JPH04128003A - Rush treated composition and rush treatment method - Google Patents
Rush treated composition and rush treatment methodInfo
- Publication number
- JPH04128003A JPH04128003A JP25071090A JP25071090A JPH04128003A JP H04128003 A JPH04128003 A JP H04128003A JP 25071090 A JP25071090 A JP 25071090A JP 25071090 A JP25071090 A JP 25071090A JP H04128003 A JPH04128003 A JP H04128003A
- Authority
- JP
- Japan
- Prior art keywords
- blue
- rush
- cobalt
- salt
- colored pigment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 22
- 238000000034 method Methods 0.000 title claims abstract description 8
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 16
- 239000010941 cobalt Substances 0.000 claims abstract description 16
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 16
- 238000004043 dyeing Methods 0.000 claims abstract description 16
- 239000000049 pigment Substances 0.000 claims abstract description 16
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- 150000003839 salts Chemical class 0.000 claims abstract description 14
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 14
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 claims abstract description 11
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910000423 chromium oxide Inorganic materials 0.000 claims abstract description 10
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 claims abstract description 8
- 239000001052 yellow pigment Substances 0.000 claims abstract description 8
- 239000007788 liquid Substances 0.000 claims abstract description 7
- 239000002689 soil Substances 0.000 claims abstract description 7
- 235000013799 ultramarine blue Nutrition 0.000 claims abstract description 6
- 239000002253 acid Substances 0.000 claims description 11
- -1 navy blue Chemical compound 0.000 claims description 7
- 239000004927 clay Substances 0.000 claims description 5
- 239000007900 aqueous suspension Substances 0.000 claims description 4
- 240000004928 Paspalum scrobiculatum Species 0.000 claims 1
- 235000003675 Paspalum scrobiculatum Nutrition 0.000 claims 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 239000010936 titanium Substances 0.000 claims 1
- 229910052719 titanium Inorganic materials 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 14
- 239000006185 dispersion Substances 0.000 abstract description 7
- 238000001035 drying Methods 0.000 abstract description 7
- 229920005610 lignin Polymers 0.000 abstract description 6
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 abstract description 5
- 208000010201 Exanthema Diseases 0.000 abstract description 4
- 201000005884 exanthem Diseases 0.000 abstract description 4
- 206010037844 rash Diseases 0.000 abstract description 4
- 238000002156 mixing Methods 0.000 abstract description 3
- 238000010130 dispersion processing Methods 0.000 abstract description 2
- 238000001704 evaporation Methods 0.000 abstract description 2
- 239000002245 particle Substances 0.000 abstract description 2
- 238000005507 spraying Methods 0.000 abstract description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract 4
- 229910052742 iron Inorganic materials 0.000 abstract 2
- 238000010276 construction Methods 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 3
- 229910052802 copper Inorganic materials 0.000 description 3
- 239000010949 copper Substances 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 241000220223 Fragaria Species 0.000 description 2
- 235000016623 Fragaria vesca Nutrition 0.000 description 2
- 235000011363 Fragaria x ananassa Nutrition 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 241000254032 Acrididae Species 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 239000005083 Zinc sulfide Substances 0.000 description 1
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- RYGMFSIKBFXOCR-AHCXROLUSA-N copper-60 Chemical compound [60Cu] RYGMFSIKBFXOCR-AHCXROLUSA-N 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 125000005624 silicic acid group Chemical group 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000010902 straw Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Chemical And Physical Treatments For Wood And The Like (AREA)
Abstract
Description
【発明の詳細な説明】
〈産業上の利用分野〉
本発明は、藺草処理組成物および藺草処理方法に関する
。DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to a rush treatment composition and a rush treatment method.
〈従来の技術および発明が解決しようとしている課題〉
畳表等に使用されている藺草は、通常染上を水に分散さ
せた液中に藺草を浸漬し染上を藺草に付着させた後、乾
燥することにより製品化されている。<Prior art and problems to be solved by the invention> The rush used for tatami mats, etc. is usually immersed in a solution in which the dyed surface is dispersed in water, the dyed surface is attached to the rush, and then dried. It is commercialized by doing this.
このような染上処理は藺草の乾燥の均一化促進、藺草の
変色防止および藺草に強靭性、柔軟性等の付与を目的と
してなされている。This dyeing treatment is carried out for the purpose of promoting uniform drying of the rush, preventing discoloration of the rush, and imparting toughness, flexibility, etc. to the rush.
また、藺草の色合いをよくする目的で、染上に顔料やあ
る種の界面活性剤を併用する方法が用いられているが、
畳表とした場合の色の均一性、耐水性や処理操作時にお
けるかぶれの問題などがあった。In addition, in order to improve the color of the rush, a method is used in which pigments and certain surfactants are used in conjunction with the dyeing process.
When used as a tatami surface, there were problems with color uniformity, water resistance, and rash during processing.
く課題を解決するための手段〉
このような状況下に、本発明者らは上記のような問題点
のし゛ない、優れた藺草処理法を見出すべく種々検討し
た結果、染土処理において特定の有色顔料、酸化チタン
およびリグニンスルホン酸及び／又はその塩を使用する
ことにより、このような目的か達せられることを見出し
本発明に至ったすなわち本発明は、
■染上、
■有機黄色顔料と銅フタロシアニンブルー又は群青、紺
青、コバルトブルーとの組合せ、酸化クロム、コバルト
グリーンからなる群より選ばれた有色顔料、
■酸化チタン
および
■リグニンスルホン酸及び／又はその塩からなる藺草処
理組成物。および該組成物の水懸濁液を処理液として用
い乙回草処理方法に関するものである。Means for Solving the Problems> Under these circumstances, the present inventors conducted various studies in order to find an excellent method for treating straw grass that does not have the above-mentioned problems. It was discovered that these objects can be achieved by using colored pigments, titanium oxide, and lignin sulfonic acid and/or its salts. That is, the present invention consists of: (1) dyeing; (2) organic yellow pigment and copper; A rush treatment composition comprising a colored pigment selected from the group consisting of phthalocyanine blue or a combination with ultramarine blue, navy blue, and cobalt blue, chromium oxide, and cobalt green, (1) titanium oxide, and (2) ligninsulfonic acid and/or its salt. The present invention also relates to a method for treating grasshoppers using an aqueous suspension of the composition as a treatment liquid.
本発明において使用される染土としては、天然染上、ア
ルカリ土類金属の酸化物、水酸化物、硫酸塩および炭酸
塩や硫化亜鉛、リトポン等およびこれらの混合物などの
合成染上を用いることができる。尚、天然染上とは、珪
酸分が主成分の粘度質鉱物である。As the dyeing soil used in the present invention, natural dyeing materials, synthetic dyeing materials such as alkaline earth metal oxides, hydroxides, sulfates, and carbonates, zinc sulfide, lithopone, etc., and mixtures thereof may be used. I can do it. Note that natural dyeing is a viscous mineral whose main component is silicic acid.
本発明における有色顔料は、有機黄色顔料と銅フタロシ
アニンブルー、又は群青、紺青、コバルトブルーとの組
合せ、酸化クロム、コバルトグリーンからなる群より選
ばれ、何れも青色系、緑色系の顔料である。The colored pigment in the present invention is selected from the group consisting of an organic yellow pigment and copper phthalocyanine blue, a combination of ultramarine blue, navy blue, and cobalt blue, chromium oxide, and cobalt green, and all of them are blue-based or green-based pigments.
また、本発明において使用されるリグニンスルボン酸お
よびその塩としては、木材より抽圧されるリグニンをス
ルホン化して得られるリグニンスルホン酸、そのナトリ
ウムなどの塩、リグニンスルホン酸を高度に化学処理し
て精製した変成りゲニンスルホン酸等が挙げられる。In addition, ligninsulfonic acid and its salts used in the present invention include ligninsulfonic acid obtained by sulfonating lignin extracted from wood, salts thereof such as sodium, and highly chemically treated ligninsulfonic acid. Examples include modified geninsulfonic acid purified by
本発明の組成物において、リグニンスルホン酸及び／又
はその塩の使用量は、通常染土１００重量部に対し０．
０１〜１０重量部程度である。In the composition of the present invention, the amount of ligninsulfonic acid and/or its salt used is usually 0.00 parts by weight per 100 parts by weight of dyed clay.
It is about 0.01 to 10 parts by weight.
本発明の藺草処理組成物は、染上に、有機黄色顔料と銅
フタロシアニンブルー、又は群青、紺青、コバルトブル
ーとの組合せ、酸化クロム、コバルトグリーンからなる
群より選ばれた有色顔料、酸化チタンおよびリグニンス
ルホン酸及び／又はその塩を配合した後、微粉砕機で粉
砕混合することにより調整される。The rush treatment composition of the present invention is dyed with a colored pigment selected from the group consisting of an organic yellow pigment and copper phthalocyanine blue, or a combination of ultramarine blue, navy blue, and cobalt blue, chromium oxide, and cobalt green, titanium oxide, and After blending ligninsulfonic acid and/or its salt, the mixture is pulverized and mixed using a pulverizer.
また、上記に使用する有色の顔料粒子は比較的硬くて分
散させ難いため、好ましくは、これらの有色の顔料とり
ゲニンスルホン酸及び／又はその塩と水を配合した後、
サンドミル等の分散機で分散加工を行い、染上又は酸化
チタンに液状で噴霧し加えるか、又は分散液を乾燥し水
分を蒸発させたのち加えることが望ましい。Furthermore, since the colored pigment particles used above are relatively hard and difficult to disperse, it is preferable that after blending these colored pigments with geninsulfonic acid and/or its salt and water,
It is preferable to carry out dispersion processing using a dispersing machine such as a sand mill, and add the dye by spraying it onto the dye or titanium oxide, or add it after drying the dispersion and evaporating the water.
本発明の組成物を用いて藺草処理を行うにあたっては、
これに新たに染上を加え、水懸濁液を調整し、これに藺
草を浸漬処理し、次いで乾燥することにより良好に行わ
れる。When performing rush treatment using the composition of the present invention,
This can be successfully carried out by adding a new dyeing agent to this, preparing an aqueous suspension, dipping the rush into this, and then drying.
尚、予め染土に、有機黄色顔料と銅フタロシアニンブル
ー、又は群青、紺青、コバルトブルーとの組合せ、酸化
クロム、コバルトグリーンからなる群より選ばれた有色
顔料および酸化チタンを配合した組成物を用意し、これ
を水に懸濁させる際にリグニンスルホン酸及び／又はそ
の塩を添加し、所望の水懸濁液を調整し、同様に処理し
てもよい。In addition, a composition containing an organic yellow pigment and copper phthalocyanine blue, or a combination of ultramarine, navy blue, and cobalt blue, a colored pigment selected from the group consisting of chromium oxide, and cobalt green, and titanium oxide is prepared in advance in the dyeing soil. However, when suspending this in water, ligninsulfonic acid and/or its salt may be added to prepare a desired aqueous suspension, and the same may be treated.
〈発明の効果〉
本発明によれば、染上処理において特定の有色顔料、酸
化チタンおよびリグニンスルボン酸及び／又はその塩を
使用することにより従来問題点とされていた藺草乾燥時
における色の均一性、耐水性や処理操作時におけるかぶ
れの問題などを改良することができる。<Effects of the Invention> According to the present invention, by using specific colored pigments, titanium oxide, and lignin sulfonic acid and/or its salts in dyeing treatment, the color change during drying of strawberry, which has been a problem in the past, can be solved. It is possible to improve uniformity, water resistance, and rash problems during processing operations.
〈実施例〉 以下、実施例により本発明を説明する。<Example> The present invention will be explained below with reference to Examples.
但し、例中、部とあるのは重量部を表す。However, in the examples, parts represent parts by weight.
実施例 １
有機の縮合アゾイエロー２７ｋｇ及び銅フタロシアニン
ブルー１３ｋｇにリグニンスルホン酸ナトリウム６０ｋ
ｇ、水１５０眩をサンドミルにて分散させた後、乾燥、
粉砕し縮合アゾイエローと銅フロタシアニンブルー混合
物の分散処理物９５ｋｇ（収率９５％）を得た。Example 1 27 kg of organic condensed azo yellow and 13 kg of copper phthalocyanine blue and 60 k of sodium lignin sulfonate
g, after dispersing 150 ml of water in a sand mill, drying,
The mixture was pulverized to obtain 95 kg (yield: 95%) of a dispersed mixture of condensed azo yellow and copper phlotocyanin blue.
次に、天然の染上１００部に酸化チタン５０部、および
縮合アゾイエローと銅フタロアニンブルーの混合物の分
散処理物１部を加え、ドラム型タンブラ−で混合した後
、微粉砕機にて粉砕し、本発明の藺草処理組成物を得た
。Next, 50 parts of titanium oxide and 1 part of a dispersion of a mixture of condensed azo yellow and copper phthaloanine blue were added to 100 parts of natural dyeing, mixed in a drum-type tumbler, and then ground in a fine grinder. Then, a rush treatment composition of the present invention was obtained.
実施例 ２
カオリンクレー１００部に酸化チタン３０部、酸化クロ
ム５部、リグニンスルホン酸カリウム３部をあらかじめ
高速ミキサーで混合後、微粉砕機にて粉砕し本発明の藺
草処理組成物を得た。Example 2 100 parts of kaolin clay, 30 parts of titanium oxide, 5 parts of chromium oxide, and 3 parts of potassium ligninsulfonate were mixed in advance in a high-speed mixer and then ground in a pulverizer to obtain a rush treatment composition of the present invention.
比較例 １
有機の縮合アゾイエロー２７ｋｇ、及び銅フタロシアニ
ンブルー１３ｋｇにポリオキシエチレンノニルフェニル
エーテル２０ｋｇ、水４０聴をサンドミルにて分散させ
た後、固形分４０％の縮合アゾイエローと銅フロタシア
ニンブルー混合物の分散処理液９８ｋｇ（収率９８％）
を得た。Comparative Example 1 After dispersing 27 kg of organic condensed azo yellow and 13 kg of copper phthalocyanine blue with 20 kg of polyoxyethylene nonylphenyl ether and 40 kg of water in a sand mill, a mixture of condensed azo yellow and copper phthalocyanine blue with a solid content of 40% was obtained. 98 kg of dispersion treatment liquid (yield 98%)
I got it.
次に、天然の染土１００部と酸化チタン５０部を高速ミ
キサーに投入後、高速ミキサー攪拌下に上記分散処理液
２．５部を、噴霧し、藺草処理組成物を得た。Next, 100 parts of natural dyed clay and 50 parts of titanium oxide were put into a high-speed mixer, and then 2.5 parts of the above dispersion treatment liquid was sprayed while stirring with the high-speed mixer to obtain a rush treatment composition.
比較例 ２
カオリンクレー１００部りこ酸化チタン３０部、酸化ク
ロム５部を加え、ドラム型タンブラ−で混合後、微粉砕
機にて粉砕し、藺草処理組成物を得た。Comparative Example 2 100 parts of kaolin clay, 30 parts of titanium oxide, and 5 parts of chromium oxide were added, mixed in a drum-type tumbler, and then ground in a pulverizer to obtain a rush treatment composition.
上記実施例１〜２、比較例１〜２で得られた藺草処理組
成物５ｋｇに対し天然の染土１４５ｋｇ水４００殻の泥
染め液を作成後、刈り取った藺草を浸漬乾燥し、仕上が
り外観の状態および畳表作成後の水に対する耐性をテス
トした。After preparing a mud dyeing solution of 145 kg of natural dyeing soil and 400 shells of water for 5 kg of the rush treatment composition obtained in Examples 1 to 2 and Comparative Examples 1 to 2 above, the cut rush was immersed and dried to achieve a finished appearance. We tested the condition and resistance to water after making the tatami mat.
又、実施例１〜２、比較例１〜２で得られた藺草処理組
成物の皮ふに対するシゲキ性を、上記浸漬作業を行なっ
た作業員
（３名）
の皮膚の刺激性
をテストした。In addition, the scrubbing properties of the strawberry treatment compositions obtained in Examples 1 and 2 and Comparative Examples 1 and 2 were tested on the skin irritation of three workers who performed the above-mentioned dipping work.
以上の結果は、 表−１の如くであった。The above results are It was as shown in Table-1.
Claims (2)
青、紺青、コバルトブルーとの組合せ、酸化クロム、コ
バルトグリーンからなる群より選ばれた有色顔料、 ［３］酸化チタン および ［４］リグニンスルホン酸及び／又はその塩からなる藺
草処理組成物。(1) [1] Dyeing soil, [2] A colored pigment selected from the group consisting of an organic yellow pigment and copper phthalocyanine blue, or a combination of ultramarine, navy blue, and cobalt blue, chromium oxide, and cobalt green, [3] Oxidation A rush treatment composition comprising titanium and [4] ligninsulfonic acid and/or its salt.
青、紺青、コバルトブルーとの組合せ、酸化クロム、コ
バルトグリーンからなる群より選ばれた有色顔料、 ［３］酸化チタンおよび ［４］リグニンスルホン酸及び／又はその塩を含有する
水懸濁液を用いる藺草処理方法。(2) As a treatment liquid, [1] dyed clay, [2] a colored pigment selected from the group consisting of organic yellow pigment and copper phthalocyanine blue, or a combination of ultramarine blue, navy blue, and cobalt blue, chromium oxide, and cobalt green; [3] A method for treating rice grass using an aqueous suspension containing titanium oxide and [4] ligninsulfonic acid and/or its salt.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP25071090A JPH04128003A (en) | 1990-09-19 | 1990-09-19 | Rush treated composition and rush treatment method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP25071090A JPH04128003A (en) | 1990-09-19 | 1990-09-19 | Rush treated composition and rush treatment method |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04128003A true JPH04128003A (en) | 1992-04-28 |
Family
ID=17211901
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP25071090A Pending JPH04128003A (en) | 1990-09-19 | 1990-09-19 | Rush treated composition and rush treatment method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH04128003A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9750249B2 (en) | 2010-09-09 | 2017-09-05 | Suncor Energy Inc. | Synergistic paraffinic oil and boscalid fungicides |
| US9801369B2 (en) | 2006-10-05 | 2017-10-31 | Suncor Energy Inc. | Herbicidal composition with increased herbicidal efficacy |
| US9826738B2 (en) | 2008-06-26 | 2017-11-28 | Suncor Energy Inc. | Turfgrass fungicide formulation with pigment |
| US9999219B2 (en) | 2004-05-18 | 2018-06-19 | Suncor Energy Inc. | Spray oil and method of use therof for controlling turfgrass pests |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS49124317A (en) * | 1973-04-04 | 1974-11-28 | ||
| JPS504313A (en) * | 1973-05-19 | 1975-01-17 | ||
| JPS54156879A (en) * | 1978-05-27 | 1979-12-11 | Kouji Mitsu | Dyeing finish of rush |
| JPS62246703A (en) * | 1986-01-24 | 1987-10-27 | 石原産業株式会社 | Rush treating agent |
-
1990
- 1990-09-19 JP JP25071090A patent/JPH04128003A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS49124317A (en) * | 1973-04-04 | 1974-11-28 | ||
| JPS504313A (en) * | 1973-05-19 | 1975-01-17 | ||
| JPS54156879A (en) * | 1978-05-27 | 1979-12-11 | Kouji Mitsu | Dyeing finish of rush |
| JPS62246703A (en) * | 1986-01-24 | 1987-10-27 | 石原産業株式会社 | Rush treating agent |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9999219B2 (en) | 2004-05-18 | 2018-06-19 | Suncor Energy Inc. | Spray oil and method of use therof for controlling turfgrass pests |
| US9801369B2 (en) | 2006-10-05 | 2017-10-31 | Suncor Energy Inc. | Herbicidal composition with increased herbicidal efficacy |
| US9826738B2 (en) | 2008-06-26 | 2017-11-28 | Suncor Energy Inc. | Turfgrass fungicide formulation with pigment |
| US9750249B2 (en) | 2010-09-09 | 2017-09-05 | Suncor Energy Inc. | Synergistic paraffinic oil and boscalid fungicides |
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