JPH0269541A - Insulating composition - Google Patents
Insulating compositionInfo
- Publication number
- JPH0269541A JPH0269541A JP22023888A JP22023888A JPH0269541A JP H0269541 A JPH0269541 A JP H0269541A JP 22023888 A JP22023888 A JP 22023888A JP 22023888 A JP22023888 A JP 22023888A JP H0269541 A JPH0269541 A JP H0269541A
- Authority
- JP
- Japan
- Prior art keywords
- mixture
- oxidative deterioration
- polyethylene
- insulating composition
- butyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 21
- 239000003112 inhibitor Substances 0.000 claims abstract description 11
- 230000006866 deterioration Effects 0.000 claims abstract description 10
- 230000001590 oxidative effect Effects 0.000 claims abstract description 10
- -1 polyethylene Polymers 0.000 claims abstract description 7
- 239000004698 Polyethylene Substances 0.000 claims abstract description 6
- 150000001412 amines Chemical class 0.000 claims abstract description 6
- 229920000573 polyethylene Polymers 0.000 claims abstract description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims abstract description 5
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000012948 isocyanate Substances 0.000 claims abstract description 3
- 150000002513 isocyanates Chemical class 0.000 claims abstract description 3
- 238000004132 cross linking Methods 0.000 abstract description 11
- 240000005572 Syzygium cordatum Species 0.000 abstract description 9
- 235000006650 Syzygium cordatum Nutrition 0.000 abstract description 9
- 238000002156 mixing Methods 0.000 abstract description 4
- 239000003431 cross linking reagent Substances 0.000 abstract description 3
- HXIQYSLFEXIOAV-UHFFFAOYSA-N 2-tert-butyl-4-(5-tert-butyl-4-hydroxy-2-methylphenyl)sulfanyl-5-methylphenol Chemical compound CC1=CC(O)=C(C(C)(C)C)C=C1SC1=CC(C(C)(C)C)=C(O)C=C1C HXIQYSLFEXIOAV-UHFFFAOYSA-N 0.000 abstract description 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract description 2
- 229920001684 low density polyethylene Polymers 0.000 abstract description 2
- 239000004702 low-density polyethylene Substances 0.000 abstract description 2
- VMZVBRIIHDRYGK-UHFFFAOYSA-N 2,6-ditert-butyl-4-[(dimethylamino)methyl]phenol Chemical compound CN(C)CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 VMZVBRIIHDRYGK-UHFFFAOYSA-N 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 8
- 239000012212 insulator Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 238000001125 extrusion Methods 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 3
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 2
- 229920003020 cross-linked polyethylene Polymers 0.000 description 2
- 239000004703 cross-linked polyethylene Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 125000003143 4-hydroxybenzyl group Chemical group [H]C([*])([H])C1=C([H])C([H])=C(O[H])C([H])=C1[H] 0.000 description 1
- OIGWAXDAPKFNCQ-UHFFFAOYSA-N 4-isopropylbenzyl alcohol Chemical compound CC(C)C1=CC=C(CO)C=C1 OIGWAXDAPKFNCQ-UHFFFAOYSA-N 0.000 description 1
- 241001441571 Hiodontidae Species 0.000 description 1
- 230000003679 aging effect Effects 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 229920005601 base polymer Polymers 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000013256 coordination polymer Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000002530 phenolic antioxidant Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
Abstract
Description
【発明の詳細な説明】
〈産業上の利用分野〉
本発明は、電線・ケーブル、特に電カケープルまたはこ
れらの接続部に用いて有用な絶縁組成物に関するもので
ある。DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to an insulating composition useful for electric wires and cables, particularly electric cables or their connections.
〈従来の技術〉
従来、電線・ケーブルの絶縁体またはこれらの接続部を
形成するには、架橋ポリエチレンを加熱架橋させていた
。そして、この架橋ポリエチレンの架橋剤としては、一
般にジクミルパーオキサイド（以下、ＤＣＰという）が
使用されている。<Prior Art> Conventionally, in order to form insulators for electric wires and cables or connection parts thereof, crosslinked polyethylene was crosslinked by heating. Dicumyl peroxide (hereinafter referred to as DCP) is generally used as a crosslinking agent for this crosslinked polyethylene.
〈発明が解決しようとする課題〉
ところが、このＤＣＰの場合には、次のようにな問題が
あった。<Problems to be Solved by the Invention> However, this DCP has the following problems.
（１）架橋度を向上させるため、ＤＣＰを多量に添加す
ると、押出時にスコーチ（早期架橋）が生じ、電線・ケ
ーブルあるいは接続部の絶縁体中にアンバー（焼は樹脂
）が発生し、絶縁性能を低下させる恐れがあった。(1) If a large amount of DCP is added to improve the degree of crosslinking, scorch (early crosslinking) will occur during extrusion, and amber (burnt resin) will be generated in the insulator of electric wires/cables or connections, resulting in poor insulation performance. There was a risk that it would reduce the
（２） Ｄ ＣＰは、架橋時にクミルアルコール（以下
、ＣＡという）とアセトフェノン（以下、ＡＰという）
とになり、このＣＡは、絶縁体のモールド時の熱により
、分解して、α−メチルスチレン（以下、α−ＭＳとい
う）と水になる。(2) D CP combines cumyl alcohol (hereinafter referred to as CA) and acetophenone (hereinafter referred to as AP) during crosslinking.
This CA is decomposed by the heat generated during molding of the insulator and becomes α-methylstyrene (hereinafter referred to as α-MS) and water.
この水は、絶縁体中で凝集され、電線・ケーブルに電場
が掛けられると、水トリー発生の原因となる。この水ト
リーは、絶縁体の絶縁破壊電圧の低下を招くと考えられ
ている。This water condenses in the insulator and causes water tree formation when an electric field is applied to the wire or cable. This water tree is thought to cause a decrease in the dielectric breakdown voltage of the insulator.
そこで、本発明者等は、このＤＣＰの使用量を相対的に
抑えるべ（、他の架橋剤（トリアリルイソシアネート、
以下、ＴＡＩＣという）や、特定の酸化劣化防止剤等を
混合して、ベースポリマーであるポリエチレンに添加し
たところ、水トリーの発生が良好に抑制されることを見
出した。Therefore, the present inventors proposed that the amount of DCP used should be relatively suppressed (and other crosslinking agents (triallyl isocyanate,
It has been found that when a mixture of TAIC (hereinafter referred to as TAIC), a specific oxidative deterioration inhibitor, etc. is added to polyethylene as a base polymer, the occurrence of water trees can be effectively suppressed.
本発明は、このような事実に基づいてなされたものであ
る。The present invention has been made based on these facts.
〈課題を解決するための手段及びその作用〉か＼る本発
明は、ポリエチレン１００重量部と、ＤＣＰとＴＡ Ｉ
Ｃとの混合物１． ０〜３．０重量部と、フェノール
系酸化劣化防止剤とアミン系酸化劣化防止剤との混合物
０．１０〜０．４０重量部とからなる絶縁組成物にある
。<Means for solving the problems and their effects> The present invention consists of 100 parts by weight of polyethylene, DCP and TA I.
Mixture with C1. 0 to 3.0 parts by weight, and 0.10 to 0.40 parts by weight of a mixture of a phenolic oxidative deterioration inhibitor and an amine oxidative deterioration inhibitor.
本発明において、ＴＡ Ｉ ＣはＤＣＰに対して、架橋
助剤として働きをするためのもので、ＤＣＰとの混合割
合は、ＤＣＰ：ＴＡＩＣ＝４ ： １〜１：１程度が好
ましく、そして、その混合合計量は１．０〜３．０重量
部とする。なぜなら、１゜０重量部未満では所望の架橋
度が得られず、逆に３．０重量部を越えるとスコーチが
生じるようになるからである。In the present invention, TAIC acts as a crosslinking aid for DCP, and the mixing ratio with DCP is preferably about 4:1 to 1:1; The total amount of the mixture is 1.0 to 3.0 parts by weight. This is because if it is less than 1.0 parts by weight, the desired degree of crosslinking cannot be obtained, and if it exceeds 3.0 parts by weight, scorch will occur.
また、本発明で使用されるフェノール系酸化劣化防止剤
としては、４，４′−チオビス（６−ｔ−ブチル−３−
メチルフェノール）（以下、４４′−チオビスという）
、ビス〔２−メチル−４−（３−ｎ−アルキル（Ｃ２２
またはＣ１４）チオプロピオニルオキシ）−５−１−ブ
チルフェニル〕スルフィド、１，３．５−トリス（３’
、５−ジ−ターシャリ−−ブチル−４−ヒドロキンベン
ゾイル）イソシアヌレ−１−（以下、１．３５−トリス
という）、ビス（３，５−ジ−ターシャリー−７’チル
−°４−ヒドロキシベンジル）スルフィド（以下、３，
５−スルフィドという）等が挙げられる。また、アミン
系酸化劣化防止剤としては、２．４−ビス−（ｎ−オチ
ルチオ）−６−（４−ヒドロキシ−３，５−ジーも一ブ
チルアニリノ）−１，３，５−トリアジン（以下、２．
４−ビス−１，３，５−）リアジンという）、Ｎ。In addition, as the phenolic antioxidant used in the present invention, 4,4'-thiobis(6-t-butyl-3-
methylphenol) (hereinafter referred to as 44'-thiobis)
, bis[2-methyl-4-(3-n-alkyl (C22
or C14) thiopropionyloxy)-5-1-butylphenyl] sulfide, 1,3,5-tris(3'
, 5-di-tert-butyl-4-hydroquinebenzoyl) isocyanure-1- (hereinafter referred to as 1.35-tris), bis(3,5-di-tert-7'thyl-°4-hydroxy benzyl) sulfide (hereinafter referred to as 3,
5-sulfide), etc. In addition, as an amine-based oxidative deterioration inhibitor, 2,4-bis-(n-ocylthio)-6-(4-hydroxy-3,5-di-butylanilino)-1,3,5-triazine (hereinafter referred to as 2.
4-bis-1,3,5-)riazine), N.
Ｎ″−へキサメチレンビス（３，５−ジーも一ブチルヒ
ドロキシーヒドロシンナマミド（以下、Ｎ。N″-hexamethylenebis(3,5-di-butylhydroxy-hydrocinnamamide (hereinafter referred to as N).
Ｎ′−へキサメチレンビスという）、２．６−ジタージ
ャジー−ブチル−α−ジメチルアミノＰ−クレゾール（
以下、２．６−Ｐ−クレゾールという）等が挙げられる
。N'-hexamethylenebis), 2,6-diterjadi-butyl-α-dimethylamino P-cresol (referred to as
(hereinafter referred to as 2,6-P-cresol).
そして、これらのフェノール系とアミン系の酸化劣防止
剤の混合合計量は、０．１０〜０．４０重量部とする。The total amount of these phenol-based and amine-based oxidation inhibitors mixed is 0.10 to 0.40 parts by weight.
なぜなら、０．１０重量部未満では熱老化特性が悪く、
十分な改善が図られず、また０、４０重量部を越えると
今度は架橋度が低下するからである。そして、さらにこ
れらのフェノール系とアミン系の酸化劣化止剤自体の配
合割合は、ＤＣＰの添加量との関係で、種々変えるもの
とする。This is because if it is less than 0.10 parts by weight, the heat aging properties will be poor.
This is because sufficient improvement cannot be achieved, and if the amount exceeds 0.40 parts by weight, the degree of crosslinking will decrease. Furthermore, the blending ratio of these phenol-based and amine-based oxidative deterioration inhibitors themselves shall be varied depending on the amount of DCP added.
また、本発明で用いられるポ・リエチレンは、特に限定
されないが、低密度ポリエチレンが好ましく、そして、
さらにその端末炭素−炭素二重結合が炭素数１０００個
当たり０．７〜１． ５個、メルトフローレシオ（Ｍ、
Ｆ、Ｒ，）が０．５〜４゜０であることが望ましい。な
ぜらな、端末炭素−炭素二重結合数値が０．７個未満で
は架橋度が低く、またこの数が１．５個を越えるとスコ
ーチが生じ易いからである。また、メルトフローレシオ
が０，５未満ではスコーチが生じ易く、これが４゜０を
越えると偏肉や垂れ落ちが生じるからである。Further, the polyethylene used in the present invention is not particularly limited, but low density polyethylene is preferable, and
Furthermore, the terminal carbon-carbon double bond is 0.7 to 1 per 1000 carbon atoms. 5 pieces, melt flow ratio (M,
F, R,) is preferably 0.5 to 4°0. This is because if the number of terminal carbon-carbon double bonds is less than 0.7, the degree of crosslinking is low, and if this number exceeds 1.5, scorch is likely to occur. Further, if the melt flow ratio is less than 0.5, scorch is likely to occur, and if it exceeds 4.0, uneven thickness or dripping will occur.
〈実施例■〉
第１表に示した配合により、本発明に係る絶縁組成物（
実施例■〜■）と本発明の条件を満たさない絶縁組成物
（比較例■〜■）とを作り、ケーブルの絶縁体およびケ
ーブル接続部の絶縁体を形成した。<Example ■> The insulating composition according to the present invention (
Examples 1 to 2) and insulating compositions that did not meet the conditions of the present invention (Comparative Examples 1 to 2) were prepared to form cable insulators and cable connection insulators.
そして、これらの各絶縁組成物について、その特性（ス
コーチタイム、押出〜加熱後の水分の発生量）を調べた
。なお、スコーチタイム測定試験、水分発生量測定試験
は次のようにして行った。The properties (scorch time, amount of moisture generated after extrusion and heating) of each of these insulating compositions were investigated. The scorch time measurement test and the water generation amount measurement test were conducted as follows.
（１）スコーチタイム測定試験
ムーニー粘度計を用い、最低トルク値より、５ポイント
上昇するまでの時間をスコーチタイムとして測定した。(1) Scorch time measurement test Using a Mooney viscometer, the time required for the torque to increase by 5 points from the lowest torque value was measured as the scorch time.
（２）水分発生量測定試験
押出後、モールドを模擬した加熱後と２段階に分けて１
．カールフィッシャー法により行った。(2) Moisture generation amount measurement test After extrusion, after heating to simulate the mold, and 1
．． This was carried out using the Karl Fischer method.
上記第１表において、各実施例■〜■と比較例■〜■と
を比べた場合、組成物の分解残漬物中における水分量は
、押出後にあってはそれほど大きな差はないが、モール
ド加熱を模擬した加熱後（１６０°ＣＸ４時間）にあっ
ては大きく異なる。In Table 1 above, when comparing each of Examples ■ to ■ and Comparative Examples ■ to ■, the water content in the decomposition residue of the composition does not differ much after extrusion, but After heating (160°C for 4 hours), which simulates
つまり、実施例■〜■においては、ＣＡはあまり分解せ
ず、押出後の水分量と同じ１１００ｐｐ以下に対して、
比較例■〜■では、ＣＡが分解して、α−ＭＳと水とな
り、その水分量は、例えば実施例■と比較例■を比べる
と、約６倍以上にもなっている。In other words, in Examples ■ to ■, CA did not decompose much, and when the moisture content after extrusion was 1100 pp or less,
In Comparative Examples (2) to (2), CA decomposes into α-MS and water, and the water content is about six times or more, for example, when comparing Example (2) and Comparative Example (2).
また、架橋特性の一つであるゲル分率とスコーチタイム
において、各実施例■〜■と比較例■〜■とを比較した
場合、実施例■〜■の組成物では架橋度が高く、なおか
つスコーチは比較例■〜■と同程度であることが判る。In addition, in terms of gel fraction and scorch time, which are one of the crosslinking properties, when comparing Examples ■ to ■ and Comparative Examples ■ to ■, it was found that the compositions of Examples ■ to ■ had a high degree of crosslinking, and It can be seen that the scorch is at the same level as Comparative Examples ■ to ■.
〈実施例■〉
上記第１表の実施例■は比較例■の組成物を用いて、６
６ｋＶ、１ｃＸ４００ｍｍ２ＣＶケーフルの接続部にモ
ールドジヨイントを施し、７０に■６カ月の長期課電通
を行い、その後、水トリーの観察を行った。<Example ■> Example ■ in Table 1 above uses the composition of Comparative Example ■.
A mold joint was applied to the connection part of a 6 kV, 1 c x 400 mm 2 CV cable, and the 70 was subjected to long-term energization for 6 months, after which the water tree was observed.
その結果は、実施例■の場合、水トリーの発生は極めて
少なく、比較例■の場合には、水トリーが多発している
ことが確認された。つまり、本発明品では水トリーの発
生が効果的に抑制されていることが判る。The results showed that in the case of Example (2), the occurrence of water trees was extremely small, and in the case of Comparative Example (2), it was confirmed that water trees occurred frequently. In other words, it can be seen that the product of the present invention effectively suppresses the occurrence of water trees.
〈発明の効果〉
以上の説明から明らかなように本発明によれば、電線・
ケーブルの絶縁体およびそれらの接続部を形成するにお
いて、高い架橋度が得られ、またスコーチが発生しにに
くかつ水トリーの発生数のない、長期に亙って安定した
性能を呈する、優れた絶縁組成物を提供することができ
る。<Effects of the Invention> As is clear from the above explanation, according to the present invention, electric wires and
An excellent product that has a high degree of cross-linking, is resistant to scorch, has no water trees, and exhibits stable performance over a long period of time when forming cable insulation and their connections. An insulating composition can be provided.
特許出願人 藤倉電線株式会社Patent applicant: Fujikura Electric Wire Co., Ltd.
Claims (1)
とトリアリルイソシアネートとの混合物１．０〜３．０
重量部と、フェノール系酸化劣化防止剤とアミン系酸化
劣化防止剤との混合物０．１０〜０．４０重量部とから
なる絶縁組成物。100 parts by weight of polyethylene, a mixture of dicumyl peroxide and triallyl isocyanate 1.0 to 3.0 parts by weight
parts by weight, and 0.10 to 0.40 parts by weight of a mixture of a phenolic oxidative deterioration inhibitor and an amine oxidative deterioration inhibitor.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22023888A JPH0269541A (en) | 1988-09-02 | 1988-09-02 | Insulating composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22023888A JPH0269541A (en) | 1988-09-02 | 1988-09-02 | Insulating composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0269541A true JPH0269541A (en) | 1990-03-08 |
Family
ID=16748055
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP22023888A Pending JPH0269541A (en) | 1988-09-02 | 1988-09-02 | Insulating composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0269541A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012007111A (en) * | 2010-06-25 | 2012-01-12 | Viscas Corp | Liquid additive composition, and method for producing power cable or power cable joint |
| JP2016503101A (en) * | 2012-12-29 | 2016-02-01 | ダウ グローバル テクノロジーズ エルエルシー | Crosslinkable polymer composition, method of making the same, and article made therefrom |
| KR20160119073A (en) * | 2013-12-19 | 2016-10-12 | 보레알리스 아게 | A new polymer composition, power cable insulation and power cable |
| KR20160119072A (en) * | 2013-12-19 | 2016-10-12 | 보레알리스 아게 | A new low MFR polymer composition, power cable insulation and power cable |
| JP2017500413A (en) * | 2013-12-19 | 2017-01-05 | ボレアリス エージー | Novel cross-linked polymer composition, power cable insulation and power cable |
| JP2017501271A (en) * | 2013-12-19 | 2017-01-12 | ボレアリス エージー | Novel cross-linked low MFR polymer composition, power cable insulation and power cable |
| JP2017222852A (en) * | 2017-06-07 | 2017-12-21 | ダウ グローバル テクノロジーズ エルエルシー | Crosslinkable polymer composition and method for producing the same, and article produced from the same |
-
1988
- 1988-09-02 JP JP22023888A patent/JPH0269541A/en active Pending
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2012007111A (en) * | 2010-06-25 | 2012-01-12 | Viscas Corp | Liquid additive composition, and method for producing power cable or power cable joint |
| JP2016503101A (en) * | 2012-12-29 | 2016-02-01 | ダウ グローバル テクノロジーズ エルエルシー | Crosslinkable polymer composition, method of making the same, and article made therefrom |
| JP2017503048A (en) * | 2013-12-19 | 2017-01-26 | ボレアリス エージー | Novel low MFR polymer composition, power cable insulation and power cable |
| KR20160119072A (en) * | 2013-12-19 | 2016-10-12 | 보레알리스 아게 | A new low MFR polymer composition, power cable insulation and power cable |
| JP2017500413A (en) * | 2013-12-19 | 2017-01-05 | ボレアリス エージー | Novel cross-linked polymer composition, power cable insulation and power cable |
| JP2017501271A (en) * | 2013-12-19 | 2017-01-12 | ボレアリス エージー | Novel cross-linked low MFR polymer composition, power cable insulation and power cable |
| KR20160119073A (en) * | 2013-12-19 | 2016-10-12 | 보레알리스 아게 | A new polymer composition, power cable insulation and power cable |
| JP2017503050A (en) * | 2013-12-19 | 2017-01-26 | ボレアリス エージー | Novel polymer composition, power cable insulation and power cable |
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| US10347390B2 (en) | 2013-12-19 | 2019-07-09 | Borealis Ag | Polymer composition, power cable insulation and power cable |
| EP3083795B1 (en) | 2013-12-19 | 2019-10-02 | Borealis AG | A new polymer composition, power cable insulation and power cable |
| EP3569648B1 (en) | 2013-12-19 | 2020-09-30 | Borealis AG | Power cable |
| US11355260B2 (en) | 2013-12-19 | 2022-06-07 | Borealis Ag | Low MFR polymer composition, power cable insulation and power cable |
| JP2017222852A (en) * | 2017-06-07 | 2017-12-21 | ダウ グローバル テクノロジーズ エルエルシー | Crosslinkable polymer composition and method for producing the same, and article produced from the same |
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