JPH03190988A - Liquid adhesive composition - Google Patents
Liquid adhesive compositionInfo
- Publication number
- JPH03190988A JPH03190988A JP32896289A JP32896289A JPH03190988A JP H03190988 A JPH03190988 A JP H03190988A JP 32896289 A JP32896289 A JP 32896289A JP 32896289 A JP32896289 A JP 32896289A JP H03190988 A JPH03190988 A JP H03190988A
- Authority
- JP
- Japan
- Prior art keywords
- parts
- meth
- acrylic acid
- ester
- liquid adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 21
- 239000000203 mixture Substances 0.000 title claims abstract description 6
- 239000000853 adhesive Substances 0.000 title claims description 24
- 239000007788 liquid Substances 0.000 title claims description 14
- 239000000178 monomer Substances 0.000 claims abstract description 11
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229920000642 polymer Polymers 0.000 claims abstract description 7
- 150000001639 boron compounds Chemical class 0.000 claims description 13
- -1 (meth)acrylic acid hydroxyalkyl ester Chemical class 0.000 claims description 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract description 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract description 3
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 abstract description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 abstract 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 125000002768 hydroxyalkyl group Chemical group 0.000 abstract 2
- SJMYWORNLPSJQO-UHFFFAOYSA-N tert-butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)(C)C SJMYWORNLPSJQO-UHFFFAOYSA-N 0.000 abstract 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 239000003292 glue Substances 0.000 description 5
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 5
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 5
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 5
- 238000010992 reflux Methods 0.000 description 4
- YMBNBZFZTXCWDV-UHFFFAOYSA-N ethane-1,2-diol;propane-1,2,3-triol Chemical compound OCCO.OCC(O)CO YMBNBZFZTXCWDV-UHFFFAOYSA-N 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 230000037303 wrinkles Effects 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- FWWXYLGCHHIKNY-UHFFFAOYSA-N 2-ethoxyethyl prop-2-enoate Chemical compound CCOCCOC(=O)C=C FWWXYLGCHHIKNY-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Natural products OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 150000001638 boron Chemical class 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- SKNDRXDKJVPLHD-UHFFFAOYSA-N cyclobutyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1CCC1 SKNDRXDKJVPLHD-UHFFFAOYSA-N 0.000 description 1
- OIWOHHBRDFKZNC-UHFFFAOYSA-N cyclohexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1CCCCC1 OIWOHHBRDFKZNC-UHFFFAOYSA-N 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、（メタ）アクリル酸ヒドロキシアルキルエス
テルと（メタ）アクリル酸を主成分とする付加重合体及
び半極性有機ホウ素化合物を含有することを特徴とする
接着後の紙の収縮性がなく接着性の優れた液状接着剤組
成物に関するものである。Detailed Description of the Invention (Industrial Application Field) The present invention is directed to an addition polymer containing (meth)acrylic acid hydroxyalkyl ester and (meth)acrylic acid as main components, and a semipolar organic boron compound. The present invention relates to a liquid adhesive composition which has excellent adhesive properties and has no shrinkage of paper after adhesion.
（発明が解決しようとする課題）
澱粉糊やポリビニルアルコール等の合成高分子系の糊等
の液状糊は、接着後紙などの基材にカールやしわを著し
く生じ易い、また初期接着性能時間も非常に遅いという
欠点があった。(Problems to be Solved by the Invention) Liquid glues such as starch glues and synthetic polymer glues such as polyvinyl alcohol tend to cause curls and wrinkles on substrates such as paper after adhesion, and the initial adhesion performance time is also short. The drawback was that it was very slow.
本発明は、従来の液状糊が有するこれらの欠点を解消し
、紙などの基材にカールやしわが生じにくいことや初期
接着性能時間を速くすることなどを目的としたものであ
る。The present invention aims to eliminate these drawbacks of conventional liquid glues, to make paper and other substrates less likely to curl or wrinkle, and to shorten the initial adhesion time.
（発明が解決するための手段）
すなわち本発明は、（メタ）アクリル酸ヒドロキシアル
キルエステルと（メタ）アクリル酸および残余量のこれ
らの単量体以外の単量体からなる付加重合体を接着剤成
分とし、さらに半極性有機ホウ素化合物類を配合するご
とにより、好都合にこれら従来の液状糊の諸欠点を改善
することを見出した。(Means for Solving the Invention) That is, the present invention provides an adhesive for adding an addition polymer consisting of (meth)acrylic acid hydroxyalkyl ester, (meth)acrylic acid, and the remaining amount of monomers other than these monomers. It has been found that the various drawbacks of these conventional liquid glues can be advantageously improved by adding semipolar organic boron compounds as a component.
本発明では、接着性成分として（メタ）アクリル酸ヒド
ロキシアルキルエステルと（メタ）アクリル酸及び必要
に応してこれら、！ｒＬ量体以外の単量体からなる付加
重合体を】０〜４０部使用することにより、接着後の紙
などの基材へのカールやしわを著しく減少てき、更に初
期接着性能も同士出来る。この接着性成分が１０部未満
では、接着後紙などの基材にカールやしわを生し易く、
初期接着性能時間も遅くなるし、４０部をこえると、増
粘により塗布性が非常に悪くなる。In the present invention, (meth)acrylic acid hydroxyalkyl ester and (meth)acrylic acid are used as adhesive components, and if necessary, these are used! By using 0 to 40 parts of an addition polymer consisting of a monomer other than the rL-mer, curling and wrinkling of the substrate such as paper after adhesion can be significantly reduced, and the initial adhesion performance can also be improved. If the adhesive component is less than 10 parts, the base material such as paper is likely to curl or wrinkle after bonding.
The initial adhesion performance time is also delayed, and if it exceeds 40 parts, the coating properties become extremely poor due to thickening.
上記接着性成分の単量体以外の単量体の例としては、例
えばスチレン、メタクリル酸メチルエステル、メタクリ
ル酸エチルエステル、メタクリル酸し−ブチルエステル
、メタクリル酸シクロへキシルエステル、アクリル酸エ
チルエステル、アクリル酸ブチルエステル、アクリル酸
プロピルエステル、アクリル酸２−エチルヘキシルエス
テル、アクリル酸エトキシエチルエステル、アクリル酸
シトキシエチルエステル、メタクリル酸プロピルエステ
ル、メタクリル酸ｎ−ブチルエステル、メタクリル酸Ｉ
・リル、アクリル酸メチルエステル、フタジエン、エチ
レン、マレイン酸エステル、フマル酸エステル、イタコ
ン酸エステル、アクリロニトリル、アクリルアミｌ′、
ツククリルアミド、酢酸ビニル等を挙げることができ、
これらの単量体は単独でもまた二種以上混合して使用し
てもよい。Examples of monomers other than the above-mentioned adhesive component monomers include styrene, methacrylic acid methyl ester, methacrylic acid ethyl ester, methacrylic acid cyclobutyl ester, methacrylic acid cyclohexyl ester, acrylic acid ethyl ester, Acrylic acid butyl ester, acrylic acid propyl ester, acrylic acid 2-ethylhexyl ester, acrylic acid ethoxyethyl ester, acrylic acid cytoxyethyl ester, methacrylic acid propyl ester, methacrylic acid n-butyl ester, methacrylic acid I
・Ril, acrylic acid methyl ester, phtadiene, ethylene, maleic acid ester, fumaric acid ester, itaconic acid ester, acrylonitrile, acrylamyl',
Examples include tsukucrylamide, vinyl acetate, etc.
These monomers may be used alone or in combination of two or more.
又、半極性有機ホウ素化合物類とは、特公昭４６３１８
４７に記載される一連のホウ素系界面活性則乃至活性剤
原料であり、東邦化学工業株式会社から下記の商品名で
市販されている下記構造式のものを挙げることができる
。In addition, semipolar organic boron compounds are described in Japanese Patent Publication No. 46318
These are a series of boron-based surfactant rules or activator raw materials described in No. 47, and those having the following structural formula and commercially available from Toho Chemical Industry Co., Ltd. under the following trade names can be mentioned.
（ＥＭＵＬＢＯＮ ＧＢ）
（ＩＥＭＵｌ、ＢＯｌぐ ＤＧＢ）
（ＥＭＵＬＢＯＮ Ｔ−６０）
Ｈ２
ＣＩ＋□
（ＥＭ旧、ＢＯＮ Ｓ−２０）
（口［ＩＬＢＯＮ ＰＧＢ）
（Ｅｌ’１ＵＬＢＯＮ Ｓ−６６）
（５−６６）（Ｅ Ｔ−２０）
（ＥＭＵＬＢＯＮ Ｓ−２６０）
これら半極性有機ホウ素化合物類を０．１〜１０部配合
するにより、粘着性、塗布性、初期接着性能を大幅に改
善できる。半極性有機ホウ素化合物類が０，１部未満で
は、粘着性や塗布性に向上効果が得られず、１０部をこ
えると、塗布性、初期接着性が低ドする。(EMULBON GB) (IEMUl, BOLG DGB) (EMULBON T-60) H2 CI+□ (EM old, BON S-20) (mouth [ILBON PGB) (El'1ULBON S-66) (5-66) (E T-20) (EMULBON S-260) By blending 0.1 to 10 parts of these semipolar organic boron compounds, tackiness, coating properties, and initial adhesive performance can be significantly improved. If the amount of the semipolar organic boron compound is less than 0.1 part, no improvement in adhesiveness or coating properties will be obtained, and if it exceeds 10 parts, coating properties and initial adhesiveness will be low.
（実施例） 以下、実施例をもって本発明を詳細に述べる。(Example) Hereinafter, the present invention will be described in detail with reference to Examples.
尚、以下に配合したものを接着成分とする。In addition, what is blended below is used as an adhesive component.
メタクリル酸２−ヒｌξロキシ ４０部エチ
ルエステル
メタクリル酸メチルエステル ３０部メメタ
リル酸 １０部アクリル酸エ
チルエステル ２０部エチルアルコール
１００部を溶媒として重合したもの
。2-Hylξroxy methacrylate 40 parts ethyl ester methyl methacrylate 30 parts memethacrylic acid 10 parts ethyl acrylate 20 parts ethyl alcohol
Polymerized using 100 parts as a solvent.
実施例１
水
接着性成分
エチレングリコール
グリセリン
ポリビニルピロリドン
半極性有機ホウ素化合物（ＥＭＵＬＢＯＮ ＧＢ）４０
部
２０部
２０部
１０部
５部
５部
これを撹拌機を備えた三ツロフラスコにを還流下に８０
〜９０°Ｃで撹拌溶解し、半透明の液状接着剤を得た。Example 1 Water-adhesive component ethylene glycol glycerin polyvinyl pyrrolidone semipolar organic boron compound (EMULBON GB) 40
20 parts 20 parts 10 parts 5 parts 5 parts This was added to a Mitsuro flask equipped with a stirrer and 80%
The mixture was stirred and dissolved at ~90°C to obtain a translucent liquid adhesive.
比較例１
実施例１の半極性有機ホウ素化合物（Ｅ）ＩＵＬＢＯＮ
ＧＢ）５部を水に置き換え、液状接着剤を得た。Comparative Example 1 Semipolar organic boron compound (E) IULBON of Example 1
GB) was replaced with water to obtain a liquid adhesive.
比較例２
実施例１の接着性成分２０部をポリビニルアルコール１
０部、水１０部に置き換え、液状接着剤を得ノこ。Comparative Example 2 20 parts of the adhesive component of Example 1 was mixed with 1 part of polyvinyl alcohol.
Replace 0 parts with 10 parts of water to obtain liquid adhesive.
実施例２
水
接着性成分
エチレングリコール
グリセリン
ポリビニルピロリドン
半極性有機ホウ素化合物（ＥＭＩＪＬＢＯＮ Ｓ−２０
）３５部
３５部
１５部
５部
５部
５部
これを還流下に８０〜９０℃で撹拌溶解し、半透明の液
状接着剤を得た。Example 2 Water-adhesive component ethylene glycol glycerin polyvinyl pyrrolidone semipolar organic boron compound (EMIJLBON S-20
) 35 parts 35 parts 15 parts 5 parts 5 parts This was stirred and dissolved under reflux at 80 to 90°C to obtain a translucent liquid adhesive.
実施例３
水
接着性成分
エチレングリコール
ペトリオール
ポリビニルピロリドン
半極性有機ホウ素化合物（ＥＭＵＬＢＯＮ ＰＣＢ）４
５部
１２部
２３部
１０部
５部
５部
これを還流下に８０〜９０℃で撹拌溶解し、半透明の液
状接着剤を得た。Example 3 Water-adhesive component ethylene glycol petriol polyvinylpyrrolidone semipolar organic boron compound (EMULBON PCB) 4
5 parts 12 parts 23 parts 10 parts 5 parts 5 parts This was stirred and dissolved under reflux at 80 to 90°C to obtain a translucent liquid adhesive.
実施例４
水
接着性成分
エチレングリコール
グリセリン
ポリビニルピロリドン
半極性好機ホウ素化合物（ＢエルＢＯＮ ＤＧＢ）４４
部
２０部
２０部
１０部
５部
】部
これを還流下に８０〜９０°Ｃで撹拌溶解し、半透明の
液状接着剤を得た。Example 4 Water-adhesive component ethylene glycol glycerin polyvinyl pyrrolidone semipolar opportunistic boron compound (BEL BON DGB) 44
20 parts 20 parts 10 parts 5 parts This was stirred and dissolved under reflux at 80 to 90°C to obtain a translucent liquid adhesive.
実施例５
水
接着性成分
エチレングリコール
ペトリオール
ポリビニルピロリドン
半極性有機ホウ素化合物（ＥＭ川、ＢＯＮ Ｓ−６６）
４２部
２０部
２０部
５部
５部
８部
０
これを還流下に８０〜９０°Ｃで撹拌溶解し、半透明の
液状接着剤を得た。Example 5 Water-adhesive component ethylene glycol petriol polyvinylpyrrolidone semipolar organic boron compound (EM River, BON S-66)
42 parts 20 parts 20 parts 5 parts 5 parts 8 parts 0 This was stirred and dissolved under reflux at 80 to 90°C to obtain a translucent liquid adhesive.
以下表−１に、紙の収縮率、初期接着性能、塗布性能の
比較結果を示す。Table 1 below shows the comparison results of paper shrinkage rate, initial adhesion performance, and coating performance.
表−１から明らかなように、接着性成分として（メタ）
アクリル酸ヒドロキシアルキルエステルと（メタ）アク
リル酸及び必要におうしてこれら単量体以外の単量体か
らなる付加重合体を１０〜４０部及び半極性有機ホウ素
化合物類を０．１〜１０部配合することにより、良好な
液状接着剤が得られる。As is clear from Table 1, as an adhesive component (meta)
10 to 40 parts of an addition polymer consisting of acrylic acid hydroxyalkyl ester, (meth)acrylic acid and, if necessary, monomers other than these monomers, and 0.1 to 10 parts of semipolar organic boron compounds. By blending, a good liquid adhesive can be obtained.
■■
Claims (1)
タ）アクリル酸および残余量のこれらの単量体以外の単
量体からなる付加重合体及び半極性有機ホウ素化合物を
含有することを特徴とする液状接着剤組成物。A liquid adhesive characterized by containing an addition polymer consisting of (meth)acrylic acid hydroxyalkyl ester, (meth)acrylic acid, and a residual amount of monomers other than these monomers, and a semipolar organic boron compound. Composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1328962A JPH0813962B2 (en) | 1989-12-19 | 1989-12-19 | Liquid adhesive composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1328962A JPH0813962B2 (en) | 1989-12-19 | 1989-12-19 | Liquid adhesive composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH03190988A true JPH03190988A (en) | 1991-08-20 |
| JPH0813962B2 JPH0813962B2 (en) | 1996-02-14 |
Family
ID=18216062
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1328962A Expired - Fee Related JPH0813962B2 (en) | 1989-12-19 | 1989-12-19 | Liquid adhesive composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0813962B2 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103333646A (en) * | 2013-05-30 | 2013-10-02 | 安徽祈艾特电子科技有限公司 | Adhesive agent used for environmental and low-cost paper boxes and preparation method thereof |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105255373B (en) * | 2015-11-17 | 2017-10-31 | 湖北回天新材料股份有限公司 | A kind of lubricating type precoating threaded locking sealing gum and preparation method thereof |
| CN105295747B (en) * | 2015-11-17 | 2017-10-31 | 湖北回天新材料股份有限公司 | A kind of lubricating type thread locking sealing anaerbic adhesive and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60112875A (en) * | 1983-11-24 | 1985-06-19 | Mitsubishi Rayon Co Ltd | Paste for protective sheet, and surface-protected synthetic resin molded article using the same |
-
1989
- 1989-12-19 JP JP1328962A patent/JPH0813962B2/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60112875A (en) * | 1983-11-24 | 1985-06-19 | Mitsubishi Rayon Co Ltd | Paste for protective sheet, and surface-protected synthetic resin molded article using the same |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103333646A (en) * | 2013-05-30 | 2013-10-02 | 安徽祈艾特电子科技有限公司 | Adhesive agent used for environmental and low-cost paper boxes and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0813962B2 (en) | 1996-02-14 |
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