JPH02234492A - Manufacture of printed board - Google Patents

Manufacture of printed board

Info

Publication number
JPH02234492A
JPH02234492A JP5575689A JP5575689A JPH02234492A JP H02234492 A JPH02234492 A JP H02234492A JP 5575689 A JP5575689 A JP 5575689A JP 5575689 A JP5575689 A JP 5575689A JP H02234492 A JPH02234492 A JP H02234492A
Authority
JP
Japan
Prior art keywords
glass fiber
resin
printed circuit
prepreg
circuit board
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP5575689A
Other languages
Japanese (ja)
Inventor
Osamu Kasai
修 笠井
Hideki Ishida
秀樹 石田
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fujitsu Ltd
Original Assignee
Fujitsu Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fujitsu Ltd filed Critical Fujitsu Ltd
Priority to JP5575689A priority Critical patent/JPH02234492A/en
Publication of JPH02234492A publication Critical patent/JPH02234492A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To increase a bonding property between a glass fiber and resin and hence reduce generation probability of any crack by subjecting the surface of the close-like glass fiber used as a core material of the surface board to a rough surface treatment. CONSTITUTION:A rough surface treatment is applied onto the surface of a close-like woven glass fiber 11 to form the unevenness thereon. Thereafter, it is impregnated with resin 12 such as epoxy, etc., to form a prepreg 1. The rough surface treatment can be performed by dissolving the surface of the glass fiber with an about 5% concentration hydrogen fluoride(HF) solution. By previously roughening the surface of the glass fiber 11 as such, the bonding property of the fiber to the resin is improved, and hence peeling strength between the prepreg 1 and the glass fiber of the substrate yielded by heating and hardening the prepreg 1, and the resin is increased.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 この発明はプリント基板に関し、特にプリント基板に用
いられるガラス繊維の表面処理に関するものである。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to printed circuit boards, and particularly to surface treatment of glass fibers used in printed circuit boards.

〔概要〕〔overview〕

プリント基板に用いられるガラス繊維の表面処理に関し
、 樹脂とガラス繊維との密着性を改善するとともに、スル
ーホールとなる加工大内でのメッキ層とガラス繊維との
密着性の向上をも図ることを目的とし、 〔従来技術〕 第4図は多層プリント基板の製造工程の一部を示すもの
である。多層プリント基板は布状に編んだガラス繊維に
エポキシ樹脂、あるいはポリイミド樹脂等を含浸するこ
とによってプリブレグが形成され、該プリプレグの表裏
に銅板を張った状態で加工加熱して硬化させ銅張基板が
作成される。
Regarding the surface treatment of glass fiber used in printed circuit boards, we aim to improve the adhesion between the resin and the glass fiber, and also to improve the adhesion between the plating layer and the glass fiber in the processing area that becomes the through hole. [Prior Art] FIG. 4 shows a part of the manufacturing process of a multilayer printed circuit board. Multilayer printed circuit boards are made by impregnating epoxy resin or polyimide resin into cloth-like glass fibers to form a pre-reg, and with copper plates stretched on the front and back sides of the prepreg, the prepreg is heated and cured to form a copper-clad board. Created.

この銅張基板を用いてパターン形成を行って内層基板を
形成し(ステップS1)、このようにして形成された各
内層基板間にブリブレグが挿入されて、積層され、多層
プリント基板が形成される(ステップSZ)。 更に、
このように形成された多層プリント基板の各層のパター
ン間の配線を確保するために、スルーホール、パイアホ
ールが設けられるが、このスルーホール、パイアホール
は穴開け工程(ステップS3)で開けられた加工穴の内
周面に例えばパネルメッキを施す(ステップS4)こと
によって形成される。
This copper-clad board is used to form a pattern to form an inner layer board (step S1), and a blob leg is inserted between each of the inner layer boards thus formed and laminated to form a multilayer printed board. (Step SZ). Furthermore,
In order to secure wiring between the patterns of each layer of the multilayer printed circuit board formed in this way, through holes and pier holes are provided, but these through holes and pier holes are made in the hole drilling process (step S3). It is formed by, for example, applying panel plating to the inner peripheral surface of the processed hole (step S4).

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

ガラス繊維の表面は極めて滑らかであるため、上記によ
うに含浸される樹脂との密着性が悪く、第3図に示すよ
うにガラス繊維11と樹脂12との境界に加工時の機械
的な衝撃によって裸眼では確認できない亀裂Cが発生す
る。
Since the surface of the glass fiber is extremely smooth, it has poor adhesion with the resin impregnated as described above, and as shown in FIG. This causes cracks C that cannot be seen with the naked eye.

このようにして生じた亀裂Cはスルーホール、パイアホ
ール用の穴明け工程によって明けられた加工穴2の内周
壁に対するパネルメッキ(無電解銅メッキ等)の析出を
阻止し、その部分にメッキ欠けが生じて不連続にすると
ともに、亀裂Cに浸透したメッキ液部分Eが洗浄後によ
っても除去されずに絶縁性を劣化させる。
The cracks C generated in this way prevent the deposition of panel plating (electroless copper plating, etc.) on the inner circumferential wall of the processed hole 2 made in the drilling process for through holes and pipe holes, causing plating to be chipped in that area. This causes discontinuity, and the portion E of the plating solution that has penetrated into the crack C is not removed even after cleaning, degrading the insulation.

また、亀裂Cが発生しなかったにしても、加工穴2内に
露出した滑らかなガラス繊維表面にメッキ層を強固に付
着させることは困難であり、この部分だけ剥離しやすい
状態となって、この点でもプリント基板の信頬性を低下
させる。
In addition, even if cracks C do not occur, it is difficult to firmly adhere the plating layer to the smooth glass fiber surface exposed inside the machined hole 2, and this part becomes susceptible to peeling. This also reduces the reliability of the printed circuit board.

この発明は上記従来の事情に鑑みて提案されたものであ
って、樹脂とガラス繊維との密着性を改善するとともに
、スルーホールとなる加工穴内でのメッキ層とガラス繊
維との密着性の向上をも図ることを目的とするものであ
る。
This invention was proposed in view of the above-mentioned conventional circumstances, and it improves the adhesion between the resin and glass fiber, and also improves the adhesion between the plated layer and the glass fiber in the processed hole, which is a through hole. The purpose is to also achieve this goal.

〔課題を解決するための手段〕[Means to solve the problem]

上記目的を達成するためにこの発明は、例えば第1図に
示すようにガラス繊維11の表面を化学的又は物理的に
粗面化した後、樹脂12を含浸したブリブレグ1を使用
するようにしたものであり、また、第2図に示すように
プリント基板の穴明け加工後、該加工穴2の内壁に゜露
出したガラス繊維11の表面を化学的に粗面化した後、
ノ々ネノレメッキするようにしている。
In order to achieve the above object, the present invention uses a brev leg 1 in which the surface of a glass fiber 11 is chemically or physically roughened and then impregnated with a resin 12, as shown in FIG. 1, for example. As shown in FIG. 2, after drilling a printed circuit board, the surface of the glass fiber 11 exposed on the inner wall of the hole 2 is chemically roughened.
I try to plate it with a special coating.

〔作 用〕[For production]

ガラス繊維11の表面を予め粗面化することGこよって
樹脂との密着性がよくなり、ブリプレグ1、及び該ブリ
プレグ1を加熱加圧して硬化させた基板のガラス繊維と
樹脂の引き剥し強度が大きくなる。
By roughening the surface of the glass fiber 11 in advance, the adhesion with the resin is improved, and the peel strength between the glass fiber and resin of the Bripreg 1 and the substrate cured by heating and pressurizing the Bripreg 1 is increased. growing.

また、積層基板へのスルーホール用の穴明け加工によっ
て形成された加工穴2の内周壁に露出したガラス繊維に
粗面化処理をすることによって、この後に行われるメッ
キによるメ・ノキ層のガラス繊維との密着力を向上させ
る。
In addition, by roughening the glass fibers exposed on the inner circumferential wall of the processed hole 2 formed by drilling holes for through holes in the laminated board, the glass of the metal wood layer by plating that will be performed later can be roughened. Improves adhesion with fibers.

〔実施例〕〔Example〕

第1図はこの発明によって成形されたブリプレグ1 (
又はプリプレグlを加熱加圧して硬化させた基板)の断
面図を示すものである。布状に編まれたガラス繊維11
表面に粗面化処理によって凹凸が形成され、その後にエ
ボキシ等の樹脂12が含浸されプリプレグlが形成され
る。上記粗面化処理は例えば5%前後の濃度のフッ化水
素(HF)の溶液により表面を溶解することによって行
うことができる。この方法はガラス繊維の素材として結
晶化ガラスを用い、結晶化部分を上記フッ化水素(H 
F)等で選択的に溶解させて、より短時間に行うことが
できる。また、物理的な方法として微細な砥粒をガラス
繊維表面にぶつける(ホーニング)ことによっても可能
である。
Figure 1 shows a Bripreg 1 (
or a substrate obtained by heating and pressurizing prepreg l to cure it). Glass fiber woven into cloth 11
Irregularities are formed on the surface by roughening treatment, and then a resin 12 such as epoxy is impregnated to form a prepreg l. The above-mentioned surface roughening treatment can be performed by dissolving the surface with a solution of hydrogen fluoride (HF) having a concentration of about 5%, for example. In this method, crystallized glass is used as the material for the glass fiber, and the crystallized portion is
F) can be selectively dissolved and the process can be carried out in a shorter time. Further, as a physical method, it is possible to bombard the glass fiber surface with fine abrasive grains (honing).

これによって樹脂12とガラス繊維11の密着度が向上
し、スルーホール用の加工穴2内での亀裂の発生確率を
少なくすることができ、メッキ欠けの発生、あるいはメ
ッキ液の浸透による絶縁不良を防止できる。上記粗面化
処理は布状体のガラス繊維に対して行うことも、あるい
は布状体にする前の縦横の各ガラス繊維束、あるいはガ
ラス繊維束を構成する各ガラス繊維の単体に対しても行
うことができ、もちろん、ガラス繊維単体に対しての粗
面化が最も大きな効果を期待できる。
This improves the degree of adhesion between the resin 12 and the glass fiber 11, reducing the probability of cracks occurring within the processed hole 2 for the through hole, and preventing insulation defects due to plating chipping or penetration of plating solution. It can be prevented. The above-mentioned surface roughening treatment can be performed on the glass fibers of the cloth-like body, or on each of the vertical and horizontal glass fiber bundles before being made into the cloth-like body, or on each individual glass fiber constituting the glass fiber bundle. Of course, the greatest effect can be expected by roughening the surface of the glass fiber alone.

第2図はこの発明の別の実施例を示すものである。FIG. 2 shows another embodiment of the invention.

第4図に示すように内層基板が形成された後、各内層基
板間にプリプレグが挿入されて積層基板4が形成され、
この後にスルーホール、あるいはパイアホールとなる加
工穴2が形成される。この後、穴開け加工された基板4
に対して本願発明が適用され、前記化学的な方法で該加
工穴2の内壁に露出したガラス繊維11の表面が粗面化
される.その後にパネルメッキがなされる。これによっ
てメッキ層3は樹脂部及びガラス繊維11に強固に付着
し剥離し難くなり、プリント基板の信頼性を向上させる
ことができる。
As shown in FIG. 4, after the inner layer substrates are formed, prepreg is inserted between each inner layer substrate to form the laminated substrate 4,
After this, a processed hole 2 that will become a through hole or a pipe hole is formed. After this, the board 4 with holes drilled
The present invention is applied to this, and the surface of the glass fiber 11 exposed on the inner wall of the processed hole 2 is roughened by the chemical method. Panel plating is then done. As a result, the plating layer 3 firmly adheres to the resin portion and the glass fiber 11 and becomes difficult to peel off, thereby improving the reliability of the printed circuit board.

〔発明の効果〕〔Effect of the invention〕

以上説明したように、この発明はプリント基板の芯材と
して用いられる布状ガラス繊維の表面に粗面化処理をし
ているので、ガラス繊維と樹脂の密着性に優れ、亀裂の
発生確率を少なくすることができる。また、スルーホー
ルとなる穴明けを行った後に、該加工穴の表面に露出し
たガラス繊維に対して、上記粗面化処理をするとメッキ
層とガラス繊維の密着力を高めることができ、メッキ層
の剥離を防止することができる。
As explained above, this invention roughens the surface of the cloth-like glass fiber used as the core material of printed circuit boards, so it has excellent adhesion between the glass fiber and resin and reduces the probability of cracking. can do. In addition, after drilling a hole to become a through hole, if the glass fiber exposed on the surface of the processed hole is subjected to the above-mentioned surface roughening treatment, the adhesion between the plating layer and the glass fiber can be increased, and the plating layer peeling can be prevented.

【図面の簡単な説明】[Brief explanation of drawings]

第1図はこの発明の一実施例を示すプリント基板の断面
図、第2図もこの発明の一実施例を示すプリント基板の
断面図、第3図はプリント基板に使用されるガラス繊維
の斜視図、第4図は従来のプリント基板の製造工程を示
す工程図である。 図中、 2・・・加工穴、    3・・・メッキ層、11・・
・ガラス繊維、  12・・・樹脂。 本発明のプリプレグ(又は基板) 第1図 従来のプリント基板断面図 第3図 本発明の基板 第2図 多層プリント基板製造工程図 第4図
Fig. 1 is a sectional view of a printed circuit board showing an embodiment of the present invention, Fig. 2 is a sectional view of a printed circuit board showing an embodiment of the invention, and Fig. 3 is a perspective view of glass fiber used in the printed board. 4 are process diagrams showing the conventional manufacturing process of a printed circuit board. In the figure, 2... machined hole, 3... plating layer, 11...
・Glass fiber, 12...resin. Prepreg (or substrate) of the present invention Fig. 1 Cross-sectional view of conventional printed circuit board Fig. 3 Substrate of the present invention Fig. 2 Multilayer printed circuit board manufacturing process diagram Fig. 4

Claims (1)

【特許請求の範囲】 〔1〕芯材となるガラス繊維(11)の表面を化学的又
は物理的に粗面化した後、樹脂(12)を含浸したプリ
プレグ(1)を用いて、プリント基板を製造することを
特徴とするプリント基板の製造方法。 〔2〕プリント基板の穴明け加工後、該加工穴(2)内
壁に露出したガラス繊維(11)の表面を化学的に粗面
化した後、メッキすることを特徴とするプリント基板の
製造方法。
[Scope of Claims] [1] After chemically or physically roughening the surface of the glass fiber (11) serving as the core material, the prepreg (1) impregnated with the resin (12) is used to fabricate a printed circuit board. A method for manufacturing a printed circuit board, the method comprising: manufacturing a printed circuit board. [2] A method for producing a printed circuit board, which comprises, after drilling a hole in the printed circuit board, chemically roughening the surface of the glass fiber (11) exposed on the inner wall of the hole (2) and then plating it. .
JP5575689A 1989-03-07 1989-03-07 Manufacture of printed board Pending JPH02234492A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP5575689A JPH02234492A (en) 1989-03-07 1989-03-07 Manufacture of printed board

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP5575689A JPH02234492A (en) 1989-03-07 1989-03-07 Manufacture of printed board

Publications (1)

Publication Number Publication Date
JPH02234492A true JPH02234492A (en) 1990-09-17

Family

ID=13007688

Family Applications (1)

Application Number Title Priority Date Filing Date
JP5575689A Pending JPH02234492A (en) 1989-03-07 1989-03-07 Manufacture of printed board

Country Status (1)

Country Link
JP (1) JPH02234492A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013097127A1 (en) * 2011-12-29 2013-07-04 广东生益科技股份有限公司 Circuit substrate and manufacturing method thereof
CN104703389A (en) * 2013-12-04 2015-06-10 罗伯特·博世有限公司 A method for manufacturing a fiber-resin composite, especially for manufacturing a circuit board

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4833353A (en) * 1971-09-01 1973-05-09
JPS62111493A (en) * 1985-11-08 1987-05-22 ユニチカ株式会社 Treatment of glass cloth
JPS62128196A (en) * 1985-11-28 1987-06-10 日立エーアイシー株式会社 Manufacture of multilayer wiring board
JPS62239593A (en) * 1986-04-08 1987-10-20 インタ−ナショナル ビジネス マシ−ンズ コ−ポレ−ション Method of eliminating contaminant
JPS6321969A (en) * 1986-07-09 1988-01-29 ユニチカ株式会社 Treatment of glass cloth
JPS6321970A (en) * 1986-07-09 1988-01-29 ユニチカ株式会社 Treatment of glass cloth

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4833353A (en) * 1971-09-01 1973-05-09
JPS62111493A (en) * 1985-11-08 1987-05-22 ユニチカ株式会社 Treatment of glass cloth
JPS62128196A (en) * 1985-11-28 1987-06-10 日立エーアイシー株式会社 Manufacture of multilayer wiring board
JPS62239593A (en) * 1986-04-08 1987-10-20 インタ−ナショナル ビジネス マシ−ンズ コ−ポレ−ション Method of eliminating contaminant
JPS6321969A (en) * 1986-07-09 1988-01-29 ユニチカ株式会社 Treatment of glass cloth
JPS6321970A (en) * 1986-07-09 1988-01-29 ユニチカ株式会社 Treatment of glass cloth

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013097127A1 (en) * 2011-12-29 2013-07-04 广东生益科技股份有限公司 Circuit substrate and manufacturing method thereof
US9744745B2 (en) 2011-12-29 2017-08-29 Shengyi Technology Co., Ltd. Circuit substrate and manufacturing method thereof
CN104703389A (en) * 2013-12-04 2015-06-10 罗伯特·博世有限公司 A method for manufacturing a fiber-resin composite, especially for manufacturing a circuit board

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