JPH025505A - Voltage non-linear resistor - Google Patents

Voltage non-linear resistor

Info

Publication number
JPH025505A
JPH025505A JP63154979A JP15497988A JPH025505A JP H025505 A JPH025505 A JP H025505A JP 63154979 A JP63154979 A JP 63154979A JP 15497988 A JP15497988 A JP 15497988A JP H025505 A JPH025505 A JP H025505A
Authority
JP
Japan
Prior art keywords
coated
lead wires
electrode
resistant layer
high resistant
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP63154979A
Other languages
Japanese (ja)
Inventor
Kaori Okamoto
岡本 香織
Takayuki Yuasa
貴之 湯浅
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Holdings Corp
Original Assignee
Matsushita Electric Industrial Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Industrial Co Ltd filed Critical Matsushita Electric Industrial Co Ltd
Priority to JP63154979A priority Critical patent/JPH025505A/en
Publication of JPH025505A publication Critical patent/JPH025505A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To prevent the discharge between lead wires and an element by a method wherein a high resistant layer is partially formed on the element to prevent the contact between the lead wires led out of an electrode formed on both sides of the element comprising a ceramic material and the element part not formed of the electrode from occurring. CONSTITUTION:Sb2O3, Bi2O3, etc., are added to ZnO to be mixed all together and formed into grains. The grains are formed and baked to produce an element. Next, the element is coated with Si-Sb-Bi base glass paste and backed to form a high resistant layer 4. Both the sides of the sintered body is coated with an electrode 2 and baked and then the produced element is held by lead wires 3 and coated with flux to be dipped in eutectic solder. Later, the element, after cleaning up with an organic solvent and drying up, is coated with an epoxy resin to manufacture the title voltage non-linear resistor 1. Through these procedures, the discharge between the lead wires 3 and the element 1 can be prevented from ocurring by partially forming a high resistant layer 4 on the element 1.

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は5セラミック素体上に高抵抗層を形成した酸化
亜鉛を主成分とする電圧非直線抵抗体に関するものであ
る。
DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a voltage nonlinear resistor whose main component is zinc oxide, which has a high resistance layer formed on a five-ceramic element body.

(従来の技術) 酸化亜鉛を主成分とする電圧非直線抵抗体は、ツェナダ
イオードに匹敵する優れた非直線電圧−電流特性と、大
きな耐電流特性を有するため、電圧安定化、パルス電圧
の抑制、サージ電圧の吸収および避雷器用として幅広く
応用展開がなされている。しかし、酸化亜鉛を主成分と
する電圧非直線抵抗体は6大電流領域で使用さス1.る
場合、素体単体では沿面においてフラッシュオーバーが
起こり、素体の劣化や破壊の原因となる。また、酸化亜
鉛を主成分とする電圧非直線抵抗体は、耐湿性が悪いた
め、素体単体での使用は困難である。そこで、リード線
を半田付けした素体をエポキシ樹脂などの絶縁物によっ
てコーティングする方法がとられている。
(Prior art) Voltage nonlinear resistors whose main component is zinc oxide have excellent nonlinear voltage-current characteristics comparable to Zener diodes and large withstand current characteristics, so they are useful for voltage stabilization and pulse voltage suppression. It has been widely used for surge voltage absorption and lightning arrester applications. However, voltage nonlinear resistors whose main component is zinc oxide are used in 6 large current regions.1. In this case, flashover occurs in the creeping surface of the element alone, causing deterioration and destruction of the element. In addition, a voltage nonlinear resistor whose main component is zinc oxide has poor moisture resistance, so it is difficult to use it as a single element. Therefore, a method has been adopted in which the element body to which the lead wires are soldered is coated with an insulating material such as epoxy resin.

第2図は、従来の酸化亜鉛をJE成分とする電圧非直線
抵抗体を示す。同図において、】は電圧非直線抵抗素体
、2は電極であり、:(はリード線である。
FIG. 2 shows a conventional voltage nonlinear resistor having zinc oxide as the JE component. In the figure, ] is a voltage nonlinear resistance element, 2 is an electrode, and :( is a lead wire.

(発明が解決しようとする課題) 上記のように、絶縁物でコーティングすることによって
沿面のフラッシュオーバは抑大るごとができた。しかし
、高バリスタ電圧を有する素体の場合、リード線と素体
が接している部分で放電が起こり、樹脂を破壊してしま
うことがあった7これは、素体内の電流密度が不均一な
ために発生するものである8すなわち、電極周辺、特に
エッジ部分では、電極間より電流密度が小さい傾向j1
工ある。そのため、電極間と同じ電位であるリード線と
素体のエツジの部分に電位差が生じ、放電が引き起こさ
れる欠点があった、 本発明の目的は、従来の欠点を解消し、大電流が流扛て
もリード線ど素体間で放電を起、τさない1i圧圧面直
線抵抗を提供することである8(3題を解決するための
−r、IQ) 本岱明の屯ハJ1直&Q 11(Ir’i体は、セラミ
ック■からなる索体の両面1.二形成され、た電極から
引き出されたリード線と電極が形成、されていない部分
との接Mを防ぐために、素体表面に部分的に高抵抗層を
形成した酸化亜鉛を主成分とするものである。
(Problems to be Solved by the Invention) As described above, by coating with an insulator, flashover along the surface can be suppressed. However, in the case of an element with a high varistor voltage, a discharge occurs at the part where the lead wire and the element are in contact, sometimes destroying the resin.7 This is because the current density inside the element is uneven. 8 In other words, the current density tends to be lower around the electrodes, especially at the edges, than between the electrodes.
There is work. Therefore, there is a drawback that a potential difference occurs between the lead wire and the edge of the element body, which have the same potential as that between the electrodes, causing discharge. Even if a discharge occurs between the lead wire and the element body, it is to provide a 1i pressure surface linear resistance that does not cause τ. (The Ir'i body is formed on both sides of the cable body made of ceramic, and is placed on the surface of the element body in order to prevent the lead wire drawn out from the electrode from coming into contact with the part where the electrode is not formed. The main component is zinc oxide with a partially formed high-resistance layer.

(作 用) 本発明の構成により、リード線と素体間に絶縁層を形成
することになり、放電を防IFすることができる。
(Function) According to the configuration of the present invention, an insulating layer is formed between the lead wire and the element body, and it is possible to prevent IF from discharging.

(実施例) 本発明の一実施例を第1図に基づいて説明する。(Example) An embodiment of the present invention will be described based on FIG.

第1図は本発明の酸化亜鉛製主成分とする電圧非直線抵
抗体を示す6同図におい−C5第2図に示した従来例と
同一部分については同一符号を付し、その説明を省略す
る。
Figure 1 shows a voltage non-linear resistor made of zinc oxide as a main component according to the present invention.6 In the same figure -C5 The same parts as those of the conventional example shown in Figure 2 are given the same reference numerals and their explanations are omitted. do.

ZnOにsb2o−Ig f3120i # Co、0
31 MnO,t Cr、Q、 I NlO+Sin、
、 AQ、l帆等を添加し5ボールミルにより20時間
混合、乾燥後、ポリビニルアルコールを用いて造粒を行
lIテう7、この造粒粉を成形圧800kg/aJで成
形し、昇降温速度100℃/h、1100℃〜1300
℃の温度で2時間焼成し、バリスタ電圧V 、mA =
 300(V/mlの素体を作成する1次に5第1図に
示すように、5i−Sb−Bi系のガラスペーストを塗
布し。
ZnO to sb2o-Ig f3120i # Co, 0
31 MnO,t Cr,Q, I NlO+Sin,
, AQ, 1, etc. were added, mixed for 20 hours in a 5-ball mill, dried, and then granulated using polyvinyl alcohol. 100℃/h, 1100℃~1300
Baked for 2 hours at a temperature of °C, the varistor voltage V, mA =
5i-Sb-Bi glass paste was applied as shown in FIG.

昇降温速度300℃/h、500℃、 10mj、nで
焼き付け。
Baking was performed at a temperature increase/decrease rate of 300°C/h, 500°C, 10mj, n.

高抵抗層4を形成する。最後に、焼結体の両面に電極2
を塗布し、800℃〜900℃で焼き付ける。このよう
にして得られた素子をリード線3にはさみ、フラックス
をつけ、共晶点半田L:′、デイツプする。
A high resistance layer 4 is formed. Finally, electrodes 2 are placed on both sides of the sintered body.
is applied and baked at 800°C to 900°C. The element thus obtained is sandwiched between lead wires 3, flux is applied, and the element is dipped in eutectic point solder L:'.

その後、有機溶剤で洗浄、乾燥後、エポキシ樹脂でコー
ティングし、150℃で2時間加熱硬化させて、電圧非
直線抵抗素体1を得る。
Thereafter, after washing with an organic solvent and drying, it is coated with an epoxy resin and cured by heating at 150° C. for 2 hours to obtain a voltage nonlinear resistance element 1.

表に、上記素体を用いて行な−〕だサージ耐量試験にお
ける素体の放電による樹脂破壊の結果を示す。なお、こ
こでサージ試験とは、8720flsecの標準波形イ
ンパルス電流をステップアップにより流したものをいう
The table shows the results of resin destruction due to discharge of the element in a surge resistance test conducted using the above element. Note that the surge test here refers to a test in which a standard waveform impulse current of 8720 flsec was caused to flow in a step-up manner.

表 抗体の正面図、第2図は従来の電圧非直線抵抗体の正面
図である。
FIG. 2 is a front view of a conventional voltage nonlinear resistor.

1・・・電圧非直線抵抗素体、 2・・・電極、3・・
・リード線、 4・・・高抵抗層。
1... Voltage nonlinear resistance element, 2... Electrode, 3...
・Lead wire, 4...High resistance layer.

特許出願人 松下電器産業株式会社 n:サージ電流印加回数 表からもわかるように、本発明品は、 15000(A
/d)という高電流にも耐えている6(発明の効果) 本発明によれば、リード線と素体との接触を防ぐために
、素体に部分的に高抵抗層を形成することにより、リー
ド線と素体間の放電を防止することができ、その実用上
の効果は大である。
Patent applicant: Matsushita Electric Industrial Co., Ltd.: As can be seen from the table of surge current application times, the product of the present invention has a power consumption of 15,000 (A
/d) 6 (Effects of the Invention) According to the present invention, in order to prevent contact between the lead wire and the element body, by forming a high resistance layer partially on the element body, It is possible to prevent electrical discharge between the lead wire and the element body, which has a great practical effect.

46  図面の簡!+4うな説明46 Simple drawing! +4 Una explanation

Claims (1)

【特許請求の範囲】[Claims] セラミック材からなる素体の両面に形成された電極から
引き出されたリード線と電極が形成されていない素体部
分との接触を防ぐために、素体上に部分的に高抵抗層を
形成した電圧非直線抵抗体。
A high-resistance layer is partially formed on the element body to prevent contact between lead wires pulled out from electrodes formed on both sides of the element body made of ceramic material and parts of the element body where no electrodes are formed. Non-linear resistor.
JP63154979A 1988-06-24 1988-06-24 Voltage non-linear resistor Pending JPH025505A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP63154979A JPH025505A (en) 1988-06-24 1988-06-24 Voltage non-linear resistor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63154979A JPH025505A (en) 1988-06-24 1988-06-24 Voltage non-linear resistor

Publications (1)

Publication Number Publication Date
JPH025505A true JPH025505A (en) 1990-01-10

Family

ID=15596058

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63154979A Pending JPH025505A (en) 1988-06-24 1988-06-24 Voltage non-linear resistor

Country Status (1)

Country Link
JP (1) JPH025505A (en)

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