JPH0312816A - Thin metallic film type magnetic recording medium - Google Patents

Thin metallic film type magnetic recording medium

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Publication number
JPH0312816A
JPH0312816A JP14764189A JP14764189A JPH0312816A JP H0312816 A JPH0312816 A JP H0312816A JP 14764189 A JP14764189 A JP 14764189A JP 14764189 A JP14764189 A JP 14764189A JP H0312816 A JPH0312816 A JP H0312816A
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JP
Japan
Prior art keywords
magnetic
film
recording medium
alloy
magnetic recording
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP14764189A
Other languages
Japanese (ja)
Other versions
JP2552546B2 (en
Inventor
Toshiaki Morichika
森近 俊明
Toshio Tani
谷 登志夫
Hideo Koshimoto
越本 秀生
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kubota Corp
Original Assignee
Kubota Corp
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Filing date
Publication date
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Priority to JP1147641A priority Critical patent/JP2552546B2/en
Publication of JPH0312816A publication Critical patent/JPH0312816A/en
Application granted granted Critical
Publication of JP2552546B2 publication Critical patent/JP2552546B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

PURPOSE:To obtain the thin metallic film type magnetic recording medium for high density recording having excellent noise characteristics by forming a magnetic film consisting of a specific metal system on a nonmagnetic substrate. CONSTITUTION:The magnetic film is constituted of the alloy of the component compsn. expressed by formula I. In the formula I, M denotes two or three kinds of the elements selected from Ta, Nb and V; x is to z denote atomic compsn. ratios; x is 0.05 to 0.25, y is 0.07 to 0.14, z is 0.02 to 0.10. Namely, this CoNiCr alloy is the alloy having a high coercive force and high residual magnetic flux density. The deposition of the M element at the grain boundaries of the Cr and the isolation of the magnetic particles are resulted and the coercive force is increased if the proper ratios of the plural elements expressed by M are added in combination thereto. The effect of improving the noise characteristics is obtd. in this way.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明はノイズ特性にすくれた金属薄膜型磁気記録媒体
に関する。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a metal thin film magnetic recording medium with poor noise characteristics.

〔従来の技術〕[Conventional technology]

近時、磁気記録装置の記録媒体として、非磁性基体上の
磁性膜を強磁性金属薄膜とした金属薄膜型磁気記録媒体
が、その高密度記録性により、従来の所謂塗布型磁気記
録媒体に置き代わりつつある。その非磁性基体上に形成
される強磁性金属薄膜の成分構成は、磁気的性質、記録
再生特性、耐候性等の総合的評価に一基づいて決定され
、−船釣にCo、、CoNi系、CoCr系、またはC
oNiCr系合金が使用されている。
Recently, metal thin film magnetic recording media, in which the magnetic film on a nonmagnetic substrate is a ferromagnetic metal thin film, have been used as recording media for magnetic recording devices, and due to their high density recording properties, they have been replaced by conventional so-called coated magnetic recording media. It is being replaced. The composition of the ferromagnetic metal thin film formed on the non-magnetic substrate is determined based on a comprehensive evaluation of magnetic properties, recording/reproducing characteristics, weather resistance, etc. CoCr-based or C
oNiCr alloy is used.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

上記金属薄膜型磁気記録媒体は、これまでの塗布型磁気
記録媒体にまさる高密度の記録が可能であるが、次世代
の磁気記録媒体としては更に記録密度の向上が要求され
る。そのためには、変調ノイズや再生波形ピークシフト
等の記録再生ノイズ特性を改善することが必要である。
The metal thin film type magnetic recording medium described above is capable of higher density recording than conventional coated type magnetic recording media, but next-generation magnetic recording media are required to further improve recording density. To this end, it is necessary to improve recording and reproduction noise characteristics such as modulation noise and reproduction waveform peak shift.

本発明は上記要請に応えるべくなされたものであり、記
録再生ノイズを可及的に低くして分解能とノイズのつり
合いのとれたピークシフトの低い高密度記録用金属薄膜
型磁気記録媒体を従供する。
The present invention has been made in response to the above requirements, and provides a metal thin film magnetic recording medium for high-density recording with low peak shift and a good balance between resolution and noise by minimizing recording and reproducing noise. .

〔課題を解決するための手段および作用〕本発明の金属
薄膜型磁気記録媒体は、その磁性膜が、下式(I)また
は(II)で示される成分組成を有する合金からなるこ
とを特徴としている。
[Means and effects for solving the problems] The metal thin film magnetic recording medium of the present invention is characterized in that the magnetic film is made of an alloy having a component composition represented by the following formula (I) or (II). There is.

CO+−x−y−z N1)I Cry Mz   −
(11)Co +−v−z Cr v Mz     
  ”・(1)式中、Mは、’Ta、Nb、Vがら選ば
れる2種もしくは3種の元素であり、x、  y、  
zは原子組成比を表し、Xは0.05〜0.107  
yは0.07〜0.142は0.02〜0.107ある
CO+-x-y-z N1)I Cry Mz-
(11) Co +-v-z Cr v Mz
”・In the formula (1), M is two or three elements selected from Ta, Nb, and V, and x, y,
z represents the atomic composition ratio, and X is 0.05 to 0.107
y is 0.07-0.142 and 0.02-0.107.

本発明の磁気記録媒体の金属系磁性膜は、上記のように
CoCr系、またはCoNiCr系合金をベースとし、
これにMで表される元素、すなわちTa、Nb、Vがら
選ばれる2種もしくは3種の元素が複合添加された成分
構成を有している。CoCr系、またはCoNiCr系
合金は、高保磁力(Hc)および高残留磁束密度(Br
)を有する合金であり、本発明に従ってこれにMで表さ
れる複数元素の適量が添加されると、M元素によるCr
の粒界析出に伴い磁性粒子(磁区)の孤立化がもたらさ
れると共に、保磁力(Hc)の増加をみる。このM元素
の添加による保磁力増加と磁性粒子の孤立化とによって
顕著なノイズ特性改善効果が得られる。なお、M元素の
いずれか1種のみの単独添加においても磁性粒子の孤立
化、保磁力増加をみるが、後記実施例に示したように、
その顕著な改善効果はその複合添加によって確保される
As mentioned above, the metal-based magnetic film of the magnetic recording medium of the present invention is based on CoCr-based or CoNiCr-based alloy,
It has a composition in which the element represented by M, that is, two or three elements selected from Ta, Nb, and V, is added in combination. CoCr-based or CoNiCr-based alloys have high coercive force (Hc) and high residual magnetic flux density (Br
), and when appropriate amounts of multiple elements represented by M are added to this according to the present invention, Cr due to the M element
Along with grain boundary precipitation, magnetic particles (magnetic domains) become isolated and coercive force (Hc) increases. The addition of the M element increases the coercive force and isolates the magnetic particles, resulting in a significant improvement in noise characteristics. It should be noted that even when only one of the M elements is added alone, the magnetic particles become isolated and the coercive force increases, but as shown in the examples below,
Its remarkable improvement effect is ensured by its combined addition.

本発明において磁性膜の合金成分組成につき、Cr量(
y)を0.07〜0.14としたのは、0.07未満で
は、磁性膜の耐候性が不足し、他方0.14より多くな
ると、良好な磁気特性・電気特性を確保できなくなるか
らでである。また、Niを含む磁性膜である場合のNi
量(X)の下限を0.05としだのは、Ni添加による
耐候性改善効果を十分ならしめるためであり、上限を0
.25としたのは、それをこえると、飽和磁束密度(B
s)が減少し、良好な磁気特性および電気特性が得られ
なくなるからである。
In the present invention, the amount of Cr (
The reason why y) is set to 0.07 to 0.14 is because if it is less than 0.07, the weather resistance of the magnetic film will be insufficient, while if it is more than 0.14, it will not be possible to ensure good magnetic and electrical properties. It is. In addition, in the case of a magnetic film containing Ni,
The reason why the lower limit of the amount (X) is set to 0.05 is to ensure that the effect of improving weather resistance by adding Ni is sufficient, and the upper limit is set to 0.05.
.. The reason for setting it to 25 is that when it exceeds the saturation magnetic flux density (B
s) decreases, making it impossible to obtain good magnetic and electrical properties.

更に、本発明の最も特徴とするM元素につき、その添加
量(複数元素の合計量)の下限値をo、o2、としたの
は、その複合添加による磁性粒子の孤立化に伴う磁化遷
移幅の減少、高保磁力化の効果を確保するためである。
Furthermore, for the M element, which is the most characteristic feature of the present invention, the lower limit value of its addition amount (total amount of multiple elements) is set to o and o2 because the magnetization transition width due to the isolation of magnetic particles due to the combined addition This is to ensure the effect of reducing the coercive force and increasing the coercive force.

好ましくは各元素の量をそれぞれ0.01以上とする。Preferably, the amount of each element is 0.01 or more.

他方M元素の上限値を0゜10、としたのは、それをこ
えると効果がほぼ飽和してしまうだけでなく、却って磁
気特性・電気特性の低下を招くからである。
On the other hand, the upper limit of the M element is set to 0°10 because exceeding this value not only substantially saturates the effect, but also causes deterioration of the magnetic and electrical properties.

本発明の金属薄膜型磁気記録媒体は、磁気ディスクをは
じめ、磁気ドラム、磁気テープ、磁気シート等を包含す
る。これらは、いずれもその磁性膜が前記[I)式また
は〔■〕式で示される組成を有する合金からなる点を除
いて、公知の工程および条件に従って製作することがで
きる。例えば、面内記録用磁気ディスクについて述べれ
ば、アルミニウム合金板等を基体とし、その表面に無電
解めっきにより硬質のN1−Pめっき膜(膜厚:例えば
15〜25μm)を設け、めっき膜面にテキスチャ処理
を施したのち、磁性膜に面内異方性を与えるための下地
層としてCr膜を適宜の膜厚(例えば500〜3000
人)に形成する。そのCr膜面上に、前記組成をもつ磁
性膜(膜厚は例えば500〜2000人)を成膜する。
The metal thin film magnetic recording medium of the present invention includes magnetic disks, magnetic drums, magnetic tapes, magnetic sheets, and the like. All of these can be manufactured according to known processes and conditions, except that the magnetic film is made of an alloy having a composition represented by the formula [I] or formula [■]. For example, regarding a magnetic disk for in-plane recording, the substrate is made of an aluminum alloy plate, etc., and a hard N1-P plating film (film thickness: e.g. 15 to 25 μm) is provided on the surface by electroless plating, and the plating film surface is After the texture treatment, a Cr film is deposited to an appropriate thickness (for example, 500 to 3000
person). A magnetic film (film thickness: 500 to 2000 layers, for example) having the above composition is formed on the Cr film surface.

ついで磁性膜の摩耗・損傷を防止するための保護膜とし
て、潤滑性と耐摩耗性を備えた被膜、例えば炭素質膜(
膜厚:例えば150〜600人)を形成することにより
、多層積層構造を有する面内記録用磁気ディスクを得る
。その積層構造は上記の例に限定されず、例えば、磁性
膜の上に:炭素質膜を成膜するに先立って、Cr膜(膜
厚約100〜500人)を形成することにより、磁気デ
ィスクの耐候性をさらに高めることができ、また磁性膜
面に炭素質膜を形成したうえ、更にその表面に潤滑剤(
膜厚:例えば10〜100人)を設けて、磁気ヘッドに
対する保護潤滑機能をより良好なものとすることもでき
る。なお、各層の成膜は、スパッタリング法、イオンブ
レーティング法、真空蒸着法などにより行うことができ
る。
Next, a coating with lubricity and wear resistance, such as a carbonaceous film (
By forming a film having a thickness of, for example, 150 to 600, a magnetic disk for in-plane recording having a multilayer laminated structure is obtained. The laminated structure is not limited to the above example, and for example, a Cr film (film thickness of about 100 to 500 ml) is formed on top of the magnetic film before forming the carbonaceous film. In addition to forming a carbonaceous film on the magnetic film surface, a lubricant (
The protective lubrication function for the magnetic head can be improved by providing a film with a thickness of, for example, 10 to 100. Note that each layer can be formed by a sputtering method, an ion blating method, a vacuum evaporation method, or the like.

〔実施例〕〔Example〕

実施丘↓(CoNiCr系磁性膜) (1)供試磁気ディスクの製作 アルミニウム合金基板(外径130mm、内径40mm
、厚さ1.9mm)の表面に、N1−P無電解めっき膜
(膜厚20μm)を形成し、表面にボリンシュとテキス
チャ処理を行ったのち、マグネトロンスパッタリング法
(但し、アルゴン雰囲気圧:0.7 Xl0−2tor
r )により、Cr膜(下地層)、CoNiCr系磁性
膜および潤滑膜としての炭素質膜(膜厚300人)とを
この順に積層成膜して供試磁気ディスクを得た。各供試
磁気ディスク同士の記録再生特性の正当な比較を行うた
めに、各供試磁気ディスクの保磁力(Hc)、および残
留磁束密度(Br)と膜厚(δ)の積(Br・δ)が互
いに等しくなるように下地層および磁性膜の成膜を行っ
た。そのHcは12500eとし、Br・δは450G
−μとした。
Implementation hill ↓ (CoNiCr magnetic film) (1) Production of test magnetic disk Aluminum alloy substrate (outer diameter 130 mm, inner diameter 40 mm)
A N1-P electroless plating film (film thickness: 20 μm) was formed on the surface of the N1-P electroless plated film (thickness: 1.9 mm), and the surface was subjected to a borinsh and texture treatment, followed by magnetron sputtering (argon atmosphere pressure: 0.5 mm). 7 Xl0-2tor
A test magnetic disk was obtained by laminating a Cr film (base layer), a CoNiCr magnetic film, and a carbonaceous film (thickness: 300 mm) as a lubricating film in this order. In order to make a fair comparison of the recording and reproducing characteristics of each magnetic disk under test, the coercive force (Hc) of each magnetic disk under test, the product of the residual magnetic flux density (Br) and the film thickness (δ) (Br・δ) ) The underlayer and magnetic film were formed so that their values were equal to each other. Its Hc is 12500e, and Br・δ is 450G
−μ.

(II)記録再生特性試験 各供試磁気ディスクについて、フェライトヘッドを使用
し、記録線密度19KPCI、および28KPCIで、
信号の記録再生試験を行い、再生信号出力とメディアノ
イズ強さの比(S/N、dB)を求めた。なお、ヘッド
仕様は、ギャップ幅:13.5μ、ギャップ長さ: 0
.79μ、インダクタンス二8μI]、フライングハイ
ド: 0.20μ、ローディング・フォース: 9.5
gf、コイル巻数:26である。
(II) Recording/reproduction characteristics test For each sample magnetic disk, a ferrite head was used at recording linear densities of 19 KPCI and 28 KPCI.
A signal recording/reproducing test was conducted to determine the ratio (S/N, dB) between the reproduced signal output and the media noise intensity. The head specifications are: gap width: 13.5μ, gap length: 0
.. 79μ, inductance 28μI], flying hide: 0.20μ, loading force: 9.5
gf, number of coil turns: 26.

各供試磁気ディスクの試験結果を、その磁性膜の合金組
成と併せて第1表に示す。表中、No、 11〜14は
M元素を複合金有する発明例、No、15,16はM元
素の単独添加の比較例である。
The test results for each sample magnetic disk are shown in Table 1 along with the alloy composition of the magnetic film. In the table, Nos. 11 to 14 are invention examples having composite gold containing the M element, and Nos. 15 and 16 are comparative examples in which the M element is added alone.

災脩尉2 (CoCr系磁性膜) 磁性膜合金をCoCr系とした点を除いて実施例1と同
じ工程と条件で供試磁気ディスクを得、それぞれについ
て前記と同じ記録再生特性試験を行った。各供試磁気デ
ィスクの磁性膜合金組成および試験結果を第2表に示す
。No、21〜24はM元素を複合金有する発明例、N
o、25.26は単独添加の例である。
Disaster Fighter 2 (CoCr-based magnetic film) Sample magnetic disks were obtained using the same process and conditions as in Example 1, except that the magnetic film alloy was CoCr-based, and the same recording and reproducing characteristics tests as above were conducted on each disk. . Table 2 shows the magnetic film alloy composition and test results of each test magnetic disk. No. 21 to 24 are invention examples having composite gold containing M element, N
o, 25.26 are examples of single addition.

上記各実施例の試験結果から、CoCr系またはCoN
iCr系合金にM元素が複合添加された磁性膜を有する
発明例の磁気ディスクは、S/N比が高く、改良された
ノイズ特性を有していることがわかる。
From the test results of each of the above examples, it was found that CoCr-based or CoN
It can be seen that the magnetic disk of the invention example, which has a magnetic film in which M element is added in combination to an iCr-based alloy, has a high S/N ratio and improved noise characteristics.

〔発明の効果〕〔Effect of the invention〕

本発明の金属薄膜型磁気記録媒体は、ノイズ特性にすぐ
れ、記録再生ノイズが低いことにより従来品を凌ぐ高密
度記録が可能であり、これにより磁気記録媒体のコラパ
フ1−化と高品質・高性能化等の効果を得ることができ
る。
The metal thin film magnetic recording medium of the present invention has excellent noise characteristics and low recording/reproduction noise, making it possible to perform higher density recording than conventional products. Effects such as improved performance can be obtained.

Claims (1)

【特許請求の範囲】 1、非磁性基体上に金属系磁性膜が形成された磁気記録
媒体において、該金属系磁性膜が、Co_1_−_X_
−_Y−ZNi_XCr_YM_Z〔但し、Mは、Ta
、Nb、Vから選ばれる2種もしくは3種の元素を表す
。x、y、zは原子組成比であり、xは0.05〜0.
25、yは0.07〜0.14、zは0.02〜0.1
0である〕 で示される組成を有することを特徴とするノイズ特性に
すぐれた金属薄膜型磁気記録媒体。 2、非磁性基体上に金属系磁性膜が形成された磁気記録
媒体において、該金属系磁性膜が、Co_1_−_Y_
−_ZCr_YM_Z 〔但し、Mは、Ta、Nb、Vから選ばれる2種もしく
は3種の元素を表す。y、zは原子組成比であり、yは
0.07〜0.14、zは0.02〜0.10である〕
で示される組成を有することを特徴とするノイズ特性に
すぐれた金属薄膜型磁気記録媒体。
[Claims] 1. In a magnetic recording medium in which a metal-based magnetic film is formed on a non-magnetic substrate, the metal-based magnetic film is Co_1_-_X_
-_Y-ZNi_XCr_YM_Z [However, M is Ta
, Nb, and V. x, y, z are atomic composition ratios, and x is 0.05 to 0.
25, y is 0.07-0.14, z is 0.02-0.1
0] A metal thin film magnetic recording medium having excellent noise characteristics. 2. In a magnetic recording medium in which a metal-based magnetic film is formed on a non-magnetic substrate, the metal-based magnetic film is Co_1_-_Y_
-_ZCr_YM_Z [However, M represents two or three elements selected from Ta, Nb, and V. y and z are atomic composition ratios, y is 0.07 to 0.14, and z is 0.02 to 0.10]
A metal thin film magnetic recording medium with excellent noise characteristics, characterized by having a composition represented by:
JP1147641A 1989-06-09 1989-06-09 Metal thin film magnetic recording medium Expired - Fee Related JP2552546B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1147641A JP2552546B2 (en) 1989-06-09 1989-06-09 Metal thin film magnetic recording medium

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1147641A JP2552546B2 (en) 1989-06-09 1989-06-09 Metal thin film magnetic recording medium

Publications (2)

Publication Number Publication Date
JPH0312816A true JPH0312816A (en) 1991-01-21
JP2552546B2 JP2552546B2 (en) 1996-11-13

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Country Link
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05109042A (en) * 1991-10-14 1993-04-30 Nec Corp Magnetic recording medium
JPH05151553A (en) * 1991-11-28 1993-06-18 Nec Corp Magnetic recording medium
US5334267A (en) * 1992-08-03 1994-08-02 Hitachi Metals, Ltd. Sputtering target for magnetic recording medium and method of producing the same
AU2014288257B2 (en) * 2013-07-09 2016-07-28 Mitsubishi Power, Ltd. Combustion device

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61222023A (en) * 1985-03-28 1986-10-02 Victor Co Of Japan Ltd Vertical magnetic recording medium
JPS6364623A (en) * 1986-09-04 1988-03-23 Fuji Electric Co Ltd Magnetic recording medium

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61222023A (en) * 1985-03-28 1986-10-02 Victor Co Of Japan Ltd Vertical magnetic recording medium
JPS6364623A (en) * 1986-09-04 1988-03-23 Fuji Electric Co Ltd Magnetic recording medium

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05109042A (en) * 1991-10-14 1993-04-30 Nec Corp Magnetic recording medium
JPH05151553A (en) * 1991-11-28 1993-06-18 Nec Corp Magnetic recording medium
US5334267A (en) * 1992-08-03 1994-08-02 Hitachi Metals, Ltd. Sputtering target for magnetic recording medium and method of producing the same
AU2014288257B2 (en) * 2013-07-09 2016-07-28 Mitsubishi Power, Ltd. Combustion device

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