JPH03139545A - Chlorosulfonated polyethylene composition - Google Patents
Chlorosulfonated polyethylene compositionInfo
- Publication number
- JPH03139545A JPH03139545A JP27594989A JP27594989A JPH03139545A JP H03139545 A JPH03139545 A JP H03139545A JP 27594989 A JP27594989 A JP 27594989A JP 27594989 A JP27594989 A JP 27594989A JP H03139545 A JPH03139545 A JP H03139545A
- Authority
- JP
- Japan
- Prior art keywords
- chlorosulfonated polyethylene
- alicyclic epoxy
- pts
- epoxy compound
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229920002681 hypalon Polymers 0.000 title claims abstract description 15
- 239000000203 mixture Substances 0.000 title claims description 10
- 239000004593 Epoxy Substances 0.000 claims abstract description 15
- 125000002723 alicyclic group Chemical group 0.000 claims abstract description 11
- 150000001875 compounds Chemical class 0.000 claims description 13
- 230000006835 compression Effects 0.000 abstract description 7
- 238000007906 compression Methods 0.000 abstract description 7
- 238000013329 compounding Methods 0.000 abstract description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract description 4
- 239000000460 chlorine Substances 0.000 abstract description 4
- 229920000092 linear low density polyethylene Polymers 0.000 abstract description 4
- 239000004707 linear low-density polyethylene Substances 0.000 abstract description 4
- 229910052801 chlorine Inorganic materials 0.000 abstract description 3
- YXALYBMHAYZKAP-UHFFFAOYSA-N 7-oxabicyclo[4.1.0]heptan-4-ylmethyl 7-oxabicyclo[4.1.0]heptane-4-carboxylate Chemical compound C1CC2OC2CC1C(=O)OCC1CC2OC2CC1 YXALYBMHAYZKAP-UHFFFAOYSA-N 0.000 abstract 1
- 230000002411 adverse Effects 0.000 abstract 1
- 239000011810 insulating material Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 7
- 239000003795 chemical substances by application Substances 0.000 description 6
- 229920001971 elastomer Polymers 0.000 description 6
- 238000002156 mixing Methods 0.000 description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- -1 propylene Chemical compound 0.000 description 3
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000004073 vulcanization Methods 0.000 description 2
- QHOMCUUGNPEUCT-UHFFFAOYSA-N 2-(7-oxabicyclo[4.1.0]heptan-4-yl)spiro[1,3-dioxane-5,4'-7-oxabicyclo[4.1.0]heptane] Chemical compound C1CC2OC2CC1(CO1)COC1C1CCC2OC2C1 QHOMCUUGNPEUCT-UHFFFAOYSA-N 0.000 description 1
- NHJIDZUQMHKGRE-UHFFFAOYSA-N 7-oxabicyclo[4.1.0]heptan-4-yl 2-(7-oxabicyclo[4.1.0]heptan-4-yl)acetate Chemical compound C1CC2OC2CC1OC(=O)CC1CC2OC2CC1 NHJIDZUQMHKGRE-UHFFFAOYSA-N 0.000 description 1
- LCFVJGUPQDGYKZ-UHFFFAOYSA-N Bisphenol A diglycidyl ether Chemical compound C=1C=C(OCC2OC2)C=CC=1C(C)(C)C(C=C1)=CC=C1OCC1CO1 LCFVJGUPQDGYKZ-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- DJUWPHRCMMMSCV-UHFFFAOYSA-N bis(7-oxabicyclo[4.1.0]heptan-4-ylmethyl) hexanedioate Chemical compound C1CC2OC2CC1COC(=O)CCCCC(=O)OCC1CC2OC2CC1 DJUWPHRCMMMSCV-UHFFFAOYSA-N 0.000 description 1
- LMMDJMWIHPEQSJ-UHFFFAOYSA-N bis[(3-methyl-7-oxabicyclo[4.1.0]heptan-4-yl)methyl] hexanedioate Chemical compound C1C2OC2CC(C)C1COC(=O)CCCCC(=O)OCC1CC2OC2CC1C LMMDJMWIHPEQSJ-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- OSVXSBDYLRYLIG-UHFFFAOYSA-N chlorine dioxide Inorganic materials O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 description 1
- 235000019398 chlorine dioxide Nutrition 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- CFFOYHZILKHZDE-UHFFFAOYSA-N cyclohexylmethyl 7-oxabicyclo[4.1.0]heptane-4-carboxylate Chemical compound C1CC2OC2CC1C(=O)OCC1CCCCC1 CFFOYHZILKHZDE-UHFFFAOYSA-N 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 229920003244 diene elastomer Polymers 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 229920003049 isoprene rubber Polymers 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 229920004889 linear high-density polyethylene Polymers 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920001084 poly(chloroprene) Polymers 0.000 description 1
- 238000010094 polymer processing Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000010058 rubber compounding Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- YBBRCQOCSYXUOC-UHFFFAOYSA-N sulfuryl dichloride Chemical compound ClS(Cl)(=O)=O YBBRCQOCSYXUOC-UHFFFAOYSA-N 0.000 description 1
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
- 229960002447 thiram Drugs 0.000 description 1
- DQZNLOXENNXVAD-UHFFFAOYSA-N trimethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OC)(OC)OC)CCC2OC21 DQZNLOXENNXVAD-UHFFFAOYSA-N 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、加硫物の物性、とりわけ疲労特性の優れたク
ロロスルホン化ポリエチレン組成物に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a chlorosulfonated polyethylene composition that has excellent physical properties of a vulcanizate, particularly excellent fatigue properties.
クロロスルホン化ポリエチレン（以下、しばしばｒＣ３
ＭＪと略称する）は耐候性、耐オゾン性、耐熱性、耐油
性、耐化学薬品性及び着色性等にすぐれたエラストマー
素材として知られており、自動車用各種ホースカバー、
電線被覆、耐酸ホース、引布、ガスホースカバー、ブー
ツ、ベルト、シート、塗料、溶液コーティング及びルー
フィング材等、広い分野で使用されている。しかし、最
近は自動車産業をはじめとして、その要求特性はよりき
びしくなってきており、様々な改良が望まれている。な
かでも、耐屈曲亀裂成長性等に代表される機械的疲労性
についての改良の要求は強いものがある。Chlorosulfonated polyethylene (hereinafter often referred to as rC3
MJ) is known as an elastomer material with excellent weather resistance, ozone resistance, heat resistance, oil resistance, chemical resistance, and coloring property, and is used for various hose covers for automobiles,
It is used in a wide range of fields, including electric wire coatings, acid-resistant hoses, canvas, gas hose covers, boots, belts, sheets, paints, solution coatings, and roofing materials. However, recently, the required characteristics have become more stringent, including in the automobile industry, and various improvements are desired. Among these, there is a strong demand for improvement in mechanical fatigue properties such as flex crack growth resistance.
しかしながら、Ｃ３Ｍは、天然ゴム、イソプレンゴム、
クロロプレンゴム等のジエン系ゴムと比較した場合、−
殻内に耐屈曲亀裂成長性に劣る欠点を有している。However, C3M is natural rubber, isoprene rubber,
When compared with diene rubber such as chloroprene rubber, -
It has the disadvantage of poor resistance to flex crack growth within the shell.
従来よりＣ３Ｍの疲労性改良を目的として多くの手法が
提案されている。−例としては、可塑剤の添加があげら
れる。ナフテン系、パラフィン系等の石油系、あるいは
植物油系オイルを加えることで、−ａにゴムに使われて
いるカーボンブラック等の充填剤の分散が良くなり、疲
労性が良くなることが知られている。しかし、Ｃ３Ｍに
可塑剤を添加する方法は、少量の場合には効果が認めら
れず、また多量に使用すると加硫物の強度や硬度が低下
する。Many methods have been proposed for the purpose of improving the fatigue properties of C3M. - Examples include the addition of plasticizers. It is known that adding petroleum-based oils such as naphthene-based or paraffin-based oils, or vegetable oil-based oils to -a improves the dispersion of fillers such as carbon black used in rubber and improves fatigue properties. There is. However, the method of adding a plasticizer to C3M is not effective when a small amount is used, and the strength and hardness of the vulcanizate decreases when a large amount is used.
一方、米国特許筒３．１４７．３１５号明細書には、Ｃ
３Ｍの製造工程（乾燥工程等）での熱履歴による劣化を
防止する目的で、ビスフェノールＡジグリシジルエーテ
ル等のエポキシ化合物を添加したＣ５Ｍ＆Ｉｌ成物が開
示されている０本発明者らの検討によれば、上記エポキ
シ化合物をＣ３Ｍに添加することにより、加硫物の屈曲
亀裂成長性を改良できる。しかしながら、この方法では
、他の物性、特に圧縮永久歪を増大させる欠点を有して
いる。On the other hand, in U.S. Patent No. 3.147.315, C.
A C5M&Il composition is disclosed in which an epoxy compound such as bisphenol A diglycidyl ether is added for the purpose of preventing deterioration due to heat history during the manufacturing process (drying process, etc.) of 3M. According to the study by the present inventors, For example, by adding the above-mentioned epoxy compound to C3M, the flexural crack growth properties of the vulcanizate can be improved. However, this method has the disadvantage of increasing other physical properties, particularly compression set.
本発明の目的は、高い耐疲労特性を持ち、かつ圧縮永久
歪の良好なＣ３ＭＭ１成物を提供することにある。An object of the present invention is to provide a C3MM1 composition having high fatigue resistance and good compression set.
〔課題を解決するための手段及び作用〕本発明者らは、
鋭意研究を行った結果、Ｃ３Ｍに特定のエポキシ化合物
を含有させることによって、圧縮永久歪を悪化させるこ
となく耐疲労性を著しく改良できることを見い出し、本
発明に到達した。[Means and effects for solving the problem] The present inventors,
As a result of extensive research, it was discovered that by incorporating a specific epoxy compound into C3M, fatigue resistance could be significantly improved without worsening compression set, and the present invention was achieved.
即ち、本発明は、クロロスルホン化ポリエチレン１００
重量部に対して、脂環式エポキシ化合物を少なくとも０
．５重量部含有することを特徴とするクロロスルホン化
ポリエチレン組成物に関するものである。That is, the present invention provides chlorosulfonated polyethylene 100
Based on the weight part, at least 0 of the alicyclic epoxy compound
．． The present invention relates to a chlorosulfonated polyethylene composition containing 5 parts by weight.
以下に本発明を更に説明する。The invention will be further explained below.
本発明で用いるクロロスルホン化ポリエチレン系エラス
トマーは線状高密度ポリエチレン（ＩＩ Ｄ Ｐ Ｅ
）、線状低密度ポリエチレン（ＬＬＤｒ’ＥＳＶＬＤＰ
ｔり、分岐状低密度ポリエチレン（ＬＤＰＲ）等密度０
．８８ ｇ ／ｃｃ〜０．９７ ｇ ／ｃｃ、分子量１
万〜８０万程度のエチレン単独重合体もしくはエチレン
とエチレンと共重合可能な単量体（たとえばプロピレン
、ｌ−ブテン、４−メチルペンテン−１１等のα−オレ
フィン又は酢酸ビニル等）との共重合体（ポリエチレン
系重合体）をクロロスルホン化させて得られるものであ
る。クロロスルホン化反応は溶媒にポリエチレン系重合
体を溶解し、ラジカル触媒（たとえば２．２′−アゾビ
スイソブチロニトリル）の存在下に塩素及び亜硫酸ガス
及び／又は塩化スルフリルを反応させることにより実施
される０通常クロロスルホン化ポリエチレン系エラスト
マーは約２０〜４５重量％の塩素及び０．２〜２６０重
景％の硫黄を含有している。The chlorosulfonated polyethylene elastomer used in the present invention is linear high-density polyethylene (II D P E
), linear low density polyethylene (LLDr'ESVLDP
Branched low density polyethylene (LDPR) equal density 0
．． 88 g/cc~0.97 g/cc, molecular weight 1
Copolymerization of ethylene homopolymer or ethylene with a monomer copolymerizable with ethylene (e.g., propylene, l-butene, α-olefin such as 4-methylpentene-11, or vinyl acetate) of approximately 800,000 to 800,000 It is obtained by chlorosulfonating a polymer (polyethylene polymer). The chlorosulfonation reaction is carried out by dissolving the polyethylene polymer in a solvent and reacting it with chlorine and sulfur dioxide gas and/or sulfuryl chloride in the presence of a radical catalyst (for example, 2,2'-azobisisobutyronitrile). Typical chlorosulfonated polyethylene elastomers contain about 20 to 45 weight percent chlorine and 0.2 to 260 weight percent sulfur.
特に、機械的強度と同時に低温特性及び動的疲労特性を
高度に要求する組成物の場合には密度０．９２５ ｇ／
ｃｃ以下の線状低密度ポリエチレン（ＬＬＤＰＥ、 Ｖ
ＬＤＰＥ）を原料とし、塩素量を２３〜３７重量％程度
とするのが好ましい。In particular, in the case of compositions that require high mechanical strength as well as low temperature properties and dynamic fatigue properties, a density of 0.925 g/
Linear low density polyethylene (LLDPE, V
LDPE) is used as the raw material, and the amount of chlorine is preferably about 23 to 37% by weight.
次に、本発明で用いられる脂環式エポキシ化合物として
は、３，４−エポキシシクロヘキシルメチル−３，４−
エポキシシクロヘキサンカルボキシレート、３−（３，
４−エポキシシクロヘキシル）−８，９−エポキシ−２
，４−ジオキサスピロ（５，５）ウンデカン、ビス（３
，４−エポキシ−６−メチルシクロヘキシルメチル）ア
ジペート、ビス（３，４−エポキシシクロヘキシルメチ
ル）アジペート、シクロヘキシルメチル−３，４エポキ
シシクロヘキサンカルボキシレート、β−（３，４−エ
ポキシシクロヘキシル）エチルトリメトキシシラン等が
挙げられるが、これらに限定するものではない。また、
その添加方法としては、Ｃ３Ｍの製造工程で予め添加し
ても、あるいは他の配合剤と同様にＣ３Ｍのゴム配合工
程で添加してもよい。Next, as the alicyclic epoxy compound used in the present invention, 3,4-epoxycyclohexylmethyl-3,4-
Epoxycyclohexane carboxylate, 3-(3,
4-epoxycyclohexyl)-8,9-epoxy-2
,4-dioxaspiro(5,5)undecane, bis(3
, 4-epoxy-6-methylcyclohexylmethyl)adipate, bis(3,4-epoxycyclohexylmethyl)adipate, cyclohexylmethyl-3,4epoxycyclohexanecarboxylate, β-(3,4-epoxycyclohexyl)ethyltrimethoxysilane etc., but is not limited to these. Also,
As for its addition method, it may be added in advance during the manufacturing process of C3M, or it may be added during the rubber compounding process of C3M like other compounding agents.
脂環式エポキシ化合物の添加量としては、Ｃ５Ｍ１００
重量部に対して０．５重量部以上、好ましくは１〜１０
重量部の範囲である。脂環式エポキシ化合物の添加量が
０．５重量部未満の場合、疲労性が改良されず本発明の
目的を達成しない。また１０重量部を越えて添加しても
疲労性はそれ以上に向上がなかなか望めない。The amount of the alicyclic epoxy compound added is C5M100
0.5 parts by weight or more, preferably 1 to 10 parts by weight
Parts by weight range. If the amount of the alicyclic epoxy compound added is less than 0.5 parts by weight, fatigue properties will not be improved and the object of the present invention will not be achieved. Further, even if more than 10 parts by weight is added, it is difficult to expect any further improvement in fatigue properties.
また、本発明の組成物には、上記の必須成分のほかゴム
業界及び樹脂業界において一般に使用される各種配合剤
、例えば、ペンタエリトリトール、Ｎ、Ｎ”−ｍ−フェ
ニレンビスマレイミド、テトラメチルチウラムジスルフ
ィド等の加硫剤や加硫促進剤、充填剤、補強剤、加工助
剤、可塑剤、老化防止剤、安定剤、顔料、難燃剤等を必
要に応じて選定、配合して用いることができる。In addition to the above-mentioned essential components, the composition of the present invention also contains various compounding agents commonly used in the rubber and resin industries, such as pentaerythritol, N,N"-m-phenylene bismaleimide, and tetramethylthiuram disulfide. Vulcanizing agents, vulcanization accelerators, fillers, reinforcing agents, processing aids, plasticizers, anti-aging agents, stabilizers, pigments, flame retardants, etc. can be selected and blended as necessary. .
この時の配合方法としては、通常ポリマーの加工分野に
おいて用いられる任意の方法が適用できる。例えば、ミ
キシングロール、バンバリーミキサ−１各種ニーダー２
混練作用を有する押出機等が使用できる。As the blending method at this time, any method commonly used in the field of polymer processing can be applied. For example, mixing rolls, Banbury mixer 1 various kneaders 2
An extruder or the like having a kneading function can be used.
〔実施例］
以下に実施例を示し、本発明についてさらに具体的に説
明するが、本発明はこれらの実施例のみに限定されるも
のではない。[Example] The present invention will be described in more detail by referring to Examples below, but the present invention is not limited to these Examples.
実施例１〜３、比較例１〜３
線状低密度ポリエチレン（密度０．９２ ）を原料とし
て作製した塩素含有量３０重景％、硫黄含有量１．１重
量％、生ゴムムーニー粘度７０ （ＭＬ＋。４．１００
°Ｃ）のクロロスルホン化ポリエチレンに脂環式エポキ
シ化合物及びその他の配合剤を表１及び表２に示す割合
で配合した。配合操作はミキシングロールにて行い、表
１及び表２に示す種々の配合剤を逐次添加した。１６０
°Ｃ１で表２に示す時間だけプレス加硫して加硫物を得
た。Examples 1 to 3, Comparative Examples 1 to 3 Raw rubber Mooney viscosity 70 (ML+ .4.100
A cycloaliphatic epoxy compound and other compounding agents were blended into chlorosulfonated polyethylene at a temperature of 10°C (°C) in the proportions shown in Tables 1 and 2. The blending operation was performed using a mixing roll, and the various blending agents shown in Tables 1 and 2 were successively added. 160
Press vulcanization was performed at 1 °C for the time shown in Table 2 to obtain a vulcanized product.
得られた加硫物について、常態物性、圧縮永久歪及び屈
曲亀裂成長性を試験し、表２に示す結果を得た。尚、常
態物性、圧縮永久歪及び屈曲亀裂成長性の測定は、ＪＩ
Ｓ Ｋ６３０１に準拠して行った。The obtained vulcanizate was tested for normal physical properties, compression set, and flexural crack growth, and the results shown in Table 2 were obtained. In addition, measurements of normal physical properties, compression set, and flexural crack growth are conducted by JI
It was carried out in accordance with SK6301.
表２の実施例１〜３は、クロロスルホン化ポリエチレン
に対して脂環式エポキシ化合物を特許請求の範囲内の量
添加した場合である。比較例１は、脂環式エポキシ化合
物を添加しない場合、比較例２は脂環式エポキシ化合物
の添加量が０．５重量部未満の場合である。また、比較
例３は、脂環式でないエポキシ化合物を添加した場合で
ある。Examples 1 to 3 in Table 2 are cases where an alicyclic epoxy compound was added in an amount within the claimed range to chlorosulfonated polyethylene. Comparative Example 1 is a case in which no alicyclic epoxy compound is added, and Comparative Example 2 is a case in which the amount of an alicyclic epoxy compound added is less than 0.5 parts by weight. Moreover, Comparative Example 3 is a case where a non-alicyclic epoxy compound was added.
表２の結果から明らかなように、本発明のＣ５Ｍ組成物
は、屈曲亀裂成長性、すなわち疲労性が極めて優れ、か
つ圧縮永久歪が良好であることが判る。As is clear from the results in Table 2, it can be seen that the C5M composition of the present invention has extremely excellent flex crack growth properties, that is, fatigue properties, and good compression set.
表１゜
配合処方
１７東海カーボン■製（商品名）ＭＡＦジースト１１６
２ゝ 日本シリカ■製 （商品名）ニブシールＶＮ３３
）薬品名は表２参照
〔発明の効果〕
以上説明した様に、本発明のクロロスルホン化ポリエチ
レン組成物は、耐疲労性に優れており、各種工業用部品
等に用いられ、とりわけ自動車用ブーツ類、ベルト類、
ホース材、防振材等の耐久性を要求される用途に好適で
ある。Table 1゜Mixing Prescription 17 Manufactured by Tokai Carbon ■ (Product name) MAF Giest 116
2. Made by Nippon Silica (Product name) Nibseal VN33
) For chemical names, see Table 2. [Effects of the Invention] As explained above, the chlorosulfonated polyethylene composition of the present invention has excellent fatigue resistance and is used for various industrial parts, especially automobile boots. types, belts,
Suitable for applications that require durability, such as hose materials and vibration isolating materials.
Claims (1)
、少なくとも０．５重量部の脂環式エポキシ化合物を含
有することを特徴とするクロロスルホン化ポリエチレン
組成物。A chlorosulfonated polyethylene composition comprising at least 0.5 parts by weight of an alicyclic epoxy compound based on 100 parts by weight of chlorosulfonated polyethylene.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP27594989A JPH03139545A (en) | 1989-10-25 | 1989-10-25 | Chlorosulfonated polyethylene composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP27594989A JPH03139545A (en) | 1989-10-25 | 1989-10-25 | Chlorosulfonated polyethylene composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03139545A true JPH03139545A (en) | 1991-06-13 |
Family
ID=17562671
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP27594989A Pending JPH03139545A (en) | 1989-10-25 | 1989-10-25 | Chlorosulfonated polyethylene composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH03139545A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0687701A1 (en) | 1994-06-16 | 1995-12-20 | Dow Corning Corporation | Preparation of polydiorganosiloxane and sulfonated polyolefin blends |
| JP2018053235A (en) * | 2016-09-26 | 2018-04-05 | アキレス株式会社 | Chlorosulfonated polyethylene rubber composition and chlorosulfonated polyethylene rubber coated fabric |
-
1989
- 1989-10-25 JP JP27594989A patent/JPH03139545A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0687701A1 (en) | 1994-06-16 | 1995-12-20 | Dow Corning Corporation | Preparation of polydiorganosiloxane and sulfonated polyolefin blends |
| US5488087A (en) * | 1994-06-16 | 1996-01-30 | Dow Corning Corporation | Preparation of polydiorganosiloxane and sulfonated polyolefin blends |
| JP2018053235A (en) * | 2016-09-26 | 2018-04-05 | アキレス株式会社 | Chlorosulfonated polyethylene rubber composition and chlorosulfonated polyethylene rubber coated fabric |
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