JPH0293054A - Production of hot dip galvanized steel sheet - Google Patents

Production of hot dip galvanized steel sheet

Info

Publication number
JPH0293054A
JPH0293054A JP24559088A JP24559088A JPH0293054A JP H0293054 A JPH0293054 A JP H0293054A JP 24559088 A JP24559088 A JP 24559088A JP 24559088 A JP24559088 A JP 24559088A JP H0293054 A JPH0293054 A JP H0293054A
Authority
JP
Japan
Prior art keywords
steel sheet
bath
alloying
zinc
concns
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP24559088A
Other languages
Japanese (ja)
Inventor
Makoto Arai
新井 信
Kuniaki Sato
邦昭 佐藤
Shinichiro Muto
武藤 振一郎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JFE Steel Corp
Original Assignee
Kawasaki Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kawasaki Steel Corp filed Critical Kawasaki Steel Corp
Priority to JP24559088A priority Critical patent/JPH0293054A/en
Publication of JPH0293054A publication Critical patent/JPH0293054A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To make it possible to regulate the coating weight of Zn and the degree of alloying of a Zn layer by setting a Zn bath for the front side of a steel sheet and a Zn bath for the rear side in the same line and regulating the concns. of Al in the Zn baths according to the degrees of alloying required for the front and rear sides. CONSTITUTION:Zn baths contain a prescribed amt. of Al. When the concns. of Al in the baths are different, Al sticks to steel sheets by different amts. even in the case of the same heat treatment, alloying proceeds at different rates and the concns. of Fe in the resulting Zn-Fe alloy layers are made different. This effect of Al on Zn-Fe alloying is utilized, a Zn bath 17 for the front side of a steel sheet 1 and a Zn bath 18 for the rear side are set in the same line and the steel sheet 1 is hot dip galvanized to coat the front and rear sides with Zn having different concns. of Al. Alloying treatment is then carried out. The concns. of Fe in the resulting Zn-Fe alloy layers on the front and rear sides are separately controlled and the coatability of the steel sheet as well as the corrosion resistance can be improved.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 この発明は、鋼板の表面と裏面とをそれぞれ独立に溶融
亜鉛めっきを一ラインにおいて行う溶融亜鉛めっき鋼板
の製造方法に関する。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a method for producing a hot-dip galvanized steel sheet, in which hot-dip galvanizing is performed independently on the front and back surfaces of the steel sheet in one line.

〔従来の技術〕[Conventional technology]

従来、溶融亜鉛めっき鋼板を製造するには、そのめっき
層の一部、あるいは全体をFe−Zn合金層とする合金
化処理を行う製造方法が知られている。
BACKGROUND ART Conventionally, in order to manufacture hot-dip galvanized steel sheets, a manufacturing method is known in which a part or all of the plating layer is alloyed to form an Fe-Zn alloy layer.

このような合金化処理を行う溶融亜鉛めっき鋼板の製造
方法としては、例えば第4図に示すように、溶融亜鉛め
っき槽4の直上に合金化炉2を配置し、ジンクロール5
によりめっき槽4中に浸漬された鋼板lを引上げるとき
、鋼板1表面に付着した溶融亜鉛を絞り取り装置3によ
り亜鉛付着量の調節を行う。この絞り取り装置としては
溝付きロールによる絞り法か高圧ガス吹き付けによる気
体絞り法によるのが一般であって、その後、直ちに合金
化炉2において鋼板1を加熱し、亜鉛層・\のFeの拡
散を行わせるものである。
As a method for manufacturing hot-dip galvanized steel sheets that undergoes such alloying treatment, for example, as shown in FIG. 4, an alloying furnace 2 is placed directly above a hot-dip galvanizing tank 4,
When the steel plate l immersed in the plating bath 4 is pulled up, the molten zinc adhering to the surface of the steel plate 1 is squeezed out and the amount of zinc deposited is adjusted by the device 3. This squeezing device generally uses a squeezing method using grooved rolls or a gas squeezing method using high-pressure gas blowing.After that, the steel sheet 1 is immediately heated in the alloying furnace 2, and the Fe in the zinc layer is diffused. It is something that allows people to do this.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

しかし、上記の例で行われる合金化処理が適正でない場
合、すなわち、めっき層のFed度が高すぎたり(過合
金化)、あるいは低すぎたり(合金化不足)すると、め
っき鋼板の塗装性等に悪影口を及ぼすことになる。
However, if the alloying treatment performed in the above example is not appropriate, that is, if the Fed degree of the coating layer is too high (overalloying) or too low (insufficient alloying), the paintability of the plated steel sheet may deteriorate. This will have a negative impact on the

また、近年、特に溶融亜鉛めっき鋼板が自動車用等に多
く使用されるようになり、耐蝕性を向上させるという点
からは亜鉛付着量を多くし、また塗装性の点からはめっ
き層のFe濃度を所望の目標範囲に任意にコントロール
する必要がある。しかし、第4図に示すような一槽の亜
鉛浴にて亜鉛を付着させ、合金化させるための熱処理を
行う場合、付着量を変化させるとめっき層中のFe[度
も変化し、両方を独立して任意に変化させることはでき
なかった。このため、耐蝕性の点から亜鉛付着量の調節
はできても、塗装性の向上を図るためのFe濃度の調節
はできなかった。
In addition, in recent years, hot-dip galvanized steel sheets have come into widespread use, especially for automobiles, and from the standpoint of improving corrosion resistance, the amount of zinc deposited must be increased, and from the standpoint of paintability, the Fe concentration of the plating layer must be increased. must be arbitrarily controlled within the desired target range. However, when heat treatment is performed to deposit and alloy zinc in a single zinc bath as shown in Figure 4, changing the amount of zinc deposited will also change the degree of Fe in the plating layer. They could not be changed independently and arbitrarily. For this reason, although it was possible to adjust the amount of zinc deposited from the viewpoint of corrosion resistance, it was not possible to adjust the Fe concentration to improve paintability.

このような技術的背景より、めっき鋼板の耐蝕性、塗装
性を改善する手段として、(1)溶融亜鉛めっき浴面に
塩化物を吹き込んで浴中A1量を低減する方法(特開昭
53−138931号公報)(2)溶融亜鉛めっき浴中
に空気又は酸素ガスを吹き込んで浴中Al量を低減する
方法(特開昭53−138932号公報)(3)特定の
めっき浴でめっきした鋼板を一定温度で加熱冷却する方
法(特開昭50−013229号公報)等が開示されて
いるが、いずれも耐蝕性、塗装性を支配する表面、裏面
の合金化度を各独立で調節することができない、といっ
た問題点があった。
Based on this technical background, as a means to improve the corrosion resistance and paintability of galvanized steel sheets, (1) a method of blowing chloride into the hot-dip galvanizing bath surface to reduce the amount of A1 in the bath (Japanese Patent Laid-Open No. 1983-1999-1) has been proposed. 138931) (2) A method of blowing air or oxygen gas into a hot-dip galvanizing bath to reduce the amount of Al in the bath (Japanese Unexamined Patent Publication No. 138932/1983) A method of heating and cooling at a constant temperature (Japanese Unexamined Patent Publication No. 50-013229) has been disclosed, but in both cases, the degree of alloying on the front and back surfaces, which govern corrosion resistance and paintability, can be adjusted independently. The problem was that it couldn't be done.

この発明は、このような従来の問題点にかんがみてなさ
れたものであって、鋼板の表面用亜鉛浴と裏面用亜鉛浴
とを併設する等により上記問題点を解決することを目的
としている。
The present invention has been made in view of these conventional problems, and aims to solve the above problems by providing a zinc bath for the front surface and a zinc bath for the back surface of the steel sheet.

〔課題を解決するための手段〕[Means to solve the problem]

この発明は、鋼板の溶融亜鉛めっきを行うに際して、鋼
板の表面用亜鉛浴と裏面用亜鉛浴とを一ラインに併設し
、鋼板の表面と裏面のそれぞれに対し製品に要求される
合金化度に応じて前記各亜鉛浴中の/l濃度を調整する
ことにより、鋼板の表面、裏面それぞれ独立に亜鉛付着
量、めっき層合金化度を調節することを特徴とする溶融
亜鉛めっき鋼板の製造方法としたものである。
When hot-dip galvanizing steel sheets, this invention involves installing a zinc bath for the front surface of the steel sheet and a zinc bath for the back surface of the steel sheet in one line, and adjusting the degree of alloying required for the product on each of the front and back surfaces of the steel sheet. A method for producing a hot-dip galvanized steel sheet, characterized in that the amount of zinc deposited and the degree of alloying of the coating layer are adjusted independently on the front and back surfaces of the steel sheet by adjusting the /l concentration in each zinc bath accordingly. This is what I did.

〔作用〕[Effect]

一般に亜鉛とFeの合金化速度はAlによって支配され
ることが知られている。したがって、亜鉛浴中には所定
量のAl!が含有されている。この浴中A#!濃度が異
なると同一の熱処理を行った場合でも鋼板へのAA付着
量が変化するので合金化速度が異なることになり、それ
に応じてめっき層中のFe濃度も異なってくる。
It is generally known that the alloying rate of zinc and Fe is controlled by Al. Therefore, in the zinc bath there is a certain amount of Al! Contains. A# in this bath! If the concentration differs, even if the same heat treatment is performed, the amount of AA deposited on the steel sheet will change, resulting in a different alloying rate, and the Fe concentration in the plating layer will also vary accordingly.

本発明は、このAlのZn−Fe合金化に及ぼす効果を
利用して、前記手段、すなわち鋼板の表面用亜鉛浴と裏
面用亜鉛浴とを同一ラインに併設したために、鋼板の表
面5裏面各々に異なるAl濃度をもった亜鉛をめっきし
、その後、合金化処理を行うことにより、めっき層中の
Fe濃度を表面、裏面独立にコントロールして、耐蝕性
はもちろん、塗装性をも向上させるものである。
The present invention takes advantage of the effect of Al on Zn-Fe alloying and provides the above-mentioned means, that is, a zinc bath for the front surface of the steel sheet and a zinc bath for the back surface of the steel sheet, in the same line. By plating zinc with different Al concentrations on the surface and then performing alloying treatment, the Fe concentration in the plating layer can be controlled independently on the front and back surfaces, improving not only corrosion resistance but also paintability. It is.

[実施例] 以下、本発明を図面に基づいて説明する。第1図〜第3
図は本発明に係る一実施例を説明する図である。
[Example] The present invention will be described below based on the drawings. Figures 1 to 3
The figure is a diagram illustrating an embodiment according to the present invention.

先ず、第3図に本発明を構成する手段(第1図)を取り
入れた鋼板の亜鉛めっきラインを説明する。
First, a galvanizing line for steel sheets incorporating the means constituting the present invention (FIG. 1) will be explained with reference to FIG.

図において、溶融亜鉛めっき用鋼板1はペイオフリール
6より払い出され、その後、せん断機7、溶接機8を通
り、脱脂、酸洗、水洗等を行うクリニングセクション9
を経て焼鈍炉10へ入り、所定の熱処理が行われ、冷却
帯11にて均熱、冷却が行われる。そして目標板温とな
って亜鉛めっき装置12へ入る。この装置12内で表面
、裏面にそれぞれ所定のA1濃度の亜鉛を付着させ、亜
鉛絞り装置3(第1図)にて所定の付着量に調節する。
In the figure, a steel sheet 1 for hot-dip galvanizing is discharged from a payoff reel 6, then passes through a shearing machine 7 and a welding machine 8, and a cleaning section 9 where it is subjected to degreasing, pickling, water washing, etc.
The material then enters the annealing furnace 10, where it is subjected to predetermined heat treatment, and soaked and cooled in the cooling zone 11. Then, the plate reaches the target temperature and enters the galvanizing apparatus 12. Zinc with a predetermined concentration of A1 is deposited on the front and back surfaces respectively in this device 12, and the deposited amount is adjusted to a predetermined amount using a zinc squeezing device 3 (FIG. 1).

なお、このとき亜鉛めっき装置12内はN2雰囲気にて
シールされている。
Note that at this time, the inside of the galvanizing apparatus 12 is sealed in an N2 atmosphere.

亜鉛めっき装置12を出た鋼板1は、合金化炉2にて合
金化処理が行われ、その後、冷却帯13にて所定の温度
まで冷却され、後処理装置14で化成処理等を施され、
せん断機15を経てテンションリール16にて巻取られ
る。
The steel sheet 1 leaving the galvanizing device 12 is subjected to alloying treatment in the alloying furnace 2, then cooled to a predetermined temperature in the cooling zone 13, and subjected to chemical conversion treatment etc. in the post-treatment device 14.
It passes through a shearer 15 and is wound up on a tension reel 16.

第1図は亜鉛めっき装置12の詳細を示したものであっ
て、鋼板1は冷却帯11からシールロール21を介して
雰囲気ガスシールチャンバとなっている亜鉛めっき装置
12に入り、外気を遮断された状態となる。
FIG. 1 shows the details of the galvanizing apparatus 12, in which the steel sheet 1 enters the galvanizing apparatus 12, which is an atmospheric gas sealing chamber, from the cooling zone 11 via the seal roll 21, and is blocked from outside air. The state will be as follows.

亜鉛めっき装置12は予め所定のA1濃度に調整した電
気的加熱によるA亜鉛浴17.B亜鉛浴18.デフレフ
クロール23.亜鉛絞り装置3゜出側シールロール21
より成っている。
The zinc plating apparatus 12 uses an A zinc bath 17. which is heated electrically and adjusted to a predetermined A1 concentration in advance. B zinc bath18. Defreef crawl 23. Zinc squeezing device 3゜output side seal roll 21
It consists of

装置12内へ入った鋼板は、B亜鉛浴18面の直上に配
設されたデフレフクロールを介して通過するとき、亜鉛
浴面ば表面張力によるメニスカス20で鋼板1の片面の
みに接触して亜鉛を付着させ、エア吹き出しノズルのエ
ア噴出量を調節して行う亜鉛絞り装置3にて所定量まで
付着量を絞る。
When the steel sheet entering the apparatus 12 passes through the deflation crawl placed directly above the B zinc bath 18 surface, the zinc bath surface contacts only one side of the steel sheet 1 with a meniscus 20 due to surface tension. Zinc is deposited and the amount of deposited is reduced to a predetermined amount by a zinc squeezing device 3 that adjusts the amount of air jetted from an air blowing nozzle.

その後、同様にA亜鉛浴17のメニスカス20にて反対
側面(裏面)に亜鉛を付着させ、亜鉛絞り装置3にて所
定量まで亜鉛付着量を絞る。以上により鋼板lの表面、
裏面それぞれに所定のA1濃度の亜鉛をめっきすること
ができた。そして、めっき後、シールロール21を経て
合金化炉2に入り、合金化処理を受ける。
Thereafter, zinc is similarly deposited on the opposite side (back surface) using the meniscus 20 of the A zinc bath 17, and the amount of zinc deposited is reduced to a predetermined amount using the zinc squeezing device 3. As a result of the above, the surface of the steel plate l,
It was possible to plate each back surface with zinc at a predetermined A1 concentration. After plating, the material passes through the seal roll 21 and enters the alloying furnace 2, where it undergoes alloying treatment.

この設備で、所定の亜鉛付着量、めっき層Fe濃度によ
りA亜鉛浴17.B亜鉛浴18のA14度を設定すれば
、鋼板1の表面、裏面それぞれの付着量、めっき層Fe
濃度を調節することができる。
With this equipment, A zinc bath 17. If the A14 degree of the B zinc bath 18 is set, the coating amount on the front and back surfaces of the steel plate 1 and the plating layer Fe
Concentration can be adjusted.

第2図に/lのZn−Fe合金化反応に及ぼす影響をグ
ラフで示す。グラフより、浴中A1濃度が高くなると鋼
板へのAl!付着量が多くなり、その分、Fe−Znの
合金化反応が抑制され、亜鉛めっき層中のFeeA度が
相対的に減少することがわかる。またこの関係は付着量
が変化することにより影響を受ける。つまり、亜鉛の付
着量が増えることにより、めっき層中のFe’4度はそ
の比率からみて減少する。この関係を利用すれば、鋼板
に要求される耐蝕性により亜鉛付着量を決定し、その付
着量と要求される塗装性によって決まるめっき層中Fe
:a度に応じて亜鉛浴中A 1 ?tN度を調節するこ
とにより耐蝕性、塗装性共に優れためっき鋼板を得るこ
とが可能となる。
FIG. 2 graphically shows the influence of /l on the Zn-Fe alloying reaction. From the graph, as the A1 concentration in the bath increases, the amount of Al on the steel plate! It can be seen that as the amount of adhesion increases, the alloying reaction of Fe-Zn is suppressed accordingly, and the degree of FeA in the galvanized layer is relatively reduced. This relationship is also affected by changes in the amount of adhesion. In other words, as the amount of zinc deposited increases, the Fe'4 degree in the plating layer decreases in terms of its ratio. Using this relationship, the amount of zinc deposited can be determined based on the corrosion resistance required of the steel sheet, and the amount of Fe in the plating layer determined by the amount of zinc deposited and the required paintability.
: A 1 in zinc bath depending on a degree? By adjusting the tN degree, it is possible to obtain a plated steel sheet with excellent corrosion resistance and paintability.

第1表に実施例の結果を示す。Table 1 shows the results of the examples.

(上段は実績値、下段は目標値) 第1表 ケース1;表裏面の付着量、Fe(%)が同じである場
合。
(The upper row is the actual value, the lower row is the target value) Table 1 Case 1: When the adhesion amount and Fe (%) on the front and back surfaces are the same.

従来法と本発明による方法の差異なし。There is no difference between the conventional method and the method according to the present invention.

ケース2;付着量が同じで、Fe(%)の目標値が異な
る場合。
Case 2: The amount of adhesion is the same, but the target value of Fe (%) is different.

従来法では表裏面でAl濃度を変化させることができな
いので、Fe(%)を変化させられないが、本発明では
可能である。
In the conventional method, it is not possible to change the Al concentration between the front and back surfaces, so it is not possible to change the Fe (%), but this is possible with the present invention.

ケース3;Fe(%)目標値が同じで付着量が異なる場
合。
Case 3: When the Fe (%) target value is the same but the amount of adhesion is different.

従来法では、Fe(%)を同じにすることができない。In the conventional method, it is not possible to make the Fe (%) the same.

以上により、従来法では塗装性の点から表面、裏面のF
e濃度を変えたい場合(ケース2)、あるいは耐蝕性の
点から付着量を1=2として同−FeW度にしたい場合
は、めっき層中のp e 4度を同一にすることはでき
ないが、本発明によれば亜鉛浴中のA1濃度を表面、裏
面各独立で調節できるために、Fefi度を変えたい場
合、あるいは付着量が異なっている場合でも槽別に浴中
A1濃度を変えて通板することによりFe濃度を同一に
することができた。
As a result of the above, in the conventional method, from the viewpoint of paintability, F-
If you want to change the e concentration (Case 2), or if you want to make the same −FeW degree by setting the adhesion amount to 1=2 from the viewpoint of corrosion resistance, it is not possible to make the p e 4 degree in the plating layer the same. According to the present invention, the A1 concentration in the zinc bath can be adjusted independently for the front and back surfaces, so even when it is desired to change the Fefi degree or the amount of adhesion is different, the A1 concentration in the bath can be changed for each bath and the plate can be threaded. By doing so, it was possible to make the Fe concentration the same.

なお、第1表中、()内、A槽、B槽は槽毎にA#PL
度を変えてA槽→B槽を通板する意味である。
In addition, in Table 1, the A#PL for each tank is in parentheses, A tank, and B tank.
This means passing the plate from tank A to tank B by changing the degree.

第1表において付着量(目標値、実績値)・・・・・・
g/ 、、7.浴中A e 濃度(A槽、B槽) −−
−−−−w t%。
In Table 1, adhesion amount (target value, actual value)...
g/,,7. A e concentration in bath (tank A, tank B) --
---wt%.

コイルサイズ(板厚×幅)・・・・・・0.8 t x
 1200−虐2 ラインスピード・・・・・・60 
m/m i nとする。
Coil size (thickness x width)...0.8 t x
1200-Bruce 2 Line speed...60
Let m/min.

[発明の効果] 以上説明したように本発明によれば、溶融亜鉛めっき鋼
板において、亜鉛付着量とめっき槽Fe濃度を表、裏各
独立に調節することが可能となり、めっき鋼板の耐蝕性
はもちろん、塗装性も飛躍的に向上させることが可能と
なった。
[Effects of the Invention] As explained above, according to the present invention, it is possible to independently adjust the amount of zinc coating and the Fe concentration in the plating bath on the front and back sides of a hot-dip galvanized steel sheet, and the corrosion resistance of the galvanized steel sheet can be improved. Of course, it has also become possible to dramatically improve paintability.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は本発明に使用する亜鉛めっき装置の概略図、第
2図は浴中A7!濃度とめっき層中Fe濃度との関係を
示すグラフ、第3図は本発明による溶融亜鉛めっき鋼板
製造ラインの概念図、第4図は従来例による亜鉛めっき
のための装置の概略図である。 1・・・・・・鋼板、17・・・・・・鋼板の表面用亜
鉛浴、18・・・・・・鋼板の裏面用亜鉛浴。
Figure 1 is a schematic diagram of the galvanizing equipment used in the present invention, and Figure 2 is an A7 in the bath! FIG. 3 is a conceptual diagram of a production line for hot-dip galvanized steel sheets according to the present invention, and FIG. 4 is a schematic diagram of a conventional galvanizing apparatus. 1... Steel plate, 17... Zinc bath for the surface of the steel plate, 18... Zinc bath for the back side of the steel plate.

Claims (1)

【特許請求の範囲】[Claims] (1)鋼板の溶融亜鉛めっきに際して、鋼板の表面用亜
鉛浴と裏面用亜鉛浴とを一ラインにおいて併設し、鋼板
の表面と裏面のそれぞれに対し製品に要求される合金化
度に応じて前記各亜鉛浴中のAl濃度を調整することに
より、鋼板の表面、裏面それぞれ独立に亜鉛付着量、め
っき層合金化度を調節することを特徴とする溶融亜鉛め
っき鋼板の製造方法。
(1) When hot-dip galvanizing a steel plate, a zinc bath for the front side of the steel plate and a zinc bath for the back side of the steel plate are installed together in one line, and the A method for manufacturing a hot-dip galvanized steel sheet, characterized in that the amount of zinc deposited and the degree of alloying of the plating layer are independently adjusted on the front and back surfaces of the steel sheet by adjusting the Al concentration in each zinc bath.
JP24559088A 1988-09-29 1988-09-29 Production of hot dip galvanized steel sheet Pending JPH0293054A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP24559088A JPH0293054A (en) 1988-09-29 1988-09-29 Production of hot dip galvanized steel sheet

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP24559088A JPH0293054A (en) 1988-09-29 1988-09-29 Production of hot dip galvanized steel sheet

Publications (1)

Publication Number Publication Date
JPH0293054A true JPH0293054A (en) 1990-04-03

Family

ID=17135992

Family Applications (1)

Application Number Title Priority Date Filing Date
JP24559088A Pending JPH0293054A (en) 1988-09-29 1988-09-29 Production of hot dip galvanized steel sheet

Country Status (1)

Country Link
JP (1) JPH0293054A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04272163A (en) * 1991-02-27 1992-09-28 Nippon Steel Corp Method for controlling alloying of hot dip galvanized steel sheet

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62196363A (en) * 1986-02-21 1987-08-29 Sumitomo Metal Ind Ltd Manufacture of one-side alloyed hot dip galvanized steel sheet

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS62196363A (en) * 1986-02-21 1987-08-29 Sumitomo Metal Ind Ltd Manufacture of one-side alloyed hot dip galvanized steel sheet

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04272163A (en) * 1991-02-27 1992-09-28 Nippon Steel Corp Method for controlling alloying of hot dip galvanized steel sheet

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