JPH02285006A - Production of fine particle of gallium-containing metal - Google Patents
Production of fine particle of gallium-containing metalInfo
- Publication number
- JPH02285006A JPH02285006A JP10499689A JP10499689A JPH02285006A JP H02285006 A JPH02285006 A JP H02285006A JP 10499689 A JP10499689 A JP 10499689A JP 10499689 A JP10499689 A JP 10499689A JP H02285006 A JPH02285006 A JP H02285006A
- Authority
- JP
- Japan
- Prior art keywords
- gallium
- metal
- fine particles
- containing metal
- alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 42
- 239000002184 metal Substances 0.000 title claims abstract description 42
- 229910052733 gallium Inorganic materials 0.000 title claims abstract description 33
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 239000010419 fine particle Substances 0.000 title claims abstract description 23
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 239000012298 atmosphere Substances 0.000 claims abstract description 8
- 239000002826 coolant Substances 0.000 claims abstract description 6
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052738 indium Inorganic materials 0.000 claims abstract description 4
- 230000000737 periodic effect Effects 0.000 claims abstract description 4
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 4
- 239000011701 zinc Substances 0.000 claims abstract description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 3
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910052718 tin Inorganic materials 0.000 claims abstract description 3
- 238000002347 injection Methods 0.000 claims description 12
- 239000007924 injection Substances 0.000 claims description 12
- 229910045601 alloy Inorganic materials 0.000 claims description 10
- 239000000956 alloy Substances 0.000 claims description 10
- 239000011261 inert gas Substances 0.000 claims description 7
- 238000002844 melting Methods 0.000 claims description 7
- 230000008018 melting Effects 0.000 claims description 7
- 239000000243 solution Substances 0.000 claims description 3
- 229910000807 Ga alloy Inorganic materials 0.000 abstract description 7
- 238000001816 cooling Methods 0.000 abstract description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 14
- 239000000843 powder Substances 0.000 description 10
- 235000019441 ethanol Nutrition 0.000 description 9
- 238000000034 method Methods 0.000 description 6
- 239000007789 gas Substances 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 4
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 4
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 4
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 4
- 239000005642 Oleic acid Substances 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 4
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 4
- BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- 238000010301 surface-oxidation reaction Methods 0.000 description 2
- JBRZTFJDHDCESZ-UHFFFAOYSA-N AsGa Chemical compound [As]#[Ga] JBRZTFJDHDCESZ-UHFFFAOYSA-N 0.000 description 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229910001111 Fine metal Inorganic materials 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 229910052792 caesium Inorganic materials 0.000 description 1
- TVFDJXOCXUVLDH-UHFFFAOYSA-N caesium atom Chemical compound [Cs] TVFDJXOCXUVLDH-UHFFFAOYSA-N 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009432 framing Methods 0.000 description 1
- 150000002258 gallium Chemical class 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 239000002923 metal particle Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 238000004663 powder metallurgy Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
Abstract
Description
【発明の詳細な説明】
（イ）技術分野
本発明は金属ガリウム又はその合金の微粒子を製造する
方法に関し、更に詳しくは金属ガリウム単独あるいは金
属ガリウムと周期率表の第■族。DETAILED DESCRIPTION OF THE INVENTION (a) Technical field The present invention relates to a method for producing fine particles of metallic gallium or its alloy, and more specifically to metallic gallium alone or together with metallic gallium from group Ⅰ of the periodic table.
第■族又は第■族の群から選ばれる少なくとも１種以上
の金属との合金の微粒子を製造する方法に関するもので
ある。The present invention relates to a method for producing fine particles of an alloy with at least one metal selected from Group ① or Group ①.
（ロ）背景技術
金、銀、銅、亜鉛、鉄等の金属粉末、特に粉末冶金用の
金属又はその合金の粉末の製造法に関しては、従来から
多種提案され工業化されているが、金属ガリウム又はガ
リウム合金の微粒子の製造法に関する技術は皆無であり
、従来がら金属ガリウム又はガリウム合金の微粉末は製
造できないものとされていた。(b) Background Art Various methods for producing metal powders such as gold, silver, copper, zinc, iron, etc., especially powders of metals or their alloys for powder metallurgy, have been proposed and industrialized. There is no technology related to a method for producing fine particles of gallium alloy, and it has conventionally been thought that it is impossible to produce fine powder of metallic gallium or gallium alloy.
その理由としては、まずガリウムは金属としては水銀、
セシウムについで三番目に融点が低く（融点２９．７８
℃）、例えばガリウム−インジウム（７６：２４）合金
にあってはその融点が１５．７℃であって、手で握りし
めたり温湯に入れるだけで容易に融解する特性があり、
微粉末製造に適さないことが上げられる。The reason for this is that gallium, as a metal, is mercury,
It has the third lowest melting point after cesium (melting point 29.78
For example, the melting point of gallium-indium (76:24) alloy is 15.7°C, and it has the property of easily melting by simply squeezing it in your hands or placing it in hot water.
One of the reasons is that it is not suitable for producing fine powder.
また、需要面からすれば、例えば金属ガリウムやガリウ
ム・砒素など半導体材料としての用途は広いものの、そ
の微粒子としての利用はほとんど要求されなかったこと
もある。In addition, from a demand perspective, although metal gallium and gallium arsenic have a wide range of uses as semiconductor materials, there has been little demand for their use in the form of fine particles.
しかし゛ながら、近時ガリウムはスキー滑走用金属ワッ
クスとして脚光を浴び、その需用も益々多くなり、その
取扱いも容易な微粒子状の金属ガリウムやガリウム合金
が広く要望されるようになった。However, recently, gallium has been in the spotlight as a metal wax for skiing, and its demand has been increasing, and there has been a wide demand for fine-particle metallic gallium and gallium alloys that are easy to handle.
このスキー滑走用ガリウムワックスは本出願人の提案に
係る特公昭−８４６０号公報や特願昭６３−１２５３８
９号等に記載されている通りであり、その特性・効果も
抜群である。This gallium wax for skiing is disclosed in Japanese Patent Publication No. Sho-8460 and Japanese Patent Application No. Sho 63-12538, which were proposed by the present applicant.
It is as described in No. 9, etc., and its characteristics and effects are outstanding.
そのため、携帯や使用時に取扱い易い微粒子状の金属ガ
リウムやガリウム合金が広く要望されるようになったの
である。Therefore, there has been a widespread demand for fine particle metal gallium and gallium alloys that are easy to handle when carried and used.
（ハ）発明の開示
本発明は上記の要望を満たすべく、研究の結果なされた
含ガリウム金属微粒子を製造する方法に関するものであ
る。(C) Disclosure of the Invention The present invention relates to a method for producing gallium-containing metal fine particles, which was developed as a result of research in order to satisfy the above-mentioned needs.
本発明は、金属ガリウム単独あるいは金属ガリウムと周
期率表の第１Ｉ族、第■族、第■族の群から選ばれる少
なくとも１種以上の金属、好ましくはインジウム、亜鉛
、錫、アルミニウム等から選ばれるいずれか１種又は２
種以上の金属との合金の微粒子粉の製造方法を提供する
ものである。The present invention uses metallic gallium alone or metallic gallium together with at least one metal selected from the group 1I, group Ⅰ, group Ⅰ of the periodic table, preferably selected from indium, zinc, tin, aluminum, etc. Either one or two
The present invention provides a method for producing fine particle powder of an alloy with one or more metals.
以下、本発明法の詳細について説明する。The details of the method of the present invention will be explained below.
本発明法は、金属ガリウム又はその合金を不活性ガス（
窒素ガス、アルゴンガス等）雰囲気中で金属ガリウム又
はその合金をその融点以上〜１００℃以下好ましくは７
０〜９０℃で融解させ、不活性ガス雰囲気中で該融解金
属を噴射ノズルから冷却用溶媒水溶液中へ直接又は間接
的に噴射させて微粒子とする。In the method of the present invention, metallic gallium or its alloy is heated in an inert gas (
Metal gallium or its alloy in an atmosphere (nitrogen gas, argon gas, etc.) above its melting point and below 100°C, preferably 7
The metal is melted at a temperature of 0 to 90°C, and the molten metal is directly or indirectly injected from an injection nozzle into an aqueous cooling solvent solution in an inert gas atmosphere to form fine particles.
上記した間接的とは、噴射ノズルから融解金属を不活性
ガス雰囲気中にいったん噴射させた後、冷却用媒体液中
へ落下投入することを意味する。The above-mentioned indirect means that the molten metal is once injected into the inert gas atmosphere from the injection nozzle and then dropped into the cooling medium liquid.
また、上記冷却用媒体としては、通常の冷却水のほか、
アルコール類、オレイン酸又はその塩（例えばオレイン
酸ソーダ等）あるいは界面活性剤等のコーティング剤の
水溶液が好ましく、該媒体液の温度は１０℃以下好まし
くは５℃以下に保持する。In addition to normal cooling water, the cooling medium mentioned above may include ordinary cooling water,
An aqueous solution of a coating agent such as an alcohol, oleic acid or its salt (eg, sodium oleate, etc.) or a surfactant is preferable, and the temperature of the medium is maintained at 10°C or lower, preferably 5°C or lower.
また、噴射ノズルから融解金属と共に噴射する不活性ガ
スのガス圧は、Ｎ２ガスでは５〜１０Ｋｇ／ｃＩＩｚ程
度がよく、噴射装置としては通常のスプレーガンでもよ
い。Further, the gas pressure of the inert gas injected together with the molten metal from the injection nozzle is preferably about 5 to 10 kg/cIIz for N2 gas, and a normal spray gun may be used as the injection device.
この噴射ノズルからの噴射圧力や噴射速度によって金属
ガリウムあるいはガリウム合金の微粒子のサイズが決ま
るので、目的とする微粒子粉の粒径や粒度分布を得るた
めには、融解金属の噴射圧力や噴射速度を適宜選択すれ
ばよい。The size of the fine particles of metallic gallium or gallium alloy is determined by the injection pressure and injection speed from this injection nozzle, so in order to obtain the desired particle size and particle size distribution of the fine particle powder, it is necessary to adjust the injection pressure and injection speed of the molten metal. You can select it as appropriate.
なお、噴射する際に不活性ガス雰囲気にしたり、噴射用
不活性ガスを使用するのは金属粉の表面酸化を防止する
ためである。Note that the purpose of creating an inert gas atmosphere or using an inert gas for injection during injection is to prevent surface oxidation of the metal powder.
次に、上記のようにして冷却溶媒水溶液中で得られた金
属ガリウムあるいはガリウム合金粉末は、その表面をエ
チルアルコール、オレイン酸又はその塩等のコーティン
グ剤でコーティング処理した後、上記水溶液と分離し、
篩で篩分けて乾燥する。Next, the surface of the metal gallium or gallium alloy powder obtained in the cooled aqueous solvent solution is coated with a coating agent such as ethyl alcohol, oleic acid or its salt, and then separated from the aqueous solution. ,
Sieve through a sieve and dry.
なお、篩網上のオーバーサイズの金属粉は原料金属工程
へ繰返して再度上記の処理を行なう。Note that the oversized metal powder on the sieve screen is repeatedly sent to the raw metal process and subjected to the above treatment again.
一方、篩網下の金属微粒子はコーティング剤（界面活性
剤等）例えばオレイン酸ソーダ等を含むアルコールを溶
媒とする媒体内に浸漬し、常温以下好ましくは２０℃以
下で数分間振動ミル等で微粉枠することによって初期の
目的とする粒径の金属微粒子が得られる。On the other hand, the fine metal particles under the sieve are immersed in a medium containing a coating agent (surfactant, etc.), such as an alcohol containing sodium oleate, etc., and then pulverized using a vibrating mill or the like for several minutes at room temperature or below, preferably below 20°C. By framing, metal fine particles having the initial target particle size can be obtained.
得られた金属ガリウムあるいはその合金微粒子は、アル
コール中で保管する。The obtained metallic gallium or its alloy fine particles are stored in alcohol.
次に、本発明を実施例によって説明する。Next, the present invention will be explained by examples.
金属ガリウム単独を原料として一３７１Ｌｍの微粒子を
製造する場合の概略フロシートを第１図に示す。FIG. 1 shows a schematic flow sheet for producing fine particles of 1371 Lm using metallic gallium alone as a raw material.
金属ガリウム単独（９９，９９９％）を１．０ Ｋｇ採
取し、融解容器内で９０℃Ｎ２ガス雰囲気中で融解させ
、スプレーガンによりＮ、ガス圧６ Ｋｇ／ ｃｍｚで
該融解金属を５℃に保持しかつＮ２雰囲気でシールした
冷却媒体水溶液槽（エチルアルコールとオレイン酸を媒
体）中へ噴射してガリウム金属微粒子とした。1.0 Kg of metallic gallium alone (99,999%) was collected and melted in a 90°C N2 gas atmosphere in a melting container, and the molten metal was heated to 5°C with N and a gas pressure of 6 Kg/cmz using a spray gun. The mixture was maintained and injected into a cooling medium aqueous solution bath (ethyl alcohol and oleic acid as medium) sealed in an N2 atmosphere to form gallium metal fine particles.
次に、該冷却用水溶液に更にエチルアルコールとオレイ
ン酸を添加し、金属微粒子の表面をコーティング１７な
がら脱水した後、篩目２５０ＩＬｍの篩で篩分けした。Next, ethyl alcohol and oleic acid were further added to the cooling aqueous solution, and the surface of the metal fine particles was dehydrated while being coated (17), and then sieved with a sieve having a mesh size of 250 ILm.
その分布は一２５０ｇｍ：８０％、＋２５０゜ｍ：２０
％であった。The distribution is -250gm: 80%, +250゜m: 20%
%Met.
一２５０ｐｍの金属粉を濃度０．５％のオレイン酸ソー
ダ（コーティング剤）を含むエチルアルコール溶媒中に
浸漬し、１５〜２０℃で２分間振動ミルによって微粉枠
し、エチルアルコール中で３７ｇｍの篩で篩分けした結
果、−３７ｇｍ：８５％、＋３７１Ｌｍ：１５％であり
、金属微粒子の表面酸化は全く認められなかった。-250 pm metal powder was immersed in an ethyl alcohol solvent containing 0.5% sodium oleate (coating agent), pulverized in a vibrating mill for 2 minutes at 15-20°C, and sieved through a 37 gm sieve in ethyl alcohol. As a result of sieving, -37 gm: 85%, +371 Lm: 15%, and no surface oxidation of the metal fine particles was observed.
＋３７ｇｍ部分は振動ミルに繰返し、−３７１Ｌｍの金
属ガリウム微粒子はアルコール中で保管した。The +37gm portion was repeated in a vibration mill, and the -371Lm metal gallium particles were stored in alcohol.
（ホ）発明の効果
本発明法によれば、従来法では製造できなかった金属ガ
リウム又はその合金の微粒子（例えば平均粒径５ＪＬｍ
又は−５Ｊｉ、ｍ）を単純な工程で低コストで多量生産
できるのである。(E) Effects of the Invention According to the method of the present invention, fine particles of metallic gallium or its alloy (for example, an average particle size of 5 JLm), which could not be produced by conventional methods, can be produced.
or -5Ji,m) can be mass-produced at low cost through a simple process.
第１図は本発明に係る含ガリウム金属微粒子の製造方法
の概略フローシートである。FIG. 1 is a schematic flow sheet of a method for producing gallium-containing metal fine particles according to the present invention.
Claims (2)
噴射ノズルから冷却用媒体水溶液中へ直接あるいは間接
的に噴射させることを特徴とする含ガリウム金属微粒子
の製造方法。(1) A method for producing gallium-containing metal fine particles, which comprises melting gallium-containing metal and directly or indirectly injecting the gallium-containing metal into an aqueous cooling medium solution from an injection nozzle in an inert gas atmosphere.
該金属ガリウムと周期率表の第II族、第III族又は第IV
族の元素群から選ばれる少なくとも１種以上の金属との
合金であり、好ましくはインジウム、亜鉛、錫、アルミ
ニウムから選ばれる少なくとも１種以上の金属との合金
である特許請求の範囲第１項記載の含ガリウム金属微粒
子の製造方法。(2) The gallium-containing metal is metal gallium alone or together with metal gallium belonging to Group II, III or IV of the periodic table.
Claim 1, which is an alloy with at least one metal selected from the group of elements of the above group, preferably with at least one metal selected from the group consisting of indium, zinc, tin, and aluminum. A method for producing gallium-containing metal fine particles.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1104996A JPH08924B2 (en) | 1989-04-25 | 1989-04-25 | Method for producing gallium-containing fine metal particles |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1104996A JPH08924B2 (en) | 1989-04-25 | 1989-04-25 | Method for producing gallium-containing fine metal particles |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02285006A true JPH02285006A (en) | 1990-11-22 |
| JPH08924B2 JPH08924B2 (en) | 1996-01-10 |
Family
ID=14395711
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1104996A Expired - Fee Related JPH08924B2 (en) | 1989-04-25 | 1989-04-25 | Method for producing gallium-containing fine metal particles |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH08924B2 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110947975A (en) * | 2019-12-20 | 2020-04-03 | 攀枝花钢城集团有限公司 | Method for utilizing waste aluminum foil |
| CN111266595A (en) * | 2020-03-27 | 2020-06-12 | 成都中建材光电材料有限公司 | Gallium particle preparation device and preparation method |
| CN111659897A (en) * | 2020-06-23 | 2020-09-15 | 楚雄川至电子材料有限公司 | Production process method of high-purity gallium particles |
| WO2024185601A1 (en) * | 2023-03-03 | 2024-09-12 | Ｄｏｗａエレクトロニクス株式会社 | Gallium powder, mixed powder, method for producing gallium powder dispersion, method for producing gallium powder, gallium powder dispersion, and conductive paste |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103157799B (en) * | 2011-12-15 | 2015-07-29 | 广东先导稀材股份有限公司 | The preparation method of gallium grain |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63290210A (en) * | 1987-05-20 | 1988-11-28 | Uchihashi Estec Co Ltd | Production of metal powder |
| JPS63290209A (en) * | 1987-05-20 | 1988-11-28 | Uchihashi Estec Co Ltd | Production of metal powder |
-
1989
- 1989-04-25 JP JP1104996A patent/JPH08924B2/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63290210A (en) * | 1987-05-20 | 1988-11-28 | Uchihashi Estec Co Ltd | Production of metal powder |
| JPS63290209A (en) * | 1987-05-20 | 1988-11-28 | Uchihashi Estec Co Ltd | Production of metal powder |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110947975A (en) * | 2019-12-20 | 2020-04-03 | 攀枝花钢城集团有限公司 | Method for utilizing waste aluminum foil |
| CN111266595A (en) * | 2020-03-27 | 2020-06-12 | 成都中建材光电材料有限公司 | Gallium particle preparation device and preparation method |
| CN111659897A (en) * | 2020-06-23 | 2020-09-15 | 楚雄川至电子材料有限公司 | Production process method of high-purity gallium particles |
| CN111659897B (en) * | 2020-06-23 | 2021-07-06 | 楚雄川至电子材料有限公司 | Production process method of high-purity gallium particles |
| WO2024185601A1 (en) * | 2023-03-03 | 2024-09-12 | Ｄｏｗａエレクトロニクス株式会社 | Gallium powder, mixed powder, method for producing gallium powder dispersion, method for producing gallium powder, gallium powder dispersion, and conductive paste |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH08924B2 (en) | 1996-01-10 |
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