JPH02254144A - Manufacture of coated cutting tool having excellent wear resistance and chipping resistance - Google Patents

Manufacture of coated cutting tool having excellent wear resistance and chipping resistance

Info

Publication number
JPH02254144A
JPH02254144A JP7200389A JP7200389A JPH02254144A JP H02254144 A JPH02254144 A JP H02254144A JP 7200389 A JP7200389 A JP 7200389A JP 7200389 A JP7200389 A JP 7200389A JP H02254144 A JPH02254144 A JP H02254144A
Authority
JP
Japan
Prior art keywords
coated
cutting tool
tool
resistance
nitride
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP7200389A
Other languages
Japanese (ja)
Inventor
Akira Katayama
片山 昌
Tatsuya Imai
達也 今井
Tetsuo Sawajima
哲郎 澤島
Hiroto Imamura
博人 今村
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toho Kinzoku Co Ltd
Nippon Steel Corp
Nittetsu Choko KK
Original Assignee
Toho Kinzoku Co Ltd
Nippon Steel Corp
Nittetsu Choko KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toho Kinzoku Co Ltd, Nippon Steel Corp, Nittetsu Choko KK filed Critical Toho Kinzoku Co Ltd
Priority to JP7200389A priority Critical patent/JPH02254144A/en
Publication of JPH02254144A publication Critical patent/JPH02254144A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To obtain the cutting tool having excellent wear resistance and chipping resistance by coating the surface of a sintered hard alloy or a high-speed steel with a hard compound layer of specified metal and thereafter subjecting it to shot peening treatment. CONSTITUTION:The surface of a cutting tool by a sintered hard alloy contg. hard carbide, nitride and carbon nitride of IVa, Va and VIa metal in a periodic table such as W, Ti, Ta, Hf, Nb and Zr and contg. Ni, Co, etc., as a bonding material at the time of sintering or of a cutting tool by a high-speed steel is coated with a single phase of hard substance such as the carbide, nitride, carbon nitride, oxide, oxygen carbide, oxygen nitride and oxygen carbon nitride of the above W or other metal and alumina, etc., or a double layer constituted of two or more kinds among the above by a PVD method, a CVD method or the like. The surface of the superhard coated layer is subjected to shot peening treatment by iron powder, cast steel powder, WC powder, ceramic powder of 10 to 2000mum grain size at >=30 degrees angle of projection and at 20 to 120m/sec projecting speed.

Description

【発明の詳細な説明】 [産業上の利用分野] 本発明は耐摩耗特性と耐欠損特性を要求される切削用工
具の製造法に関わるものである。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a method of manufacturing a cutting tool that requires wear resistance and chipping resistance.

[従来技術及び発明か解決しようとする課題〕従来の被
覆超硬合金切削工具は、−例をあげると、元素周期律表
の4a、5a及び6a族金属の炭化物、窒化物及び炭窒
化物のうちの工種または2種以上と、Co、Niのうち
1種または2種を含有する超硬合金基材の表面に、前記
4a、5aおよび6a属金属の炭化物、窒化物、炭窒化
物、酸化物、酸炭化物、酸窒化物及び酸炭窒化物、並び
にアルミニウム酸化物のうちの1種からなる単層または
2種以上からなる複層の硬質層をPVDまたはCVD被
覆することによって製造されている。ところが、これら
の従来の製造工程において製造した被覆超硬合金切削工
具は連続切削の場合は、優れた耐摩耗性を発揮するがフ
ライス加工、溝付き材料の旋削加工等の断続的荷重の負
荷する切削の場合には、耐摩耗性、耐欠損性共にかなら
ずしも満足すべき性能であるとは言えない。
[Prior Art and Problems to be Solved by the Invention] Conventional coated cemented carbide cutting tools are made of carbides, nitrides and carbonitrides of metals of groups 4a, 5a and 6a of the Periodic Table of the Elements, for example. The carbides, nitrides, carbonitrides, and oxides of the metals of groups 4a, 5a, and 6a are added to the surface of the cemented carbide base material containing one or more of the above metals and one or two of Co and Ni. Manufactured by PVD or CVD coating of a single layer or multiple hard layers consisting of two or more of the following: aluminum oxide, oxycarbide, oxynitride, oxycarbonitride, and aluminum oxide. . However, coated cemented carbide cutting tools manufactured using these conventional manufacturing processes exhibit excellent wear resistance when used for continuous cutting, but when subjected to intermittent loads such as milling or turning of grooved materials. In the case of cutting, it cannot be said that both wear resistance and chipping resistance are necessarily satisfactory.

また、高速度鋼工具は高速度鋼の表面に、前記4a、5
aおよび6a属金属の炭化物、窒化物、炭窒化物、酸化
物、酸炭化物、酸窒化物及び酸炭窒化物のうちの1種か
らなるm層または2種以上からなる複層の硬質層をPV
D被覆することによって製造されている。この方法で製
造した被覆高速度鋼切削工具は優わだ耐摩耗性を発揮す
るが、面記被覆超硬合金切削工具はとは普及していない
。それはコストとの関係でさらに高い耐摩耗性が要求さ
れる場合が多いためである。その対策として切削方法、
切削条件に合わせて被覆の方法、基材のM!類を使い分
ける消極的力q人が採用されており、製造法の改良によ
り積極的に工具の性能を改良する知見は未だ提案されて
ぃない。
In addition, the high speed steel tool has the above-mentioned 4a and 5 on the surface of the high speed steel.
m layer consisting of one type of carbide, nitride, carbonitride, oxide, oxycarbide, oxynitride, and oxycarbonitride of group A and 6A metals, or a multilayer hard layer consisting of two or more types. PV
Manufactured by D coating. Coated high-speed steel cutting tools produced by this method exhibit excellent wear resistance, but surface-coated cemented carbide cutting tools are not as popular. This is because even higher wear resistance is often required due to cost considerations. As a countermeasure, cutting methods,
Coating method and base material M! according to cutting conditions! q people are employed with the passive ability to use different types of tools, and no knowledge has yet been proposed to proactively improve the performance of tools by improving manufacturing methods.

そこて、本発明者等は耐摩耗特性、耐欠損性の層優わだ
被覆工具を製造すべく研究を行った結果、被覆工具の表
面にショットピーニングを施すことにより、被覆工具の
耐摩耗特性、耐欠損性が著しく向上することを見出した
Therefore, the inventors of the present invention conducted research to manufacture a layered coated tool with excellent wear resistance and chipping resistance, and found that by applying shot peening to the surface of the coated tool, the wear resistance of the coated tool was improved. It was found that the fracture resistance was significantly improved.

[課題を解決するための手段] −1−記の知見に基ずく本発明は次の構成を要旨とする
ものである。
[Means for Solving the Problems] The present invention, based on the knowledge described in -1-, has the following configuration.

1、元素周期律表の48.5a及びIia属金属の炭化
物、窒化物及び炭窒化物のうちの1種または2種以上と
、Co、 Njのうち1種または2種を含有する超硬合
金基材の表面に01記4a、5a及び6a族金属の炭化
物、窒化物、炭窒化物、酸化物、酸炭化物、酸窒化物及
び酸炭窒化物、並びにアルミニウム酸化物のうちの1種
からなる単層または2種以上からなる複層の硬質層を被
覆したものからなる被覆超硬合金切削工具を製造するに
際して、被覆後、被覆切削工具の表面をショットピーニ
ングすることを特徴とする耐摩耗特性、耐欠損性に優れ
た被覆超硬合金切削工具の製造方法。
1. Cemented carbide containing one or more of the carbides, nitrides, and carbonitrides of 48.5a and Iia metals in the Periodic Table of the Elements, and one or two of Co and Nj. The surface of the base material is made of one of carbides, nitrides, carbonitrides, oxides, oxycarbides, oxynitrides, and oxycarbonitrides of Group 01 metals 4a, 5a, and 6a, and aluminum oxide. Wear resistance characteristics characterized by shot peening the surface of the coated cutting tool after coating when manufacturing a coated cemented carbide cutting tool made of a single layer or a multi-layer hard layer coated with two or more types. , a method for manufacturing coated cemented carbide cutting tools with excellent fracture resistance.

2、高速度鋼の表面に前記4a、5aおよび6a属金属
の炭化物、窒化物、炭窒化物、酸化物、酸炭化物、酸窒
化物及び酸炭窒化物、並びにアルミニウム酸化物のうち
の工種からなる重層または2種以北からなる複層の硬質
層を被覆したものからなる被覆高速度鋼切削工具を製造
するに際して、被覆後、被覆切削工具の表面をショット
ピーニングすることを特徴とする耐摩耗特性、耐欠損性
に優れた被N高速度鋼切削工具の製造方法。
2. The surface of high-speed steel is coated with carbides, nitrides, carbonitrides, oxides, oxycarbides, oxynitrides, and oxycarbonitrides of metals from groups 4a, 5a, and 6a, as well as aluminum oxides. In manufacturing a coated high-speed steel cutting tool which is coated with a multi-layer hard layer or a multi-layer hard layer consisting of two or more types, the surface of the coated cutting tool is shot peened after coating. A method for manufacturing N-subject high-speed steel cutting tools with excellent properties and fracture resistance.

3、ショットの粒径lOμm〜2000μm、投射速度
20〜120m/sec、投射角度30度以−Lである
ことを特徴とする」−記第1項または第2項記載の耐摩
耗特性、耐欠損性に優れた被覆切削工具の製造方法。
3. Abrasion resistance and chipping resistance as described in item 1 or 2 of ``-L, characterized in that the particle size of the shot is 10 μm to 2000 μm, the projection speed is 20 to 120 m/sec, and the projection angle is 30 degrees or more.'' A method for manufacturing coated cutting tools with excellent properties.

しかして、この発明の対象とする代表的超硬合金は、W
、T4.Ta、)If、 Nb、ZrfjJ化物、窒化
物及び炭窒化物のうちの1種または2種以上と、Co、
Niのうち1種または2種を含有し、代表的被膜はTi
、 Hf炭化物、窒化物、炭窒化物、酸化物、酸炭化物
、酸窒化物及び酸炭窒化物、並びにアルミニウム酸化物
のうちの1種からなる単層または2種以上からなる複層
のPVDまたはCVD硬貿層からなる。また高速度鋼の
代表的組成は合金元素としてOr、Mo、 W、 V、
 Goを含有し、代表的被膜はTi、11f炭化物、窒
化物、炭窒化物、酸化物、酸炭化物、酸窒化物及び酸炭
窒化物、並びにアルミニウム酸化物のうちの工種からな
る単層または2種以」−からなる複層のPVD硬質層か
らなる。本発明においては硬質層を被覆した後、この被
覆部分にショクI・ピーニングを施す。これにより耐摩
耗特性、耐欠損性か向上するのは、被覆表層゛の残留用
−)張り応力が圧縮応力になること、被膜表面の残留応
力が圧縮の場合にはさらに圧縮応力が大きくなることか
原因と考えられる。
Therefore, the typical cemented carbide targeted by this invention is W
, T4. Ta, ) If, Nb, Zrfj one or more of J oxides, nitrides and carbonitrides, and Co,
Contains one or two types of Ni, and a typical coating is Ti.
, Hf carbide, nitride, carbonitride, oxide, oxycarbide, oxynitride, oxycarbonitride, and aluminum oxide. It consists of the CVD hard trade layer. In addition, typical compositions of high-speed steel include Or, Mo, W, V, as alloying elements.
Contains Go, and typical coatings are single or double layers of Ti, 11f carbides, nitrides, carbonitrides, oxides, oxycarbides, oxynitrides and oxycarbonitrides, and aluminum oxides. Consists of multiple PVD hard layers. In the present invention, after coating the hard layer, this coated portion is subjected to shock I/peening. This improves wear resistance and chipping resistance because the residual tension stress on the coating surface becomes compressive stress, and when the residual stress on the coating surface is compressive, the compressive stress becomes even larger. This may be the cause.

ト1紀被Tl−LJLにショットピーニングする条件は
シシ(ツトの材質 鋳鉄、鋳鋼、WC、セラミックス ショットの粒径・10μm〜2000μm投射速度: 
20〜120m/sec 投射角度:30度以上 が好ましい。
The conditions for shot peening on Tl-LJL are as follows: Material of shot: Cast iron, cast steel, WC, Ceramic Shot particle size: 10 μm to 2000 μm Projection speed:
20 to 120 m/sec Projection angle: preferably 30 degrees or more.

ショットの材質はコーティング層の材神、厚さによって
適宜、鋳鉄、鋳鋼、WC、セラミックスのいずわかを選
定ずわばよいか、同等の硬度等の特性を有するものであ
わばこれに限定するものてはない。ショットの粒径の]
限値は必要な運動エネルギーを得るために10μm以」
−1王其のコーナ一部゛v=径は0.8+r+n+以下
と小さいために均一にショットを当てるためにはショッ
トの径を2000um以下とすることか必要である。投
射速度の下限値は必要な連動エネルギーを得るために2
0m/sec以上、またT具被膜を破損させないために
120m/min以丁が好ましい。投射角度は材料に重
直な場合を90度として30度を下回ると所定の圧縮応
力が得られないため30度以上か必要である。
The material of the shot can be selected from cast iron, cast steel, WC, or ceramics depending on the quality and thickness of the coating layer, or it can be limited to those with similar properties such as hardness. Not sure. shot particle size]
The limit value is 10 μm or more in order to obtain the necessary kinetic energy.
Since the diameter of a part of the corner of the -1 core is as small as 0.8+r+n+, it is necessary to set the diameter of the shot to 2000 um or less in order to apply the shot uniformly. The lower limit of the projection speed is 2 to obtain the necessary interlocking energy.
The speed is preferably 0 m/sec or more, and preferably 120 m/min to prevent damage to the T-piece coating. The projection angle is 90 degrees when the projection angle is perpendicular to the material, and if it is less than 30 degrees, the predetermined compressive stress cannot be obtained, so it is necessary to set the projection angle to 30 degrees or more.

[実施例] 次に、この発明の方法を実施例により具体的に説明する
[Example] Next, the method of the present invention will be specifically explained with reference to Examples.

実施例 工 炭化タングステン(WC) ・90wt% 、炭化チタ
ン(Tie) : 2 wL’4 、炭化タンタル (
TaC) : 2 wt主、Co:6ivl:!tから
なる組成で、−辺12.7mmの正方形超硬合金を焼結
し、これにTiC/TlCN/A120iをこの順序に
(: V D被覆したスローアウェイ工具を製造した。
Examples Engineered tungsten carbide (WC) 90 wt%, titanium carbide (Tie): 2 wL'4, tantalum carbide (
TaC): 2 wt Lord, Co:6ivl:! An indexable tool was manufactured by sintering a square cemented carbide with a composition of T and having a side of 12.7 mm, and coating it with TiC/TlCN/A120i in this order (: V D).

この工具に平均粒径100 umの鋳鉄球を投射速度8
0m/sec 、投射角度70〜90度の条件で工具の
各面をショットシた。
Cast iron balls with an average grain size of 100 um are thrown into this tool at a speed of 8.
Each side of the tool was shot under the conditions of 0 m/sec and a projection angle of 70 to 90 degrees.

一方、比較工具としてショット以外はI−記実施例と同
一条件の工具を製造した。この結果得られた本発明被覆
工具と比較工具について切削試験を行った。その条件は
以下の通りである。
On the other hand, as a comparison tool, a tool was manufactured under the same conditions as Example I except for the shot. A cutting test was conducted on the coated tool of the present invention and a comparative tool obtained as a result. The conditions are as follows.

被剛材: JIS 545G、 直径60mmの丸棒に
圧延方向と平行に幅10vumの溝を等間隔に5木つけ
た。
Rigid material: JIS 545G, 5 grooves with a width of 10 vum were equally spaced on a round bar with a diameter of 60 mm parallel to the rolling direction.

切削速度: 150m/min 送り  0.35mm/rev 1刀込メメ   2 、 Omm 溝との衝突回数で工具寿命を比較すると、比較材は2.
:1XIO2回で工具か欠損して寿命となった。本発明
王具は1.5XlO’で工具が欠損して対向となった。
Cutting speed: 150 m/min Feed: 0.35 mm/rev 1 cutting depth: 2, Omm Comparing the tool life based on the number of collisions with the groove, the comparison material was 2.
:The tool broke after 1XIO 2 times and its life was reached. The tool of the present invention was damaged at 1.5XlO' and the tool was facing the other way.

ショク]・の効果は極めて顕著であった。The effect of Shoku] was extremely significant.

実施例 2 C: 1.3L Si : 0.25%、 Mn:0.
32%、Cr : 4.]LMo : 3.5L W 
: 10!t、V : 3.5机Co: 10%の高速
度鋼工具にTiNをpvoJ&覆したスローアウェイ工
具を製造した。この工具に平均粒径150μmの鋳鋼法
を投射速度401n/sec 、投射角度70〜90度
の条件で]−具の各面をショットした。工具の形状は幅
5+om 、ずくい角10°、前逃げ角5°の突切りタ
イプである。一方、比較工具としてショット以外は手記
実施例と同一条件の工具を製造した。この結果得らねた
本発明被覆工具と比較工具について切削試験を行った。
Example 2 C: 1.3L Si: 0.25%, Mn: 0.
32%, Cr: 4. ]LMo: 3.5L W
: 10! t, V: 3.5 machines Co: An indexable tool was manufactured by pvoJ & overturning TiN on a high speed steel tool of 10%. Each side of the tool was shot with a cast steel method having an average grain size of 150 μm at a shooting speed of 401 n/sec and a shooting angle of 70 to 90 degrees. The shape of the tool is a parting type with a width of 5+ om, a rake angle of 10°, and a front relief angle of 5°. On the other hand, as a comparison tool, a tool was manufactured under the same conditions as the manual example except for the shot. A cutting test was conducted on the coated tool of the present invention and a comparative tool that did not yield the results.

その条件は以下の通りである。The conditions are as follows.

被削材:八I S I 121.、 ] 4  直径8
0mm、長さ50mm切削機械=NO旋盤 切削速度 80n+/min 送り0 、05mm/rev 切削サイクル 2.0sec切削−B、0sec非切削
前逃げ面の摩耗幅が300μmになった時の切削サイク
ル数の大小により工具の耐摩耗性の良否を判定した。比
較工具はサイクル8×103回て而逃げ面の摩耗幅が3
00 Himになったか、本発明工具は5×104回で
はじめて摩耗幅が300μmに達した。ショットピ一二
〉りの効果は極めて顕著である。
Work material: 8I S I 121. , ] 4 Diameter 8
0mm, length 50mm cutting machine = NO lathe Cutting speed 80n+/min Feed 0, 05mm/rev Cutting cycle 2.0sec Cutting-B, 0sec Number of cutting cycles when the wear width of the front flank surface becomes 300 μm The wear resistance of the tool was judged based on the size. The comparison tool was cycled 8 x 103 times and the flank wear width was 3.
The wear width of the tool of the present invention reached 300 μm after 5×10 4 cycles. The effects of shot piping are extremely significant.

[発明の効果] 本発明はPVDまたはCVD被覆後、被膜にショットピ
ーニングする工程を付加することにより、切削工具の耐
摩耗性、耐欠損性を著しく同士させることができ、産業
上の効果は極めて顕著なものかある。
[Effects of the Invention] By adding a shot peening process to the coating after PVD or CVD coating, the present invention can significantly improve the wear resistance and chipping resistance of cutting tools, and the industrial effect is extremely high. Is there something remarkable?

Claims (1)

【特許請求の範囲】 1、元素周期律表の4a、5a及び6a属金属の炭化物
、窒化物及び炭窒化物のうちの1種または2種以上と、
Co、Niのうち1種または2種を含有する超硬合金基
材の表面に前記4a、5a及び6a族金属の炭化物、窒
化物、炭窒化物、酸化物、酸炭化物、酸窒化物及び酸炭
窒化物、並びにアルミニウム酸化物のうちの1種からな
る単層または2種以上からなる複層の硬質層を被覆した
ものからなる被覆超硬合金切削工具を製造するに際して
、被覆後、被覆切削工具の表面をショットピーニングす
ることを特徴とする耐摩耗特性、耐欠損性に優れた被覆
超硬合金切削工具の製造方法。 2、高速度鋼の表面に前記4a、5aおよび6a属金属
の炭化物、窒化物、炭窒化物、酸化物、酸炭化物、酸窒
化物及び酸炭窒化物、並びにアルミニウム酸化物のうち
の1種からなる単層または2種以上からなる複層の硬質
層を被覆したものからなる被覆高速度鋼切削工具を製造
するに際して、被覆後、被覆切削工具の表面をショット
ピーニングすることを特徴とする耐摩耗特性、耐欠損性
に優れた被覆高速度鋼切削工具の製造方法。 3、ショットの粒径10μm〜2000μm、投射速度
20〜120m/sec、投射角度30度以上であるこ
とを特徴とする特許請求の範囲第1項または第2項記載
の耐摩耗特性、耐欠損性に優れた被覆切削工具の製造方
法。
[Scope of Claims] 1. One or more carbides, nitrides, and carbonitrides of metals from groups 4a, 5a, and 6a of the Periodic Table of the Elements;
The carbides, nitrides, carbonitrides, oxides, oxycarbides, oxynitrides and oxidants of the group 4a, 5a and 6a metals are coated on the surface of a cemented carbide base material containing one or two of Co and Ni. When manufacturing a coated cemented carbide cutting tool coated with a single layer or a multi-layer hard layer made of one or more of carbonitride and aluminum oxide, after coating, coating cutting is performed. A method for manufacturing a coated cemented carbide cutting tool with excellent wear resistance and chipping resistance, which comprises shot peening the surface of the tool. 2. One of the carbides, nitrides, carbonitrides, oxides, oxycarbides, oxynitrides, and oxycarbonitrides of metals from groups 4a, 5a, and 6a, and aluminum oxide on the surface of high-speed steel. When producing a coated high-speed steel cutting tool made of a single layer or a multi-layer hard layer made of two or more types, the surface of the coated cutting tool is subjected to shot peening after coating. A method for manufacturing coated high-speed steel cutting tools with excellent wear characteristics and fracture resistance. 3. Abrasion resistance and chipping resistance according to claim 1 or 2, characterized in that the shot particle size is 10 μm to 2000 μm, the projection speed is 20 to 120 m/sec, and the projection angle is 30 degrees or more. A method for manufacturing coated cutting tools with excellent performance.
JP7200389A 1989-03-27 1989-03-27 Manufacture of coated cutting tool having excellent wear resistance and chipping resistance Pending JPH02254144A (en)

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Cited By (27)

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JPH0539817U (en) * 1991-10-29 1993-05-28 日立ツール株式会社 Throw away end mill
JPH05320913A (en) * 1992-05-25 1993-12-07 Mitsubishi Materials Corp Surface coating cutting tool
JPH06108258A (en) * 1992-09-29 1994-04-19 Toshiba Tungaloy Co Ltd High strength coated sintered alloy
US5437933A (en) * 1992-02-18 1995-08-01 Johnson Matthey Public Limited Company Coated ceramic article
DE19652872A1 (en) * 1996-12-18 1998-07-02 Fraunhofer Ges Forschung Process for increasing the surface layer strength on surfaces of workpieces made of brittle hard materials
JPH11158599A (en) * 1997-10-02 1999-06-15 Mtu Motoren & Turbinen Union Muenchen Gmbh Heat insulating layer and its production
US6132293A (en) * 1992-07-10 2000-10-17 Sandvik Ab Method of blasting cutting tool inserts
WO2000073532A1 (en) * 1999-05-28 2000-12-07 Cemecon-Ceramic Metal Coatings-Dr.-Ing. Antonius Leyendecker Gmbh Process for producing a hard-material-coated component
WO2002009908A1 (en) * 2000-07-31 2002-02-07 Sintokogio, Ltd. Method of shot peening processing and article processed thereby, and peening material and use thereof
WO2002077312A2 (en) * 2001-03-27 2002-10-03 Widia Gmbh Method for increasing compression stress or reducing internal tension stress of a layer
KR100379581B1 (en) * 2000-12-04 2003-04-10 한국야금 주식회사 Coating materials of high toughness for a cutting tool/an abrasion resistance tool
JP2003253422A (en) * 2002-03-04 2003-09-10 Sanyo Special Steel Co Ltd Method for prolonging service life of tool such as mandrel and forming die, and tool of prolonged service life such as mandrel and forming die
KR20040020316A (en) * 2002-08-30 2004-03-09 한국야금 주식회사 Coating materials for a cutting tool/an abrasion resistance tool
JP2006175560A (en) * 2004-12-22 2006-07-06 Sumitomo Electric Hardmetal Corp Surface coated cutting tool
JP2006181645A (en) * 2004-12-24 2006-07-13 Sumitomo Electric Hardmetal Corp Surface coated cutting tool
JP2007092091A (en) * 2005-09-27 2007-04-12 Sintokogio Ltd Hard film coated sintered member, and its manufacturing method
WO2008037387A1 (en) * 2006-09-28 2008-04-03 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Method for increasing the fracture toughness of the outer layer of a carbide cutting edge of a drill
DE102007042833A1 (en) * 2007-09-10 2009-03-12 Walter Ag Blast-treated cutting insert and method
JP2009061464A (en) * 2007-09-05 2009-03-26 Daido Steel Co Ltd Die for warm and hot forging, and its manufacturing method
JP2009061465A (en) * 2007-09-05 2009-03-26 Daido Steel Co Ltd Metallic mold for cold forging and its manufacturing method
EP2267185A1 (en) 2004-08-20 2010-12-29 TDY Industries, Inc. PVD coated ruthenium featured cutting tools
WO2011025630A1 (en) 2009-08-25 2011-03-03 Tdy Industries, Inc. Coated cutting tools having a platinum group metal concentration gradient and related processes
JP2011189505A (en) * 2005-03-29 2011-09-29 Sumitomo Electric Hardmetal Corp Edge replaceable cutting tip and method of manufacturing the same
JP2012030359A (en) * 2011-09-21 2012-02-16 Sumitomo Electric Hardmetal Corp Cutting edge replaceable cutting tip
WO2012026098A1 (en) * 2010-08-26 2012-03-01 住友金属工業株式会社 Method of producing cutting tool
CN103878555A (en) * 2012-12-20 2014-06-25 三菱综合材料株式会社 Excellent Cubic Boron Nitride Ultrahigh Pressure Sintering Material Surface Coated Cutting Tool
JP2017036488A (en) * 2015-08-13 2017-02-16 新日鐵住金株式会社 Hard metal tool and manufacturing method therefor

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JPS63280961A (en) * 1987-05-12 1988-11-17 Mitsubishi Heavy Ind Ltd Manufacture of sliding member

Patent Citations (1)

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JPS63280961A (en) * 1987-05-12 1988-11-17 Mitsubishi Heavy Ind Ltd Manufacture of sliding member

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0539817U (en) * 1991-10-29 1993-05-28 日立ツール株式会社 Throw away end mill
US5437933A (en) * 1992-02-18 1995-08-01 Johnson Matthey Public Limited Company Coated ceramic article
JPH05320913A (en) * 1992-05-25 1993-12-07 Mitsubishi Materials Corp Surface coating cutting tool
US6132293A (en) * 1992-07-10 2000-10-17 Sandvik Ab Method of blasting cutting tool inserts
JPH06108258A (en) * 1992-09-29 1994-04-19 Toshiba Tungaloy Co Ltd High strength coated sintered alloy
DE19652872A1 (en) * 1996-12-18 1998-07-02 Fraunhofer Ges Forschung Process for increasing the surface layer strength on surfaces of workpieces made of brittle hard materials
DE19652872C2 (en) * 1996-12-18 2000-07-06 Fraunhofer Ges Forschung Process for increasing the surface layer strength on surfaces of workpieces made of brittle hard materials
JPH11158599A (en) * 1997-10-02 1999-06-15 Mtu Motoren & Turbinen Union Muenchen Gmbh Heat insulating layer and its production
JP2003500231A (en) * 1999-05-28 2003-01-07 セメコン−セラミック メタル コーティングス−ドクトル−インジェネア アントニウス レイエンデッカー ゲーエムベーハー Method for making a hard material coated part
WO2000073532A1 (en) * 1999-05-28 2000-12-07 Cemecon-Ceramic Metal Coatings-Dr.-Ing. Antonius Leyendecker Gmbh Process for producing a hard-material-coated component
JP4778650B2 (en) * 1999-05-28 2011-09-21 ケンナメタル インコーポレイテッド Method for making a component coated with a hard material
US6869334B1 (en) 1999-05-28 2005-03-22 Cemecon-Ceramic Metal Coatings-Dr. Ing. Antonius Leyendecker Gmbh Process for producing a hard-material-coated component
WO2002009908A1 (en) * 2000-07-31 2002-02-07 Sintokogio, Ltd. Method of shot peening processing and article processed thereby, and peening material and use thereof
KR100379581B1 (en) * 2000-12-04 2003-04-10 한국야금 주식회사 Coating materials of high toughness for a cutting tool/an abrasion resistance tool
WO2002077312A3 (en) * 2001-03-27 2003-01-03 Widia Gmbh Method for increasing compression stress or reducing internal tension stress of a layer
US6884496B2 (en) 2001-03-27 2005-04-26 Widia Gmbh Method for increasing compression stress or reducing internal tension stress of a CVD, PCVD or PVD layer and cutting insert for machining
WO2002077312A2 (en) * 2001-03-27 2002-10-03 Widia Gmbh Method for increasing compression stress or reducing internal tension stress of a layer
JP2003253422A (en) * 2002-03-04 2003-09-10 Sanyo Special Steel Co Ltd Method for prolonging service life of tool such as mandrel and forming die, and tool of prolonged service life such as mandrel and forming die
KR20040020316A (en) * 2002-08-30 2004-03-09 한국야금 주식회사 Coating materials for a cutting tool/an abrasion resistance tool
EP2267185A1 (en) 2004-08-20 2010-12-29 TDY Industries, Inc. PVD coated ruthenium featured cutting tools
JP2006175560A (en) * 2004-12-22 2006-07-06 Sumitomo Electric Hardmetal Corp Surface coated cutting tool
JP2006181645A (en) * 2004-12-24 2006-07-13 Sumitomo Electric Hardmetal Corp Surface coated cutting tool
JP2011189505A (en) * 2005-03-29 2011-09-29 Sumitomo Electric Hardmetal Corp Edge replaceable cutting tip and method of manufacturing the same
JP2007092091A (en) * 2005-09-27 2007-04-12 Sintokogio Ltd Hard film coated sintered member, and its manufacturing method
WO2008037387A1 (en) * 2006-09-28 2008-04-03 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Method for increasing the fracture toughness of the outer layer of a carbide cutting edge of a drill
JP2009061465A (en) * 2007-09-05 2009-03-26 Daido Steel Co Ltd Metallic mold for cold forging and its manufacturing method
JP2009061464A (en) * 2007-09-05 2009-03-26 Daido Steel Co Ltd Die for warm and hot forging, and its manufacturing method
DE102007042833A1 (en) * 2007-09-10 2009-03-12 Walter Ag Blast-treated cutting insert and method
WO2011025630A1 (en) 2009-08-25 2011-03-03 Tdy Industries, Inc. Coated cutting tools having a platinum group metal concentration gradient and related processes
JP2012045661A (en) * 2010-08-26 2012-03-08 Sumitomo Metal Ind Ltd Method of producing cutting tool
WO2012026098A1 (en) * 2010-08-26 2012-03-01 住友金属工業株式会社 Method of producing cutting tool
JP2012030359A (en) * 2011-09-21 2012-02-16 Sumitomo Electric Hardmetal Corp Cutting edge replaceable cutting tip
CN103878555A (en) * 2012-12-20 2014-06-25 三菱综合材料株式会社 Excellent Cubic Boron Nitride Ultrahigh Pressure Sintering Material Surface Coated Cutting Tool
JP2014121748A (en) * 2012-12-20 2014-07-03 Mitsubishi Materials Corp Surface-coated cutting tool made of cubic crystal boron nitride group superhigh pressure sintered material excellent in crack resistance
CN103878555B (en) * 2012-12-20 2017-09-05 三菱综合材料株式会社 Cubic boron nitride base ultra-high pressure sintered material control surface coated cutting tool
JP2017036488A (en) * 2015-08-13 2017-02-16 新日鐵住金株式会社 Hard metal tool and manufacturing method therefor

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