JPH0255550B2 - - Google Patents
Info
- Publication number
- JPH0255550B2 JPH0255550B2 JP19998086A JP19998086A JPH0255550B2 JP H0255550 B2 JPH0255550 B2 JP H0255550B2 JP 19998086 A JP19998086 A JP 19998086A JP 19998086 A JP19998086 A JP 19998086A JP H0255550 B2 JPH0255550 B2 JP H0255550B2
- Authority
- JP
- Japan
- Prior art keywords
- antistatic agent
- weight
- water repellent
- formula
- fluorine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002216 antistatic agent Substances 0.000 claims description 49
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 40
- 239000005871 repellent Substances 0.000 claims description 24
- 125000002091 cationic group Chemical group 0.000 claims description 22
- 125000000129 anionic group Chemical group 0.000 claims description 21
- 230000002940 repellent Effects 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 18
- 229920002994 synthetic fiber Polymers 0.000 claims description 15
- 239000012209 synthetic fiber Substances 0.000 claims description 15
- -1 NH 4 Inorganic materials 0.000 claims description 12
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 10
- 229910052731 fluorine Inorganic materials 0.000 claims description 10
- 239000011737 fluorine Substances 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- 125000000217 alkyl group Chemical group 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 4
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 2
- 229910017053 inorganic salt Inorganic materials 0.000 claims 1
- 238000005406 washing Methods 0.000 description 13
- 239000003054 catalyst Substances 0.000 description 10
- 239000007787 solid Substances 0.000 description 10
- 239000004744 fabric Substances 0.000 description 9
- 229920000728 polyester Polymers 0.000 description 9
- 229920003180 amino resin Polymers 0.000 description 7
- 229920005989 resin Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 239000004677 Nylon Substances 0.000 description 5
- 229920001778 nylon Polymers 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 125000005907 alkyl ester group Chemical group 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000009991 scouring Methods 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 230000003068 static effect Effects 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 1
- YZTJKOLMWJNVFH-UHFFFAOYSA-N 2-sulfobenzene-1,3-dicarboxylic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1S(O)(=O)=O YZTJKOLMWJNVFH-UHFFFAOYSA-N 0.000 description 1
- ZEYUSQVGRCPBPG-UHFFFAOYSA-N 4,5-dihydroxy-1,3-bis(hydroxymethyl)imidazolidin-2-one Chemical compound OCN1C(O)C(O)N(CO)C1=O ZEYUSQVGRCPBPG-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 229920003233 aromatic nylon Polymers 0.000 description 1
- NDGSBJSAXJUQTE-UHFFFAOYSA-N azane;phosphorous acid Chemical compound N.OP(O)O NDGSBJSAXJUQTE-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- PJFPFKALGCPVLG-UHFFFAOYSA-N cyclohexane;3,6-dioxabicyclo[6.2.2]dodeca-1(10),8,11-triene-2,7-dione Chemical compound C1CCCCC1.O=C1OCCOC(=O)C2=CC=C1C=C2 PJFPFKALGCPVLG-UHFFFAOYSA-N 0.000 description 1
- DNUFCIOKWJELSH-UHFFFAOYSA-O diazanium dioxido(oxo)phosphanium Chemical compound [NH4+].[NH4+].[O-][P+]([O-])=O DNUFCIOKWJELSH-UHFFFAOYSA-O 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- IIRVGTWONXBBAW-UHFFFAOYSA-M disodium;dioxido(oxo)phosphanium Chemical compound [Na+].[Na+].[O-][P+]([O-])=O IIRVGTWONXBBAW-UHFFFAOYSA-M 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- PPBYBJMAAYETEG-UHFFFAOYSA-N ethene;formaldehyde;urea Chemical compound C=C.O=C.NC(N)=O PPBYBJMAAYETEG-UHFFFAOYSA-N 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910052751 metal Chemical class 0.000 description 1
- 239000002184 metal Chemical class 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 239000011112 polyethylene naphthalate Substances 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 125000002924 primary amino group Chemical class [H]N([H])* 0.000 description 1
- 229940048084 pyrophosphate Drugs 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical group [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- AQMNWCRSESPIJM-UHFFFAOYSA-N sodium;phosphenic acid Chemical compound [Na+].O[P+]([O-])=O AQMNWCRSESPIJM-UHFFFAOYSA-N 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP19998086A JPS6359479A (ja) | 1986-08-28 | 1986-08-28 | 合成繊維構造物の帯電防止ならびに撥水加工方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP19998086A JPS6359479A (ja) | 1986-08-28 | 1986-08-28 | 合成繊維構造物の帯電防止ならびに撥水加工方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6359479A JPS6359479A (ja) | 1988-03-15 |
JPH0255550B2 true JPH0255550B2 (is") | 1990-11-27 |
Family
ID=16416778
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP19998086A Granted JPS6359479A (ja) | 1986-08-28 | 1986-08-28 | 合成繊維構造物の帯電防止ならびに撥水加工方法 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS6359479A (is") |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6924329B2 (en) * | 2001-11-05 | 2005-08-02 | 3M Innovative Properties Company | Water- and oil-repellent, antistatic compositions |
JP5301142B2 (ja) * | 2007-11-16 | 2013-09-25 | 日華化学株式会社 | 帯電防止剤及び帯電防止撥水加工剤、それらを用いた帯電防止加工方法及び帯電防止撥水加工方法、並びに前記方法により処理された繊維製品 |
JP6333239B2 (ja) * | 2013-04-01 | 2018-05-30 | 株式会社Adeka | 難燃剤組成物、難燃剤組成物で処理した難燃性繊維及び該組成物により難燃成分の繊維への定着量を増加させる方法 |
-
1986
- 1986-08-28 JP JP19998086A patent/JPS6359479A/ja active Granted
Also Published As
Publication number | Publication date |
---|---|
JPS6359479A (ja) | 1988-03-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3897584A (en) | Rendering fibrous material flame retardant with cyan amide/halomethyl phosphonic acid systems | |
US2961347A (en) | Process for preventing shrinkage and felting of wool | |
US2795513A (en) | Process for finishing textile material and product | |
JPH0657912B2 (ja) | 難燃性繊維複合体 | |
US2828228A (en) | Textile fire retardant treatment | |
EP0969138B1 (en) | Method for imparting permanent press to textiles | |
JPH0255550B2 (is") | ||
US2785145A (en) | Siliconate-aminoplast compositions and textiles coated therewith | |
HK1080521A1 (en) | Flame-retardant fabrics | |
US3087905A (en) | Durable fluorochemical-melamine resin textile finish | |
US3888779A (en) | Flame retardant composition containing tetrakis (hydroxymethyl) phosphonium oxalate | |
JPH0252028B2 (is") | ||
JP2660984B2 (ja) | 制電性ならびに撥水性を有する合成繊維構造物 | |
US3813220A (en) | Process for modifying keratinous material,composition useful therein,and keratinous material bearing thereon said composition | |
JP2660983B2 (ja) | 合成繊維構造物の制電防止ならびに撥水加工方法 | |
US4376633A (en) | Zwitterion compounds as catalysts in easy-care finishing | |
JP2583814B2 (ja) | 合成繊維を含む布帛の制電撥水加工方法 | |
US4080480A (en) | Catalyzing cellulosic textile finishing processes with phosphonic acid derivatives | |
US4018950A (en) | Durable press finishing with catalysis by triazaphosphaadamantane derivatives | |
JP2000096442A (ja) | セルロース系繊維布帛の加工方法 | |
US3796596A (en) | Finishing process incorporating improved catalyst systems to produce durable flameproofed cellulosic textile products with an excellent hand | |
US3376160A (en) | Treatment of cellulosic material with apo-thiourea flame resistance and the resulting material | |
JPH01221572A (ja) | 繊維構造物の耐久性撥水撥油ならびに防汚加工法 | |
CA1040940A (en) | Curing catalyst combination for textile resins | |
JP2000192371A (ja) | セルロース系繊維含有布帛 |