base material of ceramic fiber and aluminum, so it is lightweight and has high strength, and it also forms a film with high oil and fat decomposition ability on the surface of the base material. This makes it possible to create a cooker with no internal contamination.
第１図は本発明の実施例の調理器用壁面材の一部拡大断
面図、第２図は同壁面材における５１０２被膜の電子顕
微鏡写真である。
１・・・・・・複合体基材、２・・・・・・セラミック
繊維、３・・・・・・アルミニウム、４・・・・・・５
ｉｎ２被膜（酸化物被膜）、６・・・・・・酸化物。FIG. 1 is a partially enlarged sectional view of a wall material for a cooker according to an embodiment of the present invention, and FIG. 2 is an electron micrograph of the 5102 coating on the same wall material. 1...Composite base material, 2...Ceramic fiber, 3...Aluminum, 4...5
in2 film (oxide film), 6... oxide.
Claims (2)
陽極酸化法により前記複合体基材の表面に形成された酸
化物被膜と、酸化物被膜に担持したマンガン、鉄、コバ
ルト、ニッケル、銅、セリウムのうち１種以上の酸化物
とからなる調理器用壁面材。(1) A combined base material of ceramic fiber and aluminum,
A cooker comprising an oxide film formed on the surface of the composite base material by an anodizing method, and an oxide of one or more of manganese, iron, cobalt, nickel, copper, and cerium supported on the oxide film. Wall material.
であり、酸化物被膜の主成分が酸化けい素または酸化ア
ルミニウムである請求項１記載の調理器用壁面材。(2) The wall material for a cooker according to claim 1, wherein the ceramic fiber is carbon fiber or silicon carbide fiber, and the main component of the oxide film is silicon oxide or aluminum oxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP33442589A JPH03194322A (en) | 1989-12-21 | 1989-12-21 | Wall surface material for cooking utensil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP33442589A JPH03194322A (en) | 1989-12-21 | 1989-12-21 | Wall surface material for cooking utensil |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03194322A true JPH03194322A (en) | 1991-08-26 |
Family
ID=18277234
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP33442589A Pending JPH03194322A (en) | 1989-12-21 | 1989-12-21 | Wall surface material for cooking utensil |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03194322A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011202084A (en) * | 2010-03-26 | 2011-10-13 | Sumitomo Osaka Cement Co Ltd | Antifouling-processed product and method for producing the same |
| WO2011157559A3 (en) * | 2010-06-17 | 2012-08-16 | Paul Hettich Gmbh & Co. Kg | Component, in particular for a fitting, a piece of furniture and/or a domestic appliance, method for producing a component, and a fitting, piece of furniture and/or domestic appliance |
-
1989
- 1989-12-21 JP JP33442589A patent/JPH03194322A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2011202084A (en) * | 2010-03-26 | 2011-10-13 | Sumitomo Osaka Cement Co Ltd | Antifouling-processed product and method for producing the same |
| WO2011157559A3 (en) * | 2010-06-17 | 2012-08-16 | Paul Hettich Gmbh & Co. Kg | Component, in particular for a fitting, a piece of furniture and/or a domestic appliance, method for producing a component, and a fitting, piece of furniture and/or domestic appliance |
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