JPH03159053A - Scatter preventing fluorescent light - Google Patents
Scatter preventing fluorescent lightInfo
- Publication number
- JPH03159053A JPH03159053A JP29826289A JP29826289A JPH03159053A JP H03159053 A JPH03159053 A JP H03159053A JP 29826289 A JP29826289 A JP 29826289A JP 29826289 A JP29826289 A JP 29826289A JP H03159053 A JPH03159053 A JP H03159053A
- Authority
- JP
- Japan
- Prior art keywords
- coat
- glass tube
- coating
- transparent
- ultraviolet rays
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011521 glass Substances 0.000 claims abstract description 21
- 239000002952 polymeric resin Substances 0.000 claims abstract description 14
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 14
- 239000011248 coating agent Substances 0.000 claims description 21
- 238000000576 coating method Methods 0.000 claims description 21
- 230000006866 deterioration Effects 0.000 abstract description 6
- 229920000642 polymer Polymers 0.000 abstract description 3
- 229920005989 resin Polymers 0.000 abstract description 3
- 239000011347 resin Substances 0.000 abstract description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 229920001225 polyester resin Polymers 0.000 description 4
- 239000004645 polyester resin Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 229920005749 polyurethane resin Polymers 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229920006311 Urethane elastomer Polymers 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000012634 fragment Substances 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229920005906 polyester polyol Polymers 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
Landscapes
- Vessels And Coating Films For Discharge Lamps (AREA)
Abstract
Description
【発明の詳細な説明】 産業上の利用分野 本発明は新規な飛散防止形蛍光灯に関するものである。[Detailed description of the invention] Industrial applications The present invention relates to a novel shatterproof fluorescent lamp.
従来の技術
蛍光灯はガラス管を用いていることから、取扱を誤って
ガラス管を破損させた場合、ガラス片が飛散り人身事故
をおこすおそれがある。これに対処する方法として、蛍
光灯についてはガラス管の外面を例えば、ポリエステル
樹脂等の高分子樹脂製の透明チューブで覆った飛散防止
形蛍光灯が公知である。これは熱収縮タイプのポリエス
テル樹脂のチューブをガラス管に被せ、ついでこのチュ
ーブを加熱処理することによりガラス管外面に高分子樹
脂被膜を形成したものである。Since conventional fluorescent lamps use glass tubes, if the glass tubes are damaged due to improper handling, glass fragments may fly off and cause personal injury. As a method for dealing with this, a shatterproof type fluorescent lamp is known in which the outer surface of a glass tube is covered with a transparent tube made of a polymer resin such as polyester resin. This is a method in which a glass tube is covered with a heat-shrinkable polyester resin tube, and then the tube is heat-treated to form a polymer resin coating on the outer surface of the glass tube.
発明が解決しようとする課題
従来の飛散防止形蛍光灯では耐候性、膜強度等を考慮し
て前記のようにポリエステル樹脂製のチューブが用いら
れている。Problems to be Solved by the Invention In conventional shatterproof fluorescent lamps, tubes made of polyester resin are used in consideration of weather resistance, film strength, etc., as described above.
しかしながら、このチューブは加工の難しさが原因で価
格が極めて高いうえに、完成した蛍光灯に手作業でチュ
ーブを被せるという極めて作業性が悪い工程が不可欠で
、そのために飛散防止形蛍光灯は一般形蛍光灯に比べ極
めて高価なものになってしまうという問題があった。However, this tube is extremely expensive due to the difficulty of processing it, and the process of manually covering the completed fluorescent lamp with the tube is extremely inefficient.For this reason, shatterproof fluorescent lamps are not commonly used. There was a problem in that they were extremely expensive compared to shaped fluorescent lamps.
そこで発明者らは先に、例えば有機溶剤可溶ポリエステ
ルポリオール系のウレタン樹脂、架橋構造をもったウレ
タンエラストマーを水に分散させたポリウレタン水分散
体を主成分とする樹脂等を用することにより、透明な飛
散防止用被膜の形成が極めて容易となり、コストを従来
に比べ大幅に低減することができる飛散防止形蛍光灯に
ついて提案したが、さらに高負荷形量光灯について検討
を進めた結果、前記高分子樹脂被膜の劣化が著しく進行
するといった問題が生じてきた。Therefore, the inventors first used, for example, an organic solvent-soluble polyester polyol-based urethane resin, a resin whose main component is a polyurethane water dispersion in which a urethane elastomer with a crosslinked structure is dispersed in water, etc. We proposed an anti-scattering fluorescent lamp, which makes it extremely easy to form a transparent anti-scattering film and can significantly reduce costs compared to conventional lamps.However, as a result of further studies on high-load fluorescent lamps, we found that the above-mentioned A problem has arisen in that the deterioration of the polymer resin coating progresses significantly.
これについて、発明者らは鋭意研究をした結果、蛍光灯
から放射される400nm以下の紫外線により高分子透
明樹脂を形成する高分子に遊離基が生成され、この反応
が進行すると、高分子架橋がつぎつぎに切断されて引っ
張り強度や伸び率が低下したり、樹脂が黄色に着色した
りすることが明かとなった。As a result of intensive research by the inventors, we found that ultraviolet rays of 400 nm or less emitted from fluorescent lamps generate free radicals in the polymers that form transparent polymer resins, and as this reaction progresses, polymer crosslinking occurs. It has become clear that the tensile strength and elongation rate decrease due to repeated cutting, and that the resin turns yellow.
本発明は、上記の問題点を解決するためになされたもの
であり、従来に比し被膜形成が容易でがつ作業性もよく
、しかも飛散防止用高分子樹脂の・劣化を防止すること
のできる飛散防止形蛍光灯を提供するものである。The present invention has been made to solve the above-mentioned problems, and it is easier to form a film than before, has good workability, and is effective in preventing deterioration of the anti-scattering polymer resin. The present invention provides a shatterproof fluorescent lamp.
課題を解決するための手段
この目的を達成するために本発明の飛散防止形蛍光灯は
、ガラス管の外面に400nm以下の紫外線を吸収する
被膜を形成し、さらに前記被膜上に高分子樹脂からなる
透明な被膜を形成した構成を有している。Means for Solving the Problems To achieve this object, the shatterproof fluorescent lamp of the present invention has a coating that absorbs ultraviolet rays of 400 nm or less formed on the outer surface of the glass tube, and a coating made of polymer resin on the coating. It has a structure in which a transparent film is formed.
作用
本発明によると、ガラス管の外面に400nm以下の紫
外線を吸収する被膜を形成することにより、その上に被
着された高分子の透明樹脂被膜が蛍光灯から放射される
400nm以下の紫外線による劣化を防止できるため、
蛍光灯を誤って破損させても、ガラス片の飛散防止を図
ることができる。According to the present invention, by forming a coating on the outer surface of the glass tube that absorbs ultraviolet rays of 400 nm or less, the transparent polymeric resin coating applied thereon can absorb ultraviolet rays of 400 nm or less emitted from fluorescent lamps. Because deterioration can be prevented,
Even if a fluorescent lamp is accidentally damaged, glass pieces can be prevented from scattering.
実施例
以下、本発明の一実施例について図面を用いて説明する
。EXAMPLE Hereinafter, an example of the present invention will be described with reference to the drawings.
紫外線吸収膜として、有機溶剤形酸化亜鉛溶液を用い、
この溶液中に水平保持した環形30ワツト蛍光灯を浸し
たのち、これを引き上げて、温度70℃、風速5m/s
ecの温風で乾燥することにより、第1r!!Jに示す
ようにガラス管1の外面ば酸化亜鉛からなる透明な紫外
線吸収膜[2を10μの厚さに形成する。ついで、ポリ
ウレタン水分散体(第−工業製薬株式会社製:スーパー
フレックス10107)1500の液中に、水平保持し
た前記蛍光灯を浸したのち、これを引き上げて、温度1
00℃、風速5m/seeの温風で乾燥し、前記紫外線
吸収膜[12上にポリウレタン樹脂からなる透明な被膜
3を80μの厚さに形成することにより、飛散防止形蛍
光灯を得た。なお、第1図中、4は蛍光体膜を示す。An organic solvent-based zinc oxide solution is used as the ultraviolet absorbing film.
After immersing a 30-watt annular fluorescent lamp held horizontally in this solution, it was taken out and the temperature was 70°C and the wind speed was 5m/s.
By drying with EC warm air, the 1st R! ! As shown in J, a transparent ultraviolet absorbing film [2] made of zinc oxide was formed on the outer surface of the glass tube 1 to a thickness of 10 μm. Next, the fluorescent lamp held horizontally was immersed in a solution of 1,500 ml of polyurethane aqueous dispersion (Superflex 10107, manufactured by Dai-Kogyo Seiyaku Co., Ltd.), and then pulled out and brought to a temperature of 1.
A transparent film 3 made of polyurethane resin was formed on the ultraviolet absorbing film [12] to a thickness of 80 μm to obtain a shatterproof fluorescent lamp. In addition, in FIG. 1, 4 indicates a phosphor film.
このようにして得られた蛍光灯を用いて、次のような落
下強度試験を行った。まず、蛍光灯を水平に保ち、3m
の高さからこれを自然落下させたところ、ガラス管は破
損したものの、被膜は破損せず、ガラス片はこの被膜に
強固に付着した状態になっており、したがってガラス片
は被膜で保護されて飛散るものは全くながった。次に、
耐衝撃試験として1mの長さの糸の端に取り付けた20
0grの鋼球を鉛直線から30度の角度で蛍光灯に当て
たところ、被膜は全く破損しなかった。Using the thus obtained fluorescent lamp, the following drop strength test was conducted. First, keep the fluorescent light horizontal and
When this object was allowed to fall naturally from a height of There were no scattered objects. next,
20 attached to the end of a 1 m long thread for impact resistance testing.
When a 0gr steel ball was exposed to a fluorescent lamp at an angle of 30 degrees from the vertical line, the coating was not damaged at all.
また、寿命試験として5000時間点灯したところ、本
発明にかがる蛍光灯は黄色に着色せず、問題のないこと
が認められた。しかし、ががる紫外線吸収膜l1I2を
有せず、隼にガラス管1の外面に前記透明被膜3を形成
した蛍光灯では、1000時間の点灯で黄色に着色する
ことが認められた。Furthermore, when the lamp was lit for 5000 hours as a life test, the fluorescent lamp according to the present invention did not turn yellow and was found to have no problems. However, in a fluorescent lamp in which the transparent coating 3 was formed on the outer surface of the glass tube 1 without having the abrasive ultraviolet absorbing film 11I2, it was observed that the fluorescent lamp turned yellow after being lit for 1000 hours.
また、本実施例によれば、ガラス管1の外面に紫外線吸
収被膜2を形成し、さらに前記被膜の上に透明なポリウ
レタン樹脂からなる一被膜3を形成した二層構造を有し
ているがポリエステル樹脂チューブを用いた従来のもの
に比しコストが215以下と大幅に低減できる。Further, according to this embodiment, the glass tube 1 has a two-layer structure in which an ultraviolet absorbing coating 2 is formed on the outer surface of the glass tube 1, and a coating 3 made of a transparent polyurethane resin is further formed on the coating. Compared to conventional products using polyester resin tubes, the cost can be significantly reduced to 215 or less.
発明の詳細
な説明したように、本発明は、ガラス管の外面に400
nm以下の紫外線を吸収する被膜を形成し、さらに前記
被膜上に高分子樹脂からなる透明被膜を形成することに
より、従来に比べて、ガラス管への飛散防止被膜の形成
が極めて容易となり、また材料費も安価であることから
、ランプコストを従来に比し大幅に低減することができ
ることはもちろんのこと、飛散防止用高分子樹脂の劣化
を防止することのできる飛散防止形蛍光灯を提供するこ
とができるものである。DETAILED DESCRIPTION OF THE INVENTION As described above, the present invention provides 400 mm on the outer surface of a glass tube.
By forming a coating that absorbs ultraviolet rays of nm or less and further forming a transparent coating made of polymer resin on the coating, it is much easier to form a shatterproof coating on a glass tube than in the past. To provide a shatterproof fluorescent lamp which can not only significantly reduce lamp cost compared to conventional lamps because the material cost is low, but also can prevent deterioration of the shatterproof polymer resin. It is something that can be done.
第1図は本発明の一実施例である飛散防止形蛍光ランプ
の断面図である。
1・・・・・・ガラス管、2・・・・・・紫外線吸収被
膜、3・・・・・・高分子樹脂被膜、4・・・・・・蛍
光体膜。FIG. 1 is a sectional view of a shatterproof fluorescent lamp according to an embodiment of the present invention. DESCRIPTION OF SYMBOLS 1... Glass tube, 2... Ultraviolet absorption coating, 3... Polymer resin coating, 4... Fluorescent material film.
Claims (1)
膜を形成し、さらに前記被膜の上に高分子樹脂からなる
透明な被膜を形成したことを特徴とする飛散防止形蛍光
灯。A shatterproof fluorescent lamp characterized in that a coating that absorbs ultraviolet rays of 400 nm or less is formed on the outer surface of a glass tube, and a transparent coating made of a polymer resin is further formed on the coating.
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP29826289A JPH03159053A (en) | 1989-11-16 | 1989-11-16 | Scatter preventing fluorescent light |
US07/612,311 US5124618A (en) | 1989-11-16 | 1990-11-13 | Shatter-proof fluorescent lamp |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP29826289A JPH03159053A (en) | 1989-11-16 | 1989-11-16 | Scatter preventing fluorescent light |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH03159053A true JPH03159053A (en) | 1991-07-09 |
Family
ID=17857352
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP29826289A Pending JPH03159053A (en) | 1989-11-16 | 1989-11-16 | Scatter preventing fluorescent light |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH03159053A (en) |
-
1989
- 1989-11-16 JP JP29826289A patent/JPH03159053A/en active Pending
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