JPH0261153A - Nonwoven fabric and production thereof - Google Patents

Nonwoven fabric and production thereof

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Publication number
JPH0261153A
JPH0261153A JP21201688A JP21201688A JPH0261153A JP H0261153 A JPH0261153 A JP H0261153A JP 21201688 A JP21201688 A JP 21201688A JP 21201688 A JP21201688 A JP 21201688A JP H0261153 A JPH0261153 A JP H0261153A
Authority
JP
Japan
Prior art keywords
web
nonwoven fabric
thermoplastic resin
nonwoven
melting point
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP21201688A
Other languages
Japanese (ja)
Inventor
Soichi Inoue
壮一 井上
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toyobo Co Ltd
Original Assignee
Toyobo Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toyobo Co Ltd filed Critical Toyobo Co Ltd
Priority to JP21201688A priority Critical patent/JPH0261153A/en
Publication of JPH0261153A publication Critical patent/JPH0261153A/en
Pending legal-status Critical Current

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  • Nonwoven Fabrics (AREA)

Abstract

PURPOSE:To provide a nonwoven fabric having thermoplastic resin powder adhered on the surface thereof, a soft touch and excellent surface abrasion resistance, tear strength, etc., by placing a specific amount of the specified thermoplastic resin power on the surface of the nonwoven fabric web and heating and subsequently or simultaneously pressing the placed powder at a specific temperature. CONSTITUTION:A thermoplastic resin podwer (e.g., polyester powder) having an average particle size (preferably 80-95mum) larger than the spaces between the constituting fibers of a nonwoven fabric web (e.g., rayon web) and having a melting point lower than that of the constituting fibers is placed on at least one surface of the nonwoven fabric in a density of 1-30cm<2>, preferably 3-20cm<2>, per m<2> of the web and the web is heated at a temperature lower than the melting point of the constituting fibers of the web and higher than the melting point of the powder and subsequently or simultaneously pressed to provide the nonwoven fabric.

Description

【発明の詳細な説明】 (産業1・、の利用分野) 本発明は、不織布ウェブへの熱可塑性樹脂の点接合によ
り、不織布構造を固定した不織布に係り、特に編物、織
物に近い柔軟な風合いを持ちながらも表面耐摩耗性、引
裂強力等の優れた不織布及びその製造方法に関するもの
である。
Detailed Description of the Invention (Field of Application for Industry 1) The present invention relates to a nonwoven fabric having a fixed nonwoven structure by point bonding a thermoplastic resin to a nonwoven fabric web, and particularly relates to a nonwoven fabric with a soft texture similar to that of knitted fabrics or woven fabrics. The present invention relates to a nonwoven fabric with excellent surface abrasion resistance, tear strength, etc., and a method for producing the same.

(従来の技術) 従来、不織布ウェブの接合方法に関しては種々のものが
提案されている。例えば樹脂分散溶液に不織布ウエブを
含浸した後で乾燥する方法や不織布ウェブを部分的に熱
融着する方法が主に知られている。
(Prior Art) Conventionally, various methods for joining nonwoven fabric webs have been proposed. For example, a method in which a nonwoven fabric web is impregnated with a resin dispersion solution and then dried, and a method in which a nonwoven fabric web is partially heat-sealed are known.

しかしながら、これらの方法によって接合された不織布
の柔軟性、表面耐摩耗性、引裂強力などの性能は編物、
織物のそれらに対して程遠いという欠点があった。また
、不織布ウェブに低融点樹脂粉末をラミネートする方法
が知られている(特開昭83−152472)。しかし
ながら、接合される不織布ウェブの特徴が接合条件(ラ
ミネート条件)に影響すると考えられるが、この方法で
は、まだ柔軟性等が解決されていない。
However, the flexibility, surface abrasion resistance, and tear strength of nonwoven fabrics bonded by these methods are inferior to knitted fabrics,
It had the disadvantage that it was far from being comparable to that of textiles. Furthermore, a method is known in which a nonwoven fabric web is laminated with a low melting point resin powder (Japanese Patent Laid-Open No. 83-152472). However, although the characteristics of the nonwoven fabric webs to be joined are thought to affect the joining conditions (laminating conditions), flexibility and other issues have not yet been resolved with this method.

(発明が解決しようとする課題) 本発明は、従来の技術の問題点を解決した不織布及びそ
の接合力法即ち、柔軟な風合いと表面耐摩耗性、引裂強
力に優れた不織布及びその製造方法の提供を課題とする
ものである。
(Problems to be Solved by the Invention) The present invention provides a nonwoven fabric and its bonding method that solve the problems of the conventional technology, that is, a nonwoven fabric that has excellent soft texture, surface abrasion resistance, and tear strength, and a method for producing the same. The challenge is to provide this information.

(課題を解決する為の1段) 4−記の課題を解決するため、不織布ウェブの表面層に
熱可塑性樹脂粉体を付与し、接合することによって柔軟
な風合いと優れた表面耐摩耗性、9裂強力を付lj、す
るII的で検討した結果、本発明に到達した。すなわち
、本発明は、不織布ウェブの少なくとも一方の表面層に
不織布ウェブ構成繊維間隙量りの平均粒径を有する熱可
塑性樹脂粉体が付与されて、該不織布ウェブ表面に接着
されている事を特徴とする不織布、不織布ウェブの少な
くとも一方の表面層に該不織布ウェブの構成繊維間隙以
上の平均粒径を有する熱可塑性樹脂粉体を不織布ウェブ
1r1当り、1〜30cJの付与量でムラなく付与し、
ついで不織布ウェブを構成する繊維の融点未満でしかも
前記熱可塑性樹脂の融点量[−の温度で加熱した後圧着
するか又は、加熱圧7トすることを特徴とする不織布の
製造方法をその手段とするものである。
(Step 1 to solve the problem) In order to solve the problem described in 4-, thermoplastic resin powder is added to the surface layer of the nonwoven fabric web and bonded, thereby creating a flexible texture and excellent surface abrasion resistance. The present invention was arrived at as a result of extensive investigation into the strength of nine fissures. That is, the present invention is characterized in that a thermoplastic resin powder having an average particle size determined by the gap between fibers constituting the nonwoven web is applied to at least one surface layer of the nonwoven web and is adhered to the surface of the nonwoven web. Thermoplastic resin powder having an average particle diameter larger than the gap between constituent fibers of the nonwoven web is evenly applied to at least one surface layer of the nonwoven fabric and the nonwoven web at an application amount of 1 to 30 cJ per 1 r1 of the nonwoven fabric web,
The method for producing a nonwoven fabric is then heated at a temperature below the melting point of the fibers constituting the nonwoven fabric web and at a temperature less than or equal to the melting point of the thermoplastic resin, followed by compression bonding or heating and pressure. It is something to do.

以上に本発明の詳細な説明する。The present invention will now be described in detail.

本発明において、不織布ウェブの構成繊維間隙とは、ウ
ェブを構成する網[」状の繊維同志の)14均的な間隔
をいう。この間隙の測定は、光学顕微鏡観察によって不
織布ウェブを構成する網[1状の1つの面積をn = 
20で求めた平均値の平方根であられした。
In the present invention, the term "gap between the fibers constituting the nonwoven web" refers to the uniform spacing between the net-like fibers constituting the web. The gap was measured by optical microscopic observation, where n =
It was calculated by the square root of the average value obtained in step 20.

熱++J塑性樹脂とは、好ましくはポリエステル、ポリ
オレフィンなどでありその融点が不織布ウェブの融点よ
りも低いものであればよい。ここに、融点の測定は、次
の方法による。その方法とは、JISK7121の8.
8(1)により、あらかじめ融解温度より約100°C
低い温度で装置が安定するまで保持した後、加熱速度毎
分10℃で融解定し、そのピークの頂点を融点とした(
試料約5mg)  。
The thermo++J plastic resin is preferably polyester, polyolefin, or the like, as long as its melting point is lower than the melting point of the nonwoven web. Here, the melting point is measured by the following method. The method is 8. of JISK7121.
8 (1), the temperature should be about 100°C above the melting temperature in advance.
After maintaining the device at a low temperature until it stabilized, the melting rate was determined at a heating rate of 10°C per minute, and the apex of the peak was taken as the melting point (
sample (approx. 5 mg).

また熱可塑性樹脂粉体の粒径は不織布ウェブ構成繊維間
隙以上の<1i−均粒径を有している事が必要である。
Further, the particle size of the thermoplastic resin powder must be <1i-average particle size, which is larger than the gap between the fibers constituting the nonwoven web.

これは不織布の表面層だけ、不織布ウェブ繊維を部分的
に拘束(接合)シ、不織布ウェブ内層のウェブ繊維の自
由度を高める為である。もし不織布ウェブ構成繊維間隙
未満の平均粒径を有する熱可塑性樹脂を不織布ウェブ表
面層に付与しても、ウェブ構成繊維間隙に、この熱可塑
性樹脂が入り込んでしまい不織布ウェブ内層の繊維まで
拘束を受けてしまいできた不織布はあたかも樹脂含浸さ
れた様な挙動を示してしまう。したがって柔軟な風合い
と表面耐摩耗性、引裂強力のバランスのとれた不織布で
はなくなってしまう。具体的には、熱可塑性樹脂の平均
粒径は好ましくは30u〜200戸であり、さらに好ま
しくは、50戸〜150戸であり、特に好ましくは70
戸〜100戸であり、非常に好ましくは80戸〜95u
である・Jfが望まれる。これは、30μm未満の熱0
工塑性樹脂を不織布ウェブに付’jニジても不織布ウェ
ブを構成する繊維同志の接合力が著しく低ドしてしまい
、またMIIf塑性樹脂が不織布ウェブの内層に入り込
んでしまい、前記した様に樹脂含浸処理された様な挙動
を示して、風合いが堅くなってしまう。また、200/
jJ11をこえる範囲の熱可塑性樹脂を付′j、シても
不織布ウェブ構成繊維を過度に接着してしまい、したが
って構成繊組の自由度を拘束してしまう為に風合いが堅
くなってしまうからである。なお、(1i、均粒径は、
次の測定方法による。
This is because only the surface layer of the nonwoven fabric partially restrains (bonds) the nonwoven fabric web fibers and increases the degree of freedom of the web fibers in the inner layer of the nonwoven fabric web. Even if a thermoplastic resin having an average particle diameter smaller than the gap between the fibers constituting the nonwoven web is applied to the surface layer of the nonwoven web, this thermoplastic resin will enter the gap between the fibers constituting the web, and even the fibers in the inner layer of the nonwoven web will be restrained. The resulting nonwoven fabric behaves as if it were impregnated with resin. Therefore, it is no longer a nonwoven fabric that has a good balance of soft texture, surface abrasion resistance, and tear strength. Specifically, the average particle size of the thermoplastic resin is preferably 30 u to 200 u, more preferably 50 u to 150 u, particularly preferably 70 u to 150 u.
100 units, very preferably 80 units to 95 units
・Jf is desired. This is a thermal zero below 30 μm.
Even if an engineering plastic resin is applied to a nonwoven fabric web, the bonding force between the fibers that make up the nonwoven fabric web will be significantly reduced, and the MIIF plastic resin will enter the inner layer of the nonwoven fabric web, resulting in It behaves as if it has been impregnated and the texture becomes stiff. Also, 200/
Even if a thermoplastic resin exceeding JJ11 is applied, the fibers that make up the nonwoven web will be excessively bonded, and the degree of freedom of the constituent fibers will be restricted, resulting in a stiff texture. be. In addition, (1i, average particle size is
According to the following measurement method.

その方法とは、光学顕微鏡によって、粒径をn=20以
−IJjJ察し、その平均値を・+1均粒径とした。
In this method, the particle size was observed using an optical microscope, and the average value was determined as +1 average particle size.

以」ユの様な条件でできた不織布は、不織布の断面方向
に熱可塑性樹脂が不織布表面層に付F>されているもの
で、少なくとも不織布ウエブの内層の一部分が熱可塑性
樹脂によって接着されておらずフリーな状態である事が
望ましい。
A nonwoven fabric made under the conditions described above is one in which a thermoplastic resin is attached to the surface layer of the nonwoven fabric in the cross-sectional direction of the nonwoven fabric, and at least a part of the inner layer of the nonwoven fabric web is bonded with the thermoplastic resin. It is desirable that it be in a free state.

次に、本発明の不織布の製造方法について説明する。Next, the method for manufacturing the nonwoven fabric of the present invention will be explained.

不織布ウェブのSJ Wは、メルトブロー法、フラッシ
ュ紡法、スパンボンド法など公知の方法により長繊維不
織布ウェブ、又は短繊維不織布ウェブを作ることによっ
て行なわれる。
SJW of a nonwoven fabric web is carried out by producing a long fiber nonwoven fabric web or a short fiber nonwoven fabric web by a known method such as a melt blowing method, a flash spinning method, or a spunbonding method.

なお、本発明でいう不織布ウェブとはレーヨン、ポリノ
ジックの様な化学繊維、もしくはポリエステル、ポリオ
レフィン、ポリウレタンなどの合成繊維又は天然繊維か
らなるものであり、またこれらの繊維が混合されたもの
でもよい。
The nonwoven web in the present invention is made of synthetic fibers such as rayon and polynosic, or synthetic fibers such as polyester, polyolefin, and polyurethane, or natural fibers, or may be a mixture of these fibers.

ついで、前記不織布ウェブの少なくとも1方の表面層に
該不織布ウェブの構成繊維間隙基にの平均粒径を有する
熱可塑性樹脂粉体を付与する。この樹脂粉体の融点は、
すでに述べたように、不織布ウェブの構成繊維の融点よ
り低いものでなければならない。これは、接着効果を出
すためである。
Then, a thermoplastic resin powder having an average particle size of the interstitial fibers of the nonwoven web is applied to at least one surface layer of the nonwoven web. The melting point of this resin powder is
As already mentioned, it must be lower than the melting point of the constituent fibers of the nonwoven web. This is to create an adhesive effect.

熱可塑性樹脂の不織布ウェブ表面への付与jiは不織布
ウェブ1,11’当り、1 cIW〜30cn(が好ま
しく、さらにはII当り3 cral〜20cnlが特
に好ましい。これはII当り1cIll未填であると表
面耐摩耗性や引裂強力の低ドがンしく、また1♂当り3
0c2をこえると風合いが堅くなってしまうからである
The thermoplastic resin applied to the surface of the nonwoven web ji is preferably 1 cIW to 30 cn per nonwoven web 1, 11', and particularly preferably 3 cral to 20 cnl per II. Low surface abrasion resistance and tear strength, and 3 per ♂
This is because if it exceeds 0c2, the texture becomes hard.

その後、前記熱可塑性樹脂粉体を付与した不織布ウェブ
を特定の温度で加熱した後圧着するか、又は加熱圧?t
を同時に行なうのである。ここに、特定の温度とは、不
織布ウェブの構成繊維の融点未満で前記熱可塑性樹脂の
融点以上の温度であり、接着に適した温度にする。
Thereafter, the nonwoven fabric web to which the thermoplastic resin powder has been applied is heated at a specific temperature and then pressure bonded, or is the nonwoven fabric web coated with the thermoplastic resin powder applied with heat pressure? t
are done at the same time. Here, the specific temperature is a temperature that is lower than the melting point of the constituent fibers of the nonwoven web and higher than the melting point of the thermoplastic resin, and is a temperature suitable for bonding.

(実施例) 実施例1 不織布ウェブとしてポリエステルスパンボンドウェブ(
40g/♂)に熱可塑性樹脂としてポリエステル系樹脂
粉体(融点111°C1平均拉径90戸)を所定[11
不織布ウ工ブ表面に付′jし加熱圧着して不織布を得た
(これらを試料1〜8とする)。従来品としてポリエス
テルスパンボンドウェブ(40g/m’)を亀甲柄(横
1811’/ x、縦18メツシユ、経0.923m箇
、深さ0.45冒−1圧着面積率25.3%)、230
℃の条件で熱圧着したものを得た(これを従来品1とす
る)。
(Example) Example 1 A polyester spunbond web (
Polyester resin powder (melting point: 111°C, average diameter: 90 units) was added as a thermoplastic resin to a predetermined amount [11
The nonwoven fabrics were attached to the surface of the nonwoven fabric and pressed under heat to obtain nonwoven fabrics (these are referred to as Samples 1 to 8). As a conventional product, a polyester spunbond web (40 g/m') was made with a tortoiseshell pattern (width 1811'/x, length 18 mesh, warp 0.923 m, depth 0.45 mm, crimped area ratio 25.3%). 230
A product was obtained by thermocompression bonding under conditions of ℃ (this is referred to as conventional product 1).

評価方法として柔軟性評価は、生地の風合い評価で知ら
れているKESの風合い評価項目の1つである曲げ特性
によって行い、表面耐摩耗性評価はJ l5−L−10
96に準じたテーパー摩耗試験によって評価し、引裂強
力評価はJIS−L−1085に準じたペンシュラム法
によって行なった。各評価項[1の結果を第1表に示す
As an evaluation method, flexibility was evaluated using bending properties, which is one of the texture evaluation items of KES, which is known for evaluating the texture of fabrics, and surface abrasion resistance was evaluated using J15-L-10.
The evaluation was made by a taper abrasion test according to JIS-L-1085, and the tear strength was evaluated by the Penschlum method according to JIS-L-1085. The results for each evaluation item [1 are shown in Table 1.

第1表 この結果から熱可塑性樹脂の付与量には上限があり柔か
な風合いと表面耐摩耗性、引裂強力の特性のバランスが
とれている範囲は、熱可塑性樹脂の付与iIlがllT
1′当り1 cnl 〜30 clflである°1「が
わかる(試料Nα2〜7)。
Table 1 From these results, there is an upper limit to the amount of thermoplastic resin applied, and within the range where a balance between soft texture, surface abrasion resistance, and tear strength is achieved, the amount of thermoplastic resin applied is llT.
It can be seen that °1' is 1 cnl to 30 clfl per 1' (samples Nα2 to 7).

実施例2 不織布ウェブとしてポリエステルスパンボンドウェブ(
40g/♂)に熱可塑性樹脂として、ポリエステル系樹
脂粉体(融点111℃、付’5.fu 7 g/♂)を
所定の粒径に揃えて不織布ウェブ表面に付すし加熱圧着
して、不織布を得た(これらを試料Nn9〜15とする
)。
Example 2 Polyester spunbond web (
40 g/♂) as a thermoplastic resin, polyester resin powder (melting point 111°C, 7 g/♂) with a predetermined particle size is applied to the surface of the nonwoven fabric web and heat-pressed to form a nonwoven fabric. (these are referred to as samples Nn9-15).

従来品としては実施例1の従来品1とし、比較を行なっ
た。
Conventional product 1 of Example 1 was used as the conventional product for comparison.

各評価項[1を第2表に示す。Each evaluation item [1 is shown in Table 2.

以ド余白 第2表 ウェブ表面層に付?j、シ、加熱圧前して不織布を得た
(これを試料Nα12とする)。比較として実施例1の
従来品1とEl付100g/♂、厚み1.5.ル−ヨン
の一4/ &ila物(これを比較台lとする)を利用
した。
Is there a margin attached to Table 2 of the web surface layer? j. A nonwoven fabric was obtained by heating and pressing (this is referred to as sample Nα12). For comparison, conventional product 1 of Example 1 and 100g/♂ with El, thickness 1.5. A Rouyon 14/&ila product (this was used as a comparison table) was used.

これらの各評価結果を第3表に示す。The results of each of these evaluations are shown in Table 3.

第3表 この結果から柔かい風合いと優れた表面耐摩耗性、引裂
強力を得る為の条件として熱可塑性樹脂の粒径に適正条
件があり、その範囲が30tna〜200−である事が
わかる。
From the results in Table 3, it can be seen that there is an appropriate particle size of the thermoplastic resin in order to obtain a soft texture, excellent surface abrasion resistance, and tear strength, and that the range is from 30tna to 200tna.

実施例3 実施例1,2の結果から不織布ウェブとしてポリエステ
ルスパンボンドウェブ(40g/I11”)に熱可塑性
樹脂としてポリエステル系樹脂粉体(融点tit℃、s
lJ均粒径901iJaをIIIIt当り7cIIl不
織布以上の結果から不織布ウェブの表面層に熱FIf塑
性樹脂の粉体をある条件ドで付′−j、すると、従来の
熱圧着による接合のタイプよりもはるかに柔らかい風合
いと表面耐摩耗性、引裂強力のバランスのとれた不織布
が得られるICがわかる。
Example 3 From the results of Examples 1 and 2, a polyester spunbond web (40 g/I11") was used as a nonwoven web, and a polyester resin powder (melting point tit C, s
From the result that the nonwoven fabric has an average particle size of 901iJa and 7cIIl per IIIt, when heat FIF plastic resin powder is applied to the surface layer of the nonwoven web under certain conditions, the bonding rate is much greater than that of the conventional thermocompression bonding type. It is clear that the IC provides a nonwoven fabric with a good balance of soft texture, surface abrasion resistance, and tear strength.

(発明の効果) 本発明による不織布ウェブの表面層だけに熱11塑性樹
脂の粉体を粒径と付与はを制御して付す。
(Effects of the Invention) Powder of thermal 11 plastic resin is applied only to the surface layer of the nonwoven fabric web according to the present invention while controlling the particle size and application.

し、加熱圧着されて得られた不織布は、これまで不可能
であった柔かな風合いと優れた耐摩耗性、引裂強力のバ
ランスがとれたものである°l[がわかった。
However, it was found that the nonwoven fabric obtained by heat-pressing has a balance of soft texture, excellent abrasion resistance, and tear strength, which was previously impossible.

特許出願人  東洋紡績株式会社Patent applicant: Toyobo Co., Ltd.

Claims (2)

【特許請求の範囲】[Claims] (1) 不織布ウエブの少なくとも一方の表面層に該不
織布ウエブの構成繊維間隙以上の平均粒径を有する熱可
塑性樹脂粉体が付与されて、該不織布ウエブ表面に接着
されている事を特徴とする不織布。
(1) A thermoplastic resin powder having an average particle size larger than the gap between the constituent fibers of the nonwoven web is applied to at least one surface layer of the nonwoven web, and is adhered to the surface of the nonwoven web. Non-woven fabric.
(2) 不織布ウエブの少なくとも一方の表面層に該不
織布ウエブの構成繊維間隙以上の平均粒径を有する熱可
塑性樹脂粉体を不織布ウエブ1m^2当り1〜30cm
^3の付与量でムラなく付与し、ついで前記不織布ウエ
ブを構成する繊維の融点未満でしかも前記熱可塑性樹脂
の融点以上の温度で加熱した後圧着するか又は、加熱圧
着することを特徴とする不織布の製造方法。
(2) At least one surface layer of the nonwoven fabric web is coated with thermoplastic resin powder having an average particle size larger than the gap between the constituent fibers of the nonwoven fabric web in an amount of 1 to 30 cm per 1 m^2 of the nonwoven fabric web.
It is characterized in that it is applied evenly in an application amount of ^3, and then heated at a temperature below the melting point of the fibers constituting the nonwoven fabric web and above the melting point of the thermoplastic resin, and then press-bonded or heat-bonded. Method of manufacturing nonwoven fabric.
JP21201688A 1988-08-25 1988-08-25 Nonwoven fabric and production thereof Pending JPH0261153A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP21201688A JPH0261153A (en) 1988-08-25 1988-08-25 Nonwoven fabric and production thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP21201688A JPH0261153A (en) 1988-08-25 1988-08-25 Nonwoven fabric and production thereof

Publications (1)

Publication Number Publication Date
JPH0261153A true JPH0261153A (en) 1990-03-01

Family

ID=16615485

Family Applications (1)

Application Number Title Priority Date Filing Date
JP21201688A Pending JPH0261153A (en) 1988-08-25 1988-08-25 Nonwoven fabric and production thereof

Country Status (1)

Country Link
JP (1) JPH0261153A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100358258B1 (en) * 2000-08-26 2002-10-25 정준호 Manufacturing method of inner materials for shoes
KR20030068864A (en) * 2002-02-18 2003-08-25 홍진평 Method for manufacturing the moldable fabrics
KR100429367B1 (en) * 2001-08-14 2004-04-29 정준호 Inner meterials for shoes
JP2006281768A (en) * 2005-03-07 2006-10-19 Toyota Tsusho Corp Method and apparatus for manufacturing reinforcing cloth of sheet pad

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100358258B1 (en) * 2000-08-26 2002-10-25 정준호 Manufacturing method of inner materials for shoes
KR100429367B1 (en) * 2001-08-14 2004-04-29 정준호 Inner meterials for shoes
KR20030068864A (en) * 2002-02-18 2003-08-25 홍진평 Method for manufacturing the moldable fabrics
JP2006281768A (en) * 2005-03-07 2006-10-19 Toyota Tsusho Corp Method and apparatus for manufacturing reinforcing cloth of sheet pad
JP4503538B2 (en) * 2005-03-07 2010-07-14 豊田通商株式会社 Manufacturing method and manufacturing apparatus for seat pad reinforcing cloth
US7758802B2 (en) 2005-03-07 2010-07-20 Toyota Tsusho Corporation Method of manufacturing reinforcing cloth of sheet pad and apparatus therefor
US8926309B2 (en) 2005-03-07 2015-01-06 Toyota Tsusho Corporation Method of manufacturing reinforcing cloth of a seat pad and apparatus therefor

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