JPH03174009A - Electrically conductive yarn - Google Patents
Electrically conductive yarnInfo
- Publication number
- JPH03174009A JPH03174009A JP1309066A JP30906689A JPH03174009A JP H03174009 A JPH03174009 A JP H03174009A JP 1309066 A JP1309066 A JP 1309066A JP 30906689 A JP30906689 A JP 30906689A JP H03174009 A JPH03174009 A JP H03174009A
- Authority
- JP
- Japan
- Prior art keywords
- fiber
- vapor
- grown carbon
- carbon fiber
- organic polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 15
- 150000001875 compounds Chemical class 0.000 claims abstract description 11
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 11
- 239000010439 graphite Substances 0.000 claims abstract description 11
- 229920000620 organic polymer Polymers 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims abstract description 4
- 239000000835 fiber Substances 0.000 claims description 23
- 239000002134 carbon nanofiber Substances 0.000 claims description 14
- 230000002687 intercalation Effects 0.000 claims description 8
- 238000009830 intercalation Methods 0.000 claims description 8
- 238000000034 method Methods 0.000 abstract description 21
- 239000007789 gas Substances 0.000 abstract description 9
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract description 7
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 abstract description 6
- 239000012808 vapor phase Substances 0.000 abstract description 6
- 229920000049 Carbon (fiber) Polymers 0.000 abstract description 5
- 239000004917 carbon fiber Substances 0.000 abstract description 5
- 239000003921 oil Substances 0.000 abstract description 4
- 229910052799 carbon Inorganic materials 0.000 abstract description 3
- 239000012159 carrier gas Substances 0.000 abstract description 3
- 239000004677 Nylon Substances 0.000 abstract description 2
- 229910000831 Steel Inorganic materials 0.000 abstract description 2
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 abstract description 2
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 abstract description 2
- IFEDKGXLWOLWAZ-UHFFFAOYSA-L iron(2+);3-oxobutanoate Chemical compound [Fe+2].CC(=O)CC([O-])=O.CC(=O)CC([O-])=O IFEDKGXLWOLWAZ-UHFFFAOYSA-L 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 229920001778 nylon Polymers 0.000 abstract description 2
- 229920002239 polyacrylonitrile Polymers 0.000 abstract description 2
- 229920000728 polyester Polymers 0.000 abstract description 2
- 239000010959 steel Substances 0.000 abstract description 2
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 description 6
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 5
- 239000004372 Polyvinyl alcohol Substances 0.000 description 5
- -1 ferro-sedi Chemical class 0.000 description 4
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 3
- 229910052794 bromium Inorganic materials 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 150000002736 metal compounds Chemical class 0.000 description 3
- 238000009987 spinning Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- MWPLVEDNUUSJAV-UHFFFAOYSA-N anthracene Chemical compound C1=CC=CC2=CC3=CC=CC=C3C=C21 MWPLVEDNUUSJAV-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 2
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000002166 wet spinning Methods 0.000 description 2
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 1
- KZBUYRJDOAKODT-UHFFFAOYSA-N Chlorine Chemical compound ClCl KZBUYRJDOAKODT-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 229910015400 FeC13 Inorganic materials 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- 238000006359 acetalization reaction Methods 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000003575 carbonaceous material Substances 0.000 description 1
- 238000010000 carbonizing Methods 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 229960003280 cupric chloride Drugs 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000007772 electroless plating Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 150000002222 fluorine compounds Chemical class 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 238000010574 gas phase reaction Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 150000004678 hydrides Chemical class 0.000 description 1
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 description 1
- 229910003437 indium oxide Inorganic materials 0.000 description 1
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 150000002506 iron compounds Chemical class 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000011295 pitch Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- 150000003577 thiophenes Chemical class 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Artificial Filaments (AREA)
- Inorganic Fibers (AREA)
- Chemical Treatment Of Fibers During Manufacturing Processes (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
Description
【発明の詳細な説明】 ［産業上の利用分野］ 本発明は導電性繊維に関するものである。[Detailed description of the invention] [Industrial application field] The present invention relates to conductive fibers.
［従来の技術〕
従来、導電性繊維は酸化錫、酸化亜鉛、酸化インジウム
等の導電性金属化合物をガラス繊維やチタン酸カリウム
ウィスカーの表面に被覆したものを有機重合体と混合し
繊維に成型していた。例えば、上記導電性金属化合物の
層によって表面を被覆されたガラス繊維を含有する重合
体（Ａ）と繊維形成性良好な重合体（Ｂ）とが接合され
てなる導電性複合繊維が特開昭５９−９４６１８号公報
に開示されている。また、チタン酸カリウム等の繊維質
成分の表面が炭素質を主成分とする被覆で被覆され、体
積固有抵抗率が１０− ”Ω・０未満である高導電性繊
維が特開昭６３−１２７５９号公報に開示されている。[Conventional technology] Conventionally, conductive fibers are made by coating the surface of glass fibers or potassium titanate whiskers with conductive metal compounds such as tin oxide, zinc oxide, or indium oxide, which are then mixed with organic polymers and molded into fibers. was. For example, a conductive composite fiber made by bonding a polymer (A) containing glass fiber whose surface is coated with a layer of the conductive metal compound and a polymer (B) with good fiber forming properties is disclosed in Japanese Patent Application Laid-Open No. It is disclosed in Japanese Patent No. 59-94618. In addition, a highly conductive fiber whose surface of a fibrous component such as potassium titanate is coated with a coating mainly composed of carbonaceous material and whose volume resistivity is less than 10-''Ω・0 is disclosed in JP-A-63-12759. It is disclosed in the publication No.
上記導電性金属化合物で表面を被覆されたチタン酸カリ
ウム短繊維と無機粒子とを含有する一種以上の重合体（
Ａ）と、繊維形成性重合体ＣＢ）とが接合されている導
電性複合繊維であって、重合体（Ａ）に含有される無機
粒子の量が重合体（Ａ）１００重量部に対して５重量部
以上であることを特徴とする導電性複合繊維が特開昭６
３−２７０８１１号公報に開示されている。One or more polymers (
An electrically conductive composite fiber in which A) and a fiber-forming polymer CB) are bonded together, wherein the amount of inorganic particles contained in the polymer (A) is based on 100 parts by weight of the polymer (A). A conductive composite fiber characterized by having a content of 5 parts by weight or more is disclosed in Japanese Patent Application Laid-open No. 6
It is disclosed in Japanese Patent No. 3-270811.
一方、気相法で得られる炭素繊維も知られており、特に
、インターカレートされた気相成長炭素繊維が高い導電
性を有していることも知られている（ＰＲＯＣＥＥＤＩ
ＮＧＳ ＯＦ ＴＨＥ ＴＷＥＮＴＹＦＩＲＳＴ ＳＹ
ＭＰＯ３ＩＵＭＯＮ ＥＬＥＣＴＲＩＣＡＬ ｌＮ
５ＵＬＡＴＩＮＧ ＭＡＴＥＲ■ＡＬＳ、Ｐ２５１，
１９８８）。On the other hand, carbon fibers obtained by the vapor phase method are also known, and in particular, it is known that intercalated vapor grown carbon fibers have high electrical conductivity (PROCEEDI
NGS OF THE TWENTY FIRST SY
MPO3IUMON ELECTRICAL IN
5ULATING MATER■ALS, P251,
1988).
ところで、導電性金属化合物被覆短繊維は、蒸着法、ス
パッタリング法、スプレー法、無電解メツキ法などを利
用して製造されているが、これらは工程が煩雑であった
。また、繊維表面に炭素質の被覆を形成させることによ
り導電性繊維を得る方法は８００〜１２００℃で焼成炭
化の工程があり、コストがかかる。Incidentally, conductive metal compound-coated short fibers are manufactured using vapor deposition methods, sputtering methods, spray methods, electroless plating methods, etc., but these processes are complicated. Furthermore, the method of obtaining conductive fibers by forming a carbonaceous coating on the fiber surface involves a process of firing and carbonizing at 800 to 1200° C., which is costly.
本発明はこれらの問題点を解決して簡単な工程で製造し
うる高導電性の繊維を提供するものであり、気相成長炭
素繊維をホストとした黒鉛層間化合物が容易に得られ、
かつ高い導電性を有していてこれを有機重合体と混合し
て紡糸することにより容易に高導電性繊維が得られるこ
とを見出してなされたものである。The present invention solves these problems and provides highly conductive fibers that can be manufactured in a simple process, and a graphite intercalation compound using vapor-grown carbon fiber as a host can be easily obtained.
This invention was made based on the discovery that highly conductive fibers can be easily obtained by mixing this fiber with an organic polymer and spinning it.
気相成長炭素繊維は気相法で得られたものであり、炭素
源はメタン、アセチレン、ベンゼン、トルエン等のほか
コークス炉からの副産物である粗軽油類、カルボン油、
ナフタリン、中油、アントラセン油、重油、ピッチ、コ
ールタール、これらの水素化物、これらの混合物等であ
ってもよい。Vapor-grown carbon fibers are obtained by a vapor-phase method, and carbon sources include methane, acetylene, benzene, toluene, etc., as well as crude light oils, which are by-products from coke ovens, carbon oil,
Naphthalene, medium oil, anthracene oil, heavy oil, pitch, coal tar, hydrides thereof, mixtures thereof, etc. may be used.
さらに、ヘテロ原子を有するものも使用可能であり、例
えばチオフェン類、チオール類及びチオフェノール類を
用いることができる。触媒源としてはフェロセジ、鉄ア
セチルアセテート塩、ジ（インデニル）鉄（ｎ）等の有
機鉄化合物のほか、その他の遷移金属、例えばチタン、
バナジウム、クロム、マンガン、コバルト、ニッケル、
ルビジウム、ロジウム、タングステン、パラジウム等の
有機化合物が用いられる。上記の炭素源ガスと触媒源ガ
スをキャリヤーガスで搬送して６００〜１３００″Ｃで
加熱することによって気相成長炭素繊維が形成される。Furthermore, those having heteroatoms can also be used, such as thiophenes, thiols and thiophenols. Catalyst sources include organic iron compounds such as ferro-sedi, iron acetylacetate salt, di(indenyl) iron(n), and other transition metals such as titanium,
vanadium, chromium, manganese, cobalt, nickel,
Organic compounds such as rubidium, rhodium, tungsten, and palladium are used. Vapor-grown carbon fibers are formed by conveying the above carbon source gas and catalyst source gas with a carrier gas and heating them at 600 to 1300''C.
キャリヤーガスは上記の原料ガスを搬送するほか系内を
還元性雰囲気に保つ機能も要求され、そのために水素ガ
ス等が使用されるが、製鋼工場から排出される転炉ガス
は還元性ガスであり、これを用いることによって良質の
気相成長炭素繊維を安価に製造することができる（特開
平１−９２４２２号公報）。本発明で使用される気相成
長炭素繊維の糸系は０．１〜１０ｎ程度、好ましくは１
〜３μｍ程度、そして長さは１０ｎ〜５１１ｕ１１程度
、好ましくは１００ｎ〜３帥程度である。In addition to transporting the raw material gases mentioned above, the carrier gas is also required to maintain a reducing atmosphere within the system, and hydrogen gas is used for this purpose, but the converter gas discharged from steel plants is a reducing gas. By using this, high-quality vapor-grown carbon fibers can be produced at low cost (Japanese Patent Application Laid-Open No. 1992-92422). The yarn system of the vapor grown carbon fiber used in the present invention is about 0.1 to 10n, preferably 1
~3 μm, and the length is approximately 10 nm to 511 μm, preferably approximately 100 nm to 3 μm.
この気相成長炭素繊維をホストとして黒鉛層間化合物を
形成する。気相成長炭素繊維にインターカラントとして
塩化第２鉄、塩化第２銅等の塩素化合物、ＣｕＦｚ、Ｍ
ｇＦｔＳＡｓＦｓ、５ｂＦｓ等のフッ素化合物、臭素等
を使用し、公知の方法により黒鉛層間化合物を生成させ
る。この製造法には溶融塩法、溶液法、気相法（ｔｗｏ
−ｂｕｌｂ法）等が知られており、そのいずれも利用す
ることができる。A graphite intercalation compound is formed using this vapor-grown carbon fiber as a host. Chlorine compounds such as ferric chloride and cupric chloride, CuFz, M as intercalants in vapor grown carbon fibers
A graphite intercalation compound is produced by a known method using a fluorine compound such as gFtSAsFs or 5bFs, bromine, or the like. This manufacturing method includes the molten salt method, solution method, and gas phase method (two
-bulb method), and any of them can be used.
有機重合体は繊維形成能を有するものであればよく、例
えばポリビニルアルコール、ポリアクリロニトリル、ナ
イロン、ポリプロピレン、ポリエチレン、ポリ塩化ビニ
ル、ポリエステル等から適宜選択される。The organic polymer may be any one having fiber-forming ability, and is appropriately selected from, for example, polyvinyl alcohol, polyacrylonitrile, nylon, polypropylene, polyethylene, polyvinyl chloride, polyester, and the like.
黒鉛層間化合物と有機重合体の混合比は有機重合体１０
０重量部に対して黒鉛層間化合物５〜５０重量部程度、
好ましくは１０〜４０重量部程度が適当である。５重量
部以下では導電性が不充分になり、一方、５０重量部を
越えると強度が不足する。The mixing ratio of the graphite intercalation compound and the organic polymer is 10% of the organic polymer.
About 5 to 50 parts by weight of graphite intercalation compound to 0 parts by weight,
A suitable amount is preferably about 10 to 40 parts by weight. If it is less than 5 parts by weight, the conductivity will be insufficient, while if it exceeds 50 parts by weight, the strength will be insufficient.
紡糸方法は公知の方法によればよく、例えば溶融押出法
、湿式紡糸法等を利用できる。紡糸後延伸することがで
き、さらに公知の表面処理等を施こすことができる。The spinning method may be any known method, such as a melt extrusion method or a wet spinning method. After spinning, it can be stretched, and further known surface treatments etc. can be applied.
本発明の導電性繊維は体積固有抵抗が１Ｏ−４〜１０”
Ω・ｃｍ程度であり、導電性が大きい。しかもこの抵抗
は安定であり、経時劣化が少ない。The conductive fiber of the present invention has a volume resistivity of 1O-4 to 10"
It has a high conductivity of about Ω·cm. Moreover, this resistance is stable and does not deteriorate over time.
黒鉛層間化合物を高導電材料として利用する場合、空気
中での安定性と黒鉛構造のよく発達した原料が必要であ
る。気相成長炭素繊維（ＶＧＣＦ）は断面形状が年輪状
の易黒鉛化構造と持っており、黒鉛化が容易である。本
発明においてはこの気相成長炭素繊維をホストとして高
導電性の黒鉛層間化合物を得、これを繊維形成能を有す
る有機重合体と混合して紡糸することにより高強度繊維
を得、かつ気相成長炭素繊維を有機重合体に取込ませる
ことによって眉間化合物の経時劣化を防止している。When using a graphite intercalation compound as a highly conductive material, a raw material that is stable in air and has a well-developed graphite structure is required. Vapor-grown carbon fiber (VGCF) has an easy-graphitizable structure with a tree-ring-like cross-sectional shape, and is easily graphitized. In the present invention, a highly conductive graphite intercalation compound is obtained using this vapor-grown carbon fiber as a host, and this is mixed with an organic polymer having fiber-forming ability and spun to obtain a high-strength fiber. By incorporating grown carbon fibers into an organic polymer, deterioration of the glabellar compound over time is prevented.
実施例１
特開平１−９２４２４に記載された方法により製造され
た直径２−１長さ３ＩＩＩＩ１１ノ流動気相法ＶＧＣＦ
を２５００°Ｃにて黒鉛化したグラファイトファイバー
（ＧＦ）を得た。これをホストとして気相反応法（ｔｗ
ｏ−ｂｕｌｂ法）にて臭素のＧＩＣを作った。すなわら
、ガラス容器臭素を注入し、密栓後２０°Ｃ１４８時間
保持してＧＩＣを作った。Example 1 Fluidized gas phase VGCF with diameter 2-1 length 3III11 manufactured by the method described in JP-A-1-92424
Graphite fiber (GF) was obtained by graphitizing at 2500°C. Using this as a host, the gas phase reaction method (tw
Bromine GIC was made using the o-bulb method). That is, a GIC was prepared by injecting bromine into a glass container, sealing the container, and holding the container at 20° C. for 148 hours.
このＧＩＣ３０ｇをＰＶＡ（ポリビニールアルコール）
２０ｗｔ％のＤＭＳＯ（ジメチルスルホキシド演に１
００ｇに入れて良く撹拌し均一分散液を得た。Add 30g of this GIC to PVA (polyvinyl alcohol)
20 wt% DMSO (1% dimethyl sulfoxide)
00g and stirred well to obtain a uniform dispersion.
この分散液をφ０．５附のノズルからアセトン中に押し
出す湿式紡糸によりＧＩＣ混入ＰＶＡ繊維を作った。こ
の繊維をφ０．１５ｍｍに延伸し、熱処理（２００°Ｃ
ｌｈｒ）及びアセタール化処理（ホルムアルデヒド４
％、ボウ硝２０％、硫酸２５％浴中７０”Ｃ）を施した
。GIC-containing PVA fibers were produced by wet spinning, extruding this dispersion into acetone through a nozzle with a diameter of 0.5 mm. This fiber was drawn to φ0.15 mm and heat treated (200°C
lhr) and acetalization treatment (formaldehyde 4
%, 70"C) in a bath of 20% sulfur and 25% sulfuric acid.
この繊維の体積固有抵抗を測ったところ０．０５Ω・ｃ
ｍであった。The volume resistivity of this fiber was measured and was 0.05Ω・c
It was m.
実施例２
実施例１と同じＶＧＣＦを同様に黒鉛化して得たＧＦを
用い、溶液法によりＦｅＣ１３（塩素ガスバブリング下
室温４８ｈｒ ）でＧＩＣを製造した。これをＰＶＡ中
に２０ｗｔ％混入した繊維を実施例１と同じように製造
した。Example 2 Using GF obtained by graphitizing the same VGCF as in Example 1, GIC was manufactured using FeC13 (48 hours at room temperature under chlorine gas bubbling) by a solution method. A fiber in which 20 wt % of this was mixed into PVA was produced in the same manner as in Example 1.
このものの体積固有抵抗は、０．０７Ω・ｃｍであった
。The volume resistivity of this material was 0.07 Ω·cm.
（発明の効果〕
本発明の導電繊維は導電度が高く、強度も大きい。しか
も簡便な手段で安価に製造することができる。(Effects of the Invention) The conductive fiber of the present invention has high conductivity and high strength.Moreover, it can be manufactured by simple means at low cost.
Claims (1)
形成能を有する有機重合体との混合物よりなる導電性繊
維A conductive fiber made of a mixture of a graphite intercalation compound and an organic polymer with fiber-forming ability using vapor-grown carbon fiber as a host.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1309066A JPH03174009A (en) | 1989-11-30 | 1989-11-30 | Electrically conductive yarn |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1309066A JPH03174009A (en) | 1989-11-30 | 1989-11-30 | Electrically conductive yarn |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03174009A true JPH03174009A (en) | 1991-07-29 |
Family
ID=17988473
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1309066A Pending JPH03174009A (en) | 1989-11-30 | 1989-11-30 | Electrically conductive yarn |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03174009A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007049592A1 (en) * | 2005-10-25 | 2007-05-03 | Bussan Nanotech Research Institute Inc. | Synthetic fiber |
| CN104278360A (en) * | 2014-09-28 | 2015-01-14 | 苏州长盛机电有限公司 | Preparation method of graphene-doped conductive composite fiber |
| CN109056104A (en) * | 2018-09-21 | 2018-12-21 | 佛山皖和新能源科技有限公司 | A kind of preparation method of conducting polypropylene fiber |
-
1989
- 1989-11-30 JP JP1309066A patent/JPH03174009A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007049592A1 (en) * | 2005-10-25 | 2007-05-03 | Bussan Nanotech Research Institute Inc. | Synthetic fiber |
| JP2007119931A (en) * | 2005-10-25 | 2007-05-17 | Bussan Nanotech Research Institute Inc | Synthetic fiber |
| CN104278360A (en) * | 2014-09-28 | 2015-01-14 | 苏州长盛机电有限公司 | Preparation method of graphene-doped conductive composite fiber |
| CN109056104A (en) * | 2018-09-21 | 2018-12-21 | 佛山皖和新能源科技有限公司 | A kind of preparation method of conducting polypropylene fiber |
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