JPH03153508A - Intercalation compound of aluminum dihydrogen tripolyphosphate - Google Patents
Intercalation compound of aluminum dihydrogen tripolyphosphateInfo
- Publication number
- JPH03153508A JPH03153508A JP1290413A JP29041389A JPH03153508A JP H03153508 A JPH03153508 A JP H03153508A JP 1290413 A JP1290413 A JP 1290413A JP 29041389 A JP29041389 A JP 29041389A JP H03153508 A JPH03153508 A JP H03153508A
- Authority
- JP
- Japan
- Prior art keywords
- aluminum dihydrogen
- dihydrogen tripolyphosphate
- alkylamine
- intercalation compound
- aluminum
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 82
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 81
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 77
- 235000019832 sodium triphosphate Nutrition 0.000 title claims abstract description 77
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 title claims abstract description 77
- 238000009830 intercalation Methods 0.000 title claims abstract description 34
- 230000002687 intercalation Effects 0.000 title claims abstract description 34
- 150000001875 compounds Chemical class 0.000 title claims description 34
- 150000003973 alkyl amines Chemical class 0.000 claims abstract description 30
- 239000003463 adsorbent Substances 0.000 abstract description 12
- 238000000034 method Methods 0.000 abstract description 10
- 238000001179 sorption measurement Methods 0.000 abstract description 9
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 abstract description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 abstract description 6
- 239000000049 pigment Substances 0.000 abstract description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 4
- 239000002904 solvent Substances 0.000 abstract description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 2
- 239000011229 interlayer Substances 0.000 description 19
- 239000000126 substance Substances 0.000 description 12
- 210000004709 eyebrow Anatomy 0.000 description 11
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- 239000010410 layer Substances 0.000 description 8
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- -1 boehmite type Chemical class 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 5
- 238000005342 ion exchange Methods 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000003960 organic solvent Substances 0.000 description 5
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 5
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 238000011282 treatment Methods 0.000 description 4
- BMVXCPBXGZKUPN-UHFFFAOYSA-N 1-hexanamine Chemical compound CCCCCCN BMVXCPBXGZKUPN-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 229910010293 ceramic material Inorganic materials 0.000 description 3
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical compound CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 description 3
- LAWOZCWGWDVVSG-UHFFFAOYSA-N dioctylamine Chemical compound CCCCCCCCNCCCCCCCC LAWOZCWGWDVVSG-UHFFFAOYSA-N 0.000 description 3
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 3
- 239000007772 electrode material Substances 0.000 description 3
- 229910001410 inorganic ion Inorganic materials 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- IOQPZZOEVPZRBK-UHFFFAOYSA-N octan-1-amine Chemical compound CCCCCCCCN IOQPZZOEVPZRBK-UHFFFAOYSA-N 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- FJLUATLTXUNBOT-UHFFFAOYSA-N 1-Hexadecylamine Chemical compound CCCCCCCCCCCCCCCCN FJLUATLTXUNBOT-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- MHZGKXUYDGKKIU-UHFFFAOYSA-N Decylamine Chemical compound CCCCCCCCCCN MHZGKXUYDGKKIU-UHFFFAOYSA-N 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000000969 carrier Substances 0.000 description 2
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- BMFVGAAISNGQNM-UHFFFAOYSA-N isopentylamine Chemical compound CC(C)CCN BMFVGAAISNGQNM-UHFFFAOYSA-N 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 239000012046 mixed solvent Substances 0.000 description 2
- GMTCPFCMAHMEMT-UHFFFAOYSA-N n-decyldecan-1-amine Chemical compound CCCCCCCCCCNCCCCCCCCCC GMTCPFCMAHMEMT-UHFFFAOYSA-N 0.000 description 2
- HKUFIYBZNQSHQS-UHFFFAOYSA-N n-octadecyloctadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCCCNCCCCCCCCCCCCCCCCCC HKUFIYBZNQSHQS-UHFFFAOYSA-N 0.000 description 2
- 230000010355 oscillation Effects 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000009210 therapy by ultrasound Methods 0.000 description 2
- ABVVEAHYODGCLZ-UHFFFAOYSA-N tridecan-1-amine Chemical compound CCCCCCCCCCCCCN ABVVEAHYODGCLZ-UHFFFAOYSA-N 0.000 description 2
- JPZYXGPCHFZBHO-UHFFFAOYSA-N 1-aminopentadecane Chemical compound CCCCCCCCCCCCCCCN JPZYXGPCHFZBHO-UHFFFAOYSA-N 0.000 description 1
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 1
- IIFFFBSAXDNJHX-UHFFFAOYSA-N 2-methyl-n,n-bis(2-methylpropyl)propan-1-amine Chemical compound CC(C)CN(CC(C)C)CC(C)C IIFFFBSAXDNJHX-UHFFFAOYSA-N 0.000 description 1
- NJBCRXCAPCODGX-UHFFFAOYSA-N 2-methyl-n-(2-methylpropyl)propan-1-amine Chemical compound CC(C)CNCC(C)C NJBCRXCAPCODGX-UHFFFAOYSA-N 0.000 description 1
- VJROPLWGFCORRM-UHFFFAOYSA-N 2-methylbutan-1-amine Chemical compound CCC(C)CN VJROPLWGFCORRM-UHFFFAOYSA-N 0.000 description 1
- GELMWIVBBPAMIO-UHFFFAOYSA-N 2-methylbutan-2-amine Chemical compound CCC(C)(C)N GELMWIVBBPAMIO-UHFFFAOYSA-N 0.000 description 1
- KDSNLYIMUZNERS-UHFFFAOYSA-N 2-methylpropanamine Chemical compound CC(C)CN KDSNLYIMUZNERS-UHFFFAOYSA-N 0.000 description 1
- JOZZAIIGWFLONA-UHFFFAOYSA-N 3-methylbutan-2-amine Chemical compound CC(C)C(C)N JOZZAIIGWFLONA-UHFFFAOYSA-N 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- WJYIASZWHGOTOU-UHFFFAOYSA-N Heptylamine Chemical compound CCCCCCCN WJYIASZWHGOTOU-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- PLZVEHJLHYMBBY-UHFFFAOYSA-N Tetradecylamine Chemical compound CCCCCCCCCCCCCCN PLZVEHJLHYMBBY-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910001413 alkali metal ion Inorganic materials 0.000 description 1
- 229910001420 alkaline earth metal ion Inorganic materials 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical class [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 229910001593 boehmite Inorganic materials 0.000 description 1
- RNFNDJAIBTYOQL-UHFFFAOYSA-N chloral hydrate Chemical compound OC(O)C(Cl)(Cl)Cl RNFNDJAIBTYOQL-UHFFFAOYSA-N 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 125000005265 dialkylamine group Chemical group 0.000 description 1
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 229940043279 diisopropylamine Drugs 0.000 description 1
- YWEUIGNSBFLMFL-UHFFFAOYSA-N diphosphonate Chemical compound O=P(=O)OP(=O)=O YWEUIGNSBFLMFL-UHFFFAOYSA-N 0.000 description 1
- RGPUVZXXZFNFBF-UHFFFAOYSA-K diphosphonooxyalumanyl dihydrogen phosphate Chemical compound [Al+3].OP(O)([O-])=O.OP(O)([O-])=O.OP(O)([O-])=O RGPUVZXXZFNFBF-UHFFFAOYSA-K 0.000 description 1
- WEHWNAOGRSTTBQ-UHFFFAOYSA-N dipropylamine Chemical compound CCCNCCC WEHWNAOGRSTTBQ-UHFFFAOYSA-N 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- MJEMIOXXNCZZFK-UHFFFAOYSA-N ethylone Chemical compound CCNC(C)C(=O)C1=CC=C2OCOC2=C1 MJEMIOXXNCZZFK-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- KAJZYANLDWUIES-UHFFFAOYSA-N heptadecan-1-amine Chemical compound CCCCCCCCCCCCCCCCCN KAJZYANLDWUIES-UHFFFAOYSA-N 0.000 description 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 150000002605 large molecules Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- DIAIBWNEUYXDNL-UHFFFAOYSA-N n,n-dihexylhexan-1-amine Chemical compound CCCCCCN(CCCCCC)CCCCCC DIAIBWNEUYXDNL-UHFFFAOYSA-N 0.000 description 1
- XTAZYLNFDRKIHJ-UHFFFAOYSA-N n,n-dioctyloctan-1-amine Chemical compound CCCCCCCCN(CCCCCCCC)CCCCCCCC XTAZYLNFDRKIHJ-UHFFFAOYSA-N 0.000 description 1
- OOHAUGDGCWURIT-UHFFFAOYSA-N n,n-dipentylpentan-1-amine Chemical compound CCCCCN(CCCCC)CCCCC OOHAUGDGCWURIT-UHFFFAOYSA-N 0.000 description 1
- MJCJUDJQDGGKOX-UHFFFAOYSA-N n-dodecyldodecan-1-amine Chemical compound CCCCCCCCCCCCNCCCCCCCCCCCC MJCJUDJQDGGKOX-UHFFFAOYSA-N 0.000 description 1
- MFHKEJIIHDNPQE-UHFFFAOYSA-N n-nonylnonan-1-amine Chemical compound CCCCCCCCCNCCCCCCCCC MFHKEJIIHDNPQE-UHFFFAOYSA-N 0.000 description 1
- YDFFPEXFCAUTSL-UHFFFAOYSA-N n-pentadecylpentadecan-1-amine Chemical compound CCCCCCCCCCCCCCCNCCCCCCCCCCCCCCC YDFFPEXFCAUTSL-UHFFFAOYSA-N 0.000 description 1
- PZFYOFFTIYJCEW-UHFFFAOYSA-N n-tridecyltridecan-1-amine Chemical compound CCCCCCCCCCCCCNCCCCCCCCCCCCC PZFYOFFTIYJCEW-UHFFFAOYSA-N 0.000 description 1
- FJDUDHYHRVPMJZ-UHFFFAOYSA-N nonan-1-amine Chemical compound CCCCCCCCCN FJDUDHYHRVPMJZ-UHFFFAOYSA-N 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- IGEIPFLJVCPEKU-UHFFFAOYSA-N pentan-2-amine Chemical compound CCCC(C)N IGEIPFLJVCPEKU-UHFFFAOYSA-N 0.000 description 1
- PQPFFKCJENSZKL-UHFFFAOYSA-N pentan-3-amine Chemical compound CCC(N)CC PQPFFKCJENSZKL-UHFFFAOYSA-N 0.000 description 1
- DLYUQMMRRRQYAE-UHFFFAOYSA-N phosphorus pentoxide Inorganic materials O1P(O2)(=O)OP3(=O)OP1(=O)OP2(=O)O3 DLYUQMMRRRQYAE-UHFFFAOYSA-N 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229910021647 smectite Inorganic materials 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- YBRBMKDOPFTVDT-UHFFFAOYSA-N tert-butylamine Chemical compound CC(C)(C)N YBRBMKDOPFTVDT-UHFFFAOYSA-N 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- SWZDQOUHBYYPJD-UHFFFAOYSA-N tridodecylamine Chemical compound CCCCCCCCCCCCN(CCCCCCCCCCCC)CCCCCCCCCCCC SWZDQOUHBYYPJD-UHFFFAOYSA-N 0.000 description 1
- RKBCYCFRFCNLTO-UHFFFAOYSA-N triisopropylamine Chemical compound CC(C)N(C(C)C)C(C)C RKBCYCFRFCNLTO-UHFFFAOYSA-N 0.000 description 1
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical compound CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229910000166 zirconium phosphate Inorganic materials 0.000 description 1
- LEHFSLREWWMLPU-UHFFFAOYSA-B zirconium(4+);tetraphosphate Chemical compound [Zr+4].[Zr+4].[Zr+4].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LEHFSLREWWMLPU-UHFFFAOYSA-B 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/26—Phosphates
- C01B25/38—Condensed phosphates
- C01B25/40—Polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09C—TREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
- C09C1/00—Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
- C09C1/40—Compounds of aluminium
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明はトリポリリン酸二水素アルミニウム型層間化合
物に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to an intercalation compound of the aluminum dihydrogen tripolyphosphate type.
本発明のトリポリリン酸二水素アルミニウム型層間化合
物は、トリポリリン酸二水素アルミニウムに基づく大き
な固体酸性、イオン交換能などの機能と、アルキルアミ
ンが眉間に含まれることによる層間距離の大きさとによ
り、吸着剤、防ＩＩ料、触媒、触媒担体、電極材料、光
学材料、無機イオン交換体、ガス分離剤、セラミック材
料などとして好適に使用される物質である。The aluminum dihydrogen tripolyphosphate type intercalation compound of the present invention has functions such as high solid acidity and ion exchange ability based on aluminum dihydrogen tripolyphosphate, and a large interlayer distance due to the inclusion of alkylamine between the eyebrows, making it an adsorbent. It is a substance suitably used as an anti-II material, a catalyst, a catalyst carrier, an electrode material, an optical material, an inorganic ion exchanger, a gas separation agent, a ceramic material, etc.
リン酸ジルコニウムの眉間距離を広げることや、多孔質
粘土材Ｆ４（スメクタイト型鉱物）の眉間距離を広げる
ことは、従来がらも提案されている（例えば、特開平１
−１６０８１３号公報、特公昭６２−４１１６８３号公
報など）。Increasing the distance between the eyebrows of zirconium phosphate and the distance between the eyebrows of porous clay material F4 (smectite mineral) have been proposed in the past (for example, Japanese Patent Application Laid-Open No.
-160813, Japanese Patent Publication No. 62-411683, etc.).
しかし、トリポリリン酸二水素アルミニウムの層間距離
を広げることについては、いまだ報告されていない。However, there has been no report on increasing the interlayer distance of aluminum dihydrogen tripolyphosphate.
上記トリポリリン酸二水素アルミニウムは、大きな固体
酸性、イオン交換能などを有していて、吸着剤、防ｔａ
ｎ料などに使用されているが、このトリポリリン酸二水
素アルミニウムの眉間距離を広げることによって、より
大きな分子量のものを吸着できるようになるなど、より
有用な吸着剤や防錆顔料として使用することができると
考えられる。The above-mentioned aluminum dihydrogen tripolyphosphate has a large solid acidity and ion exchange ability, and is used as an adsorbent and anti-tank.
This aluminum dihydrogen tripolyphosphate is used as a more useful adsorbent and anti-corrosion pigment, but by increasing the glabellar distance, it can adsorb substances with larger molecular weights. It is thought that it can be done.
したがって、本発明は、トリポリリン酸二水素アルミニ
ウムの眉間距離を広げた新規なトリポリリン酸二水素ア
ルミニウム型層間化合物を提供することを目的とする。Therefore, an object of the present invention is to provide a novel aluminum dihydrogen tripolyphosphate type intercalation compound in which the glabellar distance of aluminum dihydrogen tripolyphosphate is increased.
本発明は、トリポリリン酸二水素アルミニウムの層間に
アルキルアミンを含ますことによって、トリポリリン酸
二水素アルミニウムの層間距離を広げ、上記目的を達成
したものである。The present invention achieves the above object by widening the interlayer distance of aluminum dihydrogen tripolyphosphate by including an alkylamine between the layers of aluminum dihydrogen tripolyphosphate.
すなわち、本発明は、眉間にアルキルアミンを含むこと
を特徴とするトリポリリン酸二水素アルミニウム型層間
化合物に関する。That is, the present invention relates to an aluminum dihydrogen tripolyphosphate type intercalation compound characterized by containing an alkylamine between the eyebrows.
本発明に用いられるトリポリリン酸二水素アルミニウム
は、化学式ＡＩ Ｈ，Ｐ、Ｏ，。・２１Ｔ、Ｏで表され
る物質であり、例えば、日本特許第８５６，３８６号の
方法によって製造することができる。すなわち、アルミ
ニウムまたはアルミニウム含有物質とリン含有物質とを
Ｐ ｇｏｓ ／ Ａ Ｉ ｚｃｈのモル比が１〜６にな
るように配合した混合物を６０〜４５０°Ｃで加熱して
、脱水結晶化させることによって得られる。The aluminum dihydrogen tripolyphosphate used in the present invention has the chemical formula AI H, P, O,. - It is a substance represented by 21T, O, and can be produced, for example, by the method of Japanese Patent No. 856,386. That is, by heating a mixture of aluminum or an aluminum-containing substance and a phosphorus-containing substance such that the molar ratio of P gos / AI zch is 1 to 6 at 60 to 450 °C to dehydrate and crystallize it. can get.
そして、上記のアルミニウムまたはアルミニウム含有物
質としては、例えば、α−１β−１γδ−１θ−１ρ−
１ξ−１χ−１η−１に一タイプなどの各種アルミナ、
ハイドラルジライド、バイアライト、ダイアスボアー、
ベーマイト型などの各種水酸化アルミニウム、金属アル
ミニウム、あるいは各種アルミニウム塩などが用いられ
る。The above aluminum or aluminum-containing substance is, for example, α-1β-1γδ-1θ-1ρ-
Various types of alumina such as one type for 1ξ-1χ-1η-1,
Hydral dilide, vialite, diasbore,
Various aluminum hydroxides such as boehmite type, metallic aluminum, and various aluminum salts are used.
また、リン含有物質としては、例えば、リン酸、リン酸
アンモニウム、五酸化リン、オキシロハロゲン化リンな
どが用いられる。Further, as the phosphorus-containing substance, for example, phosphoric acid, ammonium phosphate, phosphorus pentoxide, phosphorus oxyhalide, etc. are used.
これらの原料は、純度の高いものほど好ましいが、純度
は特に限定されるものではなく、目的とするトリポリリ
ン酸二水素アルミニウムの用途に応じて適したものを選
べばよく、通常は工業用酸化アルミニウムや工業用７０
〜８５％リン酸などが使用される。The higher the purity of these raw materials, the more preferable they are, but the purity is not particularly limited, and it is sufficient to select a material suitable for the intended use of aluminum dihydrogen tripolyphosphate, and usually industrial aluminum oxide is used. and industrial 70
~85% phosphoric acid, etc. are used.
本発明のトリポリリン酸二水素アルミニウム型層間化合
物においては、トリポリリン酸二水素アルミニウムの眉
間距離をアルキルアミンで広げているが、これは、７’
ルー１−ルアミンで層間距離を広げた場合、トリポリリ
ン酸二水素アルミニウムが本来有していた固体酸性、イ
オン交換能などの特性をほとんど損なうことがないから
である。In the aluminum dihydrogen tripolyphosphate type intercalation compound of the present invention, the glabellar distance of aluminum dihydrogen tripolyphosphate is widened with an alkylamine, which is 7'
This is because when the interlayer distance is widened with lu-1-ruamine, the properties inherent to aluminum dihydrogen tripolyphosphate, such as solid acidity and ion exchange ability, are hardly impaired.
すなわち、トリポリリン酸二水素アルミニウムの層間距
離を広げるために、アルキルアミン以外にも、アルカリ
金属イオン、アルカリ土類金属イオン、希土類酸化物な
どをトリポリリン酸二水素アルミニウムの眉間に含ませ
ることも考え得るが、これらによる場合は、トリポリリ
ン酸二水素アルミニウムの元の結晶形が失われ、トリポ
リリン酸二水素アルミニウムの特性が失われることにな
る。That is, in order to widen the interlayer distance of aluminum dihydrogen tripolyphosphate, it is conceivable to include alkali metal ions, alkaline earth metal ions, rare earth oxides, etc. in the glabella of aluminum dihydrogen tripolyphosphate in addition to alkylamine. However, in these cases, the original crystal form of aluminum dihydrogen tripolyphosphate is lost, and the properties of aluminum dihydrogen tripolyphosphate are lost.
アルキルアミンがトリポリリン酸二水素アルミニウムの
層間に入り込むａ様は、眉間吸着によるものと考えられ
るが、このアルキルアミンでトリポリリン酸二水素アル
ミニウムの層間距離を広げる場合には、アルキルアミン
の炭素数によってトリポリリン酸二水素アルミニウムの
眉間距離を変えることができ、使用目的に応じ、適した
眉間距前を持つトリポリリン酸二水素アルミニウム型層
間化合物を得ることができる。The phenomenon a in which the alkylamine enters between the layers of aluminum dihydrogen tripolyphosphate is thought to be due to adsorption between the eyebrows, but when increasing the interlayer distance of aluminum dihydrogen tripolyphosphate with this alkylamine, the number of carbon atoms in the alkylamine The glabellar distance of aluminum dihydrogen tripolyphosphate can be changed, and it is possible to obtain an aluminum dihydrogen tripolyphosphate type intercalation compound having a suitable glabellar distance depending on the purpose of use.
上記アルキルアミンとしては、一般式Ｒ，ＮＨ２（Ｒ，
は炭素数１〜３０のアルキル基）で示されるモノアルキ
ルアミン、一般式Ｒ，Ｒ□ＮＨ（Ｒ，およびＲ８は炭素
数１〜３０のアルキル基）で示されるジアルキルアミン
、一般式Ｒ，Ｒ，Ｒ，Ｎ （Ｒ，、Ｒ３およびＲ３は炭
素数１〜３０のアルキル基）で示されるトリアルキルア
ミンのいずれもが使用できる。The alkylamine mentioned above has the general formula R, NH2(R,
is an alkyl group having 1 to 30 carbon atoms); a dialkylamine represented by the general formula R, R□NH (R and R8 are an alkyl group having 1 to 30 carbon atoms); , R, N (R, , R3 and R3 are alkyl groups having 1 to 30 carbon atoms) can be used.
上記アルキルアミンの好ましい具体例としては、例えば
、モノメチルアミン、ジメチルアミン、トリメチルアミ
ン、モノエチルアミン、ジエチルアミン、トリエチルア
ミン、モノプロピルアミン、ジプロピルアミン、トリプ
ロピルアミン、モノイソプロピルアミン、ジイソプロピ
ルアミン、トリイソプロアミン、モノブチルアミン、ジ
ブチルアミン、トリブチルアミン、モノイソブチルアミ
ン、ジイソブチルアミン、トリイソブチルアミン、モノ
−５ｅｃ−ブチルアミン、ジー５ｅｃ−ブチルアミン、
ｔｅｒｔ−ブチルアミン、ｎ−アミノペンタン、イソア
ミルアミン、２−アミノペンタン、３−アミノペンタン
、１−アミノ−２−メチルブタン、第三アミルアミン、
３−アミノ−２−メチルブタン、ｌ−アミノ−２，２−
ジメチルプロパン、トリアミルアミン、モノヘキシルア
ミン、ジオクチルアミン、トリへキシルアミン、モノへ
ブチルアミン、ジオクチルアミン、トリへブチルアミン
、モノオクチルアミン、ジオクチルアミン、トリオクチ
ルアミン、モノノニルアミン、ジノニルアミン、モノデ
シルアミン、ジデシルアミン、ウンデンルアミン、モノ
ラウリルアミン、ジラウリルアミン、トリラウリルアミ
ン、モノトリデシルアミン、ジトリデシルアミン、モノ
ミリスチルアミン、シミリスチルアミン、モノペンタデ
シルアミン、ジペンタデシルアミン、モノセチルアミン
、ジデシルアミン、トリデシルアミン、モノヘプタデシ
ルアミン、ジステアリルアミン、モノステアリルアミン
、ジステアリルアミン、トリステアリルアミンなどが挙
げられる。Preferred specific examples of the alkylamine include monomethylamine, dimethylamine, trimethylamine, monoethylamine, diethylamine, triethylamine, monopropylamine, dipropylamine, tripropylamine, monoisopropylamine, diisopropylamine, triisopropylamine, Monobutylamine, dibutylamine, tributylamine, monoisobutylamine, diisobutylamine, triisobutylamine, mono-5ec-butylamine, di-5ec-butylamine,
tert-butylamine, n-aminopentane, isoamylamine, 2-aminopentane, 3-aminopentane, 1-amino-2-methylbutane, tertiary amylamine,
3-amino-2-methylbutane, l-amino-2,2-
Dimethylpropane, triamylamine, monohexylamine, dioctylamine, trihexylamine, monohexylamine, dioctylamine, trihebutylamine, monooctylamine, dioctylamine, trioctylamine, monononylamine, dinonylamine, monodecylamine, Didecylamine, undenylamine, monolaurylamine, dilaurylamine, trilaurylamine, monotridecylamine, ditridecylamine, monomyristylamine, simyristylamine, monopentadecylamine, dipentadecylamine, monocetylamine, didecylamine , tridecylamine, monoheptadecylamine, distearylamine, monostearylamine, distearylamine, tristearylamine, and the like.
これらのアルキルアミンをトリポリリン酸二水素アルミ
ニウムの眉間に含ませてトリポリリン酸二水素アルミニ
ウム型層間化合物を製造する方法としでは、液相法と気
相法が挙げられる。Examples of methods for producing an aluminum dihydrogen tripolyphosphate type intercalation compound by including these alkylamines in the glabella of aluminum dihydrogen tripolyphosphate include a liquid phase method and a gas phase method.
液相法は、媒体として水あるいはメタノール、エタノー
ルなどのアルコール類、メチルエチルケトン、ジメチル
ケトンなどのケトン類、酢酸メチル、酢酸エチルなどの
酢酸エステル類、ベンゼン、クロロホルムなどの有機溶
剤の単独または２種以上の混合溶剤を使用し、アルキル
アミンをこれらの溶剤中に０．０５〜２ＯＮ、好ましく
は０．１〜ＩＯＮの濃度に溶解し、このアルキルアミン
の溶液にトリポリリン酸二水素アルミニウムを分散させ
て、トリポリリン酸二水素アルミニウムとアルキルアミ
ンとを反応させる方法である。The liquid phase method uses water, alcohols such as methanol and ethanol, ketones such as methyl ethyl ketone and dimethyl ketone, acetate esters such as methyl acetate and ethyl acetate, and one or more organic solvents such as benzene and chloroform as the medium. Using a mixed solvent of , dissolve an alkylamine in these solvents to a concentration of 0.05 to 2ON, preferably 0.1 to ION, and disperse aluminum dihydrogen tripolyphosphate in the solution of the alkylamine. This is a method of reacting aluminum dihydrogen tripolyphosphate with an alkylamine.
上記の分散方法としては、バッチ式、連続式のいずれも
が採用可能であり、反応装置によっては、通常の撹拌、
混合、スタティックミキサーによる混合、剪断混合、あ
るいはそれらの混合攪拌手段を適宜組み合わせて使用し
、アルキルアミンをトリポリリン酸二水素アルミニウム
に反応させればよい。As the above dispersion method, either batch type or continuous type can be adopted, and depending on the reaction equipment, normal stirring,
The alkylamine may be reacted with aluminum dihydrogen tripolyphosphate by mixing, mixing using a static mixer, shear mixing, or a suitable combination of these mixing and stirring means.
また、トリポリリン酸二水素アルミニウムとアルキルア
ミンとを反応させるための処理方法として、上記のトリ
ポリリン酸二水素アルミニウム分散アルキルアミン溶液
を超音波処理すると、反応を完結させるための処理時間
を短縮することが可能である。この超音波処理は、通常
、発振周波数１６〜５０ ｋｌｌｚ程度で行われる。Furthermore, as a treatment method for reacting aluminum dihydrogen tripolyphosphate with an alkylamine, the above-mentioned aluminum dihydrogen tripolyphosphate dispersed alkylamine solution can be treated with ultrasonic waves to shorten the treatment time to complete the reaction. It is possible. This ultrasonic treatment is normally performed at an oscillation frequency of about 16 to 50 kllz.
また、トリポリリン酸二水素アルミニウムスラリーにア
ルキルアミンを添加し、上記と同様の処理をしてもよい
。Alternatively, an alkylamine may be added to the aluminum dihydrogen tripolyphosphate slurry and the same treatment as above may be performed.
これらの処理後、得られたスラリーを濾過、乾燥、粉砕
することにより、アルキルアミンによって眉間距離が広
げられたトリポリリン酸二水素アルミニウム、つまり、
トリポリリン酸二水素アルミニウム型層間化合物が得ら
れる。得られた物質が層間にアルキルアミンを含むトリ
ポリリン酸二水素アルミニウム型層間化合物であること
は、得られた物質のＸ線回折を行うごとによって確認す
ることかできる。After these treatments, the resulting slurry is filtered, dried, and pulverized to produce aluminum dihydrogen tripolyphosphate whose glabellar distance has been increased by the alkylamine, that is,
An intercalation compound of the aluminum dihydrogen tripolyphosphate type is obtained. It can be confirmed by X-ray diffraction of the obtained substance that the obtained substance is an aluminum dihydrogen tripolyphosphate type intercalation compound containing an alkylamine between the layers.
一方、気相法では、アルキルアミンの蒸気雰囲気中にト
リポリリン酸二水素アルミニウムを放置し、アルキルア
ミンをトリポリリン酸二水素アルミニウムの層間に吸着
させればよく、それによって、トリポリリン酸二水素ア
ルミニウム型層間化合物を得ることができる。On the other hand, in the gas phase method, aluminum dihydrogen tripolyphosphate is left in an alkylamine vapor atmosphere, and the alkylamine is adsorbed between the layers of aluminum dihydrogen tripolyphosphate. compound can be obtained.
上記のようにして得られるトリポリリン酸二水素アルミ
ニウム型層間化合物は、トリポリリン酸二水素アルミニ
ウムに基づく大きな固体酸性、イオン交換能を有し、ま
た層間距離が広がったことにより、従来では眉間内に入
り込めなかった大きな分子が眉間に入り込めるようにな
って、例えば、分子量の大きな悪臭物質を吸着できるな
ど、吸着剤としての有用性が通常のトリポリリン酸二水
素アルミニウムよりも向上し、また溶剤に対する分散性
が向上して防錆顔料としての応用性がより広くなるなど
、吸着剤、防錆顔料、触媒、触媒担体、電極材料、光学
材料、無機イオン交換体、ガス分離剤、セラミック材料
などとして好適に使用される。The aluminum dihydrogen tripolyphosphate type intercalation compound obtained as described above has large solid acidity and ion exchange ability based on aluminum dihydrogen tripolyphosphate, and due to the increased interlayer distance, it has been found to be able to enter the area between the eyebrows. Large molecules that could not be absorbed can now enter between the eyebrows, making it more useful as an adsorbent than ordinary aluminum dihydrogen tripolyphosphate, such as being able to adsorb malodorous substances with large molecular weights, and its dispersibility in solvents. It is suitable for use as adsorbents, anti-rust pigments, catalysts, catalyst carriers, electrode materials, optical materials, inorganic ion exchangers, gas separation agents, ceramic materials, etc. used.
本発明のトリポリリン酸二水素アルミニウム型層間化合
物を吸着剤として用いる場合、その形態としでは、吸着
剤に通常採用されている形態、例えば、粉末状、ベレッ
ト状、あるいは水または有機溶剤に分散または熔解させ
た液状の吸着剤など、各種の形態を採用することができ
る。また、樹脂製の包装材料の作製にあたって粉末状の
ものを樹脂に練り込み、吸着能を有する包装材料を作製
するための吸着剤としても使用することができる。When the aluminum dihydrogen tripolyphosphate type intercalation compound of the present invention is used as an adsorbent, it may be in the form normally adopted for adsorbents, such as powder, pellet form, or dispersed or dissolved in water or an organic solvent. Various forms can be adopted, such as a liquid adsorbent. In addition, it can also be used as an adsorbent for producing a packaging material having adsorption ability by kneading a powder into a resin when producing a packaging material made of resin.
また、本発明のトリポリリン酸二水素アルミニウム型層
間化合物を防錆顔料として用いる場合、層間距離が広が
ったことによって有機溶剤への分散性が向上し、水系の
防錆塗料のみならず、有機溶剤系の防錆塗料も調製する
ことができる。In addition, when the aluminum dihydrogen tripolyphosphate type intercalation compound of the present invention is used as a rust-preventing pigment, the increased interlayer distance improves dispersibility in organic solvents, allowing it to be used not only in water-based rust-preventing paints but also in organic solvent-based paints. Rust-inhibiting paints can also be prepared.
つぎに実施例を挙げて本発明をより具体的に説明するが
、本発明はそれらの実施例のみに限定されるものではな
い。EXAMPLES Next, the present invention will be described in more detail with reference to Examples, but the present invention is not limited to these Examples.
実施例１
アルキルアミンとして炭素数が１〜１Ｇの１１種類のモ
ノ−ｎ−アルキルアミン、つまり、メチルアミン、エチ
ルアミン、プロピルアミン、ブチルアミン、ヘキシルア
ミン、ヘプチルアミン、オクチルアミン、デシルアミン
、ラウリルアミン、ミリスチルアミン、セチルアミンを
用い、それぞれベンゼンに濃度がＯ，ＩＮになるように
溶解し、このアルキルアミンベンゼン溶液１００ｍＮに
トリポリリン酸二水素アルミニウム（Ｎ間距＠ ： ７
．９０人）を５ｇ加えて、攪拌し分散させてスラリー化
し、このスラリーに超音波を５時間照射して処理した。Example 1 Alkylamines include 11 types of mono-n-alkylamines having a carbon number of 1 to 1G, namely methylamine, ethylamine, propylamine, butylamine, hexylamine, heptylamine, octylamine, decylamine, laurylamine, myristyl Using amine and cetylamine, dissolve them in benzene so that the concentrations are O and IN, respectively, and add aluminum dihydrogen tripolyphosphate (N distance @: 7) to 100 mN of this alkylamine benzene solution.
．． 90 people) was added, stirred and dispersed to form a slurry, and this slurry was treated by irradiating ultrasonic waves for 5 hours.
超音波の照射は、発振周波数２８ ｋＨｚで行い、処理
温度は２５°Ｃである。この超音波処理後、濾過、脱水
、乾燥、粉砕して層間にアルキルアミンを含むトリポリ
リン酸二水素アルミニウム型層間化合物を得た。Ultrasonic irradiation is performed at an oscillation frequency of 28 kHz, and the processing temperature is 25°C. After this ultrasonic treatment, it was filtered, dehydrated, dried, and pulverized to obtain an aluminum dihydrogen tripolyphosphate type intercalation compound containing an alkylamine between the layers.
上記のようにして得られたトリポリリン酸二水素アルミ
ニウム型層間化合物の眉間距離をＸ線回折法により測定
した結果を第１図に示す。The glabellar distance of the aluminum dihydrogen tripolyphosphate intercalation compound obtained as described above was measured by X-ray diffraction, and the results are shown in FIG.
第１図において、横軸はトリポリリン酸二水素アルミニ
ウムの層間に含ませたｎ−アルキルアミンの炭素数であ
り、縦軸は層間距離であるが、この第１図に示すように
、ｎ−アルキルアミンの炭素数が大きくなるにつれて眉
間距離がほぼ直線的に大きくなっている。In Figure 1, the horizontal axis is the number of carbon atoms in the n-alkylamine contained between the layers of aluminum dihydrogen tripolyphosphate, and the vertical axis is the interlayer distance. As the number of carbon atoms in the amine increases, the distance between the eyebrows increases almost linearly.
つぎに、上記のようにして得られた眉間距離が１５．６
５人のトリポリリン酸二水素アルミニウム型層間化合物
（Ｎ間にブチルアミンを含ませたトリポリリン酸二水素
アルミニウム型層間化合物）と眉間距離が２３．４０人
のトリポリリン酸二水素アルミニウム型層間化合物（層
間にオクチルアミンを含ませたトリポリリン酸二水素ア
ルミニウム型層間化合物）とトリポリリン酸二水素アル
ミニウムを用いて、吸着試験を行った。その結果を後記
の吸着試験の項における第１表に示す。Next, the distance between the eyebrows obtained as above is 15.6
Aluminum dihydrogen tripolyphosphate type intercalation compound (aluminum dihydrogen tripolyphosphate type intercalation compound with butylamine included between N) of 5 people and aluminum dihydrogen tripolyphosphate type intercalation compound of aluminum dihydrogen phosphate type intercalation compound of 23.40 people (with octyl amine between the layers) An adsorption test was conducted using an amine-containing aluminum dihydrogen tripolyphosphate type intercalation compound) and aluminum dihydrogen tripolyphosphate. The results are shown in Table 1 in the adsorption test section below.
また、上記層間距離が２３．４０人のトリポリリン酸二
水素アルミニウム型層間化合物と層間距離が３１．１５
人のトリポリリン酸二水素アルミニウム型層間化合物（
層間にラウリルアミンを含ませたトリポリリン酸二水素
アルミニウム型層間化合物）とトリポリリン酸二水素ア
ルミニウムを用い、防錆塗料を調製して、有機溶剤に対
する分散性を調べた。その結果を後記の分散性試験の項
における第２表に示す。In addition, the above interlayer distance is 23.40 and the interlayer compound of aluminum dihydrogen tripolyphosphate is 31.15.
Aluminum dihydrogen tripolyphosphate type intercalation compound (
An anticorrosive paint was prepared using an aluminum dihydrogen tripolyphosphate type interlayer compound containing laurylamine between the layers and aluminum dihydrogen tripolyphosphate, and its dispersibility in organic solvents was investigated. The results are shown in Table 2 in the Dispersibility Test section below.
容１３ｆの匂袋（におい袋）に、上記層間距離が１５．
６５人のトリポリリン酸二水素アルミニウム型層間化合
物（試料Ａ）、眉間距離が２３．４０人のトリポリリン
酸二水素アルミニウム型層間化合物（試料Ｂ）およびト
リポリリン酸二水素アルミニウム（試料Ｘ）をそれぞれ
０．５ｇずつ入れ、そこに１０２ｐｐ−のトリメチルア
ミン標準ガス（Ｎ ｔベース、製鉄化学株式会社製）を
３１入れた。これを室温下に放置し、経時的に匂袋中の
トリメチルアミン濃度を測定した。その結果を吸着率に
換算して第１表に示す。For a scent bag with a capacity of 13 f, the above-mentioned interlayer distance is 15.
Aluminum dihydrogen tripolyphosphate type intercalation compound of 65 people (sample A), aluminum dihydrogen tripolyphosphate type intercalation compound of 23.40 people (sample B), and aluminum dihydrogen tripolyphosphate (sample X) of 23.40 people, respectively. 5 g each, and 31 g of 102 pp- trimethylamine standard gas (Nt base, manufactured by Steel Chemical Co., Ltd.) was added thereto. This was left at room temperature, and the trimethylamine concentration in the scent bag was measured over time. The results were converted into adsorption rates and are shown in Table 1.
第 １ 表
第１表に示すように、試料Ａ（つまり、層間距離が１５
．６５人のトリポリリン酸二水素アルミニウム型層間化
合物）および試料Ｂ（つまり、層間距離が２３．４０人
のトリポリリン酸二水素アルミニウム型層間化合物）は
、試ｒ：４Ｘ（つまり、トリポリリン酸二水素アルミニ
ウム）に比べて、吸着率が１００％に達するまでの時間
が短く、本発明のトリポリリン酸二水素アルミニウム型
層間化合物が通常のトリポリリン酸二水素アルミニウム
に比べて、吸着剤として優れていることが明らかにされ
た。Table 1 As shown in Table 1, Sample A (that is, the interlayer distance is 15
．． Sample B (i.e., an aluminum dihydrogen tripolyphosphate type intercalation compound with an interlayer distance of 23.40) was sample r: 4X (i.e., aluminum dihydrogen tripolyphosphate). It is clear that the time required for the adsorption rate to reach 100% is shorter than that of the aluminum dihydrogen tripolyphosphate type intercalation compound of the present invention, which is superior as an adsorbent compared to ordinary aluminum dihydrogen tripolyphosphate. It was done.
前記層間距離が２３．４０人のトリポリリン酸二水素ア
ルミニウム型層間化合物（試料Ｂ）、層間距離が３１．
１５人のトリポリリン酸二水素アルミニウム型層間化合
物（試料Ｃ）およびトリポリリン酸二水素アルミニウム
（試料Ｘ）を用い、それぞれ下記の配合および分散条件
で塗料化をｊテい、分散粒子の経時的な粒径変化を調べ
ることによって、その分散性を評価した。その結果を第
２表に示す。The interlayer distance is 23.40 aluminum dihydrogen tripolyphosphate type interlayer compound (sample B), the interlayer distance is 31.
Using aluminum dihydrogen tripolyphosphate type intercalation compound (sample C) and aluminum dihydrogen tripolyphosphate (sample The dispersibility was evaluated by examining the change in diameter. The results are shown in Table 2.
なお、第２表中の分散粒子の粒径はっぷゲージによって
測定したものであり、配合量は重量部によるものである
。The particle diameters of the dispersed particles in Table 2 were measured using a Happu gauge, and the blending amounts are in parts by weight.
イーＪ【会
試料
酸化チタン ※１
エポキシ樹脂ワニス
※３
２４．５部
４４．５部
※２ ６０．０部
６０．０
１８９．０部
（注）※１：ティカ社製ＪＲ−６０２
（商品名）
※２ニジエル化学社製エピコート１００７（商品名）、
固形分濃度５０％に調整
※３：酢酸セロソルブ／キシレン／メチルエチルケトン
−１／１／１の混
合溶剤
ユニ」■辷【住
使用装置：サンドグラインドミル
回転数 ： １８００ｒｐ翔
ディスク：５ｃｍ（直径）
ビーズ ：アルミナ 径２＋ａｍ
ビーカー容量：２００ｍｊ！
第２表
第２表に示すように、試料Ｂ（つまり、眉間距離が２３
．４０人のトリポリリン酸二水素アルミニウム型層間化
合物）および試料Ｃ（つまり、眉間距離が３１．１５人
のトリポリリン酸二水素アルミニウム型層間化合物）は
、試料Ｘ（つまり、トリポリリン酸二水素アルミニウム
）に比べて、同じ分散時間で比較した場合の粒径が常に
小さく、本発明のトリポリリン酸二水素アルミニウム型
層間化合物が通常のトリポリリン酸二水素アルミニウム
に比べて、分散性が研れていることが明らかにされた。Titanium oxide *1 Epoxy resin varnish *3 24.5 parts 44.5 parts *2 60.0 parts 60.0 189.0 parts (Note) *1: JR-602 manufactured by Tika Corporation (Product name ) *2 Epicote 1007 (product name) manufactured by Nigel Chemical Co., Ltd.
Adjusted to solid content concentration 50% *3: Cellosolve acetate/xylene/methyl ethyl ketone - 1/1/1 mixed solvent Uni'' Equipment used: Sand grind mill Rotation speed: 1800 rpm Sho Disk: 5 cm (diameter) Beads: Alumina diameter 2+am Beaker capacity: 200mj! Table 2 As shown in Table 2, sample B (that is, the distance between the eyebrows is 23
．． Compared to sample The particle size is always small when compared at the same dispersion time, and it is clear that the aluminum dihydrogen tripolyphosphate type intercalation compound of the present invention has improved dispersibility compared to ordinary aluminum dihydrogen tripolyphosphate. It was done.
〔発明の効果〕
以上説明したように、本発明のトリポリリン酸二水素ア
ルミニウム型層間化合物は、分子量の大きいものに対す
る吸着力が大きく、また有ｍ 溶剤に対する分散性が優
れていて、吸着剤や防錆顔料として好適に使用すること
ができる。また、その大きな固体酸性、イオン交換能、
眉間距離の大きさなどの特性を利用して、触媒、触媒担
体、電極材料、光学材料、無機イオン交換体、ガス分離
剤、セラミック材料などにも使用可能である。[Effects of the Invention] As explained above, the aluminum dihydrogen tripolyphosphate type intercalation compound of the present invention has a large adsorption power for substances with a large molecular weight, and has excellent dispersibility in aqueous solvents, and is suitable for use as an adsorbent or preventive agent. It can be suitably used as a rust pigment. In addition, its large solid acidity, ion exchange ability,
Utilizing characteristics such as the distance between the eyebrows, it can also be used in catalysts, catalyst carriers, electrode materials, optical materials, inorganic ion exchangers, gas separation agents, ceramic materials, etc.
第１図は本発明のトリポリリン酸二水素アルミニウム型
層間化合物のｎ−アルキルアミンの炭素数と層間距離と
の関係を示す図である。FIG. 1 is a diagram showing the relationship between the carbon number of n-alkylamine and the interlayer distance of the aluminum dihydrogen tripolyphosphate type intercalation compound of the present invention.
Claims (1)
リポリリン酸二水素アルミニウム型層間化合物。(1) An aluminum dihydrogen tripolyphosphate type intercalation compound characterized by containing an alkylamine between the layers.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1290413A JP2938103B2 (en) | 1989-11-08 | 1989-11-08 | Aluminum dihydrogen tripolyphosphate intercalation compound |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1290413A JP2938103B2 (en) | 1989-11-08 | 1989-11-08 | Aluminum dihydrogen tripolyphosphate intercalation compound |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH03153508A true JPH03153508A (en) | 1991-07-01 |
| JP2938103B2 JP2938103B2 (en) | 1999-08-23 |
Family
ID=17755704
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1290413A Expired - Fee Related JP2938103B2 (en) | 1989-11-08 | 1989-11-08 | Aluminum dihydrogen tripolyphosphate intercalation compound |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2938103B2 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002049960A3 (en) * | 2000-12-20 | 2002-12-27 | Ciba Sc Holding Ag | Anti-corrosion agents |
| JP2005194377A (en) * | 2004-01-07 | 2005-07-21 | Nippon Paint Co Ltd | Wall modification method |
| JP2009056413A (en) * | 2007-08-31 | 2009-03-19 | National Institute Of Advanced Industrial & Technology | Cobalt ion adsorbing material and its production method |
-
1989
- 1989-11-08 JP JP1290413A patent/JP2938103B2/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2002049960A3 (en) * | 2000-12-20 | 2002-12-27 | Ciba Sc Holding Ag | Anti-corrosion agents |
| JP2005194377A (en) * | 2004-01-07 | 2005-07-21 | Nippon Paint Co Ltd | Wall modification method |
| JP4519469B2 (en) * | 2004-01-07 | 2010-08-04 | 日本ペイント株式会社 | Wall remodeling method |
| JP2009056413A (en) * | 2007-08-31 | 2009-03-19 | National Institute Of Advanced Industrial & Technology | Cobalt ion adsorbing material and its production method |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2938103B2 (en) | 1999-08-23 |
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