JPH02245162A - Pickling agent composition - Google Patents

Pickling agent composition

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Publication number
JPH02245162A
JPH02245162A JP1063440A JP6344089A JPH02245162A JP H02245162 A JPH02245162 A JP H02245162A JP 1063440 A JP1063440 A JP 1063440A JP 6344089 A JP6344089 A JP 6344089A JP H02245162 A JPH02245162 A JP H02245162A
Authority
JP
Japan
Prior art keywords
parts
weight
calcium
agent composition
pickling agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP1063440A
Other languages
Japanese (ja)
Inventor
Katsuhiko Hayashi
克彦 林
Yukihiro Takemura
竹村 幸弘
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHIBA SEIFUN KK
Original Assignee
CHIBA SEIFUN KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CHIBA SEIFUN KK filed Critical CHIBA SEIFUN KK
Priority to JP1063440A priority Critical patent/JPH02245162A/en
Publication of JPH02245162A publication Critical patent/JPH02245162A/en
Pending legal-status Critical Current

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  • Jellies, Jams, And Syrups (AREA)
  • Meat, Egg Or Seafood Products (AREA)

Abstract

PURPOSE:To obtain the subject composition free from a phosphate, capable of giving a ham having improved water-retainability, integrity and springiness and effective in improving the quality of ham by compounding a calcium agent to a thermally coagulable protein. CONSTITUTION:The objective composition is produced by compounding (A) 100 pts.wt. of a thermally coagulable protein (preferably having a thermal coagulation temperature of <=80 deg.C) with (B) preferably 2-100 pts.wt. of a calcium agent (preferably calcium hydroxide, calcium oxide or calcined calcium) and preferably further (C) 5-60 pts.wt. of natural gums.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、リン酸塩を添加しない畜肉ハム類を製造する
に際し、湿塩漬法またはビワクルインジェクター法によ
る塩漬工程で、保水性、結着性、弾力性をを付与する優
れた効果を示すピックル剤組成物に関するものである。
Detailed Description of the Invention [Industrial Field of Application] The present invention is aimed at improving water retention, water retention, The present invention relates to a pickling agent composition that exhibits excellent binding properties and elasticity.

〔従来の技術と発明が解決しようとする課題〕従来、畜
肉ハムの製造には、保水性、結着性ならびに弾力向上環
の機能性付与の面からリン酸塩を主剤とする添加剤、即
ち、リン酸塩製剤が塩漬工程で不可欠なものとして使用
されてきた。一方、我が国では、近年、国民の健康意識
の向上から、リン酸塩過剰摂取による生理的不均衡に対
する警戒、および、工場排水に混入するリン酸塩処理の
困難さや、これに伴うコスト高、また、流入した湖沼の
富栄養化の問題などから、リン酸塩の使用を敬遠する傾
向にある。
[Prior art and problems to be solved by the invention] Conventionally, in the production of meat ham, phosphate-based additives have been used to provide functions such as water retention, binding properties, and elasticity-improving rings. , phosphate preparations have been used as essential in the salting process. On the other hand, in Japan, as people's health awareness has improved in recent years, there has been increased concern about physiological imbalances caused by excessive intake of phosphates, and the difficulty of treating phosphates mixed in industrial wastewater and the associated high costs. There is a tendency to avoid using phosphates due to problems such as eutrophication of lakes and marshes into which they flow.

このリン酸塩を使用しない畜肉ハムには、離水防止(保
水)剤として各種の蛋白質や澱粉を添加することにより
前記機能性向上の効果を期待してはいるが、畜肉ハムに
対するリン酸塩製剤の添加は、保水性、結着性ならびに
弾力性向上の効果以外にも、食感や風味等につき優れた
品質改良効果を有するため、ピックル剤の主剤としてリ
ン酸塩製剤に優るものは未だ見出されていない。
For meat hams that do not use phosphates, it is expected that the above functionality will be improved by adding various proteins and starches as syneresis prevention (water retention) agents, but phosphates for meat hams In addition to the effects of improving water retention, binding properties, and elasticity, the addition of phosphate also has an excellent quality improvement effect on texture and flavor, so there is still no product that is superior to phosphate preparations as the main ingredient of pickling agents. Not served.

リン酸塩製剤以外の物質によって保水性、結着性、弾力
性を高める従来技術として、特開昭57−125648
号発明がある。この発明は、動・植物性蛋白質の加水分
解物に有機カルボン酸、フィチン酸、もしくは、それら
の塩類を併用することにより、畜肉ハムに対して優れた
保水性、結着性を有するピックル剤組成物に関するもの
であるが、本号発明の明細書中で示される実施例では全
てポリリン酸塩製剤が併用されていて、リン酸塩を完全
に除外したものではない。
As a conventional technique for increasing water retention, binding properties, and elasticity using substances other than phosphate preparations, Japanese Patent Application Laid-Open No. 57-125648
There is a No. 1 invention. This invention provides a pickling agent composition that has excellent water retention and binding properties for meat ham by using an organic carboxylic acid, phytic acid, or their salts in combination with a hydrolyzate of animal/vegetable protein. However, in all the examples shown in the specification of the present invention, polyphosphate preparations are used together, and phosphates are not completely excluded.

次に、特開昭62−6656号発明では、未加熱大豆蛋
白とカゼインを加熱乾燥し、ハム類清込用蛋白として使
用することを堤唱しているこの方法は、単にカゼインの
粘性と大豆蛋白の加熱時における凝固性、ならびに、両
者の保水性を複合して利用したに過ぎず、保水性、結着
性ならびに弾力性から畜肉ハムとして満足できるもので
はない。また、特開昭6’2−118841号発明では
、ピックルに使用する食塩の全部または一部をコーティ
ングすることによって食塩を不溶化させ、他の蛋白質、
塩類等の溶解性を高める方法を用いているが、畜肉ハム
の保水性、結着性、弾力性においてなお不充分である。
Next, the invention of JP-A No. 62-6656 proposes heating and drying unheated soybean protein and casein and using it as a protein for clarification of cold cuts. The coagulation property of protein upon heating and the water retention properties of both are merely utilized in combination, and the product is not satisfactory as a meat ham due to its water retention property, binding property, and elasticity. In addition, in the invention of JP-A No. 6'2-118841, all or part of the salt used in pickles is coated to insolubilize it, and other proteins,
Although methods are used to increase the solubility of salts, etc., the water retention, cohesiveness, and elasticity of meat ham are still insufficient.

以上の如く、リン酸塩製剤を添加しない畜肉ハムに、所
期の保水性、結着性ならびに弾力性を求めることは今な
お困難であって、その解決のためのピックル剤組成物の
出現が待たれていた。
As mentioned above, it is still difficult to obtain the desired water retention, cohesiveness, and elasticity in meat ham without the addition of phosphate preparations, and the emergence of pickling agent compositions to solve this problem is still difficult. It was waiting.

〔課題を解決するための手段〕[Means to solve the problem]

本発明は、リン酸塩製剤を使用せぬ畜肉ハムを作成する
際、保水性、結着性ならびに弾力性を確保するために、
熱凝固性蛋白質ならびにカルシウム剤を配合し、あるい
は、さらに天然ガム類を配合したピックル剤組成物を提
供しようとするものである。即ち、本発明は、■ 熱凝
固性蛋白質にカルシウム剤を配合したことを特徴とする
ピックル剤組成物、■ ■記載のピックル剤組成物にお
いて、天然ガム類を配合したことを特徴とするピックル
剤組成物、■ 熱凝固性蛋白質として、加熱凝固温度が
80℃以下のものの中から選ばれる1種または2種以上
を混合したものを用いたことを特徴とする■または■記
載のピックル剤組成物、■ カルシウム剤として、水酸
化カルシウム、酸化カルシウム、および、焼成カルシウ
ムから選ばれる1種または2種以上を混合したものを用
いたことを特徴とする■または■記載のピックル剤組成
物、■ 天然ガム類として、海藻抽出物の1種または2
種以上を混合したものを用いたことを特徴とする■記載
のピックル剤組成物、■ 熱凝固性蛋白質100重量部
に対しカルシウム剤2〜100重量部を配合したことを
特徴とする■または■記載のピックル剤組成物、■ 熱
凝固性蛋白質100重量部に対し天然ガム類5〜60重
量部を配合したことを特徴とする■記載のピックル剤組
成物、に係るものである。
In the present invention, when producing meat ham that does not use phosphate preparations, in order to ensure water retention, binding properties, and elasticity,
The present invention aims to provide a pickling agent composition containing a thermocoagulable protein and a calcium agent, or further containing a natural gum. That is, the present invention provides (1) a pickling agent composition characterized in that a calcium agent is blended with a thermocoagulable protein, (2) a pickling agent characterized in that a natural gum is blended in the pickling agent composition described in (2). Composition, (1) The pickling agent composition according to (1) or (2), characterized in that one or a mixture of two or more selected from those having a heating coagulation temperature of 80° C. or lower is used as the thermocoagulable protein. , ■ The pickling agent composition according to ■ or ■, characterized in that one or a mixture of two or more selected from calcium hydroxide, calcium oxide, and calcined calcium is used as the calcium agent, ■ Natural As gums, one or two types of seaweed extract
The pickling agent composition according to (1), which is characterized by using a mixture of two or more seeds, (2) or (2), which is characterized by containing 2 to 100 parts by weight of a calcium agent to 100 parts by weight of thermocoagulable protein. The present invention relates to the pickling agent composition described in (1), characterized in that 5 to 60 parts by weight of a natural gum is blended to 100 parts by weight of a thermocoagulable protein.

以下に、本発明の詳細な説明する。The present invention will be explained in detail below.

ピックルに使用される蛋白質溶液に求められる条件は、
(1)  熔解が容易であること、(2)  溶液粘度
が低いこと、(3)  加熱して生じるゲルの凝固力が
強いこと、ならびに、(4)  加熱後保水力が強いこ
と等である。本発明に使用する熱凝固性蛋白質としては
、卵蛋白質、乳蛋白質、血液蛋白質(プラズマパウダー
等)、大豆蛋白質あるいは小麦蛋白質等のごと(例示で
きる動物性・植物性蛋白質中、80℃以下で加熱凝固性
のあるものの中から選ばれる1種または2種以上を混合
したものが適切である。これらの蛋白質を例えば酵素等
により加水分解したり、脱アマイド処理したり、あるい
は、酸化・還元処理を施す等、種々の処理を行ったもの
であっても80°C以下での加熱凝固性を失っていなけ
れば、いずれも使用することができる。
The conditions required for the protein solution used for pickling are:
(1) It is easy to melt, (2) the solution viscosity is low, (3) the gel produced by heating has a strong coagulating power, and (4) it has a strong water retention capacity after heating. Thermocoagulable proteins used in the present invention include egg protein, milk protein, blood protein (plasma powder, etc.), soybean protein, wheat protein, etc. One type or a mixture of two or more types selected from coagulable proteins is suitable.These proteins can be hydrolyzed with enzymes, deamidated, or oxidized/reduced. Even if it has been subjected to various treatments, as long as it does not lose its heat coagulability at 80° C. or lower, it can be used.

カルシウム剤とは、水酸化カルシウム、酸化カルシウム
および焼成カルシウムから選ばれる1種または2種以上
を混合したものをいう。そのうち、焼成カルシウムとは
、カキ、ホタテ、サザエを含む貝殻類、牛、豚の骨を主
体とする獣骨類、あるいは、卵殻類を常法により焼成し
て得られる焼成カルシウム粉末をいう。
The calcium agent refers to one or a mixture of two or more selected from calcium hydroxide, calcium oxide, and calcined calcium. Among these, calcined calcium refers to calcined calcium powder obtained by calcining shellfish including oysters, scallops, and turban shells, animal bones mainly consisting of cow and pig bones, or eggshells by a conventional method.

また、前記の熱凝固性蛋白質とカルシウム剤からなる本
発明のピックル剤組成物に、下記の天然ガム類を組み合
わせることにより効果をさらに高めることができる。即
ち、本発明にいう天然ガム類とはカラギーナン、寒天、
ファーセラン、アルギン酸等の海藻抽出物、ローカスト
ビーンガム等の種子粘質物、ペクチ・ン等の果実粘質物
、カラヤガム等の樹脂様粘質物、さらにはキサンタンガ
ム等の微生物由来粘質物等のいずれか1種または2種以
上混合したものであるが、とくに、カラギーナン、寒天
、ファーセラン、アルギン酸等の海藻抽出物が有効であ
る。
Furthermore, the effect can be further enhanced by combining the following natural gums with the pickling agent composition of the present invention, which comprises the above-mentioned thermocoagulable protein and calcium agent. That is, the natural gums referred to in the present invention include carrageenan, agar,
Any one of seaweed extracts such as furcellan and alginic acid, seed mucilages such as locust bean gum, fruit mucilages such as pectin, resin-like mucilages such as Karaya gum, and microorganism-derived mucilages such as xanthan gum. Or a mixture of two or more kinds, and seaweed extracts such as carrageenan, agar, farcelan, and alginic acid are particularly effective.

本発明におけるピックル剤組成物は、熱凝固性蛋白質1
00重量部に対し、カルシウム剤2〜100重量部、好
ましくは2〜20重量部を通常の混合手段により混合し
て得られるものである。この場合、熱凝固性蛋白質10
0重量部に対しカルシウム剤が2重量部未満であるとき
は、熱凝固性蛋白質に対するカルシウム剤の架橋効果が
不充分であり、カルシウム剤が100重量部以上では、
熱凝固性蛋白質がカルシウムイオンによる過度の変性を
受けて、蛋白質の熱凝固性が脆弱化してくるので不適当
である。また、前記天然ガム類を配合する場合には、熱
凝固性蛋白質100重量部に対し、天然ガム類を5〜6
0重量部、好ましくは10〜40重量部を組み合わせる
ことが適当である。この場合、天然ガム類が5重量部未
満であるときは、天然ガム類の保水性ならびに結着性を
高める効果が不充分であり、天然ガム類が60重量部以
上では、ピックルの熔解粘度が高すぎて、原料肉への分
散性が悪くなるので、これを使用することはできない。
The pickling agent composition in the present invention contains thermocoagulable protein 1
It is obtained by mixing 2 to 100 parts by weight, preferably 2 to 20 parts by weight, of a calcium agent to 00 parts by weight using a conventional mixing means. In this case, thermocoagulable protein 10
When the amount of the calcium agent is less than 2 parts by weight relative to 0 parts by weight, the crosslinking effect of the calcium agent on the thermocoagulable protein is insufficient, and when the amount of the calcium agent is 100 parts by weight or more,
This is unsuitable because thermocoagulable proteins are excessively denatured by calcium ions, which weakens the thermocoagulability of the proteins. In addition, when blending the natural gums, 5 to 6 parts of the natural gums are added to 100 parts by weight of the thermocoagulable protein.
It is suitable to combine 0 parts by weight, preferably 10 to 40 parts by weight. In this case, if the amount of natural gums is less than 5 parts by weight, the effect of increasing the water retention and binding properties of natural gums is insufficient, and if the amount of natural gums is 60 parts by weight or more, the melt viscosity of the pickle will decrease. This cannot be used because it is too high and the dispersibility into raw meat becomes poor.

本発明のピックル剤組成物が使用されるハム類は、ロー
スハム、ボンレスハム、プレスハム等通常に製造されて
いる畜肉ハムであるが、本発明のピックル剤組成物は、
チキンハム等の家禽類ハムや、唐揚げ、豚カッ、白身魚
フライ等の惣菜類、珍味類の中で塩漬工程を必要とする
加工食品にも適用できる。さらに、この場合、副原料と
して魚肉すり身、澱粉、ガム質等を使用しても、通常量
程度の使用ではピックル剤組成物の効果に何等影響を与
えない。
Hams to which the pickling agent composition of the present invention is used are commonly produced meat hams such as roast ham, boneless ham, and pressed ham.
It can also be applied to poultry hams such as chicken ham, prepared foods such as fried chicken, pork cutlet, and fried white fish, and processed foods that require a salting process among delicacies. Furthermore, in this case, even if minced fish, starch, gum, etc. are used as auxiliary raw materials, the effects of the pickling agent composition will not be affected at all if used in normal amounts.

さらに、本発明のピックル剤組成物の対象となる畜肉ハ
ムは、リン酸塩無添加ハムであるが、低リン酸塩添加ハ
ム、例えば最終製品当たりのリン酸塩濃度が、0.1〜
0.2%程度の保水性、結着性、弾力性ともに不充分な
ことが予想される畜肉ハムに添加することも可能であり
、この場合、製品の品質向上をはかることができる。
Furthermore, the meat ham to which the pickling agent composition of the present invention is applied is a ham with no added phosphate, but a ham with a low phosphate added, for example, a phosphate concentration per final product of 0.1 to 1.
It is also possible to add it to meat ham that is expected to have insufficient water retention, binding properties, and elasticity of about 0.2%, and in this case, it is possible to improve the quality of the product.

〔作 用〕[For production]

本発明のピックル剤組成物の作用を実験例をもって説明
する。
The effect of the pickling agent composition of the present invention will be explained using experimental examples.

まず、本実験に使用したピックル剤組成物の配合は以下
のとおりである。即ち、プラズマパウダー70重量部、
卵白30重量部よりなる熱凝固性蛋白質混合物100重
景部に対し、水酸化カルシウム6重量部をミキサーで混
合したものを試料1とし、試料1に、カラギーナン80
重量部、寒天20重量部よりなる海藻抽出混合物を、さ
らに25重量部組み合わせたものを試料2とした。そし
て、原料肉100重量部に対しピックル注入率を25重
量部に設定したとき、対照として、南中濃度で食塩2%
、砂糖0゜5%になる様に調整したピックルのみの区を
、結着剤無添加区、この結着剤無添加区に原料肉100
重量部に対し3重量部となるように卵白を添加した区を
、卵白添加区、原料肉100重量部に対し0.3重量部
となるようにポリリン酸塩を添加した区を、ポリリン酸
塩添加区とした。また、本発明のピックル剤組成物であ
る試料1および試料2を、前記、食塩、砂糖のみのピッ
クルに、原料肉100重量部に対しそれぞれ3重量部を
添加して、試料1添加区ならびに試料2添加区とし、各
ピックルについての比較実験を行った。
First, the formulation of the pickling agent composition used in this experiment is as follows. That is, 70 parts by weight of plasma powder,
Sample 1 is prepared by mixing 6 parts by weight of calcium hydroxide with 100 parts by weight of a thermocoagulable protein mixture consisting of 30 parts by weight of egg white, and 80 parts by weight of carrageenan.
Sample 2 was prepared by combining 25 parts by weight of a seaweed extraction mixture consisting of 20 parts by weight of agar and 20 parts by weight of agar. When the pickle injection rate was set at 25 parts by weight for 100 parts by weight of raw meat, as a control, the salt concentration was 2%
, a section with only pickle adjusted to 0.5% sugar, a section with no binder added, and a section with no added binder added with 100% raw meat.
The area in which egg white was added in an amount of 3 parts by weight per part by weight was the egg white added area, and the area in which polyphosphate was added in an amount of 0.3 parts by weight per 100 parts by weight of raw meat was the polyphosphate area. It was designated as an additive area. In addition, 3 parts by weight of each of Sample 1 and Sample 2, which are the pickling agent compositions of the present invention, were added to the pickle containing only salt and sugar, and 3 parts by weight of each were added to 100 parts by weight of raw meat. A comparative experiment was conducted for each pickle in two addition groups.

本実験においては、原料肉として豚ロースを使用したが
、インジェクターを用いて各ピックルを注入後、10時
間タンブラ−にてマツサージを行い、塩漬(5℃、48
時間)・充填・加熱・冷却の順で、ロースハムを作成し
た。以上の実験において、歩留り(その大半は保水性と
して表現される)、結着性(身割れ状態)ならびに食感
を評価し、これを表1とした。ここで、歩留りは、それ
ぞれ原料肉を100重量部としたときの加熱・冷却後重
量部をラテン方路法により比較した。次に、リン酸塩を
添加しないハムにおいて、最も問題となる結着性(身割
れ状態)は、ロースハムをスライサーにて214mにス
ライスした後、10枚を真空バック詰めし24時間低温
室に放置する。開封後、1枚ずつ身割れせずに剥がれる
か否かで判断し5点法により評価した。即ち、10枚と
も全く身割れのないものを5点とし、10枚とも身割れ
剥離したものを0点とした。食感は、滑らかさを加味し
た弾力について、官能法により評価したが、その際、パ
ネラ−10人によるパネルテストを5点法で行いその平
均点を採用した。即ち、弾力の強いものを5点とし、弾
力の弱いものを1点とするとともに、その中間の配点を
行った。
In this experiment, pork loin was used as the raw meat, and after injecting each pickle using an injector, it was subjected to pine surge in a tumbler for 10 hours, and salted (5℃, 48℃).
The roast ham was prepared in the following order: time), filling, heating, and cooling. In the above experiments, the yield (most of which is expressed as water retention), binding property (splitting), and texture were evaluated, and the results are shown in Table 1. Here, the yield was determined by comparing parts by weight after heating and cooling, based on 100 parts by weight of the raw meat, using the Latin method. Next, in hams that do not contain phosphates, the most problematic problem is cohesion (splitting). After slicing the loin ham into 214-meter pieces using a slicer, 10 slices are packed in a vacuum bag and left in a cold room for 24 hours. do. After opening, it was judged whether each piece could be peeled off without cracking and evaluated using a 5-point scale. That is, a score of 5 was given for all 10 sheets with no cracking, and a score of 0 was given for all 10 sheets with peeling. The texture was evaluated by a sensory method in terms of elasticity including smoothness, and the average score of a 5-point panel test conducted by 10 panelists was used. That is, items with strong elasticity were given 5 points, items with weak elasticity were given 1 point, and scores were assigned in between.

表1より、本発明のピックル剤組成物添加ピ・7クルは
、いずれも、リン酸塩無添加のハム製造で常用されてい
る卵白添加ピックルより、はるかに有効であり、とくに
天然ガムを配合した試料2添加区は、従来からこれの代
替がないとして賞月されているポリリン酸塩添加に比し
て遜色のないことが明らかになった。
From Table 1, all of the pickling agent compositions of the present invention, Pickle 7, are much more effective than the egg white-added pickles that are commonly used in ham production without the addition of phosphates, especially those containing natural gum. It has become clear that the sample 2-added group is comparable to the polyphosphate-added group, which has been praised for its lack of an alternative.

本発明のピックル剤組成物が、肉蛋白質、脂肪質、水分
等にどのような作用をもたらすのか詳細は明らかではな
いが、概ね次のように説明することができる。即ち、ま
ず畜肉中の筋原繊維蛋白質に対しカルシウム剤がアルカ
リとして働き、この肉蛋白質の溶解性および水和性を高
める。次いで、肉蛋白質およびピックル剤組成物中の熱
凝固性蛋白質の両者の間にカルシウム剤を介して徐々に
カルシウム架橋が形成され結合を強固にする。その後、
結合した肉蛋白質は加熱により凝固し、ハムの保水性、
結着性を安定した状態に保持する。さらに、天然ガム類
は自らのもつゲル化性により、前記、保水性、結着性を
一層安定化する。従って、食感もまた向上することは明
らかである。
Although the details of the effect of the pickling agent composition of the present invention on meat protein, fat, moisture, etc. are not clear, it can be generally explained as follows. That is, first, the calcium agent acts as an alkali for the myofibrillar proteins in the meat, increasing the solubility and hydration of the meat proteins. Next, calcium crosslinks are gradually formed between the meat protein and the thermocoagulable protein in the pickling agent composition via the calcium agent to strengthen the bond. after that,
The bound meat proteins coagulate when heated, improving the water retention capacity of the ham.
Maintains binding properties in a stable state. Furthermore, natural gums further stabilize the above-mentioned water retention and binding properties due to their own gelling properties. Therefore, it is clear that the texture is also improved.

以下に実施例を以て、本発明を更に詳細に説明する。The present invention will be explained in more detail below with reference to Examples.

〔実 施 例〕〔Example〕

実施例 1゜ ラクトアルブミン粉末60重量部およびプラズマパウダ
ー40重量部の熱凝固性蛋白質混合物100重量部に、
水酸化カルシウム7重量部を加えて混合してピックル剤
組成物とした。原料肉を豚肉もも肉とし、肉100重量
部に対しピックル注入率を25重量部に設定した。南中
濃度で食塩2%、砂$180.5%、調味料0. 4%
、ピックル剤組成物2.5%になるようにピックルを作
成した後、ビンクルインジェクター法によって塩漬を行
い、ボンレスハムを製造したが、このものは、リン酸塩
無添加ハムとしては、離水が少なく身割れもない弾力性
の優れたハムであって、表1における試料1添加区と同
様の成績を得た。
Example 1 100 parts by weight of a thermocoagulable protein mixture containing 60 parts by weight of lactalbumin powder and 40 parts by weight of plasma powder,
7 parts by weight of calcium hydroxide was added and mixed to obtain a pickling agent composition. The raw meat was pork thigh, and the pickle injection rate was set at 25 parts by weight per 100 parts by weight of the meat. Namchu concentration: 2% salt, $180.5% sand, 0. 4%
After preparing a pickle with a pickling agent composition of 2.5%, salting was carried out using the Binkle injector method to produce boneless ham, but this product did not have syneresis as a phosphate-free ham. The ham had excellent elasticity with little cracking, and obtained the same results as the Sample 1 added group in Table 1.

実施例 2゜ 実施例1のピックル剤組成物100重量部に、カラギー
ナン20重量部およびキサンタンガム10重量部を配合
して新たなピックル剤組成物を作成し、原料肉をはじめ
その他の条件を実施例1と同様にしてボンレスハムを製
造した。
Example 2゜A new pickling agent composition was prepared by blending 20 parts by weight of carrageenan and 10 parts by weight of xanthan gum with 100 parts by weight of the pickling agent composition of Example 1, and the raw meat and other conditions were determined in Example 2. Boneless ham was produced in the same manner as in Example 1.

その結果、離水が殆どなく身割れもない食感の優れた製
品が得られた。そして、このものは、表1における試料
2添加区と同様に評価された実施例 3゜ 卵白40重量部、ラクトアルブミン粉末40重量部、小
麦蛋白質をパパインを用いて分解した酵素処理小麦蛋白
粉末20重量部の合計100重量部に卵殻を原料とする
焼成カルシウム8重量部、さらにファー上5フ15重量
部およびカラギーナン5重量部を混合しピックル剤組成
物とした。そして、原料肉100重量部に対しピックル
注入率を30重量部に設定してピックルを作成したが、
その際、ピックルは南中濃度で、食塩1.5%、調味料
1%、ピックル剤組成物4%とした。原料肉は豚もも肉
とし、1片が50g以下になるように細かく切り、フー
ドミキサーにて30分間混合して充分にピックルを吸収
させた後、2日間湿塩漬法にて塩漬を行い、その後リテ
ーナ−に詰めてプレスハムを作成した。斯くして得られ
たハムは、極めて保水性が高くスライサーで1.5in
厚にスライスしても身割れはほとんど観察されず、両手
で引っ張っても肉片どうしの接着力は非常に強固であっ
た。本製品についてもまた、表1における試料2添加区
と同様の成績を得た。
As a result, a product with excellent texture and almost no syneresis and no cracking was obtained. This product was evaluated in the same manner as the Sample 2 addition group in Table 1. Example 3: 40 parts by weight of egg white, 40 parts by weight of lactalbumin powder, 20 parts by weight of enzyme-treated wheat protein powder prepared by decomposing wheat protein using papain. A pickling agent composition was prepared by mixing 8 parts by weight of calcined calcium made from eggshells, 15 parts by weight of fur top 5, and 5 parts by weight of carrageenan into a total of 100 parts by weight. Then, pickles were made by setting the pickle injection rate to 30 parts by weight per 100 parts by weight of the raw meat.
At that time, the pickle had a concentration of 1.5% salt, 1% seasoning, and 4% pickle composition. The raw meat is pork thigh, cut into pieces so that each piece weighs less than 50 g, mixed in a food mixer for 30 minutes to fully absorb the pickle, and then salted using a wet salting method for 2 days. Thereafter, the ham was packed in a retainer to create a pressed ham. The ham thus obtained has extremely high water retention and can be sliced into 1.5 inch slices using a slicer.
Even when sliced thickly, almost no cracking was observed, and even when pulled with both hands, the adhesive strength between the pieces of meat was very strong. This product also obtained the same results as the Sample 2 addition group in Table 1.

実施例 4゜ プラズマパウダー75重量部、カゼインナトリウム25
重量部の合計100重量部に酸化カルシウム20重量部
、カラギーナン30重量部ローカストビーンガムとアラ
ビアガムとを各5重量部ずつ加え、充分に混合したもの
をピックル剤組成物とした。畜肉原料には豚肉、牛肉、
マトンの三種類を準備し、1片が30〜50g程度にな
るように細切した。また、魚肉原料として、タラを準備
し同様に細切した。三種類の畜肉を各25重量部ずつ、
魚肉原料も25重量部の肉塊原料合計100重量部に対
しピックル注入率を30重量部に設定した。南中濃度で
、食塩1.5%、調味料2%、ピックル剤組成物6%、
さらに、つなぎとして馬鈴薯澱粉4%となるように配合
したピックルを作成し、タンプリングマシンにて60分
間回転させ充分にピックルを吸収させた後、1日間の湿
塩漬工程を経て混合プレスハムを製造した。このものも
、保水性、結着性に優れた製品であり、食感は従来のリ
ン酸塩無添加ハムでは考えられなかった瑞々しい弾力性
のあるものであった。
Example 4 75 parts by weight of plasma powder, 25 parts by weight of sodium caseinate
To a total of 100 parts by weight, 20 parts by weight of calcium oxide, 30 parts by weight of carrageenan, 5 parts by weight each of locust bean gum and gum arabic were added and thoroughly mixed to prepare a pickling agent composition. Meat raw materials include pork, beef,
Three types of mutton were prepared and cut into pieces so that each piece weighed about 30 to 50 g. In addition, as a raw material for fish meat, cod was prepared and shredded in the same manner. 25 parts by weight of each of the three types of meat,
The pickle injection rate was set at 30 parts by weight for a total of 100 parts by weight of the fish meat raw material, which was 25 parts by weight. Namchu concentration: 1.5% salt, 2% seasoning, 6% pickling agent composition,
Furthermore, a pickle containing 4% potato starch as a binder was made and rotated in a tampling machine for 60 minutes to fully absorb the pickle.The mixed pressed ham was then subjected to a wet salting process for one day. Manufactured. This product also had excellent water retention and binding properties, and the texture was fresh and elastic, which was unimaginable with conventional phosphate-free ham.

実施例 5゜ 卵白粉末50重量部およびラクトアルブミン50重量部
の合計100重量部にサザエの貝殻を原料とする焼成カ
ルシウム20重量部、さらに寒天とカラヤガムを2対1
重量比で混合して得た粉末40重量部を混合してピック
ル剤組成物とした。鶏肉100重量部に対しピックル注
入率を20重量部に設定してピックルを作成したが、ピ
ックルには食塩、みりん、醤油等と共にピックル剤組成
物を溶解させた。ピックル剤組成物の添加料は、鶏肉1
00重量部に対して10重量部とした。鶏胸肉を唐揚げ
用に細切し、タンプリングマシンでピックルを吸収させ
た後、唐揚げ粉を付着させた。斯くして、170℃、7
分で油ちょうした唐揚げは、冷えても離水が認められず
116%の高い歩留りを示した。食感も弾力性があり、
味と共に良好なものであった。
Example 5゜A total of 100 parts by weight of 50 parts by weight of egg white powder and 50 parts by weight of lactalbumin, 20 parts by weight of calcined calcium made from turban shells, and 2:1 of agar and karaya gum.
A pickling agent composition was prepared by mixing 40 parts by weight of the powders obtained by mixing in a weight ratio. A pickle was prepared by setting the pickle injection rate to 20 parts by weight per 100 parts by weight of chicken meat, and a pickling agent composition was dissolved in the pickle along with salt, mirin, soy sauce, etc. The additives of the pickling agent composition include chicken meat 1
00 parts by weight to 10 parts by weight. Chicken breast was cut into strips for fried chicken, soaked with pickles using a tamping machine, and then coated with fried chicken powder. Thus, 170℃, 7
The fried chicken, which was fried in oil for a few minutes, showed no syneresis even after cooling, and showed a high yield of 116%. The texture is also elastic,
It had a good taste as well.

実施例 6゜ カゼインナトリウム70重量部およびラクトアルブミン
30重量部の合計100重量部に対し、水酸化カルシウ
ム3重量部および酸化カルシウム5重量部、計8重量部
のカルシウム剤とアルギン酸40重量部とを混合してピ
ックル剤組成物とした。原料魚肉をタラとし、タラ肉1
00重量部に対しピックルをタンプリングマシンで30
重量部注入して一晩塩漬を行った。なお、ピックル剤組
成物は南中濃度で5%となるように調整した。翌日、小
麦粉・卵・パン粉付けを行い油ちょうしたが、この白身
魚フライは保水性が高く食感も大変まとまったものであ
った。
Example 6 To a total of 100 parts by weight of 70 parts by weight of sodium caseinate and 30 parts by weight of lactalbumin, 3 parts by weight of calcium hydroxide and 5 parts by weight of calcium oxide, a total of 8 parts by weight of a calcium agent, and 40 parts by weight of alginic acid were added. The mixture was mixed to form a pickling agent composition. Raw fish meat is cod, cod meat 1
30 parts by weight of pickle using a tampling machine
Parts by weight were injected and salted overnight. The pickling agent composition was adjusted to have a concentration of 5%. The next day, it was coated with flour, eggs, breadcrumbs, and oiled, but the fried white fish had a high water retention capacity and a very consistent texture.

〔発明の効果〕〔Effect of the invention〕

本発明におけるピックル剤組成物は、その配合に全くリ
ン酸塩を含有しないため、食生活上リン酸塩の過剰摂取
を防ぐのみでなく、ハム類の生産上は通常除去が困難な
リン酸塩を排水中に含まぬため、工場の合理化が容易と
なり、且つ、製品ハムの保水性、結着性ならびに弾力性
を改善し、品質を向上せしめることができる。
Since the pickling agent composition of the present invention does not contain any phosphates in its formulation, it not only prevents excessive intake of phosphates in the diet, but also phosphates, which are normally difficult to remove in the production of cold meats. Since it is not contained in the wastewater, it is easy to rationalize the factory, and it is also possible to improve the water retention, binding, and elasticity of the product ham, and improve the quality.

従って、本発明は食生活において、さらには、食肉産業
上に資するところが極めて大なるものがある。
Therefore, the present invention has an extremely large contribution to the eating habits and furthermore to the meat industry.

Claims (7)

【特許請求の範囲】[Claims] (1)熱凝固性蛋白質にカルシウム剤を配合したことを
特徴とするピックル剤組成物。
(1) A pickling agent composition characterized in that a calcium agent is blended with a thermocoagulable protein.
(2)請求項1記載のピックル剤組成物において、天然
ガム類を配合したことを特徴とするピックル剤組成物。
(2) The pickling agent composition according to claim 1, characterized in that it contains natural gums.
(3)熱凝固性蛋白質として、加熱凝固温度が80℃以
下のものの中から選ばれる1種または2種以上を混合し
たものを用いたことを特徴とする請求項1または請求項
2記載のピックル剤組成物。
(3) The pickle according to claim 1 or 2, characterized in that the thermocoagulable protein is one or a mixture of two or more selected from those having a heat coagulation temperature of 80° C. or lower. agent composition.
(4)カルシウム剤として、水酸化カルシウム、酸化カ
ルシウム、および、焼成カルシウムから選ばれる1種ま
たは2種以上を混合したものを用いたことを特徴とする
請求項1または請求項2記載のピックル剤組成物。
(4) The pickling agent according to claim 1 or 2, characterized in that the calcium agent is one or a mixture of two or more selected from calcium hydroxide, calcium oxide, and calcined calcium. Composition.
(5)天然ガム類として、海藻抽出物の1種または2種
以上を混合したものを用いたことを特徴とする請求項2
記載のピックル剤組成物。
(5) Claim 2, characterized in that one type or a mixture of two or more types of seaweed extracts is used as the natural gum.
The pickling agent composition described.
(6)熱凝固性蛋白質100重量部に対しカルシウム剤
2〜100重量部を配合したことを特徴とする請求項1
または請求項2記載のピックル剤組成物。
(6) Claim 1 characterized in that 2 to 100 parts by weight of a calcium agent is blended with 100 parts by weight of thermocoagulable protein.
Or the pickling agent composition according to claim 2.
(7)熱凝固性蛋白質100重量部に対し天然ガム類5
〜60重量部を配合したことを特徴とする請求項2記載
のピックル剤組成物。
(7) 5 parts of natural gum per 100 parts by weight of thermocoagulable protein
3. The pickling agent composition according to claim 2, wherein the pickling agent composition contains 60 parts by weight.
JP1063440A 1989-03-17 1989-03-17 Pickling agent composition Pending JPH02245162A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1063440A JPH02245162A (en) 1989-03-17 1989-03-17 Pickling agent composition

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1063440A JPH02245162A (en) 1989-03-17 1989-03-17 Pickling agent composition

Publications (1)

Publication Number Publication Date
JPH02245162A true JPH02245162A (en) 1990-09-28

Family

ID=13229324

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1063440A Pending JPH02245162A (en) 1989-03-17 1989-03-17 Pickling agent composition

Country Status (1)

Country Link
JP (1) JPH02245162A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06217703A (en) * 1992-04-08 1994-08-09 Taiichiro Iwakura Food with gluten as chief material
JPH10165115A (en) * 1996-12-04 1998-06-23 Snow Brand Food Co Ltd Opaque material-containing carrageenin xerogel powder and food containing the same
EP1366677A1 (en) * 2002-05-30 2003-12-03 Ajinomoto Co., Inc. Composition for treatment of whole muscle product and method for producing whole muscle product using said composition
JP2009089686A (en) * 2007-10-11 2009-04-30 Q P Corp Ground meat processed product, sauce mixed with the processed product, method for producing the processed product and the sauce, and ground meat quality modifying agent

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63169961A (en) * 1987-01-06 1988-07-13 San Ei Chem Ind Ltd Processed animal and fish meat
JPS6460354A (en) * 1987-08-31 1989-03-07 Chiba Seifun Kk Quality improver composition for sausage
JPH01144961A (en) * 1987-12-01 1989-06-07 Fuji Oil Co Ltd Pickling liquid for edible meat product

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63169961A (en) * 1987-01-06 1988-07-13 San Ei Chem Ind Ltd Processed animal and fish meat
JPS6460354A (en) * 1987-08-31 1989-03-07 Chiba Seifun Kk Quality improver composition for sausage
JPH01144961A (en) * 1987-12-01 1989-06-07 Fuji Oil Co Ltd Pickling liquid for edible meat product

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06217703A (en) * 1992-04-08 1994-08-09 Taiichiro Iwakura Food with gluten as chief material
JPH10165115A (en) * 1996-12-04 1998-06-23 Snow Brand Food Co Ltd Opaque material-containing carrageenin xerogel powder and food containing the same
EP1366677A1 (en) * 2002-05-30 2003-12-03 Ajinomoto Co., Inc. Composition for treatment of whole muscle product and method for producing whole muscle product using said composition
JP2009089686A (en) * 2007-10-11 2009-04-30 Q P Corp Ground meat processed product, sauce mixed with the processed product, method for producing the processed product and the sauce, and ground meat quality modifying agent

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