JPH0249703A - Composition for controlling minamikiroazamiuma (insect pest of thrips having invaded from southeasten asia) and control - Google Patents
Composition for controlling minamikiroazamiuma (insect pest of thrips having invaded from southeasten asia) and controlInfo
- Publication number
- JPH0249703A JPH0249703A JP63202062A JP20206288A JPH0249703A JP H0249703 A JPH0249703 A JP H0249703A JP 63202062 A JP63202062 A JP 63202062A JP 20206288 A JP20206288 A JP 20206288A JP H0249703 A JPH0249703 A JP H0249703A
- Authority
- JP
- Japan
- Prior art keywords
- composition
- ionone
- beta
- eugenol
- thrips
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 25
- 241001414989 Thysanoptera Species 0.000 title claims description 30
- 241000607479 Yersinia pestis Species 0.000 title description 6
- 241000238631 Hexapoda Species 0.000 title description 3
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 claims abstract description 56
- PSQYTAPXSHCGMF-BQYQJAHWSA-N β-ionone Chemical compound CC(=O)\C=C\C1=C(C)CCCC1(C)C PSQYTAPXSHCGMF-BQYQJAHWSA-N 0.000 claims abstract description 56
- SFEOKXHPFMOVRM-UHFFFAOYSA-N (+)-(S)-gamma-ionone Natural products CC(=O)C=CC1C(=C)CCCC1(C)C SFEOKXHPFMOVRM-UHFFFAOYSA-N 0.000 claims abstract description 28
- NPBVQXIMTZKSBA-UHFFFAOYSA-N Chavibetol Natural products COC1=CC=C(CC=C)C=C1O NPBVQXIMTZKSBA-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000005770 Eugenol Substances 0.000 claims abstract description 28
- UVMRYBDEERADNV-UHFFFAOYSA-N Pseudoeugenol Natural products COC1=CC(C(C)=C)=CC=C1O UVMRYBDEERADNV-UHFFFAOYSA-N 0.000 claims abstract description 28
- 229960002217 eugenol Drugs 0.000 claims abstract description 28
- 239000004480 active ingredient Substances 0.000 claims abstract description 11
- 238000002156 mixing Methods 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims description 9
- 239000000443 aerosol Substances 0.000 abstract description 6
- 239000003795 chemical substances by application Substances 0.000 abstract description 5
- 239000007787 solid Substances 0.000 abstract description 3
- 238000005507 spraying Methods 0.000 abstract 2
- 239000002304 perfume Substances 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 27
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 24
- 239000000341 volatile oil Substances 0.000 description 9
- 238000012360 testing method Methods 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 239000000284 extract Substances 0.000 description 7
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 6
- 240000003768 Solanum lycopersicum Species 0.000 description 6
- 241000339373 Thrips palmi Species 0.000 description 6
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 5
- 239000004615 ingredient Substances 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 238000004440 column chromatography Methods 0.000 description 4
- 238000007796 conventional method Methods 0.000 description 4
- 239000000287 crude extract Substances 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 239000012046 mixed solvent Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 240000009088 Fragaria x ananassa Species 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000000741 silica gel Substances 0.000 description 3
- 229910002027 silica gel Inorganic materials 0.000 description 3
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 3
- 235000017557 sodium bicarbonate Nutrition 0.000 description 3
- 206010059866 Drug resistance Diseases 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 238000001793 Wilcoxon signed-rank test Methods 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000008187 granular material Substances 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 230000002940 repellent Effects 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 238000001256 steam distillation Methods 0.000 description 2
- 235000021012 strawberries Nutrition 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 1
- 235000008534 Capsicum annuum var annuum Nutrition 0.000 description 1
- 240000008384 Capsicum annuum var. annuum Species 0.000 description 1
- 244000241235 Citrullus lanatus Species 0.000 description 1
- 235000012828 Citrullus lanatus var citroides Nutrition 0.000 description 1
- 241000219112 Cucumis Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- 240000008067 Cucumis sativus Species 0.000 description 1
- 235000009849 Cucumis sativus Nutrition 0.000 description 1
- 241000219104 Cucurbitaceae Species 0.000 description 1
- PNVJTZOFSHSLTO-UHFFFAOYSA-N Fenthion Chemical compound COP(=S)(OC)OC1=CC=C(SC)C(C)=C1 PNVJTZOFSHSLTO-UHFFFAOYSA-N 0.000 description 1
- 241000896365 Haplothrips statices Species 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 241000208292 Solanaceae Species 0.000 description 1
- 244000061458 Solanum melongena Species 0.000 description 1
- 235000002597 Solanum melongena Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000012230 colorless oil Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- DIRFUJHNVNOBMY-UHFFFAOYSA-N fenobucarb Chemical compound CCC(C)C1=CC=CC=C1OC(=O)NC DIRFUJHNVNOBMY-UHFFFAOYSA-N 0.000 description 1
- 244000037666 field crops Species 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 244000144972 livestock Species 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- -1 polyoxyethylene Polymers 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
【発明の詳細な説明】
本発明は、施設栽培作物の重要害虫であるミナミキイロ
アザミウマの防除用組成物および防除方法に関する。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a composition and method for controlling southern thrips, which is an important pest of greenhouse-grown crops.
従来の技術および課題
近年、施設栽培作物に重大な被害を及ぼす害虫としてミ
ナミキイロアザミウマが注目されている。Conventional Technologies and Issues In recent years, southern thrips has attracted attention as a pest that causes serious damage to cultivated crops.
かかる害虫は、体長１〜１．．４ｊＩｘ程度の総翅類に
属する昆虫であり、キュウリ、メロン、スイカ、ナスビ
、ピーマンなどのウリ科およびナス科果菜類に発生し、
吸汗加害が激しい。従来より、本害虫の防除に種々の殺
虫剤が試みられているが、ミナミキイロアザミウマはア
ザミウマの中では特異的に殺虫剤が効きにくく、実用的
な防除効果を期待できるものとしてはＤＭＴＰ水和剤や
ＢＰＭＣ乳剤など少数のものに限られている。さらに、
本害虫は、１年に十数世代を経過し、薬剤耐性が発達し
易く、その防除は困難を極めている。Such pests have a body length of 1 to 1. ．． It is an insect belonging to the 4jIx class of total insects, and occurs in fruit vegetables of the Cucurbitaceae family and Solanaceae family, such as cucumbers, melons, watermelons, eggplants, and green peppers.
Severe sweat absorption. In the past, various insecticides have been tried to control this pest, but southern thrips is a type of thrips that insecticides are not particularly effective against, and DMTP hydration is the only one that can be expected to have a practical control effect. It is limited to a few products such as emulsions and BPMC emulsions. moreover,
This pest goes through more than ten generations in a year and tends to develop drug resistance, making it extremely difficult to control.
本発明者らは、ミナミキイロアザミウマがトマトおよび
イチゴには全く発生せず、被害を及ぼさないことに着目
し種々検討した結果、該植物に共通する含有成分である
オイゲノールおよびベータ・ヨノンが単独で、あるいは
両者を組み合わせることによりミナミキイロアザミウマ
に対して優れた忌避作用を有することを見出し、本発明
を完成するに至った。The present inventors focused on the fact that southern yellow thrips does not occur on tomatoes and strawberries at all and does not cause any damage, and as a result of various studies, we found that eugenol and beta-ionone, which are common components of these plants, are alone. The present inventors have discovered that the present invention has an excellent repellent effect on southern thrips by using the present invention or a combination of the two, and has completed the present invention.
課題を解決するための手段
すなわち、本発明は、１つの態様において、オイゲノー
ルおよび／またはベータ・ヨノンを有効成分として含有
することを特徴とするミナミキイロアザミウマ防除用組
成物を提供するものである。Means for Solving the Problems In one aspect, the present invention provides a composition for controlling southern thrips, which is characterized by containing eugenol and/or beta-ionone as an active ingredient.
また、本発明は、もう１つの態様において、オイゲノー
ルおよび／またはベータ・ヨノンを有効成分として含有
する組成物を適用することを特徴とするミナミキイロア
ザミウマの防除方法を提供するものである。In another aspect, the present invention provides a method for controlling southern thrips, which comprises applying a composition containing eugenol and/or beta-ionone as an active ingredient.
本発明において用いられるオイゲノールおよびベータ・
ヨノンは香料の一種として公知の化合物であり、商業的
に入手可能であるが、これらがミナミキイロアザミウマ
防除作用を有するとの報告は未だ見当たらない。Eugenol and beta-
Ionone is a compound known as a type of fragrance and is commercially available, but there have been no reports yet that these have an effect on controlling southern thrips.
本発明においては、これらの商業的に入手可能なオイゲ
ノールおよびベータ・ヨノンは、必要により、適宜精製
して使用してもよく、また、以下に記載するごとく、ト
マトまたはイチゴより抽出したエキスをそのまま使用し
てもよい。In the present invention, these commercially available eugenol and beta-ionone may be used after being purified as necessary, or the extract extracted from tomatoes or strawberries may be used as is, as described below. May be used.
有効成分の抽出を行うには、まず、トマトまたはイチゴ
の全草あるいは葉部または茎部を常法に従って水蒸気蒸
留し、留出物をエーテルなどの有機溶媒で抽出して揮発
性油分を得る。ついで、この揮発性油分を炭酸水素ナト
リウムなどのアルカリで処理して酸性成分を除去し、ア
ルカリ不溶性の粗抽出エキスを得る。得られた粗抽出エ
キスをシリカゲル上でヘキサン／エーテル混合溶媒を用
いてカラムクロマトグラフィーに付し、後記のごときミ
ナミキイロアザミウマ防除作用のスクリーニング試験に
おいて最も強い活性を示すフラクションを集め、常法に
従って溶出溶媒を除去して無色油状物の精製抽出エキス
を得る。To extract the active ingredients, first, the whole tomato or strawberry plant, leaves, or stems are steam-distilled according to a conventional method, and the distillate is extracted with an organic solvent such as ether to obtain a volatile oil. Next, this volatile oil is treated with an alkali such as sodium bicarbonate to remove acidic components and obtain an alkali-insoluble crude extract. The obtained crude extract was subjected to column chromatography on silica gel using a hexane/ether mixed solvent, and the fraction showing the strongest activity in the screening test for control of southern thrips as described below was collected and eluted according to a conventional method. The solvent is removed to obtain a purified extract of colorless oil.
本発明のミナミキイロアザミウマ防除用組成物には、有
効成分として、これらの粗抽出エキス、精製抽出エキス
、商業的に入手できるオイゲノールおよびベータ・ヨノ
ンを単独で、または組合わせて用いることができる。In the composition for controlling southern thrips of the present invention, these crude extracts, purified extracts, commercially available eugenol and beta ionone can be used alone or in combination as active ingredients.
特に、オイゲノールおよびベータ・ヨノンが１：ｌＯ〜
２０：１、好ましくは、１０：１〜Ｉｌｌの混合割合の
抽出物または市販薬剤の混合物を用いるとミナミキイロ
アザミウマ防除効果が大きくなり、好ましい。In particular, eugenol and beta-ionone are 1:1O ~
It is preferable to use an extract or a mixture of commercially available drugs at a mixing ratio of 20:1, preferably 10:1 to 111, because the effect of controlling southern thrips becomes greater.
本発明のミナミキイロアザミウマ防除用組成物は、前記
有効成分をそのまま用いてもよく、また、常法に従って
、固体担体もしくは液体担体、界面活性剤、その他の製
剤用補助剤の一種またはそれ以上と組合わせて、例えば
、乳剤、エアロゾル、粉剤、粒剤、水和剤、懸濁剤など
の形態として用いてもよい。補助剤と組合わせて用いる
場合、本発明の有効成分を製剤全量に対して０．１〜５
０重量％、好ましくは、１−１ｏ重量％の範囲で含有さ
せることができ、常法に従ってそれぞれの形態に調製す
ることができる。The composition for controlling southern thrips of the present invention may be prepared by using the above-mentioned active ingredients as they are, or by adding one or more of solid or liquid carriers, surfactants, and other formulation auxiliaries according to conventional methods. They may be used in combination, for example, in the form of emulsions, aerosols, powders, granules, wettable powders, suspensions, and the like. When used in combination with an adjuvant, the amount of the active ingredient of the present invention is 0.1 to 5% based on the total amount of the preparation.
It can be contained in an amount of 0% by weight, preferably in the range of 1-10% by weight, and can be prepared in any form according to a conventional method.
本発明の組成物を用いてミナミキイロアザミウマを防除
するには、通常、調製した製剤を直接対象植物体に噴霧
または散布するが、エアロゾルの形態にて噴霧するのが
特に好ましい。また、本発明の組成物を含有する大型固
形剤をハウス内の適当な場所に数カ所つり下、げておく
だけでも有効にミナミキイロアザミウマを防除すること
ができる。In order to control southern thrips using the composition of the present invention, the prepared preparation is usually sprayed or dispersed directly onto the target plant, but it is particularly preferable to spray it in the form of an aerosol. In addition, southern thrips can be effectively controlled simply by hanging and hanging large solid preparations containing the composition of the present invention at several appropriate locations within the house.
施用量は、施用場所、施用方法、製剤形態などによりこ
となるが、通常、１０’〜ＩＯ’ｐｐｍの濃度に希釈し
て用いる。The application amount varies depending on the application site, application method, formulation form, etc., but it is usually used after diluting to a concentration of 10' to IO' ppm.
本発明の組成物は、通常、施設栽培に適用されるが、そ
の他に露地栽培などにも適用することができ、野菜、畑
作物、花 などに発生するミナミキイロアザミウマを有
効に防除することができる。The composition of the present invention is usually applied to greenhouse cultivation, but can also be applied to outdoor cultivation, etc., and can effectively control southern yellow thrips on vegetables, field crops, flowers, etc. can.
寒鼻鯉
つぎに参考例、試験例および実施例を挙げて本発明をさ
らに詳しく説明するが、本発明はこれらに限定されるも
のではない。Next, the present invention will be explained in more detail with reference to reference examples, test examples, and examples, but the present invention is not limited thereto.
参考例
抽出エキスの調製
トマトの全草１６ｋｇを長さ５ｃｍ程度に細断した後水
蒸気蒸留に付し、面出物をエーテル抽出して揮発性油分
（Ａ）１．５３９を得た。同様に、トマト葉茎部１２ｋ
ｇから揮発性油分（Ｂ）１．７５９を得た。Reference Example Preparation of Extract 16 kg of whole tomato plants were chopped into pieces of about 5 cm in length, and then subjected to steam distillation, and the extracted matter was extracted with ether to obtain a volatile oil (A) of 1.539 g. Similarly, tomato leaf and stem part 12k
1.759 of volatile oil (B) was obtained from g.
ついで、揮発性油分（Δ）１．４９および（Ｂ）１．３
９を、それぞれ、５％炭酸水素ナトリウムで処理して酸
性成分を除去し、揮発性油分（Ａ）から中性成分（Ｃ）
Ｏ−，５７ｇおよび揮発性油分（Ｉ３）から中性成分（
＋））１．２ｏｇ得た。中性成分（Ｃ）および（Ｄ）は
、さらに、それぞれ、内径Ｉ２ｕのビユレットに３００
メツシユの活性シリカゲルを約３０ｃｍ充ｔＪ’ｔした
カラムを用い、ヘキサン、ヘキサン／エーテル、エーテ
ル、酢酸エヂル、メタノールの順に溶出して粗抽出エキ
スを得、ついで同カラムにてヘキサン、ヘキサン／エー
テル、エーテルの順に溶出］２て抽出エキスを得た。Then, volatile oil content (Δ) 1.49 and (B) 1.3
9 was treated with 5% sodium hydrogen carbonate to remove acidic components, and the volatile oil (A) was separated from the neutral component (C).
O-, 57g and volatile oil (I3) to neutral component (
+)) 1.2 og was obtained. Neutral components (C) and (D) were each further added to a biulet with an inner diameter of I2u at a temperature of 300
Using a column filled with about 30 cm of activated silica gel from Messhu, elute hexane, hexane/ether, ether, ethyl acetate, and methanol in this order to obtain a crude extract, and then use the same column to elute hexane, hexane/ether, [Ether was eluted in this order]]2 to obtain an extracted extract.
得られた抽出エキスまたはそれらの有効成分であるオイ
ゲノールおよびベータ・ヨノンを用いて以下に示す試験
を行った。なお、結果はウイルコクソン検定法により評
価した。The following tests were conducted using the obtained extracts or their active ingredients, eugenol and beta-ionone. Note that the results were evaluated using the Wilcoxon test method.
試験例！
前記のごと＜トマ）・の茎葉部を水７に′Ａ１蒸留１７
て得た揮発性油分（１３）０．５解を０ 、５ ｍＱの
エーテルに溶解して幅５１肩、長さ３ｃｒｎの濾紙片に
吸収させた。対照として同じ大きさの濾紙片をエーテル
で湿した後乾燥させた物を用いた。つぎに、これらの濾
紙片を用い、５匹のミナミキイロアザミウマにて選択実
験を１０回繰り返し行った。結果を第１表に示す。Test example! Distilled the stems and leaves of Tomato as described above into 7 parts of water.
0.5 solution of the volatile oil (13) obtained was dissolved in 0.5 mQ of ether and absorbed onto a piece of filter paper with a width of 51 cm and a length of 3 crn. As a control, a piece of filter paper of the same size was moistened with ether and then dried. Next, using these filter paper pieces, a selection experiment was repeated 10 times with 5 southern yellow thrips. The results are shown in Table 1.
実験例２
前記の揮発性′ＡＩ＋分（Ｉ３）をさらに５％炭酸水素
ナトリウム水溶液で処理してｉｌ、；られた中＋ｉ酸成
分ンリカゲルカラムクロマトグラフィーに付し、ヘキザ
ン／エーテル＝９：Ｉ混合溶媒溶出部をシリカゲル上町
カラムクロマトグラフィーに付し、ヘキサン／エーテル
＝１２：ｌおよび１０：１混合溶媒にて溶出して得られ
た以下の組成を有するフラクション各０．５Ｎを用い、
前記試験例１と同様の選択実験を１０
回繰り返し行った。結果を第１表に示す。Experimental Example 2 The above volatile AI+ component (I3) was further treated with a 5% aqueous sodium bicarbonate solution and subjected to licage gel column chromatography to obtain a solution of hexane/ether=9:I. The mixed solvent eluate was subjected to silica gel Kamimachi column chromatography, and 0.5N of each fraction having the following composition obtained by elution with hexane/ether = 12:l and 10:1 mixed solvent was used.
The same selection experiment as in Test Example 1 was repeated 10 times. The results are shown in Table 1.
再カラムクロマトグラフィーにより得られたフラクショ
ンの主成分の組成
第 １ 表
注二表中、＊＊はウイルコクソン検定法にて危険率５％
で有意にミナミキイロアザミウマを忌避したことを示す
。Composition of the main components of the fractions obtained by re-column chromatography Table 1 Note 2 In the table, ** indicates a 5% risk rate according to the Wilcoxon test method.
showed that it significantly repelled southern yellow thrips.
第１表から明らかなごとく、水蒸気蒸留にて得られた揮
発性油分（Ｂ）ならびにシリカゲルカラムにてヘキサン
／エーテル−１２・ＩおよびＩ Ｏ：１混合溶媒により
溶出したフラクションは全てミナミキイロアザミウマを
強く忌避し、ミナミキイロアザミウマの防除剤として有
効であることを示している。As is clear from Table 1, the volatile oil (B) obtained by steam distillation and the fraction eluted with hexane/ether-12.I and I O:1 mixed solvent in the silica gel column all contained southern thrips. It is strongly repellent and has been shown to be effective as a control agent for southern thrips.
試験例３
前記試験例２の溶出物の主成分であるオイゲノールおよ
びベータ・ヨノンをそれぞれ０ 、５ ＊ｇｍい、前記
と同様にして選択実験を１０回繰り返し行った。結果を
第２表に示す。Test Example 3 A selection experiment was repeated 10 times in the same manner as above, using 0 and 5*gm of eugenol and beta-ionone, which are the main components of the eluate in Test Example 2, respectively. The results are shown in Table 2.
試験例４
オイゲノールおよびベータ・ヨノンを重量比にてＩＯ・
ｌおよび１．１の割合で配合した混合物釜０ 、５ ｙ
ｔｇを用い、前記と同様にして選択実験を１０回繰り返
し行った。結果を第２表に示す。Test Example 4 Eugenol and beta-ionone in weight ratio of IO.
Mixture pot 0,5 y blended in the ratio of l and 1.1
Using tg, the selection experiment was repeated 10 times in the same manner as above. The results are shown in Table 2.
第２表
注二表中、＊および＊＊は、ウイルコクソン検定法にて
危険率１０％および５％でそれぞれミナミキイロアザミ
ウマを有意に忌避したことを示す。In Table 2 Note 2, * and ** indicate that southern thrips was significantly repelled at a risk rate of 10% and 5%, respectively, using the Wilcoxon assay.
第２表から明らかなごとく、ベータ・ヨノンおよびオイ
ゲノール／ベータ・ヨノン（１０：１重量比（Ｗ／Ｗ）
）の混合物はミナミキイロアザミウマを強く忌避し、ま
た、オイゲノールおよびオイゲノール／ベータ・ヨノン
（１： １ ｗ／ｖ）の混合物もミナミキイロアザミウ
マを忌避した。As is clear from Table 2, beta-ionone and eugenol/beta-ionone (10:1 weight ratio (W/W)
) strongly repelled southern thrips, and a mixture of eugenol and eugenol/beta-ionone (1:1 w/v) also repelled southern thrips.
実施例１
成分
オイゲノール／ベータ・ヨノン
重量部
（１０：Ｉｖ／ｗ）
キシレン
ポリオキシエチレンアルキルフェニル
エーテル ８アルキ
ルベンゼンスルホン酸ナトリウム ２以上の成分をよ
く混合してミナミキイロアザミウマ防除用乳剤を得た。Example 1 Ingredients Eugenol/Beta-ionone weight parts (10:Iv/w) Xylene polyoxyethylene alkylphenyl ether Sodium 8-alkylbenzenesulfonate Two or more components were thoroughly mixed to obtain an emulsion for controlling southern thrips.
実施例２
成 分 重量部オイゲノ
ール／ベータ・ヨノン
（１０二ｌｖ／ｗ）
２脱臭ケロシン
１０ジエチルエーテル
Ｉ５フロン１１３ ’ ７
３以上の成分を密閉容器に充填してミナミキイロアザミ
ウマ防除用エアロゾルを得た。Example 2 Ingredients Parts by weight Eugenol/Beta-ionone (102 lv/w)
2 Deodorized kerosene
10 diethyl ether
I5 Freon 113' 7
Three or more components were filled into a sealed container to obtain an aerosol for controlling southern yellow thrips.
実施例３
オイゲノール／ベータ・ヨノン（１０：１ｗ／ｗ）をベ
ータ・ヨノンに代える以外前記と同様にしてミナミキイ
ロアザミウマ防除用エアロゾルを得た。Example 3 An aerosol for controlling southern thrips was obtained in the same manner as above except that eugenol/beta-ionone (10:1 w/w) was replaced with beta-ionone.
実施例４
オイゲノール／ベータ・ヨノン（１０：１ｗ／ｗ）をオ
イゲノールに代える以外前記と同様にしてミナミキイロ
アザミウマ防除用エアロゾルを得た。Example 4 An aerosol for controlling southern thrips was obtained in the same manner as above except that eugenol/beta-ionone (10:1 w/w) was replaced with eugenol.
実施例５
成分 重量部
オイゲノール／ベータ・ヨノン
（１０：１ｗ／ｖ） ３
クレー ８７タル
ク ｉ。Example 5 Ingredients Parts by weight Eugenol/Beta-ionone (10:1 w/v) 3
Clay 87 Talc i.
以上の成分をよく混合してミナミキイロアザミウマ防除
用粉剤を得た。The above components were thoroughly mixed to obtain a powder for controlling southern yellow thrips.
実施例６
成 分 重量部オイゲノ
ール／ベータ・ヨノン
（１０：Ｉｗ／ｗ） Ｉ
Ｏリグニンスルホン酸カルシウム ２ベント
ナイト ３゜クレー
５８以上の成分を均一
に混合し、ついで適当量の水を加えて練合した後、造粒
し、乾燥してミナミキイロアザミウマ防除用粒剤を得た
。Example 6 Ingredients Part by weight Eugenol/Beta-ionone (10: Iw/w) I
O Calcium ligninsulfonate 2 Bentonite 3゜Clay
58 or more components were uniformly mixed, then an appropriate amount of water was added and kneaded, then granulated and dried to obtain granules for controlling southern thrips.
実施例７
成 分 重量部オイゲノ
ール／ベータ・ヨノン
（１０：Ｉｖ／ｗ） ５０
アルキルベンゼンスルホン酸ナトリウム ６リグニン
スルポン酸ナトリウム ４クレー
４０以上の成分をよく混合し
てミナミキイロアザミウマ防除用水和剤を得た。Example 7 Ingredients Part by weight Eugenol/Beta-ionone (10:Iv/w) 50
Sodium alkylbenzenesulfonate 6 Sodium lignin sulfonate 4 Clay
More than 40 components were thoroughly mixed to obtain a wettable powder for controlling southern thrips.
発明の効果
本発明によれば、ミナミキイロアザミウマに対して優れ
た防除作用を有し、かっ、薬剤耐性や薬害なども生じる
ことなく、人畜に対して無害な組成物および防除方法が
提供される。Effects of the Invention According to the present invention, there is provided a composition and control method that has an excellent control effect against southern thrips, does not cause drug resistance or drug damage, and is harmless to humans and livestock. .
手続補正書（白色
特許庁長官殿 平成１年３月９目発明の名称
ミナミキイ〔ノアザミウマ防除用組成物および防除方法
補正をする者
事件との関係Procedural amendment (Dear Commissioner of the White Patent Office, March 9, 1999 Name of the invention Minamikii [Relationship with the case of the person amending the composition and method for controlling black thrips)
Claims (4)
効成分として含有することを特徴とするミナミキイロア
ザミウマ防除用組成物。(1) A composition for controlling southern thrips, which is characterized by containing eugenol and/or beta-ionone as an active ingredient.
１：１０〜２０：１である前記第（１）項のミナミキイ
ロアザミウマ防除用組成物。(2) The composition for controlling southern thrips according to item (1) above, wherein the blending ratio of eugenol and beta-ionone is 1:10 to 20:1.
効成分として含有する組成物を適用することを特徴とす
るミナミキイロアザミウマの防除方法。(3) A method for controlling southern thrips, which comprises applying a composition containing eugenol and/or beta-ionone as an active ingredient.
１：１０〜２０：１である前記第（３）項のミナミキイ
ロアザミウマの防除方法。(4) The method for controlling southern thrips according to item (3) above, wherein the blending ratio of eugenol and beta-ionone is 1:10 to 20:1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63202062A JP2602912B2 (en) | 1988-08-11 | 1988-08-11 | Composition for controlling Thrips palmi Karny and control method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63202062A JP2602912B2 (en) | 1988-08-11 | 1988-08-11 | Composition for controlling Thrips palmi Karny and control method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0249703A true JPH0249703A (en) | 1990-02-20 |
| JP2602912B2 JP2602912B2 (en) | 1997-04-23 |
Family
ID=16451313
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63202062A Expired - Fee Related JP2602912B2 (en) | 1988-08-11 | 1988-08-11 | Composition for controlling Thrips palmi Karny and control method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2602912B2 (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2699051A1 (en) * | 1992-12-16 | 1994-06-17 | Roger Catherine | Polyphenol-based insecticide compositions. |
| US5635760A (en) * | 1993-07-01 | 1997-06-03 | Nec Corporation | Surface mount semiconductor device |
| WO1998054971A1 (en) * | 1997-06-06 | 1998-12-10 | Ecosmart Technologies, Inc. | Non-hazardous pest control |
| JP2002521406A (en) * | 1998-07-28 | 2002-07-16 | エコスマート テクノロジーズ，インコーポレーテッド | Synergistic residual pest control compounds containing plant essential oils |
| WO2005046330A1 (en) | 2003-11-13 | 2005-05-26 | New Zealand Institute For Crop & Food Research Limited | Insect behaviour modifying compounds |
| JP2008137940A (en) * | 2006-12-01 | 2008-06-19 | Taiyo Corp | Thrips controlling agent |
| US7618645B2 (en) | 1998-07-28 | 2009-11-17 | Ecosmart Technologies, Inc. | Synergistic and residual pesticidal compositions containing plant essential oils |
| CN115413682A (en) * | 2022-08-29 | 2022-12-02 | 京博农化科技有限公司 | Application and composition of tomato stem and leaf extract for preventing and treating thrips |
-
1988
- 1988-08-11 JP JP63202062A patent/JP2602912B2/en not_active Expired - Fee Related
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2699051A1 (en) * | 1992-12-16 | 1994-06-17 | Roger Catherine | Polyphenol-based insecticide compositions. |
| WO1994013141A1 (en) * | 1992-12-16 | 1994-06-23 | Elf Atochem S.A. | Polyphenol-based insecticide compositions |
| US5635760A (en) * | 1993-07-01 | 1997-06-03 | Nec Corporation | Surface mount semiconductor device |
| WO1998054971A1 (en) * | 1997-06-06 | 1998-12-10 | Ecosmart Technologies, Inc. | Non-hazardous pest control |
| JP2002521406A (en) * | 1998-07-28 | 2002-07-16 | エコスマート テクノロジーズ，インコーポレーテッド | Synergistic residual pest control compounds containing plant essential oils |
| US7618645B2 (en) | 1998-07-28 | 2009-11-17 | Ecosmart Technologies, Inc. | Synergistic and residual pesticidal compositions containing plant essential oils |
| JP2007511506A (en) * | 2003-11-13 | 2007-05-10 | ニュージーランド インスティテュート フォー クロップ アンド フード リサーチ リミティド | Insect behavior modifying compounds |
| WO2005046330A1 (en) | 2003-11-13 | 2005-05-26 | New Zealand Institute For Crop & Food Research Limited | Insect behaviour modifying compounds |
| JP4927553B2 (en) * | 2003-11-13 | 2012-05-09 | ザ ニュージーランド インスティテュート フォー プラント アンド フード リサーチ リミティド | Insect behavior modifying compounds |
| JP2012087137A (en) * | 2003-11-13 | 2012-05-10 | New Zealand Inst For Plant & Food Research Ltd | Insect behaviour modifying compound |
| JP2008137940A (en) * | 2006-12-01 | 2008-06-19 | Taiyo Corp | Thrips controlling agent |
| CN115413682A (en) * | 2022-08-29 | 2022-12-02 | 京博农化科技有限公司 | Application and composition of tomato stem and leaf extract for preventing and treating thrips |
| CN115413682B (en) * | 2022-08-29 | 2024-04-05 | 山东京博农化科技股份有限公司 | Application of tomato stem and leaf extract in preventing and treating thrips and composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2602912B2 (en) | 1997-04-23 |
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