JPH02225593A - 接触クラッキングから生じたガスの有効利用方法およびガソリンのベンゼン含量の減少方法 - Google Patents
接触クラッキングから生じたガスの有効利用方法およびガソリンのベンゼン含量の減少方法Info
- Publication number
- JPH02225593A JPH02225593A JP1334696A JP33469689A JPH02225593A JP H02225593 A JPH02225593 A JP H02225593A JP 1334696 A JP1334696 A JP 1334696A JP 33469689 A JP33469689 A JP 33469689A JP H02225593 A JPH02225593 A JP H02225593A
- Authority
- JP
- Japan
- Prior art keywords
- fraction
- mordenite
- benzene
- gasoline
- atomic ratio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 title claims abstract description 42
- 238000000034 method Methods 0.000 title claims abstract description 16
- 239000003502 gasoline Substances 0.000 title claims description 12
- 238000004523 catalytic cracking Methods 0.000 title description 6
- 239000003054 catalyst Substances 0.000 claims abstract description 24
- 229910052680 mordenite Inorganic materials 0.000 claims abstract description 19
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000005336 cracking Methods 0.000 claims abstract description 4
- 150000005673 monoalkenes Chemical class 0.000 claims abstract description 4
- 238000004519 manufacturing process Methods 0.000 claims abstract description 3
- 239000002253 acid Substances 0.000 claims description 16
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 9
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 8
- 239000011148 porous material Substances 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 238000002407 reforming Methods 0.000 claims description 2
- 239000000203 mixture Substances 0.000 abstract description 8
- 239000000446 fuel Substances 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract 1
- 238000006057 reforming reaction Methods 0.000 abstract 1
- 239000007787 solid Substances 0.000 description 13
- 238000005804 alkylation reaction Methods 0.000 description 12
- 239000007789 gas Substances 0.000 description 12
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 10
- 230000029936 alkylation Effects 0.000 description 10
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 8
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 8
- 239000010457 zeolite Substances 0.000 description 8
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 7
- 238000001354 calcination Methods 0.000 description 7
- 238000004821 distillation Methods 0.000 description 7
- 150000001336 alkenes Chemical class 0.000 description 6
- 238000009835 boiling Methods 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 5
- 239000005977 Ethylene Substances 0.000 description 5
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 5
- 229910021536 Zeolite Inorganic materials 0.000 description 5
- 229910052782 aluminium Inorganic materials 0.000 description 5
- 239000001273 butane Substances 0.000 description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 5
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 5
- 238000003860 storage Methods 0.000 description 5
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000002243 precursor Substances 0.000 description 4
- 239000001294 propane Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 238000001833 catalytic reforming Methods 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 230000003628 erosive effect Effects 0.000 description 3
- 238000010304 firing Methods 0.000 description 3
- 239000003915 liquefied petroleum gas Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 229910052759 nickel Inorganic materials 0.000 description 3
- 229910017604 nitric acid Inorganic materials 0.000 description 3
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000005194 fractionation Methods 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 238000005342 ion exchange Methods 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- 239000002574 poison Substances 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 206010009691 Clubbing Diseases 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- NBZANZVJRKXVBH-GYDPHNCVSA-N alpha-Cryptoxanthin Natural products O[C@H]1CC(C)(C)C(/C=C/C(=C\C=C\C(=C/C=C/C=C(\C=C\C=C(/C=C/[C@H]2C(C)=CCCC2(C)C)\C)/C)\C)/C)=C(C)C1 NBZANZVJRKXVBH-GYDPHNCVSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 238000010001 crabbing Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000012013 faujasite Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 210000003127 knee Anatomy 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 150000002815 nickel Chemical class 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 125000004817 pentamethylene group Chemical class [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 230000007847 structural defect Effects 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/04—Liquid carbonaceous fuels essentially based on blends of hydrocarbons
- C10L1/06—Liquid carbonaceous fuels essentially based on blends of hydrocarbons for spark ignition
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G29/00—Refining of hydrocarbon oils, in the absence of hydrogen, with other chemicals
- C10G29/20—Organic compounds not containing metal atoms
- C10G29/205—Organic compounds not containing metal atoms by reaction with hydrocarbons added to the hydrocarbon oil
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR8817164A FR2640994B1 (fr) | 1988-12-22 | 1988-12-22 | |
| FR8817164 | 1988-12-22 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02225593A true JPH02225593A (ja) | 1990-09-07 |
Family
ID=9373408
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1334696A Pending JPH02225593A (ja) | 1988-12-22 | 1989-12-22 | 接触クラッキングから生じたガスの有効利用方法およびガソリンのベンゼン含量の減少方法 |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP0375547B1 (fr) |
| JP (1) | JPH02225593A (fr) |
| KR (1) | KR930006819B1 (fr) |
| AT (1) | ATE77640T1 (fr) |
| CA (1) | CA2006550A1 (fr) |
| DE (1) | DE68901921T2 (fr) |
| ES (1) | ES2034718T3 (fr) |
| FR (1) | FR2640994B1 (fr) |
| GR (1) | GR3005500T3 (fr) |
| ZA (1) | ZA899770B (fr) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2033250C (fr) * | 1990-01-16 | 1998-08-18 | Lawrence A. Smith, Jr. | Procede pour ameliorer l'indice d'octane |
| US5252197A (en) * | 1992-09-28 | 1993-10-12 | Abb Lummus Crest Inc. | Process for upgrading gasolines and other hydrocarbon mixtures |
| IT1397886B1 (it) | 2009-12-23 | 2013-02-04 | Eni Spa | Procedimento per la produzione di componenti di carburanti per autotrazione. |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4140622A (en) * | 1977-11-03 | 1979-02-20 | Uop Inc. | Process to reduce the benzene content of gasoline |
| FR2519335B1 (fr) * | 1982-01-04 | 1986-05-02 | Azote & Prod Chim | Production d'hydrocarbures a partir de methanol en presence de catalyseurs du type zeolithe |
-
1988
- 1988-12-22 FR FR8817164A patent/FR2640994B1/fr not_active Expired - Fee Related
-
1989
- 1989-12-19 AT AT89403571T patent/ATE77640T1/de not_active IP Right Cessation
- 1989-12-19 ES ES198989403571T patent/ES2034718T3/es not_active Expired - Lifetime
- 1989-12-19 EP EP89403571A patent/EP0375547B1/fr not_active Expired - Lifetime
- 1989-12-19 DE DE8989403571T patent/DE68901921T2/de not_active Expired - Lifetime
- 1989-12-20 ZA ZA899770A patent/ZA899770B/xx unknown
- 1989-12-21 KR KR1019890019367A patent/KR930006819B1/ko not_active IP Right Cessation
- 1989-12-22 JP JP1334696A patent/JPH02225593A/ja active Pending
- 1989-12-22 CA CA002006550A patent/CA2006550A1/fr not_active Abandoned
-
1992
- 1992-08-20 GR GR920401842T patent/GR3005500T3/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ZA899770B (en) | 1990-09-26 |
| ES2034718T3 (es) | 1993-04-01 |
| FR2640994B1 (fr) | 1993-05-14 |
| CA2006550A1 (fr) | 1990-06-22 |
| ATE77640T1 (de) | 1992-07-15 |
| EP0375547B1 (fr) | 1992-06-24 |
| KR930006819B1 (ko) | 1993-07-24 |
| EP0375547A1 (fr) | 1990-06-27 |
| DE68901921T2 (de) | 1992-12-10 |
| GR3005500T3 (fr) | 1993-05-24 |
| DE68901921D1 (de) | 1992-07-30 |
| KR900009942A (ko) | 1990-07-06 |
| FR2640994A1 (fr) | 1990-06-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US8247631B2 (en) | Process for catalytic cracking of hydrocarbons using UZM-35 | |
| JP4767393B2 (ja) | オレフィン類の製造 | |
| JP4767392B2 (ja) | オレフィン類の製造 | |
| JP4048459B2 (ja) | オレフイン類の製造 | |
| JP4767394B2 (ja) | オレフィンの製造 | |
| KR100572842B1 (ko) | 올레핀 전환반응용 촉매의 제조 방법 | |
| JP4864179B2 (ja) | オレフイン類の製造 | |
| KR100803993B1 (ko) | 프로필렌의 제법 | |
| KR101217915B1 (ko) | 에탄올로부터의 올레핀의 제조 방법 | |
| US6646175B1 (en) | Production of olefins | |
| CN101795766B (zh) | 磷改性分子筛上的烯烃裂化 | |
| US20110105815A1 (en) | Process to Make Olefins from Ethanol | |
| EA016179B1 (ru) | Модифицированные фосфором молекулярные сита и их применение в конверсии органических соединений в олефины | |
| US7981273B2 (en) | Process for catalytic cracking of hydrocarbons using UZM-35 | |
| Maftei et al. | Conversion of industrial feedstock mainly with butanes and butenes over HZSM-5 and Zn/HZSM-5 (nitrate) catalysts | |
| JP7440530B2 (ja) | メソ多孔性触媒化合物及びその使用 | |
| US4902847A (en) | Method for producing olefin oligomers using a modified mordenite based catalyst | |
| US8157985B2 (en) | Process for catalytic cracking of hydrocarbons using UZM-35HS | |
| JPH02225593A (ja) | 接触クラッキングから生じたガスの有効利用方法およびガソリンのベンゼン含量の減少方法 | |
| EP2039427A1 (fr) | Craquage d'oléfines sur des tamis moléculaires modifiés au phosphore | |
| WO2024073706A1 (fr) | Procédé de production de propylène à partir de gaz sec de raffinerie | |
| JPS6338077B2 (fr) |