JPH03141145A - Polymer cement concrete product and production thereof - Google Patents
Polymer cement concrete product and production thereofInfo
- Publication number
- JPH03141145A JPH03141145A JP1276030A JP27603089A JPH03141145A JP H03141145 A JPH03141145 A JP H03141145A JP 1276030 A JP1276030 A JP 1276030A JP 27603089 A JP27603089 A JP 27603089A JP H03141145 A JPH03141145 A JP H03141145A
- Authority
- JP
- Japan
- Prior art keywords
- aggregate
- polymer
- cement concrete
- concrete product
- polymer cement
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011388 polymer cement concrete Substances 0.000 title claims abstract description 23
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000011230 binding agent Substances 0.000 claims abstract description 16
- 239000000203 mixture Substances 0.000 claims abstract description 13
- 239000004815 dispersion polymer Substances 0.000 claims abstract description 10
- 239000000843 powder Substances 0.000 claims abstract description 8
- 229920000642 polymer Polymers 0.000 claims abstract description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical class O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 10
- 239000000835 fiber Substances 0.000 claims description 9
- 239000004568 cement Substances 0.000 claims description 8
- 238000005056 compaction Methods 0.000 claims description 8
- 239000010881 fly ash Substances 0.000 claims description 5
- 239000007787 solid Substances 0.000 claims description 2
- 238000001035 drying Methods 0.000 abstract description 9
- 238000002156 mixing Methods 0.000 abstract description 5
- 238000012856 packing Methods 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract 1
- 239000004567 concrete Substances 0.000 description 24
- 238000000465 moulding Methods 0.000 description 9
- 238000009415 formwork Methods 0.000 description 8
- 239000011414 polymer cement Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- 239000000377 silicon dioxide Substances 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000000452 restraining effect Effects 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000531785 Rhynochetos jubatus Species 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
Abstract
Description
【産業上の利用分野1
本発明は、ポリマーセメンI・コンクリ−1・製品及び
その製造方法に関するものである。
【発明の背景]
いわゆる;1でリマーセメントコンクリートは、コンク
リ−1・内部にポリマーが存在するか故に、通常のコン
クリ−1・に比べて強度、耐水性及び前(集品性等の1
1性がf塁れていると言われている。
従って、例えば埋設型枠として用いることが考えられて
いる。
しかしながら、ポリマーセメントコンクリートは収縮歪
(1000x 10−’以」ユ、普通コンクリ−I・の
・乾すが収縮が600〜1oooX 10−’程度)が
大きく、これに対する対策が必要である。
すなわち、例えばセメンh 380〜500Kg/ m
’及び水150〜180に1(/n’程度、その池ボリ
マーデ仁スパーシコン念所望の特性に必要な址に調整し
たボリマーセ2インドコンクリート
枠に流し込み、水中養生又は湿空養生等の後、気中養生
してポリマーセメントコンクリートは製造される。
ところで、このようにし゛ζ製造されたポリマーセメン
トコンクリ−l−製品には、貯蔵や使用環境下において
乾燥収縮が生しる。特に、乾燥が促進される■マ境下に
長期間置かれると反り等を生じたり、あるいは使用状態
において収縮変形が拘束される場合には、内部応力が発
生し、製品の強度低下を招くことにもなる。
従って、製品の乾燥収縮変形を軽減することが大事であ
る。
【発明の開示]
本発明の目的は、ポリマーセメンI・コンクリートにお
ける乾燥収縮歪を改善することである。
この本発明の目的は.ITI骨材及び細骨材による骨材
充填率が実質上最大となるよう配合された骨材の空隙部
に、結合材及びポリマーが介在してなることを特徴とす
るポリマーセメントコンクリート製品によって達成され
る。
又、加圧振動締め固めした際に1’Il骨材及び細・1
1材による骨材充Q1率が実質上最大となるよう配合さ
れた粗骨材及び、ta骨材と、粉体結合材と、水と、ポ
リマーディスパージョンの混合物を型に入れ、加圧振動
締め固めすることを特徴とするポリマーセメントコンク
リート製品の製造方法によっても達成される。
すなわち、本発明者による研究開発が精力的に行なわれ
た結果、乾燥収縮等による歪の防止は、骨材く粗骨材及
び細骨材)が変形拘束効果を呈する如く密に詰められて
おれば達成できることに気ffいたのである。
ここで、変形拘束効果を呈する如く密に詰めるとは、粗
骨材と細骨材との混合物をポリマーセメントコンクリー
ト
振動締め固めを行った場合に、骨材の充填率が最大とな
るよう1■骨材と」骨材とを配合した材料を型枠に流し
込み、加圧振動締め固y)を行うことで達成される。
尚、鋼繊維やカーボン!a維あるいは合成樹脂繊維のよ
うな繊維を混入したポリマーセメントコンクリート製品
を製造する場αにあっては、該繊維の混入率は該製品に
要求される性能によって定まる為、この!a維の混入率
を所定のらのとして、この繊維の他に粗骨材と粗骨材と
のlIL合物をコンクリート製品成形時と同一の条1′
トで加圧振動締め固めを行った場αに、骨材の充填率が
最大となるように粗骨材と細骨材と3配きしたものと結
合材ペースi・とを混練した後、この材料を型枠に流し
込み、加圧振動締め固めを行うことで達成される。
又、コンクリートの乾燥収縮変形は結合材ペーストの部
分で起きると考えられるから、単位水量は出来るだけ少
なくすることが好ましい。例えば、水粉体結合材比は2
5〜30%程度のむのである。
尚、ここで水粉体結合材比は(ポリマーディスパージョ
ン中の水量十混線時に加える水量)/(セメント既(−
フライアッシュ量+シリカヒユーム量)で求められる値
である。
そして、コンクリートの流動性を向上させるポリマーデ
ィスパージョンは固形分換算で結合材重量の5〜10%
程度用いることができる。
又、さらにコンクリ−1・練り混ぜ時の流動性を向上さ
せる為、粒形の良い(はぼ球形)フライアッシ.lや耐
酸性向上を目的としてシリカヒユーム等の活性シリカを
セメントの一部として、セメント重量の5〜2026程
度用いることも良い。
そして、上記のような材料を所定の枠に混入し、所定の
凹凸(突出高さ0.8〜2cII+程度で、−辺が2〜
5cI++程度)を形成した加圧板を用い、005〜0
.2にヒf/′cI112程度の圧力を加えて振動成形
することで、乾燥収縮歪みが改善されたポリマーセメン
トコンクリート製品が得られる。
このようにして得たコンクリ−1・製品は、即時脱型コ
ンクリート製品に近い状態である為、加圧板を成形を麦
すぐに取り去っても、加圧板によってコンクリート製品
に形成された凹凸はその形を保持している。
又、型枠の底板及び側板を付けたまま蒸気養生笠をすれ
ば、即時脱型製品に近いコンクリ−1・製品てありなが
ら、美しい仕上げ面のものが得られる。
尚、上記の加圧板の凹凸は、加圧振動成形時に骨材を動
きづらくすることによってコンクリートの締め固め性を
向上させると共に、ポリマーセメンI・コンクリート製
品を埋設型枠として使用する際に、加圧板の凹凸から転
写された凸凹が現場打設コンクリートとの付着性を高め
ることになる。
そして、この凹凸は、加圧振動成形後に加圧板を取り除
くだけで簡単に構成できるものである。
【実施例1】
第1図(a)、(b)は本発明に係るポリマーセフイン
ドコンクリ−1−製品を得る為に用いる振動成形装置の
平面図及び側面図、第2I7I輸) 、 (b)は加圧
板の底面図及び側面図、第312]は上記の振動成形装
置に加圧板が組み合わされた概略図である。
各図中、1は振動台、2はバイブレータtIIltf4
であり、4gのバイブレータ機n1が振動台1のr面に
設けられている。
3は加圧板てあり、この加圧板3のド面に面には、突出
高さ0.8〜2c+a程度で、−・辺が2〜5cI11
程度の凹凸4が形成されている。
5は、振動台1上に配置ηされた型枠である。
そして、セメンl−1t310K)1/+n’、水jl
l 75KH/m’、フライアッシュ12Kg/I11
’、ポリマーディスパージョン址37 、2 K F1
7 Il+ ’、水扮体結合材比2596、最大寸法1
51以下のit骨材1i971に1(/+a″、K4ト
ij材敬]045にビ/悄3の混合物をll1f記のT
XII枠5内に充填し、0.05〜0.2にビf/cm
2程度の圧力を加えてflip動成形型成形、埋設型枠
用のポリマーセメン川・コンクリート体が得られる。
そして、このポリマーセメントコンクリート体の収縮歪
を調べると、これは著しく小さいものであった。[Industrial Field of Application 1] The present invention relates to polymer cement I/concrete 1/products and methods for producing the same. [Background of the Invention] So-called 1-reamer cement concrete has improved strength, water resistance, and stability (collectability, etc.) compared to ordinary concrete 1 due to the presence of polymer inside the concrete.
It is said that the first character is f base. Therefore, it is being considered to use it, for example, as an embedded formwork. However, polymer cement concrete has a large shrinkage strain (more than 1000 x 10-' when dry, ordinary concrete has a shrinkage of about 600 to 100 x 10-' when dried), and countermeasures are needed to deal with this. That is, for example, cement h 380-500Kg/m
' and 150 to 180 parts of water (about 1/n'), poured into a concrete frame of 2 indian concrete that had been adjusted to the desired properties, and after curing in water or in a humid air, submerged in the air. Polymer cement concrete is produced by curing. By the way, polymer cement concrete products produced in this way suffer from drying shrinkage during storage and usage environments. In particular, drying shrinkage occurs when drying is accelerated. If the product is left in the environment for a long period of time, it may warp, or if shrinkage and deformation are restricted during use, internal stress will occur, leading to a decrease in the strength of the product. It is important to reduce the drying shrinkage distortion of the product. [Disclosure of the Invention] The purpose of the present invention is to improve the drying shrinkage distortion in polymer cement I concrete. This is achieved by a polymer-cement concrete product characterized in that a binder and a polymer are interposed in the voids of aggregates that are blended so that the aggregate filling rate of concrete and fine aggregate is substantially maximized. In addition, when compacted by pressurized vibration, 1'Il aggregate and fine 1
A mixture of coarse aggregate, TA aggregate, powder binder, water, and polymer dispersion blended so that the aggregate filling Q1 rate of one material is substantially maximized is placed in a mold, and the mixture is subjected to pressurized vibration. It is also achieved by a method for producing polymer-cement concrete products, which is characterized by compaction. In other words, as a result of vigorous research and development by the present inventors, distortion due to drying shrinkage, etc. can be prevented by ensuring that the aggregates (coarse aggregates and fine aggregates) are tightly packed to exhibit a deformation restraining effect. I was nervous about what I could accomplish. Here, packing densely so as to exhibit a deformation restraining effect means that when a mixture of coarse aggregate and fine aggregate is subjected to vibration compaction of polymer cement concrete, the filling rate of aggregate is maximized by 1. This is achieved by pouring a mixture of aggregate and aggregate into a mold and performing pressurized vibration compaction. In addition, steel fiber and carbon! When manufacturing polymer cement concrete products containing fibers such as a-fibers or synthetic resin fibers, the mixing rate of the fibers is determined by the performance required of the product. In addition to this fiber, a mixture of coarse aggregate and coarse aggregate was added in the same row 1' as when forming the concrete product, with the mixing ratio of a fiber being set to a predetermined value.
When pressurized vibration compaction was performed at step α, after kneading coarse aggregate and fine aggregate in three parts and binder paste i so that the aggregate filling rate was maximized, This is achieved by pouring this material into a mold and subjecting it to pressure vibration compaction. Furthermore, since drying shrinkage deformation of concrete is thought to occur in the binder paste portion, it is preferable to reduce the unit amount of water as much as possible. For example, the water powder binder ratio is 2
It consumes about 5-30%. Here, the water/powder binder ratio is (amount of water in the polymer dispersion)/(amount of water added at the time of mixing)/(cement already (-)
This is the value determined by the amount of fly ash + amount of silica hume). Polymer dispersion, which improves the fluidity of concrete, accounts for 5 to 10% of the weight of the binder in terms of solid content.
It can be used to some extent. In addition, in order to further improve the fluidity of concrete 1 and mixing, fly ash with good particle shape (spherical shape) is used. It is also good to use activated silica such as silica hume as a part of cement for the purpose of improving acid resistance and acid resistance. Then, the above materials are mixed into a predetermined frame, and a predetermined unevenness (protrusion height of about 0.8 to 2 cII+, negative side of about 2 to 2 cm) is formed.
005 to 0 using a pressure plate formed with
.. A polymer cement concrete product with improved drying shrinkage distortion can be obtained by applying a pressure of approximately 112 h f/'cI to 2 and performing vibration molding. The concrete product obtained in this way is in a state close to that of an instant demolding concrete product, so even if the molding is immediately removed from the pressure plate, the unevenness formed on the concrete product by the pressure plate will remain in its shape. is held. Furthermore, if a steam curing shade is applied with the bottom and side plates of the formwork attached, a concrete product close to that of an instant demolding product but with a beautiful finished surface can be obtained. The above-mentioned unevenness of the pressure plate improves the compaction of concrete by making it difficult for the aggregate to move during pressurized vibration molding, and also improves the compaction properties of the concrete when using Polymer Cement I/concrete products as buried formwork. The unevenness transferred from the unevenness of the pressure plate increases the adhesion with the concrete poured on site. The unevenness can be easily formed by simply removing the pressure plate after pressure vibration molding. [Example 1] Figures 1 (a) and (b) are a plan view and a side view of a vibration molding device used to obtain a polymer sealed concrete 1 product according to the present invention. ) is a bottom view and a side view of the pressure plate, and 312] is a schematic diagram of the pressure plate combined with the above-mentioned vibration molding device. In each figure, 1 is a vibration table, 2 is a vibrator tIIltf4
A 4g vibrator machine n1 is installed on the r-plane of the vibration table 1. 3 has a pressure plate, and the protrusion height is about 0.8 to 2c+a, and the - side is 2 to 5cI11 on the front side of the pressure plate 3.
A certain degree of unevenness 4 is formed. 5 is a formwork placed on the vibration table 1. And cement l-1t310K)1/+n', water jl
l 75KH/m', fly ash 12Kg/I11
', Polymer dispersion site 37, 2K F1
7 Il+', water body binder ratio 2596, maximum dimension 1
51 or less it aggregate 1i971 to 1 (/+a'', K4 material) 045 to the mixture of Bi/悄3 to ll1f T
Fill in the XII frame 5 and set the bif/cm to 0.05 to 0.2.
By applying a pressure of about 2 degrees, a polymer cement concrete body for use in flip dynamic molding and buried formwork is obtained. When the shrinkage strain of this polymer cement concrete body was examined, it was found to be extremely small.
【実施例2】
実施例1における混合物の組成を、セメント量350に
ビ/lコ、水量83にビ/輸コ、シリカヒユーム旦35
Kg/nl’、フライアッシュ量35Kg/+11’、
ポリマーディスパージョンJi70Kg/+・3、水粉
体結合材比28%、最大71法1511以下の1■骨材
旦738Kg/m’、細骨材鼠1099Kg/鴎1、鋼
繊維78.5KH/m″として同様に行い、埋設型枠用
のポリマーセメントコンクリート・体を得る。
そして、このポリマーセメントコンクリート体の収縮歪
を調べると、これは著しく小さいものであった。[Example 2] The composition of the mixture in Example 1 was as follows: cement amount: 350 V/L, water amount: 83 V/L, silica hume: 35%
Kg/nl', fly ash amount 35Kg/+11',
Polymer dispersion Ji 70Kg/+・3, water/powder binder ratio 28%, maximum 71 method 1511 or less 1 ■ Aggregate 738Kg/m', fine aggregate 1099Kg/Kagu 1, steel fiber 78.5KH/m '' to obtain a polymer cement concrete body for buried formwork. When the shrinkage strain of this polymer cement concrete body was examined, it was found to be extremely small.
【実施例3】
実施例1における混合物の組成分、セメント量300K
H/n’、水足(i4Kg/m’、シリカヒユームff
L60h/餉3、ポリマーディスパージョン60に+l
/m’、水粉体結り打止26%、最大寸法15mm以下
の粗骨材呈962Kg/輸’、a+骨材量1034にビ
/横1として同様に行い、埋設型枠用のポリマーセメン
トコンクリ−1−Ikと得る。
そして、このボリマーセメ装置・コンクリ−1・体の収
縮歪を調べると、これは著し・く小さいらので1Pンっ
た。[Example 3] Composition of the mixture in Example 1, cement amount 300K
H/n', water foot (i4Kg/m', silica hium ff
L60h/3, Polymer dispersion 60 +l
/m', water powder binding 26%, coarse aggregate with maximum dimension of 15 mm or less 962Kg/m', a+aggregate amount 1034 and Bi/horizontal 1, and polymer cement for buried formwork. Concrete 1-Ik is obtained. When we investigated the shrinkage strain of this polymer cement device, concrete 1, and body, we found that it was extremely small, so it was 1P.
第1図(a)、(b)は本発明に係るポリマーセメント
コンクリ−1〜製晶企得る為に用いる振SJノ成形装置
の平面図及び側面図、第2図(、) 、 (b)は加圧
板の底面図及び側面図、第3図は上記σ)振動成形装置
に加圧板が組み合わされた概略図である。
1・・振動台、2・・・パイブレーク機構、3・・加圧
板、11 凹凸、5・・型枠。FIGS. 1(a) and (b) are a plan view and a side view of a shaking SJ molding apparatus used for producing polymer cement concrete 1 to crystallization according to the present invention, and FIGS. 2(a) and (b) are 3 is a bottom view and a side view of the pressure plate, and FIG. 3 is a schematic diagram of the pressure plate combined with the above-mentioned σ) vibration molding device. 1. Vibration table, 2. Pie break mechanism, 3. Pressure plate, 11 unevenness, 5. Formwork.
Claims (7)
となるよう配合された骨材の空隙部に、結合材及びポリ
マーが介在してなることを特徴とするポリマーセメント
コンクリート製品。(1) A polymer cement concrete product characterized in that a binder and a polymer are interposed in the voids of aggregate mixed so that the aggregate filling rate of coarse aggregate and fine aggregate is substantially maximized. .
ンクリート製品において、繊維がさらに充填されてなる
もの。(2) The polymer cement concrete product according to claim 1, which is further filled with fibers.
ンクリート製品において、水結合材比が25〜30%で
あるもの。(3) A polymer cement concrete product according to claim 1, in which the water binder ratio is 25 to 30%.
ンクリート製品において、ポリマーディスパージョンの
添加量が固形分で結合材の5〜10%であるもの。(4) The polymer cement concrete product according to claim 1, in which the amount of polymer dispersion added is 5 to 10% of the binder as a solid content.
ンクリート製品において、フライアッシュがセメントの
5〜20%含まれてなるもの。(5) The polymer cement concrete product according to claim 1, wherein fly ash is contained in an amount of 5 to 20% of the cement.
ンクリート製品において、活性シリカがセメントの5〜
20%含まれてなるもの。(6) In the polymer cement concrete product according to claim 1, the activated silica is
Contains 20%.
る骨材充填率が実質上最大となるよう配合された粗骨材
及び細骨材と、粉体結合材と、水と、ポリマーディスパ
ージョンの混合物を型に入れ、加圧振動締め固めするこ
とを特徴とするポリマーセメントコンクリート製品の製
造方法。(7) Coarse aggregate and fine aggregate, powder binder, and water that are blended so that the aggregate filling rate of coarse aggregate and fine aggregate is substantially maximized when compacted by pressurized vibration. , a method for producing a polymer cement concrete product, characterized in that a mixture of polymer dispersion is placed in a mold and subjected to pressure vibration compaction.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1276030A JPH03141145A (en) | 1989-10-25 | 1989-10-25 | Polymer cement concrete product and production thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1276030A JPH03141145A (en) | 1989-10-25 | 1989-10-25 | Polymer cement concrete product and production thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH03141145A true JPH03141145A (en) | 1991-06-17 |
JPH0567581B2 JPH0567581B2 (en) | 1993-09-27 |
Family
ID=17563817
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1276030A Granted JPH03141145A (en) | 1989-10-25 | 1989-10-25 | Polymer cement concrete product and production thereof |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH03141145A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006036607A (en) * | 2004-07-29 | 2006-02-09 | Taiheiyo Cement Corp | Polymer cement mortar hardened body |
JP2017179928A (en) * | 2016-03-30 | 2017-10-05 | 太平洋マテリアル株式会社 | Construction method for pavement concrete, and pavement concrete |
JP2018140899A (en) * | 2017-02-28 | 2018-09-13 | 太平洋マテリアル株式会社 | Polymer cement concrete and method for applying the same |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01244808A (en) * | 1988-03-28 | 1989-09-29 | Showa Shell Sekiyu Kk | Manufacture of cement molded matter having high strength and precise structure |
-
1989
- 1989-10-25 JP JP1276030A patent/JPH03141145A/en active Granted
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01244808A (en) * | 1988-03-28 | 1989-09-29 | Showa Shell Sekiyu Kk | Manufacture of cement molded matter having high strength and precise structure |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2006036607A (en) * | 2004-07-29 | 2006-02-09 | Taiheiyo Cement Corp | Polymer cement mortar hardened body |
JP2017179928A (en) * | 2016-03-30 | 2017-10-05 | 太平洋マテリアル株式会社 | Construction method for pavement concrete, and pavement concrete |
JP2018140899A (en) * | 2017-02-28 | 2018-09-13 | 太平洋マテリアル株式会社 | Polymer cement concrete and method for applying the same |
Also Published As
Publication number | Publication date |
---|---|
JPH0567581B2 (en) | 1993-09-27 |
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