JPH0260637B2 - - Google Patents
Info
- Publication number
- JPH0260637B2 JPH0260637B2 JP12692580A JP12692580A JPH0260637B2 JP H0260637 B2 JPH0260637 B2 JP H0260637B2 JP 12692580 A JP12692580 A JP 12692580A JP 12692580 A JP12692580 A JP 12692580A JP H0260637 B2 JPH0260637 B2 JP H0260637B2
- Authority
- JP
- Japan
- Prior art keywords
- parts
- painting
- picture
- ceramics
- transfer paper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000010422 painting Methods 0.000 claims description 42
- 239000000919 ceramic Substances 0.000 claims description 38
- 238000012546 transfer Methods 0.000 claims description 38
- 238000000034 method Methods 0.000 claims description 25
- 239000000049 pigment Substances 0.000 claims description 12
- 238000010304 firing Methods 0.000 claims description 8
- 239000011342 resin composition Substances 0.000 claims description 6
- 238000000016 photochemical curing Methods 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 3
- 239000000123 paper Substances 0.000 description 35
- 239000000976 ink Substances 0.000 description 27
- 239000002904 solvent Substances 0.000 description 25
- 239000011347 resin Substances 0.000 description 12
- 229920005989 resin Polymers 0.000 description 12
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 8
- 230000000903 blocking effect Effects 0.000 description 7
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 6
- 229920001353 Dextrin Polymers 0.000 description 6
- 239000004375 Dextrin Substances 0.000 description 6
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 235000019425 dextrin Nutrition 0.000 description 6
- 239000000203 mixture Substances 0.000 description 6
- 238000007639 printing Methods 0.000 description 6
- 238000001035 drying Methods 0.000 description 5
- FYGHSUNMUKGBRK-UHFFFAOYSA-N 1,2,3-trimethylbenzene Chemical compound CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000007650 screen-printing Methods 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 3
- 229910052573 porcelain Inorganic materials 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000001723 curing Methods 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000001678 irradiating effect Effects 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229910052711 selenium Inorganic materials 0.000 description 2
- 239000011669 selenium Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000008096 xylene Substances 0.000 description 2
- RLPSARLYTKXVSE-UHFFFAOYSA-N 1-(1,3-thiazol-5-yl)ethanamine Chemical compound CC(N)C1=CN=CS1 RLPSARLYTKXVSE-UHFFFAOYSA-N 0.000 description 1
- ILBBNQMSDGAAPF-UHFFFAOYSA-N 1-(6-hydroxy-6-methylcyclohexa-2,4-dien-1-yl)propan-1-one Chemical compound CCC(=O)C1C=CC=CC1(C)O ILBBNQMSDGAAPF-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000010981 drying operation Methods 0.000 description 1
- ZANNOFHADGWOLI-UHFFFAOYSA-N ethyl 2-hydroxyacetate Chemical compound CCOC(=O)CO ZANNOFHADGWOLI-UHFFFAOYSA-N 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 239000011088 parchment paper Substances 0.000 description 1
- 229920001483 poly(ethyl methacrylate) polymer Polymers 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000013518 transcription Methods 0.000 description 1
- 230000035897 transcription Effects 0.000 description 1
Landscapes
- Printing Methods (AREA)
- Decoration By Transfer Pictures (AREA)
Description
【発明の詳細な説明】
この発明は、陶磁器に絵画、文字（以下これを
絵画と略称する）を形成する方法に関するもので
ある。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for forming pictures and letters (hereinafter referred to as "paintings") on ceramics.
陶磁器に量産的に絵付けを行う１つの方法とし
て、溶剤型インキを用いて例えば、スクリーン印
刷によつて転写紙に絵画を印刷し、この転写紙を
陶磁器に転写する方法が知られている。ところ
が、溶剤型インクを用いているので、印刷作業中
などすべての作業工程の間、インキ中の溶剤が絶
えず蒸発することになり、発生する有害ガスによ
つて作業環境が悪化し、又、印刷途中においても
溶剤の蒸発に伴つてインキの流動性も次第に低下
するので、スクリーン印刷においては、スクリー
ン版に目詰りを生じ易く、印刷枚数を多くするこ
とや微細な線等を印刷することが極めて困難とな
つている。そしてこの目詰り防止のために、高沸
点の溶剤を使用することになり、そうすると印刷
された転写紙の乾燥所要時間が長くなるうえ、乾
燥のために広い作業場と多くの人手を必要とする
ことになつて、乾燥作業コスストが著しく高価と
なり、重ね刷りを行うには夫々の印刷終了後に長
い乾燥時間を要することになつて、実施化が困難
であつた。又、揮発性の溶剤を完全に蒸発させる
のは極めて困難であり、多少共、溶剤が残存して
いるため、乾燥終了後の転写紙相互間に、例えば
硫酸紙の如き離型紙をはさみ込む手数も必要とな
つている。そこで出願人は、紫外線硬化型樹脂を
用いることによつて溶剤型インクにみられる上記
の問題を解決せんとしたものである。 One known method for mass-producing paintings on ceramics is to print a picture on transfer paper using solvent-based ink, for example, by screen printing, and then transfer the transfer paper to the ceramics. However, since solvent-based ink is used, the solvent in the ink constantly evaporates during all work processes such as printing, and the work environment deteriorates due to the harmful gases generated. During the process, the fluidity of the ink gradually decreases as the solvent evaporates, so in screen printing, the screen plate tends to become clogged, making it extremely difficult to print a large number of sheets or print fine lines. It's becoming difficult. In order to prevent this clogging, a solvent with a high boiling point is used, which increases the time it takes to dry the printed transfer paper, and requires a large work area and many hands for drying. As a result, the cost of drying operations becomes extremely high, and overprinting requires a long drying time after each print, making it difficult to implement. In addition, it is extremely difficult to completely evaporate volatile solvents, and since some solvent remains, it is time consuming to insert release paper, such as parchment paper, between the transfer sheets after drying. is also becoming necessary. Therefore, the applicant attempted to solve the above-mentioned problems found in solvent-based inks by using an ultraviolet curable resin.
そして、特公昭52−42808号及び特開昭54−
120613号の夫々の公報には、陶磁器の釉掛けに紫
外線硬化型樹脂を使用した技術が開示されている
が、これらの技術は、単なる釉薬だけでは釉薬層
が弱いので、これを強化するために紫外線硬化型
樹脂を加えたものであり、しかも、転写紙用イン
キについてこれを使用しているものでは無く、絵
付けインクとしての前記問題点解決には到つてい
ないのである。 And, JP 52-42808 and JP 54-
Each publication of No. 120613 discloses a technology that uses ultraviolet curable resin to glaze ceramics, but since the glaze layer is weak with just a simple glaze, these technologies require a method to strengthen the glaze layer. This ink contains an ultraviolet curable resin, and is not used in ink for transfer paper, so the above-mentioned problems have not been solved as a decorative ink.
そしてこの発明の構成は、微細に分割した顔料
50〜95重量部と、紫外線硬化性樹脂組成物５〜50
重量部からなる焼成用重合ペーストで転写紙に絵
画を形成し、光硬化させる工程と、前記工程で得
られた転写紙の絵画を陶磁器上に転写させる工程
と、該絵画を焼成して前記顔料から形成された絵
画を陶磁器上に固着する工程からなる陶磁器の絵
画形成法である。 The structure of this invention consists of finely divided pigments.
50 to 95 parts by weight and 5 to 50 parts by weight of the ultraviolet curable resin composition
a step of forming a painting on a transfer paper using a polymeric paste for firing consisting of parts by weight and curing it with light; a step of transferring the painting on the transfer paper obtained in the step onto ceramics; and a step of firing the painting and adding the pigment. This is a method of forming paintings on ceramics, which consists of the process of fixing the formed paintings on ceramics.
ここでこの発明において顔料とは、一般的に陶
磁器界で使用せられているものを云う。 In this invention, pigments refer to those commonly used in the ceramics field.
次にこの発明の実施例における製造工程を図に
もとづいて説明する。 Next, a manufacturing process in an embodiment of the present invention will be explained based on the drawings.
先づ、微細に分割した顔料50〜95重量部Ｓと紫
外線硬化性樹脂組成物５〜50重量部からなる焼成
用重合ペーストＰ（以下ペーストと称す）で転写
紙に絵画を形成し、光硬化させ、更にこの絵画上
に他の絵画を重ねて画きたいときは、前記光硬化
せしめた絵画上に再び前述のペーストＰを用い
て、絵画を形成し、光硬化させる。 First, a painting is formed on a transfer paper using a polymeric paste P for firing (hereinafter referred to as paste) consisting of 50 to 95 parts by weight of finely divided pigment S and 5 to 50 parts by weight of an ultraviolet curable resin composition, and then photocured. If you want to overlay another painting on top of this painting, use the above-mentioned paste P again on the photo-cured painting to form the painting, and then photo-cure it.
次に、前記工程で得られた転写紙の絵画を陶磁
器上に転写し、焼成し、前記微細に分割した顔料
50〜95重量部（以下固形分と称す）を陶磁器上に
焼成する。このような方法により、単色のペース
トＰ又は混合色のペーストＰ上に、更に重ねて、
他の色彩のペーストＰを用いて、絵画を形成した
陶磁器を製造し得る。 Next, the painting on the transfer paper obtained in the above step is transferred onto ceramics, fired, and the finely divided pigment is
50 to 95 parts by weight (hereinafter referred to as solid content) is fired onto ceramics. By such a method, it is further layered on the single color paste P or the mixed color paste P,
Painted ceramics can be manufactured using pastes P of other colors.
本発明による転写紙に依る陶磁器の絵画形成法
の工程の一実施例を図に示す。台紙１にデキスト
リン２を塗布した工程１（m1）から工程２（m2）
で所要の色彩を持つ固形分を主成分としたペース
トＰにより、転写紙に印刷等の手段により絵画を
形成する。次に工程３（m3）で紫外線U.Vを照射
し、工程４（m4）に示す如く、光重合したペース
ト３で形成された絵画を得、更に、この絵画の上
に他の絵画を重ねる場合は、再び前述の工程２
（m2）、工程３（m3）を繰返す。次に、工程５
（m5）で、紫外線硬化型樹脂組成物100重量部又
は熱分解重合体組成物100重量部からなる透明イ
ンキＣにより前記絵画を覆いオーバコート４を形
成し、工程６（m6）により再び紫外線U.Vを該オ
ーバコート４に照射するか、又は、透明インキＣ
が熱分解重合体の場合は該オーバコート４を乾燥
させ、工程７（m7）に示す如く光重合又は熱分解
により硬化したオーバコート４ａに被覆された転
写紙を得る。該工程７（m7）により転写紙への絵
画形成が終るので、この状態で保存又は製品とし
て取扱うことも可能である。 An embodiment of the process of forming a picture on ceramics using transfer paper according to the present invention is shown in the figure. Step 1 (m 1 ) to step 2 (m 2 ) in which dextrin 2 was applied to mount 1
Then, a picture is formed on a transfer paper using a method such as printing using a paste P mainly composed of solids having a desired color. Next, in step 3 (m 3 ), ultraviolet rays are irradiated to obtain a painting formed from the photopolymerized paste 3, as shown in step 4 (m 4 ), and another painting is then layered on top of this painting. If so, repeat step 2 above.
(m 2 ) and repeat step 3 (m 3 ). Next, step 5
(m 5 ), the painting is covered with transparent ink C consisting of 100 parts by weight of an ultraviolet curable resin composition or 100 parts by weight of a pyrolyzable polymer composition, and an overcoat 4 is formed, and in step 6 (m 6 ), the painting is again coated. Either irradiate the overcoat 4 with ultraviolet rays or apply transparent ink C.
When is a pyrolytic polymer, the overcoat 4 is dried to obtain a transfer paper coated with an overcoat 4a cured by photopolymerization or pyrolysis as shown in step 7 (m 7 ). Since the process 7 (m 7 ) completes the formation of the picture on the transfer paper, it can be stored or handled as a product in this state.
次に、工程８（m8）で前記工程７（m7）を完了
した転写紙を水５に１分〜１分30秒浸漬し、台紙
１上に塗布されたデキストリン２を溶解して工程
９（m9）に示す如く台紙１から転写物６を剥離す
る。更に剥離した転写物６を柔かいスキージ（ゴ
ムの箟）上に載せ、工程10（m10）に示す如く陶
磁器７上にスライド転写する。この工程10（m10）
完了後、工程11（m11）に示す如く炉８で焼成す
る。該工程11（m11）により前述の硬化したオー
バコート４ａは焼失し陶磁器上に所望の絵画が焼
成される。 Next, in step 8 (m 8 ), the transfer paper that has undergone the step 7 (m 7 ) is immersed in water 5 for 1 minute to 1 minute and 30 seconds to dissolve the dextrin 2 coated on the mount 1 and complete the process. The transfer material 6 is peeled off from the mount 1 as shown in 9 (m 9 ). Further, the peeled transfer material 6 is placed on a soft squeegee (rubber squeegee) and is slid onto the ceramic 7 as shown in step 10 (m 10 ). This process 10 (m 10 )
After completion, it is fired in a furnace 8 as shown in step 11 (m 11 ). In step 11 (m 11 ), the above-mentioned hardened overcoat 4a is burned out, and the desired painting is fired on the ceramic.
本発明の前記実施例はこれに限定されるもので
なく、例えば、転写物６を転写する際裏返す方
法、又は、台紙１上に薄いライスペーパーを設け
た転写紙を使用する方法等があるが、全く任意で
ある。 The embodiments of the present invention are not limited to this, and there are, for example, a method of turning the transfer material 6 upside down when transferring it, a method of using a transfer paper with a thin rice paper provided on the mount 1, etc. , is completely optional.
この発明に係る陶磁器の絵画形成法は上述のよ
うに、微細に分割した顔料50〜95重量部と、紫外
線硬化性樹脂組成物５〜50重量部からなる焼成用
重合ペーストで転写紙に絵画を形成し、光硬化さ
せる工程と、前記工程で得られた転写紙の絵画を
陶磁器上に転写させる工程と、該絵画を焼成して
前記顔料から形成された絵画を陶磁器上に固着す
る工程からなる陶磁器の絵画形成法であつて、紫
外線硬化性樹脂を含むペーストを用いて印刷した
転写紙によつて絵付けを行つているので、印刷作
業を含むすべての作業工程において、インキから
蒸発する溶剤の如き物質が全く無いので、作業環
境は著しく向上することになり、又、印刷工程中
にインキの固化が進行するようなことが無いの
で、微細な絵や文字等を鮮明に印刷できるもので
あつて、特にスクリーン印刷を用いたとき、スク
リーン版に目詰りが発生し難くなつて、微細な絵
画を、多数枚の転写紙に印刷できるため、美麗な
絵画を能率良く印刷できることになつた。又、印
刷されたインキは、通常10秒ていどの極めて短時
間の紫外線照射によつて充分に重合、固形化する
ので、溶剤型インキの如く約１時間もの長い乾燥
工程は、この発明によつて省略できることになつ
て、印刷工程時間と作業コストを大巾に短縮でき
ると共に、多色の重ね刷りを行うにも、極めて短
時間で印刷→光硬化→印刷→光硬化の工程を繰返
すことができるものであつて、多色の複雑な絵付
けを容易に行うことができることになつた。又、
転写紙に塗付してあるデキストリンは加熱に弱い
ため、従来の溶剤型インクの場合、乾燥温度を高
くできず、固形化が不充分となり勝ちであつて、
溶剤が残溜し易く、この結果、転写紙を積重ねて
保管する際に、インキ部分が固着するいわゆるブ
ロツキング現象が発生し易く、この対策として転
写紙相互間にいちいち離型紙をはさみ込まねばな
らないが、この発明では、光硬化工程によつて充
分に固形化しているため、ブロツキングの発生が
無く、保管作業も極めて容易となつたのであり、
しかも、上記のように構成された転写紙によつて
陶磁器に極めて容易に絵画を形成できることにな
つたのである。 As described above, the method for forming a picture on ceramics according to the present invention is to form a picture on transfer paper using a polymeric paste for firing consisting of 50 to 95 parts by weight of finely divided pigment and 5 to 50 parts by weight of an ultraviolet curable resin composition. A step of transferring the painting on the transfer paper obtained in the above step onto ceramics, and a step of firing the painting to fix the painting formed from the pigment on the ceramics. This is a method of forming paintings on ceramics, and the painting is done using transfer paper printed with a paste containing ultraviolet curable resin, so all work processes, including printing, are free of solvents that evaporate from the ink. Since there are no substances such as Especially when screen printing is used, the screen plate is less likely to become clogged, and fine paintings can be printed on multiple sheets of transfer paper, making it possible to print beautiful paintings efficiently. In addition, printed ink is sufficiently polymerized and solidified by ultraviolet irradiation for a very short period of time, typically 10 seconds, so the present invention eliminates the long drying process of about 1 hour as in the case of solvent-based inks. Since this can be omitted, printing process time and work costs can be greatly reduced, and even when overprinting multiple colors, the process of printing → photocuring → printing → photocuring can be repeated in an extremely short time. It became possible to easily create complex multicolored paintings. or,
The dextrin applied to the transfer paper is sensitive to heat, so in the case of conventional solvent-based inks, the drying temperature cannot be raised, resulting in insufficient solidification.
Solvent tends to remain, and as a result, when transfer papers are stacked and stored, the so-called blocking phenomenon in which the ink parts stick together tends to occur, and as a countermeasure to this, it is necessary to insert release paper between each transfer paper. In this invention, since the material is sufficiently solidified through the photocuring process, there is no blocking and storage work is extremely easy.
Furthermore, by using the transfer paper constructed as described above, it became possible to form pictures on ceramics extremely easily.
次にこの発明の実施例を、従来の溶剤型インキ
を用いた場合に比較して説明する。 Next, an example of the present invention will be described in comparison with a case where a conventional solvent-based ink is used.
使用インキ
ａ 紫外線硬化型陶磁器絵付用インキ（）
紫外線硬化性樹脂バインダー40部、陶磁器絵付
用顔料（セレン赤）60部、光開始剤４部、レベリ
ング剤２部を３本ロールで練肉し、紫外線硬化型
陶磁器絵付用インキ（）を得た。 Ink used: UV-curable ceramic painting ink () 40 parts of UV-curable resin binder, 60 parts of pigment for ceramic painting (selenium red), 4 parts of photoinitiator, and 2 parts of leveling agent were kneaded using 3 rolls. An ultraviolet curing ink for painting ceramics was obtained.
ｂ 溶剤型陶磁器絵付用インキ（）
メタクリル酸メチル（MMA）とメタクリル酸
ｎ−ブチル（ｎ−BMA）の共重合体（組成比：
MMA／ｎ−BMA＝18／82モル比）を41部、溶
剤（トルエン、キシレン、トリメチルベンゼン、
ジメチルベンゼンなどの混合物）を57部、可塑剤
（エチルフタル、エチルグリコレート）７部をそ
れぞれ加え、よく混合して溶剤型バインダーを
得、この溶剤型バインダー40部、陶磁器絵付用顔
料（セレン赤）60部を３本ロールで練肉し、溶剤
型陶磁器絵付用インキ（）を得た。b Solvent-based ceramic painting ink () Copolymer of methyl methacrylate (MMA) and n-butyl methacrylate (n-BMA) (composition ratio:
41 parts of MMA/n-BMA=18/82 molar ratio), solvent (toluene, xylene, trimethylbenzene,
Add 57 parts of dimethylbenzene (mixtures such as dimethylbenzene) and 7 parts of plasticizers (ethyl phthalate, ethyl glycolate), mix well to obtain a solvent-based binder, and add 40 parts of this solvent-based binder and a pigment for ceramic painting (selenium red). 60 parts were kneaded using three rolls to obtain a solvent-based ceramic painting ink ().
カバーコート
ａ カバーコート用紫外線硬化型樹脂（）
紫外線硬化性樹脂100部、レベリング剤２部、
光開始剤７部を室温で混合し、カバーコート用紫
外線硬化型樹脂（）を得た。 Cover coat a UV curable resin for cover coat () 100 parts of UV curable resin, 2 parts of leveling agent,
Seven parts of a photoinitiator were mixed at room temperature to obtain an ultraviolet curable resin for cover coat (2).
ｂ カバーコート用溶剤型樹脂（）
ポリエチルメタクリレート34部、溶剤（トルエ
ン、キシレン、トリメチルベンゼン、ジメチルベ
ンゼンなどの混合物）56部、可塑剤（ジデシルフ
タレート）８部、有機顔料２部を加え、よく混合
させてカバーコート用溶剤型樹脂（）を得た。b Solvent-based resin for cover coat () Add 34 parts of polyethyl methacrylate, 56 parts of a solvent (a mixture of toluene, xylene, trimethylbenzene, dimethylbenzene, etc.), 8 parts of a plasticizer (didecyl phthalate), and 2 parts of an organic pigment, The mixture was thoroughly mixed to obtain a solvent-based resin for cover coating.
実施例
デキストリン溶液を塗布した単紙に上記紫外線
硬化型陶磁器絵付用インキ（）を用いて、
100μ〜５mmの線巾から成る250meshのスクリーン
版により絵柄をスクリーン印刷した。この際に印
刷枚数が1000枚を越えても、スクリーン版の目詰
まりによる線巾のカスレは生じなかつた。印刷さ
れた絵柄は5.6kw水銀灯下15cmの距離で10秒間照
射し硬化させた。次いでカバーコート層として、
上記カバーコート用紫外線硬化型樹脂（）を絵
上に印刷し、同じく紫外線を10秒間照射して硬化
させ、本発明の陶磁器絵付用転写紙を得た。得ら
れた転写紙を湿式法で白磁器に転写し、100℃／
時間の昇温速度で800℃に達するまで焼成したと
ころ、クラツク、絵柄のとび、ピンホールはな
く、外観の良好な磁器を得た。 Example Using the above ultraviolet curable ceramic painting ink () on a sheet of paper coated with a dextrin solution,
The pattern was screen printed using a 250 mesh screen plate with a line width of 100 μm to 5 mm. At this time, even when the number of printed sheets exceeded 1,000, no line width fading due to clogging of the screen plate occurred. The printed pattern was cured by irradiating it under a 5.6kw mercury lamp at a distance of 15cm for 10 seconds. Then, as a cover coat layer,
The above-mentioned ultraviolet curable resin for cover coating () was printed on the picture and cured by irradiating it with ultraviolet rays for 10 seconds to obtain a transfer paper for ceramic decoration of the present invention. The resulting transfer paper was transferred to white porcelain using a wet method, and heated at 100℃/
When the porcelain was fired at a heating rate of 1 hour until it reached 800°C, the porcelain had a good appearance, with no cracks, skipped patterns, or pinholes.
尚、上述の実施例で得られた陶磁器絵付用転写
紙のブロツキング性を調べるため、印刷面と紙裏
面とを重ね、荷重を加え、下記の条件で陶磁器絵
付用転写紙100枚について試験を行なつたところ、
全くブロツキングは起こしていなかつた。 In order to investigate the blocking properties of the ceramic painting transfer paper obtained in the above example, a test was conducted on 100 sheets of ceramic painting transfer paper under the following conditions, with the printed side and the back side of the paper stacked and a load applied. When I got old,
No blocking occurred at all.
ブロツキング試験条件
荷重：17ｇ／cm2 温度：25℃
湿度：60％RH 放置時間：24hr
比較例
上記実施例と同一のデキストリン液を塗布した
単紙に上記溶剤型陶磁器絵付用インキ（）を用
い、上記実施例と同様にスクリーン印刷し、35
℃、50％RHの乾燥機中に１時間放置し乾燥させ
た。 Blocking test conditions Load: 17 g/cm 2 Temperature: 25°C Humidity: 60% RH Standing time: 24 hr Comparative example Using the above solvent-based ceramic painting ink () on a sheet of paper coated with the same dextrin solution as in the above example, Screen printed in the same way as the above example, 35
It was left to dry in a dryer at 50% RH for 1 hour.
次いで、カバーコート層としてカバーコート用
溶剤型樹脂（）で絵柄上に印刷し、同じく35
℃、50％RHの乾燥機中に１時間放置し乾燥させ
た。転写及び焼成条件は上記実施例と全く同様に
行なつた結果、クラツク、ピンホールなどは見ら
れなかつたが、発色性は紫外線硬化型インキ
（）を使用した方が良かつた。 Next, as a cover coat layer, a solvent-based cover coat resin () is printed on the pattern, and the same 35
It was left to dry in a dryer at 50% RH for 1 hour. The transfer and baking conditions were exactly the same as in the above examples, and as a result, no cracks or pinholes were observed, but the color development was better using the ultraviolet curable ink ().
尚、この溶剤型陶磁器絵付用インキ（）を使
用してスクリーン印刷を行なつた場合は、印刷枚
数が20枚を越えると、スクリーン版の目詰まりに
より100μの線巾にカスレが生じた。また、上記
実施例と同様な方法で溶剤型インキ（）で構成
された陶磁器絵付用転写紙のブロツキング試験を
行なつたところ、転写紙100枚のうち30％にあた
る30枚の転写紙にブロツキングが観察された。 In addition, when screen printing was performed using this solvent-based ceramic painting ink (), when the number of printed sheets exceeded 20, the screen plate was clogged and a line width of 100 μm became blurred. In addition, when a blocking test was conducted on transfer paper for painting ceramics made with solvent-based ink (2018) in the same manner as in the above example, blocking was observed on 30 transfer papers (30%) out of 100 transfer papers. observed.
図は本発明に係る陶磁器の絵画形成法の解説図
である。
符号説明、１……台紙、２……デキストリン、
３……光重合したペースト、４……オーバコー
ト、４ａ……硬化したオーバコート、５……水、
６……転写物、７……陶磁器、８……炉、Ｃ……
透明インキ、Ｐ……焼成用光重合ペースト（ペー
スト）、U.V……紫外線。
The figure is an explanatory diagram of the ceramic painting forming method according to the present invention. Code explanation, 1... mount, 2... dextrin,
3... Photopolymerized paste, 4... Overcoat, 4a... Cured overcoat, 5... Water,
6...transcription, 7...ceramics, 8...furnace, C...
Transparent ink, P...photopolymerized paste for baking (paste), UV...ultraviolet light.
Claims (1)
硬化性樹脂組成物５〜50重量部からなる焼成用重
合ペーストで転写紙に絵画を形成し、光硬化させ
る工程と、前記工程で得られた転写紙の絵画を陶
磁器上に転写させる工程と、該絵画を焼成して前
記顔料から形成された絵画を陶磁器上に固着する
工程からなる陶磁器の絵画形成法。 ２ 前記微細に分割した顔料50〜95重量部と紫外
線硬化性樹脂組成物５〜50重量部からなる焼成用
光重合ペーストで転写紙に絵画を形成後、紫外線
により当該絵画を硬化し、更に、この絵画上に重
ねて他の絵画を形成することを特徴とする特許請
求の範囲第１項記載の陶磁器の絵画形成法。[Scope of Claims] 1. A step of forming a picture on a transfer paper using a polymer paste for firing consisting of 50 to 95 parts by weight of a finely divided pigment and 5 to 50 parts by weight of an ultraviolet curable resin composition, and photocuring it. A method for forming a picture on ceramics, which comprises the steps of transferring the picture on the transfer paper obtained in the above step onto ceramics, and firing the picture to fix the picture formed from the pigment on the ceramics. 2. After forming a painting on a transfer paper using a photopolymerizable paste for firing consisting of 50 to 95 parts by weight of the finely divided pigment and 5 to 50 parts by weight of an ultraviolet curable resin composition, the painting is cured by ultraviolet rays, and further, The method for forming a picture on ceramics according to claim 1, characterized in that another picture is formed by superimposing this picture.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12692580A JPS5751179A (en) | 1980-09-12 | 1980-09-12 | Ceramic picture formation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP12692580A JPS5751179A (en) | 1980-09-12 | 1980-09-12 | Ceramic picture formation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5751179A JPS5751179A (en) | 1982-03-25 |
| JPH0260637B2 true JPH0260637B2 (en) | 1990-12-17 |
Family
ID=14947287
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP12692580A Granted JPS5751179A (en) | 1980-09-12 | 1980-09-12 | Ceramic picture formation |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5751179A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0562348U (en) * | 1992-01-30 | 1993-08-20 | 株式会社松山製作所 | Mirror angle adjustment device |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5935079A (en) * | 1982-08-16 | 1984-02-25 | 日本写真印刷株式会社 | Transfer sheet for painting ceramic product and manufacture of painted ceramic product therewith |
| JP6440556B2 (en) * | 2015-04-07 | 2018-12-19 | 株式会社ミマキエンジニアリング | Transfer sheet manufacturing method and use thereof |
-
1980
- 1980-09-12 JP JP12692580A patent/JPS5751179A/en active Granted
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0562348U (en) * | 1992-01-30 | 1993-08-20 | 株式会社松山製作所 | Mirror angle adjustment device |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5751179A (en) | 1982-03-25 |
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