JPH02252556A - Composite pipe - Google Patents
Composite pipeInfo
- Publication number
- JPH02252556A JPH02252556A JP7616089A JP7616089A JPH02252556A JP H02252556 A JPH02252556 A JP H02252556A JP 7616089 A JP7616089 A JP 7616089A JP 7616089 A JP7616089 A JP 7616089A JP H02252556 A JPH02252556 A JP H02252556A
- Authority
- JP
- Japan
- Prior art keywords
- thermoplastic resin
- vibrator
- fiber
- reinforcing
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002131 composite material Substances 0.000 title claims abstract description 20
- 229920005992 thermoplastic resin Polymers 0.000 claims abstract description 56
- 239000012783 reinforcing fiber Substances 0.000 claims abstract description 22
- 239000000835 fiber Substances 0.000 claims abstract description 15
- 230000003014 reinforcing effect Effects 0.000 abstract description 25
- 229920005989 resin Polymers 0.000 abstract description 23
- 239000011347 resin Substances 0.000 abstract description 23
- 239000003365 glass fiber Substances 0.000 abstract description 6
- -1 polyethylene Polymers 0.000 abstract description 6
- 239000004698 Polyethylene Substances 0.000 abstract description 4
- 238000001125 extrusion Methods 0.000 abstract description 4
- 229920000573 polyethylene Polymers 0.000 abstract description 4
- 229920000915 polyvinyl chloride Polymers 0.000 abstract description 4
- 239000004800 polyvinyl chloride Substances 0.000 abstract description 4
- 239000004952 Polyamide Substances 0.000 abstract description 3
- 229920002647 polyamide Polymers 0.000 abstract description 3
- 229920000049 Carbon (fiber) Polymers 0.000 abstract description 2
- 239000004743 Polypropylene Substances 0.000 abstract description 2
- 239000004917 carbon fiber Substances 0.000 abstract description 2
- 229920000728 polyester Polymers 0.000 abstract description 2
- 229920001155 polypropylene Polymers 0.000 abstract description 2
- 238000003466 welding Methods 0.000 abstract 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract 1
- 238000010438 heat treatment Methods 0.000 description 7
- 229920001187 thermosetting polymer Polymers 0.000 description 7
- 235000001270 Allium sibiricum Nutrition 0.000 description 6
- 230000004927 fusion Effects 0.000 description 6
- 238000002844 melting Methods 0.000 description 5
- 230000008018 melting Effects 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 239000002184 metal Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000003381 stabilizer Substances 0.000 description 3
- 229920003002 synthetic resin Polymers 0.000 description 3
- 239000000057 synthetic resin Substances 0.000 description 3
- 238000004804 winding Methods 0.000 description 3
- BMASLOOHTMQIGP-ZOKJKDLISA-H (z)-but-2-enedioate;butyltin(3+) Chemical compound CCCC[Sn+3].CCCC[Sn+3].[O-]C(=O)\C=C/C([O-])=O.[O-]C(=O)\C=C/C([O-])=O.[O-]C(=O)\C=C/C([O-])=O BMASLOOHTMQIGP-ZOKJKDLISA-H 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 230000002787 reinforcement Effects 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 229920006337 unsaturated polyester resin Polymers 0.000 description 2
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 229910001111 Fine metal Inorganic materials 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 239000004696 Poly ether ether ketone Substances 0.000 description 1
- 239000004734 Polyphenylene sulfide Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920006231 aramid fiber Polymers 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000011162 core material Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000007499 fusion processing Methods 0.000 description 1
- 239000012784 inorganic fiber Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 125000005609 naphthenate group Chemical group 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002530 polyetherether ketone Polymers 0.000 description 1
- 229920000069 polyphenylene sulfide Polymers 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、樹脂層が複数層積層された複合バイブに関す
る。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a composite vibrator in which a plurality of resin layers are laminated.
（従来の技術）
合成樹脂製バイブは、軽量であり、錆びない等、金属製
バイブと比較して優れた特性を有しており、従来より広
く用いられている。しかし、合成樹脂製パイプは、耐水
性及び耐衝撃性において金属製バイブに劣っている。(Prior Art) Synthetic resin vibrators have superior properties compared to metal vibrators, such as being lightweight and not rusting, and have been widely used in the past. However, synthetic resin pipes are inferior to metal vibrators in terms of water resistance and impact resistance.
これらの問題を解決する手段として、繊維強化熱硬化性
樹脂製バイブ（特開昭６２−２４４６２１号公報）及び
繊維強化熱可塑性樹脂製バイブ（特開昭６１−２２０８
２４号公報、特開昭６２−２４４６２２号公報）が提案
され、また熱可塑性樹脂製バイブの外周に繊維強化熱硬
化性樹脂層を設けたバイブ（特開昭５９−４７５９０号
公報、特開昭６０−１６２６３２号公報、特公昭６２−
７７３号公報）が提案されている。As a means to solve these problems, a vibrator made of fiber-reinforced thermosetting resin (Japanese Unexamined Patent Publication No. 62-244621) and a vibrator made of fiber-reinforced thermoplastic resin (Japanese Unexamined Patent Publication No. 61-2208) are proposed.
No. 24, JP-A No. 62-244622) has been proposed, and a vibrator in which a fiber-reinforced thermosetting resin layer is provided around the outer periphery of a thermoplastic resin vibrator (JP-A No. 59-47590, JP-A-Sho Publication No. 60-162632, Special Publication No. 62-
No. 773) has been proposed.
（発明が解決しようとする課題）
しかし、繊維強化熱硬化性樹脂製バイブ及び繊維強化熱
熱可塑性樹脂製バイブは、強度及び耐衝撃性において優
れているが、強化繊維と樹脂との間、あるいは強化繊維
間に微細な間隙が形成され易く、強化繊維を含まない合
成樹脂製パイプに比べ水密性に劣っている。(Problems to be Solved by the Invention) However, although the fiber-reinforced thermosetting resin vibrator and the fiber-reinforced thermosetting resin vibrator have excellent strength and impact resistance, Fine gaps are likely to be formed between reinforcing fibers, resulting in poor watertightness compared to synthetic resin pipes that do not contain reinforcing fibers.
また、熱可塑性樹脂バイブの外周に繊維強化熱硬化性樹
脂層を設けたバイブは、水密性に優れてはいるが、熱可
塑性樹脂バイブと繊維強化熱硬化性樹脂層との接着性が
悪く、衝撃を受けた時に両層の界面で剥離し易いという
欠点があつた。Furthermore, a vibrator in which a fiber-reinforced thermosetting resin layer is provided around the outer periphery of a thermoplastic resin vibrator has excellent watertightness, but has poor adhesion between the thermoplastic resin vibe and the fiber-reinforced thermosetting resin layer. The drawback was that the two layers tend to peel off at the interface when subjected to impact.
本発明は上記欠点を解決したものであり、水密性に優れ
、かつ耐衝撃性に優れた複合バイブを提供することを目
的とする。The present invention solves the above-mentioned drawbacks, and aims to provide a composite vibrator with excellent watertightness and impact resistance.
（課題を解決するための手段）
本発明の複合バイブは、強化繊維を含まない熱可塑性樹
脂バイブの外周に、連続繊維で強化された熱可塑性樹脂
の強化層が融着されてなり、そのことにより上記目的が
達成される。(Means for Solving the Problems) The composite vibrator of the present invention has a reinforced layer of thermoplastic resin reinforced with continuous fibers fused to the outer periphery of a thermoplastic resin vibrator that does not contain reinforcing fibers. The above objective is achieved.
内層の熱可塑性樹脂バイブは、強化繊維を含まない熱可
塑性樹脂で形成されているので、水密性に優れている。The inner layer thermoplastic resin vibrator is made of a thermoplastic resin that does not contain reinforcing fibers, so it has excellent watertightness.
外層の強化層は、連続する繊維で強化された熱可塑性樹
脂で形成されているので、耐衝撃性に優れている。また
、内層と外層は熱可塑性樹脂で形成されていてその樹脂
の融着により一体化されているので、衝撃等を受けたと
しても両店の界面で剥離し難い。The outer reinforcing layer is made of a thermoplastic resin reinforced with continuous fibers, so it has excellent impact resistance. Further, since the inner layer and the outer layer are made of thermoplastic resin and are integrated by fusion of the resin, it is difficult for the inner layer and the outer layer to separate at the interface between the two layers even if subjected to an impact or the like.
以下に本発明の詳細な説明する。The present invention will be explained in detail below.
第１図に示すように、本発明の複合バイブＡは、熱可塑
性樹脂バイブ２０の外周に強化層２１を融着−体化させ
て形成されている。As shown in FIG. 1, the composite vibrator A of the present invention is formed by fusing and bonding a reinforcing layer 21 to the outer periphery of a thermoplastic resin vibrator 20. As shown in FIG.
内層の熱可塑性樹脂バイブ２０は、強化繊維１を含まな
い熱可塑性樹脂で形成されている。この熱可塑性樹脂と
しては、バイブ状に成形可能な樹脂であれば特に制限な
く使用でき、例えば、ポリ塩化ビニル、ポリエチレン、
ポリプロピレン、ポリアミド、ポリフェニレンサルファ
イド、ポリエーテルエーテルケトン等が用いられる。ま
た、これらの熱可塑性樹脂の混合物も使用し得る。さら
に、安定剤、潤滑剤、加工助剤、可塑剤、染料、顔料の
ような添加剤が熱可塑性樹脂に添加されていてもよい。The inner layer thermoplastic resin vibe 20 is made of a thermoplastic resin that does not contain the reinforcing fibers 1. As this thermoplastic resin, any resin that can be molded into the shape of a vibrator can be used without any particular restrictions.For example, polyvinyl chloride, polyethylene,
Polypropylene, polyamide, polyphenylene sulfide, polyether ether ketone, etc. are used. Mixtures of these thermoplastics may also be used. Additionally, additives such as stabilizers, lubricants, processing aids, plasticizers, dyes, and pigments may be added to the thermoplastic resin.
熱可塑性樹脂バイブ２０は、通常、押出成形により成形
することができる。The thermoplastic resin vibe 20 can usually be molded by extrusion molding.
外層の強化層２１は、強化繊維で補強された熱可塑性樹
脂で形成されている。熱可塑性樹脂は、上記熱可塑性樹
脂バイブ２０に融着可能な樹脂が選定され、熱可塑性樹
脂バイブ２０に用いた樹脂があげられる。強化層２１の
樹脂は熱可塑性樹脂バイブ２０と同一種類の樹脂であっ
ても異なってもよいが、同一種類の樹脂を用いるのが、
熱可塑性樹脂バイブ２０と強化層２１間の融着強度を高
めることができるので好ましい。また、内層の熱可塑性
樹脂バイブ２０の熱可塑性樹脂に比べて融着温度、融着
粘度あるいは重合度の低い樹脂を選定するのが、融着工
程において熱可塑性樹脂バイブ２０の変形が起こり難く
、高い融着強度が得られるので好ましい。The outer reinforcing layer 21 is made of thermoplastic resin reinforced with reinforcing fibers. As the thermoplastic resin, a resin that can be fused to the thermoplastic resin vibrator 20 is selected, and examples thereof include the resin used for the thermoplastic resin vibrator 20. The resin of the reinforcing layer 21 may be the same type of resin as the thermoplastic resin vibe 20 or different, but it is preferable to use the same type of resin.
This is preferable because the strength of the fusion bond between the thermoplastic resin vibe 20 and the reinforcing layer 21 can be increased. In addition, selecting a resin with a lower fusion temperature, fusion viscosity, or degree of polymerization than the thermoplastic resin of the thermoplastic resin vibrator 20 of the inner layer makes it difficult for the thermoplastic resin vibrator 20 to deform during the fusion process. This is preferred because high fusion strength can be obtained.
強化繊維１としては、強化層２１として使用する熱可塑
性樹脂の溶融温度以上の耐熱性を有する繊維が選ばれる
。例えば、ガラス繊維、炭素繊維、ボロン繊維、微細な
金属繊維等の無機繊維や、アラミド繊維、エコノール繊
維、ポリエステル繊維、ポリアミド繊維等の耐熱性有機
繊維が好適に用いられる。これらの強化繊維はモノフィ
ラメント状のもの、あるいは多数のモノフィラメントを
収束したストランド、ロービング状態のものいずれでも
使用できる。As the reinforcing fiber 1, a fiber having a heat resistance higher than the melting temperature of the thermoplastic resin used as the reinforcing layer 21 is selected. For example, inorganic fibers such as glass fibers, carbon fibers, boron fibers, and fine metal fibers, and heat-resistant organic fibers such as aramid fibers, econol fibers, polyester fibers, and polyamide fibers are preferably used. These reinforcing fibers can be used in the form of monofilaments, strands of a large number of monofilaments, or rovings.
本発明の複合パイプＡは種々の方法によって製造されて
よ（、例えば、第２図に示すように押出成形によって得
られた熱可塑性樹脂バイブ２０の外周に、上記強化繊維
に熱可塑性樹脂を付着または含浸した紐状あるいはテー
プ状のプリプレグ１０を、プリプレグｌＯ及びバイブ２
０表面を熱風等を用いた加熱装置３０で加熱溶融させな
がら、熱可塑性樹脂バイブ２０を矢印方向に回転するこ
とによりパイプ２０表面にプリプレグ１０を巻き付けて
得られる。プリプレグｌＯをパイプ２０外周に巻き付け
る際には、バイブ２０がその巻き付は力で変形しないよ
うにバイブ２０の内側に、内面に接する金属製心材を挿
入した状態で行ってもよい。The composite pipe A of the present invention can be manufactured by various methods (for example, as shown in FIG. 2, a thermoplastic resin is attached to the reinforcing fibers on the outer periphery of a thermoplastic resin vibe 20 obtained by extrusion molding. Alternatively, the impregnated string-like or tape-like prepreg 10 is combined with the prepreg lO and the vibrator 2.
The prepreg 10 is obtained by wrapping the prepreg 10 around the surface of the pipe 20 by rotating the thermoplastic resin vibrator 20 in the direction of the arrow while heating and melting the surface with a heating device 30 using hot air or the like. When wrapping the prepreg lO around the outer periphery of the pipe 20, the wrapping may be performed with a metal core material in contact with the inner surface inserted inside the vibrator 20 to prevent the vibrator 20 from being deformed by force.
上記プリプレグ１０を巻回するロールｌｏａの軸方向は
、熱可塑性樹脂パイプ２０の軸方向に対して傾斜させて
配置し、熱可塑性樹脂バイブ２０の軸方向に対して所定
角度でプリプレグ１０を巻回するのがよく、またプリプ
レグ１０がパイプ２０外周で互いに交差するように、複
数のプリプレグ１０を巻回してもよく、このようにすれ
ば耐衝撃性に優れた複合バイブＡが得られる。The axial direction of the roll loa around which the prepreg 10 is wound is arranged to be inclined with respect to the axial direction of the thermoplastic resin pipe 20, and the prepreg 10 is wound at a predetermined angle with respect to the axial direction of the thermoplastic resin vibe 20. Alternatively, a plurality of prepregs 10 may be wound so that the prepregs 10 intersect with each other on the outer periphery of the pipe 20. In this way, a composite vibe A with excellent impact resistance can be obtained.
強化層２１は強化繊維ｌがモノフィラメント状態で分散
し、モノフィラメント間に熱可塑性樹脂が充分含浸して
いるのが好ましい。このような強化層２１を得る方法と
しては、例えば、第３図に示す方法があげられる。すな
わち、粉末状の熱可塑性樹脂２がエアー４により流動化
している流動床３中をロービング状の強化繊維１を通過
させて、強化繊維１を構成するモノフィラメント間に粉
体状の熱可塑性樹脂２を付着させ、その後、加熱ロール
５により加圧下、樹脂を溶融させて強化繊維１と一体化
することによりプリプレグ１０を得、得られたプリプレ
グ１０を上記したように熱可塑性樹脂バイブ２０上に、
プリプレグ】０及びバイブ２０表面を熱風加熱装置３０
で加熱溶融させ両者を融着させながら巻き付けることに
より得られる。In the reinforcing layer 21, reinforcing fibers 1 are preferably dispersed in the form of monofilaments, and the thermoplastic resin is preferably sufficiently impregnated between the monofilaments. An example of a method for obtaining such a reinforcing layer 21 is the method shown in FIG. 3. That is, the roving-shaped reinforcing fibers 1 are passed through a fluidized bed 3 in which powdered thermoplastic resin 2 is fluidized by air 4, and the powdered thermoplastic resin 2 is passed between the monofilaments constituting the reinforcing fibers 1. Thereafter, the resin is melted under pressure by the heating roll 5 and integrated with the reinforcing fibers 1 to obtain the prepreg 10, and the obtained prepreg 10 is placed on the thermoplastic resin vibe 20 as described above.
[Prepreg] 0 and the vibrator 20 surface with hot air heating device 30
It is obtained by heating and melting the two and winding them together while fusing them.
強化層２１における強化繊維１と熱可塑性樹脂２の比率
は複合バイブＡの要求物性や使用する樹脂、強化ｗ４維
等によって適宜決定されるが、強化繊維量として５〜８
０容盟％の範囲とするのが好ましい。The ratio of reinforcing fibers 1 to thermoplastic resin 2 in the reinforcing layer 21 is appropriately determined depending on the required physical properties of the composite vibe A, the resin used, the reinforcing W4 fibers, etc., but the amount of reinforcing fibers is 5 to 8.
The range is preferably 0% by volume.
５容量％を下回ると補強効果が低下し、また８０容盟％
を超えると強化層２１と熱可塑性樹脂バイブ２０との融
着性が低下する。熱可塑性樹脂バイブ２０及び強化層２
１の厚さは適宜決定されるが、０．５〜２０ｍｍが通常
選択される。If it is less than 5% by volume, the reinforcing effect will decrease, and if it is less than 80% by volume.
If it exceeds this, the fusion properties between the reinforcing layer 21 and the thermoplastic resin vibe 20 will decrease. Thermoplastic resin vibe 20 and reinforcing layer 2
Although the thickness of 1 is determined as appropriate, 0.5 to 20 mm is usually selected.
（実施例） 次に、本発明を実施例に基づいて具体的に説明する。(Example) Next, the present invention will be specifically explained based on examples.
１皇側、
〔熱可塑性樹脂バイブの成形〕
ポリ塩化ビニル（平均重合度８００）・・・１００重量
部ブチル錫マレエート系安定剤・・・３重量部ポリエチ
レンワックス・・・０．５重量１部アリルアルコール・
・・１ｊｌｌｌ
顔料・・・１重量部
以上の配合物より押出成形により、外径５０關、肉厚４
＋ａｍの熱可塑性樹脂パイプを得た。1 Emperor's side, [Forging of thermoplastic resin vibrator] Polyvinyl chloride (average degree of polymerization 800)...100 parts by weight Butyltin maleate stabilizer...3 parts by weight Polyethylene wax...0.5 parts by weight Allyl alcohol・
...1jllll Pigment...By extrusion molding from a compound containing 1 part by weight or more, the outer diameter is 50 mm and the wall thickness is 4 mm.
A thermoplastic resin pipe of +am was obtained.
ポリ塩化ビニル（平均重合度４００）・・・１００ＩＩ
１１部ブチル錫マレエート系安定剤・・・３重量部ポリ
エチレンワックス・・・０．５重量部ステアリルアルコ
ール・・・ｉｍｍ部
以上の配合物をスーパーミキサーで混合しテ粉体状混合
物を得、この混合物で第３図に示す流動床３を形成し、
この流動床３中を、直径１３μｍのモノフィラメントが
多数収束されてなるロービング状ガラス繊維１を通過さ
せ、モノフィラメント間に上記粉体状混合物を付着させ
た後、約２００°Ｃの加熱ロールで加圧しつつ樹脂を溶
融させ、幅約５０ｍ臥厚み０．５關、ガラス繊維量約２
５重量％のプリプレグチーブを得た。Polyvinyl chloride (average degree of polymerization 400)...100II
11 parts Butyltin maleate stabilizer...3 parts by weight Polyethylene wax...0.5 parts by weight Stearyl alcohol...More than imm parts of the formulation were mixed in a super mixer to obtain a powdery mixture. Forming a fluidized bed 3 shown in FIG. 3 with the mixture,
Through this fluidized bed 3, a roving-shaped glass fiber 1 consisting of a large number of converged monofilaments with a diameter of 13 μm is passed through, and the powdery mixture is adhered between the monofilaments. The resin is melted, and the width is about 50 meters, the thickness is 0.5 meters, and the amount of glass fiber is about 2.
A 5% by weight prepreg chive was obtained.
次に、上記で得られた熱可塑性樹脂バイブ表面及びプリ
プレグチーブを約３００°Ｃの熱風加熱袋Ｕで加熱溶融
させながら、プリプレグテープをバイブの軸方向に対し
て約＋７５°傾斜させてバイブ外周に連続的に巻き付け
て強化層を設けた。続いて、上記強化層の上に、前回と
は逆方自からバイブの軸方向に対して、約−７５°傾斜
させて上記強化層の巻回方向と交差するようにプリプレ
グチーブを、強化層表面とプリプレグチーブを溶融させ
ながら連続的に巻き付けた。続いて、さらに同様の方法
で＋７５６傾斜させて別のプリプレグチーブを強化層上
に巻き付け、さらに−７５°傾斜させて別のプリプレグ
チーブを強化層上に巻き付け、合計４層の強化層を熱可
塑性樹脂バイブ周囲に設けて複合バイブを得た。Next, while heating and melting the surface of the thermoplastic resin vibrator and the prepreg chive obtained above in a hot air heating bag U at about 300°C, the prepreg tape is tilted at about +75° with respect to the axial direction of the vibrator, and the outer circumference of the vibrator is A reinforcing layer was provided by continuously wrapping the material around the material. Next, a prepreg chive is placed on top of the reinforcing layer so as to be inclined at about -75 degrees from the previous direction to the axial direction of the vibrator and intersect with the winding direction of the reinforcing layer. The surface and prepreg chives were continuously wrapped while melting. Subsequently, in the same manner, another prepreg chive is wrapped on the reinforcing layer with an inclination of +756 degrees, and another prepreg chive is wrapped on the reinforcing layer with an inclination of -75 degrees, so that a total of four reinforcement layers are made of thermoplastic. A composite vibrator was obtained by installing it around the resin vibrator.
得られた複合バイブは、強化繊維を含まない熱可塑性樹
脂バイブの外周に強化繊維が互いに交差するように巻き
付けられた強化層（厚み約２ ｍｍ）が融着されたもの
であった。The obtained composite vibrator had a reinforcing layer (approximately 2 mm thick) in which reinforcing fibers were wound so as to intersect with each other, and was fused to the outer periphery of a thermoplastic resin vibe that did not contain reinforcing fibers.
この複合パイプを長さ２０ｃｍに切断して試料とし、バ
イブ試料上に直径５０＋ｕｉの円筒形の鉄製錘（重量９
Ｋｇ）を高さ５００ｃｍから落下させた。バイブ試料は
破壊しなかつた。また衝撃部を切断し、断面を目視観察
したところ、内層の熱可塑性樹脂バイブと外層の強化層
との界面は接合した状態であり、剥離は認められなかっ
た。This composite pipe was cut to a length of 20 cm as a sample, and a cylindrical iron weight with a diameter of 50+ ui (weight 9
Kg) was dropped from a height of 500 cm. The vibrator sample was not destroyed. Further, when the impact portion was cut and the cross section was visually observed, it was found that the interface between the inner layer thermoplastic resin vibe and the outer reinforcing layer was in a bonded state, and no peeling was observed.
監蚊且
実施例と同様にして肉厚２ｍｍの強化繊維を含まない熱
可塑性樹脂バイブを得た。A thermoplastic resin vibrator having a wall thickness of 2 mm and containing no reinforcing fibers was obtained in the same manner as in the examples.
硬化剤としてメチルエチルケトンパーオキサイドを１ｆ
ｆｉｆｆｉ部、促進剤として６％ナフテン酸コバル）
Ｏ，１ｆｉ１１部を配合した不飽和ポリエステル樹脂（
日本ユビカ製、ユピカ＃ ５１３６）を含浸したガラス
繊維ロービング（直径］３μ冨のモノフィラメントが多
数収束されてなるロービング状ガラス繊維）を、実施例
と同様に上記バイブの軸方向に対して＋７５° −７５
°の傾斜角度で交互に４層巻き付けて厚さ２＋ａｍの熱
硬化性樹脂層を設けた後、３０°Ｃ雰囲気中に５時間放
置し、不飽和ポリエステル樹脂を得た。1f of methyl ethyl ketone peroxide as a hardening agent
fiffi part, 6% cobal naphthenate as accelerator)
Unsaturated polyester resin containing 11 parts of O,1fi (
A glass fiber roving (roving-shaped glass fiber formed by converging a large number of monofilaments with a diameter of 3 μm) impregnated with U-Pica #5136 (manufactured by Nippon Ubika) was placed at +75° − to the axial direction of the above-mentioned vibrator as in the example. 75
After forming a thermosetting resin layer with a thickness of 2+ am by winding four layers alternately at an inclination angle of .degree., it was left in an atmosphere of 30.degree. C. for 5 hours to obtain an unsaturated polyester resin.
得られた複合バイブを２００１こ切断したバイブ試料に
対して、実施例と同じ落錘試験を行うた。試料は破壊し
なかったが、衝撃部の切断面を目視観察したところ、内
層バイブと強化層とが剥離していた。The same falling weight test as in the example was performed on a vibrator sample obtained by cutting 2001 pieces of the obtained composite vibrator. Although the sample did not break, visual observation of the cut surface of the impact part revealed that the inner layer vibrator and the reinforcing layer had peeled off.
（発明の効果）
本発明の複合パイプは、軽量であり、錆びることがなく
、しかも水密性と耐衝撃性に優れたバイブとして、種々
の用途に使用することができる。(Effects of the Invention) The composite pipe of the present invention is lightweight, does not rust, and can be used for various purposes as a vibrator with excellent watertightness and impact resistance.
４、 の な！ 口。4. No! Mouth.
第１図は本発明の複合パイプの一実施例の断面図、第２
図及び第３図はその複合パイプの製造方法の一例を示す
説明図である。Fig. 1 is a sectional view of one embodiment of the composite pipe of the present invention, Fig. 2 is a sectional view of an embodiment of the composite pipe of the present invention;
3 and 3 are explanatory diagrams showing an example of a method for manufacturing the composite pipe.
１・・・強化繊維、１０・・・プリプレグ、２０・・・
熱可塑性樹脂バイブ、２１・・・強化層、Ａ・・・複合
パイプ。1... Reinforced fiber, 10... Prepreg, 20...
Thermoplastic resin vibe, 21... Reinforcement layer, A... Composite pipe.
以上 用１ 第２図 第３図that's all Use 1 Figure 2 Figure 3
Claims (1)
連続繊維で強化された熱可塑性樹脂の強化層が融着され
てなる複合パイプ。1. On the outer periphery of a thermoplastic resin pipe that does not contain reinforcing fibers,
A composite pipe made by fusion-bonding a reinforced layer of thermoplastic resin reinforced with continuous fibers.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1076160A JP2533640B2 (en) | 1989-03-27 | 1989-03-27 | Composite pipe |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1076160A JP2533640B2 (en) | 1989-03-27 | 1989-03-27 | Composite pipe |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02252556A true JPH02252556A (en) | 1990-10-11 |
| JP2533640B2 JP2533640B2 (en) | 1996-09-11 |
Family
ID=13597308
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1076160A Expired - Fee Related JP2533640B2 (en) | 1989-03-27 | 1989-03-27 | Composite pipe |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2533640B2 (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60108876U (en) * | 1983-12-27 | 1985-07-24 | 古河電気工業株式会社 | Heat resistant piping material |
-
1989
- 1989-03-27 JP JP1076160A patent/JP2533640B2/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60108876U (en) * | 1983-12-27 | 1985-07-24 | 古河電気工業株式会社 | Heat resistant piping material |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2533640B2 (en) | 1996-09-11 |
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