JP2015145329A - Casting explosive composition - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a casting explosive composition having reduced sensitiveness to factors such as friction, impact and heat by reducing the number of void and/or total volume in the casting explosive composition without reducing performance, and a method for reducing the number of void and/or total volume.SOLUTION: There is provided a casting explosive composition containing a polymer bound explosive and an antifoaming agent. There is provided a casting explosive composition containing a binder resin such as cellulose and polybutadiene, the polymer bound explosive such as RDX, FOX-7, nitroglycerine, DNAN trinitrotoluene and ammonium perchlorate, the antifoaming agent and metal powder such as Al, Mg and W. There is provided a method for reducing the number of void and/or total volume in the casting explosive composition including a process of mixing the polymer bound explosive and the antifoaming agent to cast the explosive composition.

Description

  The present invention relates to cast explosive compositions, their preparation and use. Specifically, the present invention relates to polymer-bonded explosive compositions.

  Explosive compositions are generally shaped into the shape required by the intended purpose. Molding may be by casting, pressure molding, extrusion or casting; casting and pressure molding are the most common molding techniques. However, it is generally desirable to cast an explosive composition because casting provides greater design flexibility than pressure molding.

  Polymer bonded explosives (also known as plastic bonded explosives and PBX) are typically explosive powders bonded to a polymer matrix. The presence of the matrix changes the physical and chemical properties of the explosive, often promoting the casting and curing of high melting point explosives. Otherwise, such explosives could only be cast using melt casting technology. Melt casting techniques typically involve a fusible binder and may require high process temperatures. The higher the melting point of this binder, the greater the potential danger. In addition, the matrix may be used to prepare polymer-bonded explosives that are less sensitive to friction, impact and heat, for example, an elastic matrix will provide these properties. The matrix also facilitates the manufacture of glazes that are not susceptible to damage with respect to their response to shock, impact, thermal and other dangerous stimuli. Alternatively, a hard polymer matrix will allow the resulting polymer-bonded explosive to be shaped, for example, by machining using a lathe, and allow for the production of explosive materials with complex structures if necessary.

  US 6,893,516 describes an explosive mixture in which a crystalline explosive is coated with polysiloxane to produce a granular product. Application of this coating to each crystal smooths the surface of the crystal by eliminating pores that would otherwise cause unwanted reactions of the explosive. As such, the polysiloxane coating reduces the sensitivity of the particulate explosive and improves safety during handling and any subsequent molding steps.

  Conventional casting techniques often result in a solidified composition that retains bubbles that are entrained during mixing of the material and by placement of the composition in the mold. Typically such placement in the mold will be by injection of the composition. The fewer explosives present per unit volume, the more these voids can degrade the performance of the composition. In addition, pores or voids, when present in sufficient amounts, can affect the impact sensitivity of the composition and can make the composition more unstable to shock or ignition by shock waves.

  The present invention seeks to provide a cast explosive composition with improved composition stability, either by reducing the number of voids and / or the total volume, or by other means such as volatile components present This may be due to a reduction in the number of the like. Such compositions will not only provide improved stability, but will also provide reduced sensitivity to factors such as friction, impact and heat. In other words, reduce the risk of accidental explosion of explosives.

  In one aspect of the invention, a cast explosive composition comprising a polymer-bound explosive and an antifoaming agent is provided.

  The presence of the antifoaming agent can substantially eliminate voids that will often remain in the composition. Accordingly, as used herein, the term “antifoam” is intended to mean an additive having surface active properties that act to eliminate voids from the interior of the polymeric binder of the cast explosive composition. Is done. Any additive that does not have this action is not considered to constitute an antifoam within the meaning of the present invention. In the art, such additives are also known as “antifoaming agents”, “degassing agents” and “defoaming agents”.

  The voids are typically found within the body of the binder component of the polymer-bound explosive, rather than at the interface with the binder and explosive component. The removal of these voids is particularly desirable when the intended use of the explosives results in exposure to high gravitational accelerations (which can be, for example, cannon shells, mortars or missiles). Under such conditions, it is conceivable that adiabatic compression of the voids is found to cause the area surrounding the voids to tend to ignite quickly. Another application where air gap removal is particularly important is when the intended use of the explosive can impact the target and at the same time cause a sudden slowdown, but require a target penetration before exploding the munitions. This may be the case with bombs and missiles. In the presence of voids, these adiabatic compressions will ignite upon impact before target penetration occurs.

In addition, the antifoaming agent lowers the viscosity of the composition and allows the casting process to be performed more quickly compared to the absence of this additive. Furthermore, it has been found that compositions containing antifoam agents have a higher density in some cases in terms of the% TMD obtained in the absence of this additive. This increase in density is also associated with improved stability and reduced sensitivity of the explosives. In many cases, void reduction can be associated with increased density; however, because the compositions of the present invention are complex, the increase in density can only be taken as an indication that the number of voids has decreased.
In many cases, other methods, such as radiography, are used to visualize the voids directly to determine the effectiveness of the antifoam.

In a further aspect of the invention, there is provided a method for reducing the number and / or total volume of voids in a cast explosive composition comprising the following steps:
Mixing polymer-bonded explosive and antifoam agent;
Cast the explosive composition.

  Another aspect of the present invention relates to the use of the cast explosive composition described herein in an explosive product, and a further aspect of the present invention relates to an explosive product comprising the cast explosive composition described herein. .

  The polymer-bonded explosive includes a polymer binder that forms explosive particles that are matrix-bonded therein. Thus, the binder can be selected from a wide range of polymers depending on the application for which the explosive will be used. However, in general, at least a part of the binder is polyurethane, cellulosic material such as cellulose acetate, polyester, polybutadiene, polyethylene, polyisobutylene, PVA, chlorinated rubber, epoxy resin, two-component polyurethane system, alkyd / melanin, vinyl resin, alkyd, It will be selected from self-crosslinking acrylates, thermoplastic elastomers such as butadiene-styrene block copolymers, and blends, copolymers and / or combinations thereof. Energetic polymers may be used alone or in combination, which include poly NIMMO (poly (3-nitratomethyl-3-methyloxetane), poly GLYN (polyglycidyl nitrate) and GAP (glycidyl azide polymer). It is preferred that the binder components be selected solely from the above list of binders, alone or in combination.In some embodiments, the binder comprises at least a portion of polyurethane, often the binder is 50-100 wt%. Polyurethane, optionally including 80-100 wt% polyurethane, In some embodiments, the binder will comprise polyurethane, MDI (methylene diphenyl diisocyanate) and TDI ( Polyurethanes derived from (endiisocyanate) and IPDI (isophorone diisocyanate) may be used, IPDI is generally preferred because it is liquid and thus easy to serve; Results in longer pot life and slower temperature changes during the reaction, and has relatively low toxicity compared to most other isocyanates.If the binder includes polyurethane, the polyurethane binder contains polybutadiene having hydroxy termination It is also preferable to do.

The explosive component of the polymer-bound explosive may, in some embodiments, include one or more heteroalicyclic nitroamine compounds. Nitroamine compounds are those having at least one N—NO ₂ group. Heteroalicyclic nitramine having a ring containing a N-NO ₂ group.
Such a ring may contain, for example, 2 to 10 carbon atoms and 2 to 10 ring nitrogen atoms. Examples of preferred heteroalicyclic nitroamines are RDX (cyclo-1,2,3-trimethylene-2,4,6-trinitroamine, hexogen), HMX (cyclo-1,3,5,7-tetramethylene- 2,4,6,8-tetranitroamine, octogen), and mixtures thereof. The explosive component may additionally or alternatively TATND (tetranitro-tetraaminodecalin), HNS (hexanitrostilbene), TATB (triaminotrinitrobenzene), NTO (3-nitro-1,2,4-triazol-5-one), HNIW (2,4,6,8,10,12-hexanitrohexaazai Seoul titanium), GUDN (guanyldyl urea dinitride), FOX-7 (1,1-diamino-2,2-dinitroethane), And a combination thereof.

  Other high energy materials may be used in place of or in addition to the compounds described above. Examples of other suitable known high energy substances are picrite (nitroguanidine), aromatic nitroamines such as tetril, ethylenedinitroamine, and nitrate esters such as nitroglycerin (glycerol trinitrate), butanetriol trinitrate or pentaerythritol tetra Nitrate, DNAN (dinitroanisole), trinitrotoluene (TNT), inorganic oxidants such as ammonium salts such as ammonium nitrate, ammonium dinitroamide (ADN) or ammonium perchlorate, and energetic alkali metal salts and alkaline earths Contains metal salts.

  The explosive component of the polymer-bound explosive may be mixed with a metal powder that can function as a fuel or can be included to obtain a unique end effect. The metal powder may be selected from a wide range of metals including aluminum, magnesium, tungsten, alloys of these metals and combinations thereof. Usually the fuel will be aluminum or an alloy thereof, and in many cases the fuel will be aluminum powder.

  In some embodiments, the polymer-bound explosive comprises RDX. The polymer-bound explosive may contain RDX only as an explosive component or in combination with a second explosive component such as HMX. Preferably, RDX constitutes 50-100 wt% of the explosive component.

  In many cases, the binder will be present in the range of about 5-20 wt%, often about 5-15 wt%, or about 8-12 wt% of the polymer bound explosive. The polymer-bonded explosive may include about 88 wt% RDX and about 12 wt% polyurethane binder. However, the relative levels of RDX and polyurethane binder will be in the range of about 75-95 wt% RDX and 5-25 wt% polyurethane binder. Polymer-bonded explosives of this composition are commercially available, for example Rowanex 1100 ™.

  Many antifoaming agents are known, and any antifoaming agent or combination thereof that generally does not chemically react with the explosive can be used. However, in many cases the antifoam will be polysiloxane. In many embodiments, the polysiloxane is selected from polyalkyl siloxanes, polyalkylaryl siloxanes, polyether siloxane copolymers, and combinations thereof. In many cases it is preferred that the polysiloxane is a polyalkylsiloxane; polydimethylsiloxane will typically be used. Alternatively, the antifoaming agent may be a silicone free surfactant polymer, or a combination of these with a polysiloxane. Such silicone-free polymers include alkoxylated alcohols, triisobutyl phosphate, and fumed silica. Commercially available products that can be used are BYK 088, BYK A500, BYK 066N and BYK A535, available from BYK Additives and Instruments, respectively, part of Altana; available from TEGO MR2132, Evonik; and BASF SD23 and SD40 , Both available from BASF. Of these, BYK A535 and TEGO MR2132 are often used. This is because these are solventless products having good void reduction characteristics.

  An antifoaming agent may be added to the composition in the solvent carrier. However, it is generally preferred that no solvent be present. It has been found advantageous to use an antifoaming agent that is not retained in the solvent, and more particularly to use a solvent-free system. This is because there are few (or substantially no) volatile components present during processing of the composition to mitigate required safety measures and / or plant changes. Furthermore, solvent elimination is the separation of residual volatiles from the composition during storage (eg, by evaporation or leakage), and composition properties such as void formation as a result of volatile evaporation cannot be predicted. Eliminate the risk of bringing about change.

  Antifoam is present in the range of about 0.01-2 wt%, sometimes about 0.03-1.5 wt%, often about 0.05-1 wt%, often about 0.25 or 0.5-1 wt% Often done. At levels below this (ie, less than 0.01 wt%), insufficient antifoam in the composition often significantly changes the properties of the polymer-bound explosive, while above this level (ie, about 2 wt.%), The viscosity of the casting solution is so low that the composition becomes inhomogeneous as a result of precipitation and separation processes occurring in the mixture.

  While not being bound by theory, the antifoaming agent not only serves to reduce the viscosity and promotes the elimination of voids from the casting process and the composition during casting, but the antifoaming agent is an interface at the void-composition interface. It is conceivable to release from the composition as a result of the greater buoyancy of the larger bubbles produced by coalescence of the void bubbles with activity. This results in a composition with almost no visible voids, which is more stable than known explosive compositions.

  The explosive composition may include a solvent, and any solvent in which at least one component dissolves and does not adversely affect the safety of the final product, as will be understood by those skilled in the art. However, for reasons described above, it is preferred that in some embodiments no solvent is present.

  If present, the solvent may be added as a carrier for the antifoam or other component of the composition. Although the solvent will typically be removed from the explosive composition during the casting process, it is uneconomical that solvent residues are due to imperfections in processing techniques or to remove residual solvent from the composition. It may remain if it becomes. As a result, in some embodiments, the polymer-bound explosive and the antifoam are mixed in the presence of a solvent. In many cases, the solvents are diisobutyl ketone, polypropylene glycol, isoparaffin, propylene glycol, cyclohexanone, butyl glycol, ethyl hexanol, white spirit, isoparaffin, xylene, methoxypropyl acetate, butyl acetate, naphthene, butyl glycolate, alkylbenzene and It will be selected from these combinations. In some cases, the solvent is selected from diisobutyl ketone, polypropylene glycol, isoparaffin, propylene glycol, isoparaffin, and combinations thereof.

  Although a melt casting process is compatible with the present invention, typically the compositions of the present invention may be cast using a “cast and cure” technique. Thus, if the components of the cast explosive composition do not inherently cure (eg, if all polymer components are thermoplastic polymers), a curing agent may optionally be present. In many embodiments, the casting technique used is vacuum casting. This is because the resulting product is generally of greater density than the corresponding air cast product and has no visible voids. Generally, the curing process will be performed after the casting process has been performed.

  The composition may contain small amounts of other additives commonly used in explosive compositions. Examples include microcrystalline waxes, energy plasticizers, non-energy plasticizers, antioxidants, catalysts, curing agents, metal fuels, coupling agents, surfactants, dyes and combinations thereof. The energy plasticizer is a combination of alkyl nitrobenzene (eg, dinitro- and trinitro-ethylbenzene), alkyl derivatives of linear nitroamine (eg, N-alkylnitratoethyl-nitroamine, eg, butyl-NENA), and glycidyl azide digomer. It may be selected from a melt mixture.

Casting explosive compositions provides greater flexibility in process design than can be obtained with pressure techniques. This is because casting of different shapes can be facilitated by a simple replacement of one casting mold with another. In other words, the casting process adapts backwards to past processing tools. On the contrary, if a change in product shape is required using pressurization techniques, typically a significant portion of the manufacturing equipment or munitions to be filled are redesigned for compatibility with the mold. There is a need for time and cost penalties.
Furthermore, the casting technique has little size limitation compared to the pressing technique, which depends on the transmission of pressure through the casting powder that causes compression. The pressure drops rapidly with distance, making uniform ammunition with a large length-to-diameter ratio (eg, many shell fills) more difficult to manufacture.

  In addition, the casting process of the present invention provides a cast product (the described casting explosive composition) with a relatively uniform filling regardless of the shape required for each casting. This may be due in part to the use of casting techniques and in part due to the presence of antifoam. Antifoaming agents substantially reduce the number of voids in the binder and thus in the cast explosive composition. In some cases, the voids are substantially removed. Casting can be done on-site and the housing to be filled (eg, munitions) can serve as a mold; or the composition can be cast and transferred into the housing in a separate process. In many cases, casting will be done on the spot.

  Furthermore, compositions comprising a polymer-bonded explosive and a hydroxy-terminated polybutadiene binder are particularly more elastic when cast compared to when pressurized. This makes them less prone to transition from deflagration to explosion when exposed to unexpected stimuli. On the contrary, such systems burn without exploding, making their use safer compared to pressurized systems.

  In addition, the shapes that can reliably apply the pressing process are even more limited. For example, it is often difficult to achieve full conical filling using pressure techniques. This is because air is often trapped at or at the apex of the cone. The casting process, which is essentially a “flow” process, is not thus limited.

  The method of the present invention may be a continuous process or a batch process as required. Many known casting processes will be compatible for use with the present invention. These method modifications that allow the addition of an antifoam to the polymer-bound explosive and allow the antifoam to perform its antifoam function during casting are within the ability of one skilled in the art. is there. If a continuous process is used, a static mixing technique can be used, which is the technique described in EP 1485669.

  The process may utilize a premix or precure as a starting material, but these are not essential. The premix will typically be a mixture of an explosive component and a binder component, usually a plasticizer. Sometimes the explosive component is a process known as wetting or phlegmatization that desensitizes with water before the premix is formed. However, since it is generally undesirable to retain water in the premix, it is typically removed from the premix prior to further processing, for example by heating in the mixture of explosive components and plasticizer. May be.

  In some cases, a plasticizer may not be present; however, the plasticizer is typically in the range of 0-10 wt% of the plasticizer and explosive premix, often in the range of 0.01-8 wt%, sometimes 0 It will be present at 5-7 wt% or 4-6 wt%. The plasticizer will often be a non-energy plasticizer and many are known in the art; however, an energy plasticizer may sometimes be used. Precure can typically be a combination of a premix and other components of the composition excluding the catalyst and curing agent. In some cases, the antifoaming agent may not be present in the precure.

  The cast explosive composition of the present invention has utility as the main explosive or explosive in explosive products. In many cases, the composition will be the main explosive. The composition of the present invention can be used in any “energy” application where the presence of voids causes safety or functional problems. Such uses include mortar bombs and cannon bombs described above. In addition, the composition of the present invention is used to prepare explosive fillings for projectiles including gunpowder explosives, bombs and warheads, composite projectiles, base bleed compositions, gun projectiles and gas generators Can be used.

  Except where noted or otherwise explicitly indicated, all numbers in this description that indicate material amounts or reaction conditions, material physical properties and / or amounts used are modified by the word “about”. I want you to understand. All amounts are by weight of the final composition unless otherwise stated. Further, the cast explosive composition can comprise, consist essentially of, or consist of any possible combination of the components described above and in the claims, unless explicitly indicated otherwise. . The method of reducing voids in the composition can comprise, consist essentially of, or consist of the steps described above and as specified in the claims.

  The following non-limiting examples illustrate the invention.

Example Example 1
A series of commercially available antifoams were cast and cured with Rowanex 1100 (88 wt% RDX and 12 wt% polyurethane reagent). Curing was performed at 65 ° C. for 5 days. The 105 mm and 155 mm shells prepared with the resulting composition were found to have no detectable voids, and no adverse effects on the chemical or mechanical properties of the polymer-bound explosives were observed. Table 1 below shows the effect of binder type and level on the viscosity and density of the composition.

  As will be appreciated, the presence of each antifoam at a level above 0.1 wt% reduces the viscosity of the composition and facilitates casting. Furthermore, as the antifoam level increases to 1.0 wt%, the viscosity of the composition further decreases.

  The presence of the antifoam also increases the density and provides an indication that the number of voids has decreased. The calculation of TMD provides an additional indication that the increase in TMD relative to that obtained in the absence of additive indicates that the number of voids in the sample has decreased compared to the composition without additive.

  The addition of dibutyl ketone alone (ie solvent only) reduces the density of the composition, whether prepared by vacuum casting or air casting techniques, so it is the defoamer that has the effect of increasing density. It is clear that there is.

  The above data show that vacuum casting generally produces higher relative density compositions than air casting technology when antifoam is present. Furthermore, vacuum casting techniques generally have a more pronounced effect on the density of compositions containing antifoaming agents compared to compositions with no additive or solvent alone.

  However, even when using air casting techniques, each antifoam is tested to provide a composition with a higher or higher TMD than the control composition with no additive or solvent alone. It is clear that the antifoaming agent acts to reduce the number of voids in the composition.

Example 2
The compatibility of Rowanex 1100 with the defoamer was tested and the results are described in Table 2 below.

  Suitability was measured according to STANAG 4147 Test 1: Method B, 40 hours at a temperature of 100 ° C. All of the tested antifoams met the requirements of this test, as shown by the results in the table above showing that each of the tested materials generates less than 1 ml / g of gas for a 5 g sample. Therefore, it was found to be compatible with the Rowanex 1100 PBX product. No adverse reaction was observed with any antifoam, but a particularly good compatibility was observed between Rowanex 1100 and BYK A535. Indeed, the use of BYK A535, a solvent-free antifoam, has been found to provide a particularly stable product with activity that meets the requirements for void removal.

Example 3
The sensitivity of the Rowanex 1100 and antifoam mixture was tested for sensitivity to mechanical impact (rotter impact) to determine the relative risks associated with using the mixture versus pure PBX products. The results are listed in Table 3.

The test determined a 50% drop height for the test sample. This examines the overall probability of firing for a stimulus-level relationship. Select seven test heights evenly spaced on a logarithmic scale and test the paper explosive (cap) to see if ignition occurs. Insensitive results (F
of I) compared to the reference RDX. All tests are performed on powdered material samples. Using the rotter impact test method, F of I using an LSM rotter machine was determined.

The F of I value for all of the Rowanex 1100 / antifoam samples was found to be greater than or equal to the F of I value for Rowanex 1100 alone. This means that the presence of an antifoam does not adversely affect the sensitivity of PBX to mechanical shock, and as a result, the mixed product is no more dangerous to use than Rowanex 1100 alone, Depending on the situation, there is little danger. Without being bound by theory, this may be due to a slight increase in binder due to the presence of antifoam and the resulting decrease in nitroamine content.
It is further shown that the Rowanex 1100 / antifoam sample is not expected to be more sensitive to ignition compared to the untreated Rowanex 1100.

Example 4
A series of compositions containing RDX are prepared, three of these compositions containing an antifoam agent.

  The composition was prepared using a casting and curing process as described in Example 1 and no voids were detected. No adverse effects on chemical and mechanical properties were observed when compared to RDX compositions that did not contain an antifoam agent.

Example 5
The following example shows how to prepare a PBX composition of the invention, such as the composition of Example 4, using a premix. The technique used will be well known to those skilled in the art.

  A vertical mixer having a water jacket and having a rotating stirring blade was used for the preparation of the composition. All mixing was performed under reduced pressure at a pressure of less than 10 mmHg. The composition of this example was prepared on a 5 Kg scale using the relative proportions of the ingredients described in Example 4 above.

  A premix was prepared from RDX which was insensitive with water. The water was then removed using techniques common in the art. Subsequently, the insensitive RDX (94 wt%) was mixed with a DOA plasticizer (6 wt%) to form a premix.

The mixer was preheated to 60 ± 2 ° C. and the following ingredients were weighed into the mixer in order, in relative amounts as described in Example 2 above:
1. HTPB
2. DOA
3. Lecithin 4. AO 2246
5. Premix (first quarter portion, ie 25 wt% of the total premix to be added).

  The composition was mixed for 15 minutes. Subsequently, the second, third and fourth quarter portions of the premix were added and mixed for 10 minutes between each addition and after the final addition. The mixing blade and bowl were rubbed to ensure that any unmixed material was transferred to the mixing area of the bowl and the composition was mixed for an additional 60 minutes.

  Subsequently, the antifoam was added and mixed until the maximum decrease in viscosity was observed during the addition of the antifoam to the composition. In this case, mixing is for 25 minutes, and when the viscosity drop is measured using a torque meter attached to the mixer, it is necessary to achieve a torque-stabilized mixing at a lower level than before addition of the antifoaming agent. Consider the maximum decrease in viscosity observed.

  DBTL was added and the composition was mixed for 15 minutes, after which IPDI was added and the composition was mixed for an additional 15 minutes. After mixing, the viscosity of the composition was recorded using a Brookfield viscometer (60 ° C.).

  The composition was cast to remove any excess mixture from the shell housing. The shell was placed on a vibration test bench and vibrated for 5 minutes. The ammunition was cured at 65 ± 2 ° C. for 5 days.

Example 6
The following example shows how to prepare a PBX composition of the invention, such as the composition of Example 4, from a precure. The techniques used will be well known to those skilled in the art.

  Mixing conditions were as in Example 5. Precure was prepared from the premix described in Example 5 above. To this premix was added all of the components of the composition of Example 5 except the antifoam, catalyst and curing agent.

The mixer was preheated to 60 ± 2 ° C., precure ingredients were added and heated for 15 minutes. The precure was then mixed for 30 minutes to rub the mixing blade and bowl to ensure that any unmixed material was transferred to the mixing area of the bowl. Antifoam was added and the composition was mixed until an effect on viscosity reduction of the antifoam was observed, which was measured as described in Example 5 and required 25 minutes of stirring in this example. DBTL was added and the composition was mixed for 15 minutes, followed by IPDI and the composition was mixed for an additional 15 minutes. The mixer blade and bowl were rubbed to ensure that any unmixed material was transferred to the mixing area of the bowl.
After mixing, the viscosity of the composition was recorded using a Brookfield viscometer (60 ° C.).

  The composition was cast to remove any excess mixture from the shell housing. The ammunition was cured at 65 ± 2 ° C. for 5 days.

  It should be understood that the compositions of the present invention can be incorporated in the form of various embodiments, only a few of which have been described and described above.

It should be understood that the compositions of the present invention can be incorporated in the form of various embodiments, only a few of which have been described and described above.
In the following, embodiments of the present invention are appended.
1. A cast explosive composition comprising a polymer-bound explosive and an antifoaming agent.
2. The polymer-bonded explosive includes polyurethane, cellulosic materials such as cellulose acetate, polyester, polybutadiene, polyethylene, polyisobutylene, PVA, chlorinated rubber, epoxy resin, two-component polyurethane, alkyd / melanin, vinyl resin, alkyd, self-crosslinking acrylate, The cast explosive composition of 1, comprising a butadiene-styrene block copolymer, poly NIMMO, poly GLYN, GAP, and a binder selected from blends, copolymers and / or combinations thereof.
3. The polymer-bonded explosives are RDX, HMX, FOX-7, TATND, HNS, TATB, NTO, HNIW, GUDN, picrite, aromatic nitroamines such as tetril, ethylenedinitroamine, nitroglycerin, butanetriol trinitrate, pentaerythritol tetrani 3. Casting according to 1 or 2, selected from trat, DNAN trinitrotoluene, inorganic oxidants such as ammonium nitrate, ADN, ammonium perchlorate, energetic alkali metal salts, energy alkaline earth metal salts, and combinations thereof Explosive composition.
4). 4. The cast explosive composition according to any one of 1 to 3, further comprising a metal powder selected from aluminum, magnesium, tungsten, alloys of these metals, and combinations thereof mixed with the polymer-bonded explosive.
5. The cast explosive composition of 3, wherein the polymer-bound explosive comprises RDX in the range of about 75-95 wt% and a polyurethane binder in the range of about 5-25 wt%.
6). 6. The cast explosive composition according to any one of 1 to 5, wherein the antifoaming agent is polysiloxane.
7). 7. The cast explosive composition according to 6, wherein the polysiloxane is selected from polyalkyl siloxanes, polyalkylaryl siloxanes, polyether siloxane copolymers, and combinations thereof.
8). A cast explosive composition in which the antifoaming agent is present in a range of 0.05 to 1 wt%.
9. A method of reducing the number and / or total volume of voids in a cast explosive composition comprising the following steps:
Mixing polymer-bonded explosive and antifoam agent;
Cast the explosive composition.
10. 10. The method according to 9, wherein the casting explosive composition is cured.
11. The method according to 9 or 10, wherein the polymer-bonded explosive and the antifoaming agent are mixed in the presence of a solvent.
12 The method according to any one of 9 to 11, wherein the casting includes vacuum casting.
13. Use of the cast explosive composition according to any one of 1 to 8 in an explosive product.
14 An explosive product comprising the cast explosive composition according to any one of 1 to 8.
15. Use of an antifoam to reduce the number and / or total volume of voids in a cast explosive composition.
16. A cast explosive composition substantially as herein described with reference to the examples.

Claims (16)

  A cast explosive composition comprising a polymer-bound explosive and an antifoaming agent.   The polymer-bonded explosive includes polyurethane, cellulosic materials such as cellulose acetate, polyester, polybutadiene, polyethylene, polyisobutylene, PVA, chlorinated rubber, epoxy resin, two-component polyurethane, alkyd / melanin, vinyl resin, alkyd, self-crosslinking acrylate, The cast explosive composition of claim 1 comprising a binder selected from butadiene-styrene block copolymers, poly NIMMO, poly GLYN, GAP, and blends, copolymers and / or combinations thereof.   The polymer-bonded explosives are RDX, HMX, FOX-7, TATND, HNS, TATB, NTO, HNIW, GUDN, picrite, aromatic nitroamines such as tetril, ethylenedinitroamine, nitroglycerin, butanetriol trinitrate, pentaerythritol tetrani 3. The trait, DNAN trinitrotoluene, inorganic oxidant such as ammonium nitrate, ADN, ammonium perchlorate, energetic alkali metal salt, energetic alkaline earth metal salt, and combinations thereof according to claim 1 or 2. Casting explosive composition.   The cast explosive composition according to any one of claims 1 to 3, further comprising a metal powder selected from aluminum, magnesium, tungsten, alloys of these metals, and combinations thereof mixed with the polymer-bonded explosive.   The cast explosive composition of claim 3, wherein the polymer-bonded explosive comprises RDX in the range of about 75-95 wt% and a polyurethane binder in the range of about 5-25 wt%.   The casting explosive composition according to any one of claims 1 to 5, wherein the antifoaming agent is polysiloxane.   7. The cast explosive composition according to claim 6, wherein the polysiloxane is selected from polyalkyl siloxanes, polyalkylaryl siloxanes, polyether siloxane copolymers and combinations thereof.   A cast explosive composition in which the antifoaming agent is present in a range of 0.05 to 1 wt%. A method of reducing the number and / or total volume of voids in a cast explosive composition comprising the following steps:
Mixing polymer-bonded explosive and antifoam agent;
Cast the explosive composition.   The method of claim 9, wherein the casting explosive composition is cured.   The method according to claim 9 or 10, wherein the polymer-bound explosive and the antifoaming agent are mixed in the presence of a solvent.   The method according to claim 9, wherein the casting includes vacuum casting.   Use of the cast explosive composition according to any one of claims 1 to 8 in an explosive product.   An explosive product comprising the cast explosive composition according to any one of claims 1 to 8.   Use of an antifoam to reduce the number and / or total volume of voids in a cast explosive composition.   A cast explosive composition substantially as herein described with reference to the examples.