JPH02271987A - Casting type composition for explosive - Google Patents
Casting type composition for explosiveInfo
- Publication number
- JPH02271987A JPH02271987A JP9189889A JP9189889A JPH02271987A JP H02271987 A JPH02271987 A JP H02271987A JP 9189889 A JP9189889 A JP 9189889A JP 9189889 A JP9189889 A JP 9189889A JP H02271987 A JPH02271987 A JP H02271987A
- Authority
- JP
- Japan
- Prior art keywords
- explosive
- surfactant
- composition
- compsn
- tables
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002360 explosive Substances 0.000 title claims abstract description 33
- 239000000203 mixture Substances 0.000 title claims description 27
- 238000005266 casting Methods 0.000 title abstract description 9
- 239000004094 surface-active agent Substances 0.000 claims abstract description 14
- UZGLIIJVICEWHF-UHFFFAOYSA-N octogen Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)CN([N+]([O-])=O)C1 UZGLIIJVICEWHF-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000011230 binding agent Substances 0.000 claims abstract description 11
- XTFIVUDBNACUBN-UHFFFAOYSA-N 1,3,5-trinitro-1,3,5-triazinane Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)C1 XTFIVUDBNACUBN-UHFFFAOYSA-N 0.000 claims abstract description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000012948 isocyanate Substances 0.000 claims abstract description 5
- 150000002513 isocyanates Chemical class 0.000 claims abstract description 5
- 239000004014 plasticizer Substances 0.000 claims abstract description 5
- 150000001450 anions Chemical class 0.000 claims abstract 2
- 150000001768 cations Chemical class 0.000 claims abstract 2
- 125000002091 cationic group Chemical group 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims 6
- 125000000129 anionic group Chemical group 0.000 claims 1
- 239000003093 cationic surfactant Substances 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 239000003945 anionic surfactant Substances 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 3
- LSLGCKBDVWXMSH-UHFFFAOYSA-N 1-[1-(2,2-dinitropropoxy)ethoxy]-2,2-dinitropropane;1-(2,2-dinitropropoxymethoxy)-2,2-dinitropropane Chemical compound [O-][N+](=O)C([N+]([O-])=O)(C)COCOCC(C)([N+]([O-])=O)[N+]([O-])=O.[O-][N+](=O)C(C)([N+]([O-])=O)COC(C)OCC(C)([N+]([O-])=O)[N+]([O-])=O LSLGCKBDVWXMSH-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 125000005442 diisocyanate group Chemical group 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- -1 polyoxyethylene Polymers 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000003760 tallow Substances 0.000 description 2
- PJANXHGTPQOBST-VAWYXSNFSA-N trans-stilbene Chemical group C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 2
- KAKVFSYQVNHFBS-UHFFFAOYSA-N (5-hydroxycyclopenten-1-yl)-phenylmethanone Chemical compound OC1CCC=C1C(=O)C1=CC=CC=C1 KAKVFSYQVNHFBS-UHFFFAOYSA-N 0.000 description 1
- MPNXSZJPSVBLHP-UHFFFAOYSA-N 2-chloro-n-phenylpyridine-3-carboxamide Chemical compound ClC1=NC=CC=C1C(=O)NC1=CC=CC=C1 MPNXSZJPSVBLHP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B25/00—Compositions containing a nitrated organic compound
- C06B25/34—Compositions containing a nitrated organic compound the compound being a nitrated acyclic, alicyclic or heterocyclic amine
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B45/00—Compositions or products which are defined by structure or arrangement of component of product
- C06B45/04—Compositions or products which are defined by structure or arrangement of component of product comprising solid particles dispersed in solid solution or matrix not used for explosives where the matrix consists essentially of nitrated carbohydrates or a low molecular organic explosive
- C06B45/06—Compositions or products which are defined by structure or arrangement of component of product comprising solid particles dispersed in solid solution or matrix not used for explosives where the matrix consists essentially of nitrated carbohydrates or a low molecular organic explosive the solid solution or matrix containing an organic component
- C06B45/10—Compositions or products which are defined by structure or arrangement of component of product comprising solid particles dispersed in solid solution or matrix not used for explosives where the matrix consists essentially of nitrated carbohydrates or a low molecular organic explosive the solid solution or matrix containing an organic component the organic component containing a resin
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dispersion Chemistry (AREA)
- Molecular Biology (AREA)
- Crystallography & Structural Chemistry (AREA)
- Mold Materials And Core Materials (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
Description
【発明の詳細な説明】
〈産業上の利用分野)
本発明は注型式爆薬用組成物に関する。詳しくはシクロ
テトラメチレンテトラニトラミン(HMX)、シクロト
リメチレントリニトラミン(RDX)の爆薬成分を従来
のものより多量に含有する注型式爆薬製造用組成物に関
する。DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to compositions for cast explosives. Specifically, the present invention relates to a composition for producing a cast explosive that contains a larger amount of explosive components such as cyclotetramethylenetetranitramine (HMX) and cyclotrimethylenetrinitramine (RDX) than conventional compositions.
〈従来の技術)
従来、注型式爆薬は高分子アルコール、イソシアネート
及び可塑剤を実質的主成分として含有するバインダにR
DX、HMX等の爆薬成分を混合し、得られたスラリー
状組成物を注型容器に減圧下で注型して製造されていた
。<Prior art> Conventionally, cast explosives are made by adding R to a binder containing polymeric alcohol, isocyanate, and plasticizer as substantial main components.
It was produced by mixing explosive components such as DX and HMX and casting the resulting slurry composition into a casting container under reduced pressure.
注型式爆薬のスラリー状組成物よりの製造性はスラリー
状組成物の粘度、流動性、ポットライフに影響される。The productivity of cast explosives from slurry compositions is influenced by the viscosity, fluidity, and pot life of the slurry composition.
即ち粘度、流動性の向上は混和温度、混合時間、爆薬成
分の粒度調整を行なうことにより、又ボットライフの調
整は硬化触媒により実施されてきた。That is, the viscosity and fluidity have been improved by adjusting the mixing temperature, mixing time, and particle size of the explosive components, and the bott life has been adjusted by using a curing catalyst.
〈発明が解決しようとする課題〉
近年注型式爆薬の高威力化が要求されている。このため
には組成物中の爆薬成分の割合を増加する必要がある。<Problem to be solved by the invention> In recent years, there has been a demand for higher power cast explosives. This requires increasing the proportion of explosive components in the composition.
然し従来の組成物においては爆薬成分を増加すると、ス
ラリー粘度が高くなり、流動性も消失する。従って従来
の方式では高威力のある注型式爆薬の製造が困難であり
爆薬成分の量が限定され、通常、注型可能な爆薬成分の
量は70重量%が限界であった。However, in conventional compositions, increasing the explosive component increases slurry viscosity and loses fluidity. Therefore, it is difficult to produce high-power cast explosives using conventional methods, and the amount of explosive components is limited, and usually the limit for the amount of explosive components that can be cast is 70% by weight.
本発明の目的は、爆薬成分を多量に含有した注型式爆薬
製造可能な組成物、即ち注型に必要な流動性を有し減圧
下で注型可能な爆薬用組成物を提供することにある。An object of the present invention is to provide a composition for producing a cast explosive that contains a large amount of explosive components, that is, an explosive composition that has the fluidity necessary for casting and can be cast under reduced pressure. .
〈課題を解決するための手段〉
前記目的を達するための本発明は、
HMXまたはRDXが70〜90重量%と、高分子アル
コール、イソシアネート及び可塑剤とを実質的主成分と
するバインダ成分が10〜30重量%とから成る組成物
と、該組成物に対して更に0,1〜2重量部の界面活性
剤を含有することを特徴とする注型式爆薬用組成物に間
する。<Means for Solving the Problems> The present invention for achieving the above object includes the following: a binder component containing 70 to 90% by weight of HMX or RDX, and 10 to 10% of a binder component substantially consisting of a polymeric alcohol, an isocyanate, and a plasticizer. 30% by weight, and a cast explosive composition characterized in that it further contains 0.1 to 2 parts by weight of a surfactant based on the composition.
本発明に係る爆薬用組成物の製造方法は、爆薬成分に対
し界面活性剤を0.1〜2重量部を直接添加するか、あ
るいは界面活性剤を上記重量%のHMX又はRDXにコ
ーティングした爆薬成分を用いて、所要成分と混合する
等、特に限定されない。The method for producing an explosive composition according to the present invention involves directly adding 0.1 to 2 parts by weight of a surfactant to the explosive component, or preparing an explosive by coating HMX or RDX with the above-mentioned weight percentage of a surfactant. There are no particular limitations, such as using the components and mixing them with required components.
本発明で用いる界面活性剤は、カチオン型アニオン型が
好ましい。The surfactant used in the present invention is preferably a cationic or anionic surfactant.
カチオン型の界面活性剤としては次のような構造を持つ
ものが好ましい。The cationic surfactant preferably has the following structure.
■ θ
[1] [RN (GHslslC!アニオン型
の界面活性剤としては次のような構造を持つものが好ま
しい。■ θ [1] [RN (GHslslC!) The anionic surfactant preferably has the following structure.
[1] ncoo14
[11] RCONC,t1.SO,Na
C11゜
[III ] n03OsNa界面活性剤
が0.1重量%未満では流動性が不充分で効果が出す、
2重量部を越えると爆薬の性能を低下させる傾向にある
。高分子アルコールは例^ばポリオキシエチレンクリコ
ール、イソシアネートはトルイレン2゜4ジイソシアネ
ート、可塑剤はビスジニトロプロピルアセタール
尚、界面活性剤を加えた場合も従来の注型方法で爆薬を
製造できる。[1] ncoo14 [11] RCONC, t1. SO,Na
C11゜[III] If the content of the n03OsNa surfactant is less than 0.1% by weight, the fluidity is insufficient and the effect is not achieved.
If it exceeds 2 parts by weight, it tends to reduce the performance of the explosive. For example, the polymeric alcohol is polyoxyethylene glycol, the isocyanate is toluylene 2.4 diisocyanate, and the plasticizer is bisdinitropropyl acetal.Also, even if a surfactant is added, the explosive can be manufactured by the conventional casting method.
〈発明の効果〉
本発明の注型式爆薬用組成物はRDX、H M Xの爆
薬成分を多量に含有しているにもか\ねらず充分な流動
性を有し、容易に注型により爆薬を製造できるので、実
用的な価値がある。<Effects of the Invention> Although the composition for cast explosives of the present invention contains a large amount of RDX and HMX explosive components, it has sufficient fluidity and can easily be cast into explosives by casting. can be manufactured, so it has practical value.
(実 施 例〉
次に本発明を実施例、比較例により詳細に説明する(例
中の部はNJt部を表わす)。(Example) Next, the present invention will be explained in detail with reference to Examples and Comparative Examples (the part in the example represents the NJt part).
入れ、組成物表面を平にして、加温し温度を60℃にす
る。その後、ポリビー力を10分間直角に傾け、その流
動速度を測定した。その結果を表1に表わす、11!イ
オン界面活性剤で最も流動速度に効果的であったのは硬
化牛脂トリメチルアンモニウムクロライドであった。The surface of the composition is flattened and heated to a temperature of 60°C. Thereafter, the polyvy force was tilted at right angles for 10 minutes and the flow rate was measured. The results are shown in Table 1, 11! Among the ionic surfactants, the most effective on flow rate was hardened tallow trimethylammonium chloride.
実施例 l
ニトロ可塑剤(ビスジニトロプロピルアセター)し/フ
ォルマール:
含有した活性剤バインダ20部(BDNPA/F:ボリ
オキシエチレングリコール#4000ニトリメチロール
プロパン=7.6:2.2:0.2 )に表1に示した
陽イオン界面活性剤1部でコーティングしたRDX75
部(RDXクラスA/E=7/3)を添加し、60℃、
1時間真空混合し、次いでトルイレン2.4ジイソシア
ネト(TDI)5部添加し、60℃、30分間真空混合
し、本発明の注型式爆薬用組成物を得た.該組成物10
0gを300II11のポリビー力に実施例 2
実施例1の活性バインダ16部は表1に示した陽イオン
界面活性剤1部をコーティングしたH M X 80部
(HMXクラスA/E=7/3)を加え混合し、
次いでTDIJ部を加λ、実施例1と同様な方法で本発
明の組成物を製造し、同様な方法で流動速度を測定した
.その結果を表1に示す.ここで、流動速度の傾向は実
施例1と同様であった。Example l Nitroplasticizer (bisdinitropropylacetate)/formal: Activator binder contained 20 parts (BDNPA/F: polyoxyethylene glycol #4000 nitrimethylolpropane = 7.6:2.2:0. 2) RDX75 coated with 1 part of the cationic surfactant shown in Table 1.
(RDX class A/E = 7/3) and heated at 60°C.
After vacuum mixing for 1 hour, 5 parts of toluylene 2.4 diisocyanate (TDI) was added and vacuum mixing was carried out at 60° C. for 30 minutes to obtain a cast explosive composition of the present invention. The composition 10
Example 2: 16 parts of the active binder of Example 1 was mixed with 80 parts of HMX (HMX class A/E=7/3) coated with 1 part of the cationic surfactant shown in Table 1. The composition of the present invention was prepared in the same manner as in Example 1, and the flow rate was measured in the same manner. The results are shown in Table 1. Here, the tendency of the flow rate was the same as in Example 1.
実施例 3
実施例1の活性バインダ20部に表2に示した陰イオン
界面活性剤1部をコーティングしたR D X 75s
を加え混合し,次いでTDI5部を加え、実施例1と同
様な方法で本発明の組成物を製造し、同様な方法で流動
速度を測定した.その結果を表2に示す.ここで、陰イ
オン界面活性剤で最も流動速度に効果的であったのはラ
ウリル酸カリウムと牛脂メチルタウリン酸ナトリウムで
あった。Example 3 RD
was added and mixed, and then 5 parts of TDI was added to produce a composition of the present invention in the same manner as in Example 1, and the flow rate was measured in the same manner. The results are shown in Table 2. Here, among the anionic surfactants, potassium laurate and sodium beef tallow methyltaurate were the most effective on flow rate.
た陽イオン界面活性剤1部及びRDX75部(RDXク
ラ;2.A/E=7/3)を加^混合し、次いでTDI
J部を加え実施VAIと同様な方法で本発明の組成物を
製造し、同様な方法で流動速度を測定した.その結果を
表1に示す。1 part of the cationic surfactant and 75 parts of RDX (RDX Clar; 2. A/E = 7/3) were added and mixed, and then TDI
A composition of the present invention was prepared in the same manner as in Example VAI by adding Part J, and the flow rate was measured in the same manner. The results are shown in Table 1.
ここで、流動速度は実施例1、実施ta11 2とは譬
同程度であった。Here, the flow rate was almost the same as in Example 1 and Example ta112.
実施例4
実施例1の活性バインダ16部に表2の陰イオン界面活
性剤1部をコーティングしたHMX80部を加太混合し
、次いでTDI4部を加え、実施例1と同様な方法で本
発明の組成物を製造し、同様な方法で流動速度を測定し
た.その結果を表2に示す.ここで、流動速度の傾向は
実施例3と同様であった。Example 4 16 parts of the active binder of Example 1 was mixed with 80 parts of HMX coated with 1 part of the anionic surfactant shown in Table 2, and then 4 parts of TDI was added, and the composition of the present invention was prepared in the same manner as in Example 1. A sample was manufactured and the flow rate was measured using the same method. The results are shown in Table 2. Here, the tendency of the flow rate was the same as in Example 3.
比較例
実施例1、2、3,4、5において界面活性剤を含有し
ない組成物において同様な方法で流動速度を測定した結
果、流動速度は零であった。Comparative Example The flow rate of the compositions containing no surfactant in Examples 1, 2, 3, 4, and 5 was measured using the same method, and as a result, the flow rate was zero.
実施例 5
実施例1の活性バインダ16部に表1に示しデ王−一」
−
碧玉−2Example 5 16 parts of the active binder of Example 1 was added to 16 parts of the active binder shown in Table 1.
- Jasper-2
Claims (4)
ロトリメチレントリニトラミンが70〜90重量%と高
分子アルコール、イソシアネート及び可塑剤とを実質的
主成分とするバインダ成分が10〜30重量%とから成
る組成物と、該組成物に対して更に0.1〜2重量%の
界面活性剤を含有することを特徴とする注型式爆薬用組
成物。(1) Consisting of 70 to 90% by weight of cyclotetramethylenetetranitramine or cyclotrimethylenetrinitramine and 10 to 30% by weight of a binder component whose substantial main components are a polymeric alcohol, an isocyanate, and a plasticizer. A composition for a cast explosive, characterized in that it further contains a surfactant in an amount of 0.1 to 2% by weight based on the composition.
とも一種である請求項第1項に記載の注型式爆薬用組成
物。(2) The composition for cast explosives according to claim 1, wherein the surfactant is at least one of a cation type and an anion type.
表等があります▼、 ▲数式、化学式、表等があります▼、▲数式、化学式、
表等があります▼ {ただしRはC_nH_2_n_+_1(n=12〜2
2)、x+y=2〜30}の少なくとも一種である請求
項第2項の注型式爆薬用組成物。(3) Surfactants are cationic, and there are ▲mathematical formulas, chemical formulas, tables, etc.▼, ▲mathematical formulas, chemical formulas,
There are tables, etc. ▼, ▲ There are mathematical formulas, chemical formulas, tables, etc. ▼, ▲ Mathematical formulas, chemical formulas,
There are tables etc. ▼ {However, R is C_nH_2_n_+_1 (n=12~2
2), x+y=2 to 30}.
式、化学式、表等があります▼、 ▲数式、化学式、表等があります▼、 {ただしRはC_nH_2_n_+_1(n=12〜2
2)、MはNaまたはK}の少なくとも一種である請求
項第2項の注型式爆薬用組成物。(4) Surfactants are anionic type, RCOOM, ▲There are mathematical formulas, chemical formulas, tables, etc.▼, ▲There are mathematical formulas, chemical formulas, tables, etc.▼, {However, R is C_nH_2_n_+_1 (n = 12 to 2
2) The composition for cast explosives according to claim 2, wherein M is at least one of Na or K}.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1091898A JP2799726B2 (en) | 1989-04-13 | 1989-04-13 | Composition for castable explosives |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1091898A JP2799726B2 (en) | 1989-04-13 | 1989-04-13 | Composition for castable explosives |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH02271987A true JPH02271987A (en) | 1990-11-06 |
JP2799726B2 JP2799726B2 (en) | 1998-09-21 |
Family
ID=14039387
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1091898A Expired - Lifetime JP2799726B2 (en) | 1989-04-13 | 1989-04-13 | Composition for castable explosives |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2799726B2 (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997042138A1 (en) * | 1996-05-03 | 1997-11-13 | Eastman Chemical Company | Explosive formulations |
WO1997042137A1 (en) * | 1996-05-06 | 1997-11-13 | Eastman Chemical Company | Explosive formulations |
WO1997042140A1 (en) * | 1996-05-03 | 1997-11-13 | Eastman Chemical Company | Explosive formulations |
WO1998016485A1 (en) * | 1996-10-15 | 1998-04-23 | Eastman Chemical Company | Explosive formulations |
WO2007123120A1 (en) * | 2006-04-19 | 2007-11-01 | Nipponkayaku Kabushikikaisha | Explosive composition, explosive composition molded body, and their production methods |
JP2012500774A (en) * | 2008-08-29 | 2012-01-12 | ビ−エイイ− システムズ パブリック リミテッド カンパニ− | Cast explosive composition |
JP2017518955A (en) * | 2014-05-02 | 2017-07-13 | レイセオン カンパニー | Binder for nitrogen-containing oxidants |
-
1989
- 1989-04-13 JP JP1091898A patent/JP2799726B2/en not_active Expired - Lifetime
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997042138A1 (en) * | 1996-05-03 | 1997-11-13 | Eastman Chemical Company | Explosive formulations |
WO1997042140A1 (en) * | 1996-05-03 | 1997-11-13 | Eastman Chemical Company | Explosive formulations |
WO1997042137A1 (en) * | 1996-05-06 | 1997-11-13 | Eastman Chemical Company | Explosive formulations |
WO1998016485A1 (en) * | 1996-10-15 | 1998-04-23 | Eastman Chemical Company | Explosive formulations |
WO2007123120A1 (en) * | 2006-04-19 | 2007-11-01 | Nipponkayaku Kabushikikaisha | Explosive composition, explosive composition molded body, and their production methods |
JPWO2007123120A1 (en) * | 2006-04-19 | 2009-09-03 | 日本化薬株式会社 | Explosive composition, explosive composition molded body, and production method thereof |
JP2012500774A (en) * | 2008-08-29 | 2012-01-12 | ビ−エイイ− システムズ パブリック リミテッド カンパニ− | Cast explosive composition |
JP2015145329A (en) * | 2008-08-29 | 2015-08-13 | ビ−エイイ− システムズ パブリック リミテッド カンパニ−BAE SYSTEMS plc | Casting explosive composition |
JP2017518955A (en) * | 2014-05-02 | 2017-07-13 | レイセオン カンパニー | Binder for nitrogen-containing oxidants |
US10227267B2 (en) | 2014-05-02 | 2019-03-12 | Raytheon Company | Bonding agents for nitrogen-containing oxidizers |
Also Published As
Publication number | Publication date |
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JP2799726B2 (en) | 1998-09-21 |
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