JPH03183505A - Treated composition of rush and treatment - Google Patents
Treated composition of rush and treatmentInfo
- Publication number
- JPH03183505A JPH03183505A JP32321089A JP32321089A JPH03183505A JP H03183505 A JPH03183505 A JP H03183505A JP 32321089 A JP32321089 A JP 32321089A JP 32321089 A JP32321089 A JP 32321089A JP H03183505 A JPH03183505 A JP H03183505A
- Authority
- JP
- Japan
- Prior art keywords
- copper phthalocyanine
- salt
- treatment
- colored pigment
- titanium oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 20
- 150000003839 salts Chemical class 0.000 claims abstract description 20
- 238000004043 dyeing Methods 0.000 claims abstract description 17
- 239000000049 pigment Substances 0.000 claims abstract description 17
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 16
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 15
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 claims abstract description 15
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 15
- GUYIZQZWDFCUTA-UHFFFAOYSA-N (pentadecachlorophthalocyaninato(2-))-copper Chemical compound [Cu+2].N1=C([N-]2)C3=C(Cl)C(Cl)=C(Cl)C(Cl)=C3C2=NC(C2=C(Cl)C(Cl)=C(Cl)C(Cl)=C22)=NC2=NC(C2=C(Cl)C(Cl)=C(Cl)C(Cl)=C22)=NC2=NC2=C(C(Cl)=C(C(Cl)=C3)Cl)C3=C1[N-]2 GUYIZQZWDFCUTA-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000002689 soil Substances 0.000 claims abstract description 8
- 239000007788 liquid Substances 0.000 claims abstract description 6
- 239000007900 aqueous suspension Substances 0.000 claims abstract description 5
- 239000002253 acid Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 7
- 125000000018 nitroso group Chemical group N(=O)* 0.000 claims description 3
- 240000004928 Paspalum scrobiculatum Species 0.000 claims 1
- 235000003675 Paspalum scrobiculatum Nutrition 0.000 claims 1
- 239000004927 clay Substances 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 14
- 229920005610 lignin Polymers 0.000 abstract description 10
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 abstract description 9
- 239000006185 dispersion Substances 0.000 abstract description 8
- 238000001035 drying Methods 0.000 abstract description 5
- 239000004576 sand Substances 0.000 abstract description 5
- 238000010130 dispersion processing Methods 0.000 abstract description 2
- 239000002245 particle Substances 0.000 abstract description 2
- 238000005507 spraying Methods 0.000 abstract description 2
- 238000013329 compounding Methods 0.000 abstract 1
- VQTGUFBGYOIUFS-UHFFFAOYSA-N nitrosylsulfuric acid Chemical compound OS(=O)(=O)ON=O VQTGUFBGYOIUFS-UHFFFAOYSA-N 0.000 abstract 1
- 244000025254 Cannabis sativa Species 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 4
- 239000000975 dye Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 208000010201 Exanthema Diseases 0.000 description 2
- 241000220223 Fragaria Species 0.000 description 2
- 201000005884 exanthem Diseases 0.000 description 2
- 206010037844 rash Diseases 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 235000016623 Fragaria vesca Nutrition 0.000 description 1
- 235000011363 Fragaria x ananassa Nutrition 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 229930182559 Natural dye Natural products 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 1
- 239000001055 blue pigment Substances 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 235000021384 green leafy vegetables Nutrition 0.000 description 1
- 239000001056 green pigment Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- -1 lithium Chemical class 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000000978 natural dye Substances 0.000 description 1
- GSGDTSDELPUTKU-UHFFFAOYSA-N nonoxybenzene Chemical compound CCCCCCCCCOC1=CC=CC=C1 GSGDTSDELPUTKU-UHFFFAOYSA-N 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 210000001747 pupil Anatomy 0.000 description 1
- 125000005624 silicic acid group Chemical group 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 235000021012 strawberries Nutrition 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000979 synthetic dye Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
Description
【発明の詳細な説明】
〈産業上の利用分野〉
本発明は、藺草処理組成物および藺草処理方法に関する
。DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to a rush treatment composition and a rush treatment method.
〈従来の技術および発明が解決しようとしている課題〉
４１表等に使用されているｌ１ｆｌ草は、通常染上を水
に分散させた液中にすｉ（草を浸漬し染上を藺草に付着
させた後、乾燥することにより製品化されている。<Prior art and problems to be solved by the invention> The l1fl grass used in Table 41, etc. is usually prepared by dipping the dyed surface in a solution in which it is dispersed in water (soaking the grass and attaching the dyed surface to the rush). After that, it is made into a product by drying it.
このような染上処理はｔｌＪＩ草の乾燥の均一化促進１
１ｉ草の変色防止および１７ＩＩ草に強靭性、柔軟性等
の付与を目的としてなされている。Such dyeing treatment promotes uniform drying of tlJI grass1
It is used for the purpose of preventing discoloration of 1i grass and imparting toughness, flexibility, etc. to 17II grass.
また、藺草の色合いをよくする目的で、染上に顔料やあ
る種の界面活性剤を併用する方法が用いられているが、
促表とした場合の色の均一性、耐水性や処理操作時にお
けるかぶれの問題などがあった。In addition, in order to improve the color of the rush, a method is used in which pigments and certain surfactants are used in conjunction with the dyeing process.
There were problems with color uniformity, water resistance, and rash during processing when used as a template.
＜縄題を解決するための手段〉
このような状況下に、本発明者らは上記のような問題点
の少ない、優れた凹草処理法を見出すべく種々検討した
結果、染上処理において特定の有色顔料、酸化チタンお
よびリグニンスルホン酸及び／又はその塩を使川するこ
とにより、このようなＬ１的が達せられ°ることを見出
し本発明に至ったすなわち本発明は、
■染上、
■黄色酸化鉄と銅フタロシアニンブルーとの組合せ、銅
フタロシアニンブルー、銅フタロシアニングリーン及び
ニトロソグリーンからなる群より選ばれた有色顔料、
■酸化チタン
および
■リグニンスルホン酸及び／又はその塩からなるＩＩＩ
■草処理紙処理組成物該組成物の水懸濁液全処理液とし
て用いるＩＩＩ草処理方法に関するものである。<Means for solving the problem> Under these circumstances, the present inventors conducted various studies in order to find an excellent method for treating weeds with fewer problems as described above. It was discovered that such L1 target can be achieved by using colored pigments, titanium oxide, and ligninsulfonic acid and/or its salts, leading to the present invention. A combination of yellow iron oxide and copper phthalocyanine blue, a colored pigment selected from the group consisting of copper phthalocyanine blue, copper phthalocyanine green and nitroso green, III consisting of ■ titanium oxide and ■ lignin sulfonic acid and/or its salt.
(2) Grass Treatment Paper Treatment Composition This relates to the III grass treatment method in which an aqueous suspension of the composition is used as a total treatment solution.
本発明において使用される染上としては、天然染上、ア
ルカリ土類金属の酸化物、水酸化物、硫Ｒ，塩および炭
Ｗｉ塩や硫化亜鉛、リトポン等およびこれらの混合物な
どの合成染上を用いることができる。ｊｊ％Ｉ、、天然
染上とは、珪酸分が主成分の粘度質鉱物である。The dyes used in the present invention include natural dyes, synthetic dyes such as alkaline earth metal oxides, hydroxides, sulfur R, salts, charcoal Wi salts, zinc sulfide, lithopone, etc., and mixtures thereof. can be used. jj%I, Natural dyeing is a clay mineral whose main component is silicic acid.
本発明における有色顔料は、蓋色酸化鉄と銅フタロシア
ニンブルーとの組合せ、銅フタロシアニンブルー、銅フ
タロシアニングリーン及び二１−口ソグリーンからなる
群より選ばれ、何れも青色系、緑色系の顔料である。The colored pigment in the present invention is selected from the group consisting of a combination of lid color iron oxide and copper phthalocyanine blue, copper phthalocyanine blue, copper phthalocyanine green, and 21-crystalline green, all of which are blue or green pigments. be.
また、本発明において使用されるリグニンスルホン酸お
よびその塩としては、木材より抽出されるリグニンをス
ルホン化して得られるリグニンスルホン酸、そのす１−
リウムなどの塩、リグニンスルホン酸を高度に化学処理
して精製した変成リグニンスルホン酸等が挙げられる。In addition, ligninsulfonic acid and its salts used in the present invention include ligninsulfonic acid obtained by sulfonating lignin extracted from wood;
Examples include salts such as lithium, modified ligninsulfonic acid obtained by highly chemically treating ligninsulfonic acid, and the like.
本発明の組成物において、リグニンスルホン酸及び／又
はその塩の使用量は、通常染上１００重量部に対し０．
０１〜工０重量部程度である。In the composition of the present invention, the amount of ligninsulfonic acid and/or its salt used is usually 0.00 parts by weight per 100 parts by weight of dyeing.
It is about 0.01 to 0 parts by weight.
本発明の０１１草処理組戒物は、染土に、黄色酸化鉄と
銅フタロシアニンブルーとの組合せ、銅フタロシアニン
ブルー、銅フタロシアニングリーン及び二１〜日ソゲリ
ーンからなる群より選ばれた有色顔料、酸化チタンおよ
びリグニンスルホン酸及び／又はその塩を配合した後、
微粉砕機で粉砕混合することにより調整される。The 011 grass treatment composition of the present invention includes a dyed soil, a combination of yellow iron oxide and copper phthalocyanine blue, a colored pigment selected from the group consisting of copper phthalocyanine blue, copper phthalocyanine green, and 21 to nisogerine, and oxidized soil. After blending titanium and ligninsulfonic acid and/or its salt,
It is adjusted by grinding and mixing with a fine grinder.
また、上記に使用する有色の顔料粒子は比較的硬くて分
散させ難いため、好ましくは、これらの有色の顔料とり
ゲニンスルホン酸及び／又はその塩と水を配合した後、
サンドミル等の分散機で分散加工を行い、染上又は酸化
チタンに液状で噴霧し加えるか、又は分散液を乾燥し水
分を蒸発させたのち加えることが望ましい。Furthermore, since the colored pigment particles used above are relatively hard and difficult to disperse, it is preferable that after blending these colored pigments with geninsulfonic acid and/or its salt and water,
It is preferable to carry out dispersion processing using a dispersing machine such as a sand mill, and add the dye by spraying it onto the dye or titanium oxide, or add it after drying the dispersion and evaporating the water.
本発明の組成物を用いて１ｌｆｆ草処理を行うにあたっ
ては、これに新たに染上を加え、水懸濁液を調整し、こ
れにす「草を浸漬処理し、次いで乾燥することにより良
好に行われる。When treating 1lff grass using the composition of the present invention, a new dye is added to it, an aqueous suspension is prepared, and the grass is immersed in this and then dried. It will be done.
尚、予め染上に、黄色酸化鉄と銅フタロシアニンブルー
との組合せ、銅フタロシアニンブルー銅フタロシアニン
グリーン及び二１〜口ソグリーンからなる群より選ばれ
た有色顔料および酸化チタンを配合した組成物を用意し
、これを水に層温させる際にリグニンスルホン酸及び／
又はその塩を添加し、所望の水懸濁液を調整し、同様に
処理してもよい。In addition, a composition containing titanium oxide and a colored pigment selected from the group consisting of a combination of yellow iron oxide and copper phthalocyanine blue, copper phthalocyanine blue, copper phthalocyanine green, and 21 to 100% green is prepared in advance for dyeing. When this is heated in water, lignin sulfonic acid and/or
or its salt may be added to prepare the desired aqueous suspension and treated in the same manner.
〈発明の効果〉
本発明によれば、染上処理において特定の有色顔料、酸
化チタンおよびリグニンスルホン酸及び／又はその塩を
使川することにより従来問題点とされていた藺草乾燥時
における色の均一性、耐水性や処理操作時におけるかぶ
れの問題などを改良することができる。<Effects of the Invention> According to the present invention, by using specific colored pigments, titanium oxide, and lignin sulfonic acid and/or its salts in the dyeing process, the color change when the strawberry is dried, which has been a problem in the past, can be solved. It is possible to improve uniformity, water resistance, and rash problems during processing operations.
〈実施例〉 以下、実施例により本発明を説明する。<Example> The present invention will be explained below with reference to Examples.
但し、例中、部とあるのは重量部を表す。However, in the examples, parts represent parts by weight.
実施例 １
銅フタロアニングリーンのウェットケーキ（顔料濃度５
０％）８０ｋｇに、リグニンスルホン酸す１〜９９６６
０ｋｇ、水１１． Ｏｋ ｇをサンドミルにて分散させ
た後、乾燥、粉砕し銅フロタシアニングリーンの分散処
理物９５ｋｇ （収率９５％）を得た。Example 1 Copper phthaloanine green wet cake (pigment concentration 5
0%) 80 kg, lignin sulfonic acid 1-9966
0kg, water 11. After dispersing the powder in a sand mill, it was dried and pulverized to obtain 95 kg (yield: 95%) of copper phlotocyanin green dispersed product.
次に、天然の染上ｌ００部に酸化チタン５０部、銅フロ
タシアニングリーンの分散処理物１部をあらかじめ、ド
ラム型タンブラ−で混合後微粉砕機にて粉砕し、本発明
のｌ１ｆｆ草処理組成物を得た。Next, 100 parts of natural dyeing, 50 parts of titanium oxide, and 1 part of a dispersion of copper phlotocyanin green were mixed in advance in a drum-type tumbler and then ground in a fine grinder to form the l1ff grass treatment composition of the present invention. I got something.
実施例 ２
重質炭酸カルシラｌｓ １００部に酸化チタン３０！テ
１；銅フタロシアニンブルー０．２部、英仏酸化鉄２
ｒ？ｌ’ 、 リグニンスルホン酸カリウム３部をあ
らかじめ高速ミキサーで混合後、微粉砕機にて粉砕し本
発明の＋ＪＨ華処種処理組成物；）た。Example 2 100 parts of heavy calcilyl carbonate and 30 parts of titanium oxide! Te1; Copper phthalocyanine blue 0.2 parts, English and French iron oxide 2
r? 1', 3 parts of potassium ligninsulfonate were mixed in advance in a high-speed mixer and then ground in a pulverizer to obtain the +JH Kasho seed treatment composition of the present invention.
実施例 ３
二１−日ソグリーンのウェットケーキ（ｇｌ料濃度４０
％）ｉｏｏｋｇに、変性リグニンスルホン酸６０ｋｇ、
水９０ｋｇをサンドミルにて分散させた後、固形分４０
％の分散処理液２４５ｋｇを得た。（収率９８％）
次に、天然の染上１００部に酸化チタン５０部をあらか
じめ高速ミキサー攪ｆＩ！下に上記分散処理液７．５部
を噴霧し、藺草処理組成物を得た。Example 3 Wet cake of 21-day greens (gl concentration 40
%) iook, 60 kg of modified lignin sulfonic acid,
After dispersing 90 kg of water in a sand mill, the solid content was 40
% dispersion treatment liquid was obtained. (Yield 98%) Next, 50 parts of titanium oxide was added to 100 parts of natural dyeing and mixed in advance with a high-speed mixer fI! 7.5 parts of the above-mentioned dispersion treatment liquid was sprayed onto the bottom to obtain a rush treatment composition.
比較例 １
銅フタロシアニングリーンのウェットケーキ（顔料濃度
５０％）４０ｋｇに、ポリエキシエチレンノニルフェニ
ルエーテル２０ｋｇ、水４０ｋｇをサンドミルにて分散
させた後、固形分４０％の銅フロタシアニングリーンの
分散処理液９８ ｋ ｇ（収率９８％）を得た。Comparative Example 1 After dispersing 40 kg of copper phthalocyanine green wet cake (pigment concentration 50%) with 20 kg of polyexyethylene nonylphenyl ether and 40 kg of water using a sand mill, a dispersion treatment liquid of copper phthalocyanine green with a solid content of 40% was obtained. 98 kg (yield 98%) was obtained.
次に、天然の染上１． Ｏ０部に酸化チタン５０部をあ
らかじめ高速ミキサーに投入後、高速ミキサー攪拌下に
上記分散処理液３部を噴霧し、Ｍ草処理組成物を得た。Next, natural dyeing 1. After adding 50 parts of titanium oxide to 0 parts of O in advance into a high-speed mixer, 3 parts of the above dispersion treatment liquid was sprayed while stirring with the high-speed mixer to obtain an M grass treatment composition.
比較例 ２
天然の染上１００部に酸化チタン５０部、銅フタロシア
ニングリーンＱ、５部をあらかじめドラム型タンブラ−
で混合後、微粉砕機にて粉砕し、υｉｔ草処卵処理組成
物た。Comparative Example 2 100 parts of natural dyeing, 50 parts of titanium oxide, and 5 parts of Copper Phthalocyanine Green Q were mixed in advance in a drum-shaped tumbler.
After mixing with a pulverizer, the mixture was pulverized with a pulverizer to obtain a υit grass egg treatment composition.
上記実施例１〜３、比較例１〜２で得られたＴＩ汀、Ｊ
、ｌ＜処理組成物５瞳に対し天然の染上１４５ｋｇ水４
ｏ ｏ ｘ、ｃの泥染め液を作成後、刈り取った藺草を
浸漬乾燥し、仕上がり外観の状態および畳表作成後の水
に対する耐性をデス１−シた。TI soils obtained in Examples 1 to 3 and Comparative Examples 1 to 2, J
, l<treatment composition 5 pupil natural dyeing 145 kg water 4
After preparing the mud dyeing solution of o x and c, the cut straw grass was soaked and dried to determine the finished appearance and water resistance after making the tatami surface.
又、実施例１〜３、比較例１〜２で得られた藺ｉ、°〔
処理組成物の皮ふに対するシゲキ性をテストした。In addition, the strawberries obtained in Examples 1 to 3 and Comparative Examples 1 to 2 [
The treatment composition was tested for its ability to be applied to the skin.
以」―の結果は、表７１の如くであった。The results were as shown in Table 71.
Claims (2)
、銅フタロシアニンブルー、銅フタロシアニングリーン
及びニトロソグリーンからなる群より選ばれた有色顔料
、 〔３〕酸化チタン および 〔４〕リグニンスルホン酸及び／又はその塩からなる藺
草処理組成物。(1) [1] Dyeing soil, [2] a combination of yellow iron oxide and copper phthalocyanine blue, a colored pigment selected from the group consisting of copper phthalocyanine blue, copper phthalocyanine green and nitroso green, [3] titanium oxide and [ 4] A rush treatment composition comprising ligninsulfonic acid and/or its salt.
、銅フタロシアニンブルー、銅フタロシアニングリーン
及びニトロソグリーンからなる群より選ばれた有色顔料
、 〔３〕酸化チタンおよび 〔４〕リグニンスルホン酸及び／又はその塩を含有する
水懸濁液を用いる藺草処理方法。(2) As a treatment liquid, [1] dyed clay, [2] a combination of yellow iron oxide and copper phthalocyanine blue, a colored pigment selected from the group consisting of copper phthalocyanine blue, copper phthalocyanine green, and nitroso green, [3] A method for treating rice grass using an aqueous suspension containing titanium oxide and [4] ligninsulfonic acid and/or its salt.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP32321089A JPH03183505A (en) | 1989-12-13 | 1989-12-13 | Treated composition of rush and treatment |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP32321089A JPH03183505A (en) | 1989-12-13 | 1989-12-13 | Treated composition of rush and treatment |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03183505A true JPH03183505A (en) | 1991-08-09 |
Family
ID=18152272
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP32321089A Pending JPH03183505A (en) | 1989-12-13 | 1989-12-13 | Treated composition of rush and treatment |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03183505A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9226504B2 (en) | 2010-09-09 | 2016-01-05 | Suncor Energy Inc. | Synergistic paraffinic oil and boscalid fungicides |
| US9451773B2 (en) | 2011-06-03 | 2016-09-27 | Suncor Energy Inc. | Paraffinic oil-in-water emulsions for controlling infection of crop plants by fungal pathogens |
| US9801369B2 (en) | 2006-10-05 | 2017-10-31 | Suncor Energy Inc. | Herbicidal composition with increased herbicidal efficacy |
| US9826738B2 (en) | 2008-06-26 | 2017-11-28 | Suncor Energy Inc. | Turfgrass fungicide formulation with pigment |
| US9999219B2 (en) | 2004-05-18 | 2018-06-19 | Suncor Energy Inc. | Spray oil and method of use therof for controlling turfgrass pests |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS49124317A (en) * | 1973-04-04 | 1974-11-28 | ||
| JPS504313A (en) * | 1973-05-19 | 1975-01-17 | ||
| JPS54156879A (en) * | 1978-05-27 | 1979-12-11 | Kouji Mitsu | Dyeing finish of rush |
| JPS62246703A (en) * | 1986-01-24 | 1987-10-27 | 石原産業株式会社 | Rush treating agent |
-
1989
- 1989-12-13 JP JP32321089A patent/JPH03183505A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS49124317A (en) * | 1973-04-04 | 1974-11-28 | ||
| JPS504313A (en) * | 1973-05-19 | 1975-01-17 | ||
| JPS54156879A (en) * | 1978-05-27 | 1979-12-11 | Kouji Mitsu | Dyeing finish of rush |
| JPS62246703A (en) * | 1986-01-24 | 1987-10-27 | 石原産業株式会社 | Rush treating agent |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9999219B2 (en) | 2004-05-18 | 2018-06-19 | Suncor Energy Inc. | Spray oil and method of use therof for controlling turfgrass pests |
| US9801369B2 (en) | 2006-10-05 | 2017-10-31 | Suncor Energy Inc. | Herbicidal composition with increased herbicidal efficacy |
| US9826738B2 (en) | 2008-06-26 | 2017-11-28 | Suncor Energy Inc. | Turfgrass fungicide formulation with pigment |
| US9226504B2 (en) | 2010-09-09 | 2016-01-05 | Suncor Energy Inc. | Synergistic paraffinic oil and boscalid fungicides |
| US9750249B2 (en) | 2010-09-09 | 2017-09-05 | Suncor Energy Inc. | Synergistic paraffinic oil and boscalid fungicides |
| US9451773B2 (en) | 2011-06-03 | 2016-09-27 | Suncor Energy Inc. | Paraffinic oil-in-water emulsions for controlling infection of crop plants by fungal pathogens |
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