JPH0286658A - New solid polyelectrolyte - Google Patents

New solid polyelectrolyte

Info

Publication number
JPH0286658A
JPH0286658A JP63237937A JP23793788A JPH0286658A JP H0286658 A JPH0286658 A JP H0286658A JP 63237937 A JP63237937 A JP 63237937A JP 23793788 A JP23793788 A JP 23793788A JP H0286658 A JPH0286658 A JP H0286658A
Authority
JP
Japan
Prior art keywords
alkaline earth
metal salt
segments
solid polyelectrolyte
polymeric compound
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP63237937A
Other languages
Japanese (ja)
Other versions
JP2833626B2 (en
Inventor
Ryuichi Yamamoto
隆一 山本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP63237937A priority Critical patent/JP2833626B2/en
Publication of JPH0286658A publication Critical patent/JPH0286658A/en
Application granted granted Critical
Publication of JP2833626B2 publication Critical patent/JP2833626B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/056Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0565Polymeric materials, e.g. gel-type or solid-type
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Abstract

PURPOSE:To obtain a solid polyelectrolyte excellent in heat resistance, low- temperature properties and mechanical properties by mixing a specified polymeric compound with an alkali (alkaline earth) metal salt. CONSTITUTION:A solid polyelectrolyte is formed by mixing a specified polymeric compound with an alkali metal salt or an alkaline earth metal salt, wherein the polymeric compound is a polyparabanic acid or its imino precursor having segments (I) comprising repeating unit of formula I or comprising segments (I) and segments (II) comprising repeating units of formula II. In the formulas, Ar and Ar' are different bivalent aromatic groups; and X is NH or O. Examples of the desired alkali metal salts and alkaline earth metal salts include LiClO4, LiBF4, LiAsF6, Li[CF3SO3], LiI, LiBr, and LiPF6.

Description

【発明の詳細な説明】 [産業上の利用#アイi 本発明11 、電光7エし7トロ70ミ、、747集び
゛コシテ゛シブーな乙のtJ4碑的f”)<’イア  
+4トノ、Jl−ろ高防)1電角♀買に関1名七ので゛
ある。
[Detailed Description of the Invention] [Industrial Application #I Invention 11, Lightning 7E, 7Tro 70M, 747 Gathers Cositive Otsu's TJ4 Monument F'') <'Ia
+4 Tono, Jl-Rotakabo) There are 1 person and 7 people for 1 electric angle ♀ purchase.

[従床技指歳の盾題、乞」 従#f)高今j固イ本電解巽乙し11工7手゛ソエナレ
レλキシド 庄ぐソデC3ヒ0し〉オキシド°スーエエ
’yルンズN〉ド乙ブIl:I乙゛レンオキニドのバ、
永澄捧泡主彰+i(j’!Q・・、、flプろ高今各イ
し会刺乙アルh ゛、、+J、、、4]1又1エアjレ
カツJ二S、布A歩と乏脣ぢり入て芒Ftめが土に却ら
ルtLIろ =i3’+の高斧寺固ず本電解質Σ構べ゛する嵩かY枝
材のポソエーテ1し1〕−膜内1こが゛ラスttJ+溝
、虜力力δく(半°ソエ斗しンオキシにめ場合1オーz
7°C)て・Jろ、−f:J7 希繋ん掬u勝の及びJ
に(チな\)、電光ムこ、の屯気イしイ的デ゛ノぐイス
ΣYソ高瓢下又」工K ’)底シ区千で゛便用1ろ羊水
が゛高エヮてh・ソ、−ヒーお間し升、市34jU1ろ
二Y−p”r交1−℃な7て・・ろ。
[Shube technique finger year's shield title, beg.'' Ju #f) Takama j solid main electrolysis Tatsumi Otsushi 11 work 7 moves ゛Soenarere λ oxido Shogu Sode C3 Hi0shi〉Oxide°Sueeee'y Runs N > Door Il: I
Nagasumi Hoshuaki +i (j'!Q...,, fl Pro high now each Ishikai Sashitsu al h ゛,, +J,,,4] 1 or 1 air j Rekatsu J2S, Cloth A Stepping in and out, the awn Ft is thrown into the soil, and the electrolyte Σ of the Takakiji of i3'+ is fixed, and the bulk of the Y branch material posoete 1 and 1]-inside the membrane. 1 Koga last ttJ + groove, captivating force δ
7°C) te・Jro, -f: J7 Nozomi Tsunaru Kikku u Katsuno and J
ni(china\), electric light muko, it's so high that the amniotic fluid is high. te h・so, -hi omashi masu, city 34j U1 ro 2 Y-p"r intersection 1-℃na 7 te...ro.

[沁明の目的1 %p(+shi己o Ll ty>  I’−’ta、
!’、+=、$i、IA j AT= ’hのでかり、
酵V争1°乍7耐ダ・1゛工尾び°抑ψゆ9瀕9麹にチ
喚dup−、Jl 、# 1固有ト叱バ賀Σ弔色侭1ろ
 〕乙芝目的乙す、づ。
[Kinmei's purpose 1 %p(+shiko Ll ty>I'-'ta,
! ', +=, $i, IA j AT= 'The size of h,
Fermentation battle 1° to 7 resistance, 1゛゛゛゛゛゛〈〈〈〈〈㈱㈱㈱㈱㈱㈱㈱〈〈〈〈〈〈〈〈〈〈〈〉〈〈〉〈〈〈〈〈〈〈〈〈〕 , zu.

[発明の宥1反] 上言己目的Σ尤べするための高餘斗rD (j−9,7
?+Q’であり 、特許請求の範囲竿1坤、1;詑へ〇
高分手lωv7J(、にコツハラパン酸Aミ高介ぷlこ
7合物戸ニアルカソカリ金五イλン疋4アルカッfニー
娩tA(オン力゛該ぼ言庁壬イ巳合@乙楯犯・ハンΔと
 カ1阻亙r信れ4巧゛ち良女チル高分子口11解貿乙
Δ名。
[Accomplishment of invention 1] Takayoto rD (j-9,7
? +Q', and the scope of the claims is 1 kon, 1; (On force ゛The word agency 嬬ii 巳 @Second criminal, Han Δ and the 1th obstruction r believe 4 skill ゛ good woman Chill polymer mouth 11 dissolution of trade Δname.

ラバじ酸系高庭手イじ合部71工 墓しイ高・・ガ′う
/私后裂、乞廂■1憑て゛七q虹τ・力ろ、64え1.
・、ヤワ1、メJ工(X二〇 Ar−=−()帆4)つ カーら△る該高分手化棚(以下間型PPAlあ弥ず名)
1工2’?O’Cf)力゛クス恵塀セ点、乏有し  乞
グ′メジ1−BX二O A「二+CH2+ ) h″帆べろ該高次斗イり合物(以下下図型PPA と用
泪ホ1ろ) +13SO’Cの力゛′ラヌ、私物、y、
乙2・λずれ1井にr!:!高廻1ろ力゛4れ1ニフぐ
面戸牟(峰肩し 4ト介解、ぷち−渡はyoo ′c以
三でか′ハ肴JIA耐然・トケ毛Uに過度指数で’/’
jo’c  ”e−ル、てb ソ  260°こ にb
1ブろ3框A・1ろ、一方で′1i、鮪呂今手化2合物
1よ耐薬品)°工、 化・享0勺憂と7序−・1うL 
1・1°ζ′匹7 才角(横勺j乍ζ2し、も Kセ・
)。
Lavadic acid system high garden hand joint part 71 construction grave high...ga'u/privacy, begging ■1 Possessed゛7q rainbow τ・power, 64e1.
・, Yawa 1, MEJ Engineering (X20 Ar-=-() Sai 4) Tsuka et al. (hereinafter referred to as PPAl name)
1 engineering 2'? O'Cf) Force is a good point, and it is scarce. 1ro) +13 SO'C's power゛'Ranu, personal property, y,
Otsu 2・λ difference 1 well r! :! Takatsuki 1 Roki 4 Re 1 Nifugu Mendo Mu (Mine Shoulder Shi 4 Tosukei, Petit Watari is yoo 'C is bigger than 'Ha' is a side dish JIA durable, Tokege U with excessive exponent' / '
jo'c ``e-le, te b so 260° here b
1 bro 3 stile A, 1 ro, on the other hand '1i, tunaro imoteka 2 compound 1 yo chemical resistance) degree engineering, ka kyō 0 勺う and 7 order - 1 u L
1.1°ζ′7
).

サラに/ M高G仝化か勿1まN、N−ジ゛スヶル井・
ルムプミド呵/)兄ぼ戚た腸・江楕君しあ某1・斉樋♀
さ告−r、4灸(= 、145上11妹ざ辻あろ、Jl
)吻イl+=’feさ也たイ友に5履を序良く 二 ζ
にY リ (b乙)、+f’バKを!慣努分)!6)ア
イ 1しThある1111g、1、とする二乙力゛゛て
゛でろ乙、νう連索のU暎へ1・工2耐頻ノ1゛工高今
子化合物には斤・・利、に、ε持乞油7弾釉・犀不酔某
1」秦て゛あろアルカッ43μ阪 アルカッf−#J、
溪鳴ン7る不づ也でAG’s固体電所質2乃八さこの1
ち有利ヱ°°ある。
To Sarah / M high G has changed, of course, N, N-Jisukarui.
Rumpumido 2/) Brother-in-law, Eiji-kun, and a certain person, Saihi♀
Warning-r, 4 moxibustion (=, 145 upper 11 younger sister Tsuji Aro, Jl
)Another + = 'fe Sayata I will order 5 shoes to my friend 2 ζ
ni Y ri (b ot), +f' ba K! customary effort)! 6) Eye 1 and Th are 1111 g, 1, and the second force is 1, 1, 1, 2, 1, 2, 1, 2, 1, 2, 1, 2, 1, 2, 1, 1, 1, 1, 2, ε Mochi oil 7th glaze, Sai Fusui 1" Hata Aro Aruka 43μ Saka Aruka f-#J,
Kei Ning 7 Rufuzuya de AG's solid electric place 2 Nohachi Sako 1
There are advantages.

ン乙手抄豹ガ4工rノオυ互イ脣用E fihう のに
、〒す7ビ、)ろ。
N otsu hand shoga ga 4 k r no υ mutual i 脣 use E fih, but 〒su 7 bi, )ro.

該高今冷イし郭に1柚ろぞグメ〉ト (1)7(互)1
: 本発明に用・・−)爪ろ〆高介子イし合物ぼ、ヅ列え1
工゛賃公韻初−2o’tto男云老11団υU・・ろ方
去1つyって(イもれろ6 本発明に用11ろアルカッ途為爪ス\エアルカリエ刀(
危五塩1ユ肴IZ隈滅9℃斤、・ガ゛、科上L4は・は
ラム爪がy・〕。将にLiCンOtt  L充e、F、
tんA五f)バ伍か゛ブ今よ し・ノ U実施f別1 木タト1月の火方色r」とyil+ニゾ負ず。
The high school is cold now, and I'm going to have a yuzu in the middle of the day (1) 7 (mutual) 1
: Used for the present invention...-) Tsumeroji Takasukeko Ichimonobo, Zu row 1
11th group υU...Lo way left 1 y (Imolero 6 11 ro used for this invention 11 ro Aruka temporary nails \Ecalier sword (
1 cup of salt, 9℃ catty, ・ga, medically, L4 is ・ha lamb claw is y・]. General LiC Ott L charge, F,
tn A 5 f) Ba 5 ka ゛ bu now shi ・ ノ U implementation f another 1 wood tato January's fire color r'' and yil + nizo.

11i&イ万111] )しW〜ルムアミト(y’、<下用「乙略將いづカーに
溶解し27″うA−+77県匁上に2匂直し、′?詩閏
【囁涜黄名尤明で゛あ゛)、獣°ノラウム視府物ガ′均
−i・高肴浮フィ ルム中1−介散してIIろニ乙Σ示
し ワ寸つムイズシガ゛高宥手イし合物と、錯形べBと
・・の7■的81互イγ用炙彊つ二と11、して(Iろ
、上J己め慴Iff、イし火Eグ′121 扇―乙丁1司望PPA  Av’l−ソフルオロメナ1
し又ルポ〉酸リーブ−ラフ乙、21ハA・書、デ施1万
ji’1目、4〕「、にし−(1,リチウムバ己の該高
冷¥ft、合」吻乙ソケウムづLのよ口1・汀する重量
B+ /)P斤ろザンフ”!し乏調泉しフイ不ン冴電左
91芝しb4 Zカ吟の25°cにあ1する贋1定、紹
果乏畏工1晰、5゜ 未 1 〔火陀例3] 岨にしてサンプ」し塩#A %E シ、イオン4i *
 33Jの(直にイと2)ニット博。
11i&iwan 111]) and W~rumamito (y', <lower use ``Otsuryakusho Iduka''27'' U A- + 77 prefecture momme above 2 odors,'? Poetry [whispers blasphemy Huangna Yumei in゛A゛), the Beast Noraum's visual object is a uniform, high-quality film, 1-intervening, and the second stage is shown. Shape B and...'s 7 ■ 81 Mutual I γ for Roki Tsu 2 and 11, Do (Iro, upper J self Iff, Ishibi Egu'121 Ougi - Otcho 1 Tsujibo PPA Av'l-Sofluoromena 1
Shimata report〉Acid Libraf Otsu, 21 Ha A, writing, deshi 10,000 ji'1st, 4] ", Nishi-(1, Lithium bar's own high cooling ¥ft, combination" proboscis Sokeumzu L Noyo mouth 1, weight B + /) Ai 1 Luci, 5゜Mi 1 [Fire Example 3] Salt #A %E Shi, Ion 4i *
33J's (directly A and 2) Knit Expo.

rA 70− ’10°c z’ p、叫シてρFA 
(3ffi、 k 、 4会2斥プ。
rA 70- '10°c z' p, scream ρFA
(3ffi, k, 4kai2pu.

表−2力 N。izlひ N02 のヅシブJし1コフ
昧蔑グ銃] M型f)PA  CDMF  中t’n 30°C+=
h゛l ’p劇画10痰≦糸 1シ2不、ン酸ソチクム2用・I 、宏7rU万J1〜
(ヒ鈎3 と4鋳@iLf)MF  を彩υ知・l忙鍾
し、吃扁艷で′9時間−17、又N,乾jlしfZもの
1 ’! $’.’C ?g’.ーパー違ンUb・・し
正  書  (自 発) :協和63年10月11日 5 A h・)じ20 ’10の士14)−力′見らシ
氏F。二カようへ市量為非は/bO’こτ゛台片間東墾
彰J呆したザ〉プ)しに−7+Iて(工*Vυ勺に4υ
ら小h6カ゛つり. 玖しつt,l宋帽己1列の上J己
ぬLも米1工゛す゛〉1°・V中D 川「カイλ>S導
41ニズ寸1ろ丈J子斤4yy W <ガ、して・・る
Table-2 Force N. izlhi N02's Zushibu J Shi 1 Coff Majid Gun] M type f) PA CDMF Medium t'n 30°C+=
h゛l'p Gekiga 10 phlegm ≦ thread 1 shi 2 no, acid sochikum 2 for I, Hiroshi 7rU million J1 ~
(Hi hook 3 and 4 casting @iLf) I was busy with the MF, '9 hours - 17 with a flat board, and N, dry jl and fZ thing 1'! $'. 'C? g'. - Per wrong Ub... original text (spontaneous): October 11, 1963 5 A h.) Ji 20 '10 no Shi 14) - Mr. Riki'mirashi F. Nika Yohe Ichikata Tamehi / bO' τ ゛ Tai Katama Token Akira J dumbfounded Za〉 ) to -7 + I ( 工 * Vυ 勺 to 4υ
Small h6 fishing. Kushitsu t, l Song hat 1 row above J own L also 1 rice ゛゛゛〉1°・V middle D river ``Chi λ>S lead 41 size 1 length J child cat 4yy W < Gah, do it...

[)MF.会千の柚十車(ニー血史に・肘つム丙翫イと
オル亙j=¥ffiと持つのτ′1 サンプ”1し中−
nDMFの一音p1ま゛2ーケウ!−)(ソ相ター1乍
用乞持つ。斤カー、冬犬方巳/FJ言調の!!:殴(里
イ友16・、2て七♂プンフ01しの」シル1゛虫に児
カ゛(プ」二 D Σεイt9+;丁八へが 、 ブ三
 。
[)MF. Kaisen no Yujuguruma (in the history of history, elbows, arms, legs, etc. = ¥ffi and τ′1 sump” 1 and medium-
One sound of nDMF p1 ma2-keu! -) (Sosaitar 1 is begging. Ka, Fuyuinu Katsumi/FJ's tone!!: Beating (Ritomo 16, 2 7♂ Punfu 01 Shino) Sil 1゛ Insects and children Ka ゛(pu) 2 D Σε it9+;

Claims (2)

【特許請求の範囲】[Claims] (1)高分子化合物にアルカリ金属塩又はアルカリ土類
金属を含有させてなる高分子固 体電解質において、該高分子化合物が下記一般式(I)
の繰り返し単位からなるセグメント(I)またはセグメ
ント(I)および下記一般式(II)の繰り返し単位から
なるセグメント(II)の結合を有するポリパラバン酸ま
たはそのイミノ酸前駆体であることを特徴とする高分子
固体電界質: ▲数式、化学式、表等があります▼・・・(I) ▲数式、化学式、表等があります▼・・・(II) (ただし、ArおよびAr′は異なる2価の芳香族基で
あり、XはNHまたはOを表す)
(1) In a solid polymer electrolyte in which a polymer compound contains an alkali metal salt or an alkaline earth metal, the polymer compound has the following general formula (I).
or a polyparabanic acid or its imino acid precursor having a segment (I) consisting of a repeating unit of Molecular solid electrolyte: ▲There are mathematical formulas, chemical formulas, tables, etc.▼...(I) ▲There are mathematical formulas, chemical formulas, tables, etc.▼...(II) (However, Ar and Ar' are different divalent aromatic (X represents NH or O)
(2)極性溶剤をアルカリ金属又はアルカリ土類金属の
付加体又は該極性溶剤単独として又は該極性溶剤と該付
加体の混合物として含有することを特徴とする特許請求
の範囲第1項に記載の高分子固体電解質。
(2) The method according to claim 1, which contains a polar solvent as an adduct of an alkali metal or an alkaline earth metal, or as the polar solvent alone or as a mixture of the polar solvent and the adduct. Polymer solid electrolyte.
JP63237937A 1988-09-21 1988-09-21 Polymer solid electrolyte Expired - Fee Related JP2833626B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP63237937A JP2833626B2 (en) 1988-09-21 1988-09-21 Polymer solid electrolyte

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63237937A JP2833626B2 (en) 1988-09-21 1988-09-21 Polymer solid electrolyte

Publications (2)

Publication Number Publication Date
JPH0286658A true JPH0286658A (en) 1990-03-27
JP2833626B2 JP2833626B2 (en) 1998-12-09

Family

ID=17022671

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63237937A Expired - Fee Related JP2833626B2 (en) 1988-09-21 1988-09-21 Polymer solid electrolyte

Country Status (1)

Country Link
JP (1) JP2833626B2 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005209379A (en) * 2004-01-20 2005-08-04 Samsung Sdi Co Ltd Gel electrolyte, electrode for fuel cell, and fuel cell
WO2006001083A1 (en) * 2004-06-29 2006-01-05 Samsung Yokohama Research Institute Solid polymer electrolyte, electrode for fuel cell, and fuel cell

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7537853B2 (en) 2004-01-20 2009-05-26 Samsung Sdi Co., Ltd. Gel electrolyte, electrode for fuel cell, and fuel cell
JP4913397B2 (en) 2005-12-12 2012-04-11 三星エスディアイ株式会社 Proton conducting solid polymer electrolyte and fuel cell

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005209379A (en) * 2004-01-20 2005-08-04 Samsung Sdi Co Ltd Gel electrolyte, electrode for fuel cell, and fuel cell
JP4637488B2 (en) * 2004-01-20 2011-02-23 三星エスディアイ株式会社 Gel electrolyte and fuel cell electrode and fuel cell
WO2006001083A1 (en) * 2004-06-29 2006-01-05 Samsung Yokohama Research Institute Solid polymer electrolyte, electrode for fuel cell, and fuel cell

Also Published As

Publication number Publication date
JP2833626B2 (en) 1998-12-09

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