JPH02207032A - Azeotropic mixture and azeotrope-like mixture of dichloropentafluoropropane - Google Patents
Azeotropic mixture and azeotrope-like mixture of dichloropentafluoropropaneInfo
- Publication number
- JPH02207032A JPH02207032A JP1025647A JP2564789A JPH02207032A JP H02207032 A JPH02207032 A JP H02207032A JP 1025647 A JP1025647 A JP 1025647A JP 2564789 A JP2564789 A JP 2564789A JP H02207032 A JPH02207032 A JP H02207032A
- Authority
- JP
- Japan
- Prior art keywords
- mixture
- dichloroethylene
- weight
- dichloro
- pentafluoropropane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 25
- COAUHYBSXMIJDK-UHFFFAOYSA-N 3,3-dichloro-1,1,1,2,2-pentafluoropropane Chemical compound FC(F)(F)C(F)(F)C(Cl)Cl COAUHYBSXMIJDK-UHFFFAOYSA-N 0.000 title claims abstract description 7
- KFUSEUYYWQURPO-UPHRSURJSA-N cis-1,2-dichloroethene Chemical group Cl\C=C/Cl KFUSEUYYWQURPO-UPHRSURJSA-N 0.000 claims abstract description 10
- 150000002430 hydrocarbons Chemical class 0.000 claims description 7
- 229930195733 hydrocarbon Natural products 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 5
- 239000002904 solvent Substances 0.000 abstract description 7
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 abstract description 4
- UJIGKESMIPTWJH-UHFFFAOYSA-N 1,3-dichloro-1,1,2,2,3-pentafluoropropane Chemical compound FC(Cl)C(F)(F)C(F)(F)Cl UJIGKESMIPTWJH-UHFFFAOYSA-N 0.000 abstract description 3
- 238000004064 recycling Methods 0.000 abstract description 3
- 238000013329 compounding Methods 0.000 abstract 1
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 6
- -1 chlorine radicals Chemical class 0.000 description 6
- AFABGHUZZDYHJO-UHFFFAOYSA-N 2-Methylpentane Chemical compound CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 230000004907 flux Effects 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 239000004604 Blowing Agent Substances 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 239000010721 machine oil Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- HNRMPXKDFBEGFZ-UHFFFAOYSA-N 2,2-dimethylbutane Chemical compound CCC(C)(C)C HNRMPXKDFBEGFZ-UHFFFAOYSA-N 0.000 description 2
- KDSNLYIMUZNERS-UHFFFAOYSA-N 2-methylpropanamine Chemical compound CC(C)CN KDSNLYIMUZNERS-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- RWRIWBAIICGTTQ-UHFFFAOYSA-N difluoromethane Chemical compound FCF RWRIWBAIICGTTQ-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000003380 propellant Substances 0.000 description 2
- 239000003507 refrigerant Substances 0.000 description 2
- FRCHKSNAZZFGCA-UHFFFAOYSA-N 1,1-dichloro-1-fluoroethane Chemical compound CC(F)(Cl)Cl FRCHKSNAZZFGCA-UHFFFAOYSA-N 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical group ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- OPLWDQVQIWKMSG-UHFFFAOYSA-N 1-chloro-1-fluoropropane Chemical compound CCC(F)Cl OPLWDQVQIWKMSG-UHFFFAOYSA-N 0.000 description 1
- JSZOAYXJRCEYSX-UHFFFAOYSA-N 1-nitropropane Chemical compound CCC[N+]([O-])=O JSZOAYXJRCEYSX-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- QQZOPKMRPOGIEB-UHFFFAOYSA-N 2-Oxohexane Chemical compound CCCCC(C)=O QQZOPKMRPOGIEB-UHFFFAOYSA-N 0.000 description 1
- NAMYKGVDVNBCFQ-UHFFFAOYSA-N 2-bromopropane Chemical compound CC(C)Br NAMYKGVDVNBCFQ-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 1
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 231100001231 less toxic Toxicity 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- YKYONYBAUNKHLG-UHFFFAOYSA-N n-Propyl acetate Natural products CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 1
- 125000004971 nitroalkyl group Chemical group 0.000 description 1
- MCSAJNNLRCFZED-UHFFFAOYSA-N nitroethane Chemical compound CC[N+]([O-])=O MCSAJNNLRCFZED-UHFFFAOYSA-N 0.000 description 1
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229940090181 propyl acetate Drugs 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000013020 steam cleaning Methods 0.000 description 1
- 239000005437 stratosphere Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
- 229940029284 trichlorofluoromethane Drugs 0.000 description 1
- 239000005436 troposphere Substances 0.000 description 1
- 238000004506 ultrasonic cleaning Methods 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は１代替フロンとして使用できるとともに溶剤等
として優れた特性を有する新規なフッ素化炭化水素系共
沸混合物及び共沸様混合物に関するものである。[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a novel fluorinated hydrocarbon azeotrope and azeotrope-like mixture that can be used as a CFC substitute and has excellent properties as a solvent. be.
［従来の技術］
フッ素化炭化水素系化合物（以下単にフロンという）は
、毒性が少なく化学的に安定なものが多く、標準沸点の
異なる各種フロンが入手できることから、これらの特性
を活かして溶剤、発泡剤、プロペラントあるいは冷媒等
として１．１．２〜トリクロロ−１，２，２−）リフル
オロエタン（Ｒ１１３）が、発泡剤としてトリクロロモ
ノフルオロメタン（Ｒ１１）が、プロペラントや冷媒と
してジクロロジフルオロメタン（Ｒ１２）が使われてい
る。[Prior Art] Fluorinated hydrocarbon compounds (hereinafter simply referred to as fluorocarbons) are often less toxic and chemically stable, and various types of fluorocarbons with different standard boiling points are available.Using these characteristics, they can be used as solvents, 1.1.2-trichloro-1,2,2-)lifluoroethane (R113) is used as a blowing agent, propellant, or refrigerant, trichloromonofluoromethane (R11) is used as a blowing agent, and dichloromethane is used as a propellant or refrigerant. Difluoromethane (R12) is used.
［発明が解決しようとする課題］
化学的に特に安定なＲ１１、Ｒ１２、Ｒ１１３は対流圏
内での寿命が長く、拡散して成層圏に達し、ここで太陽
光線により分解して発生する塩素ラジカルがオゾンと連
鎖反応を起こし、オゾン層を破壊するとのことから、こ
れら従来のフロンの使用規制が実施されることとなった
。このため、これらの従来のフロンに変わり、オゾン層
を破壊しにくい代替フロンの探索が活発に行なわれてい
る。[Problem to be solved by the invention] R11, R12, and R113, which are particularly stable chemically, have a long life in the troposphere and diffuse into the stratosphere, where they are decomposed by sunlight and generate chlorine radicals, which are converted into ozone. Conventional regulations on the use of these fluorocarbons have been implemented because they are believed to cause a chain reaction and destroy the ozone layer. For this reason, there is active search for alternative fluorocarbons that are less likely to deplete the ozone layer in place of these conventional fluorocarbons.
本発明は、従来のフロンと同等な種々の優れた特性を有
しており代替フロンとして有用な炭素数が３の新規な含
水素クロロフルオロプロパン系フロンを含む混合物を提
供することを目的とするものである。An object of the present invention is to provide a mixture containing a novel hydrogen-containing chlorofluoropropane-based fluorocarbon with a carbon number of 3, which has various excellent properties equivalent to conventional fluorocarbons and is useful as an alternative fluorocarbon. It is something.
［課題を解決するための手段］
本発明は１，１−ジクロロ−２，２，３，３，３−ペン
タフルオロプロパン（Ｒ２２５ｃａ）、１，３−ジクロ
ロ−１，１，２，２，３−ペンタフルオロプロパン（Ｒ
２２５ｃｂ）、及びｃｉｓ−１，２−ジクロロエチレン
からなるフッ素化炭化水素系共沸混合物及び共沸様混合
物に関するものである０本発明の混合物は共沸組成が存
在し、特に洗浄溶剤として従来のＲ１１３単体よりも洗
浄力が高いため、Ｒ１１３代替として極めて有用なもの
である。[Means for Solving the Problems] The present invention provides 1,1-dichloro-2,2,3,3,3-pentafluoropropane (R225ca), 1,3-dichloro-1,1,2,2,3 -pentafluoropropane (R
225cb), and fluorinated hydrocarbon azeotropes and azeotrope-like mixtures consisting of cis-1,2-dichloroethylene. Since it has higher detergency than that of a single substance, it is extremely useful as a substitute for R113.
更に、リサイクルしても組成の変動が少ないこと、又従
来の単一フロンと同じ使い方ができ、従来技術の大幅な
変更を要しないこと等の利点かある。Furthermore, it has the advantage that there is little change in composition even after recycling, it can be used in the same way as conventional single fluorocarbons, and it does not require major changes to the conventional technology.
本発明の混合物としてはＲ２２５ｃａが６〜７０重量％
、Ｒ２２５ｃｂが４〜７４重量％、及びｃ １ｓ−１＋
２−ジクロロエチレンが２０〜３８重量％、好ましく
は、Ｒ２２５ｃａが５３〜６４重景％、重量２５ｃｂが
６〜１７重量％、及びｃｉｓ−１，２−ジクロロエチレ
ンが２４〜３５重量％であり、さらに好ましくは、Ｒ２
２５ｃａの約５８重量％、Ｒ２２５ｃｂの約１２重量％
及び、ｃｉｓ−１，２−ジクロロエチレンの約３０重量
％からなる共沸混合物である。The mixture of the present invention contains 6 to 70% by weight of R225ca.
, 4 to 74% by weight of R225cb, and c 1s-1+
2-dichloroethylene is 20 to 38% by weight, preferably R225ca is 53 to 64% by weight, weight 25cb is 6 to 17% by weight, and cis-1,2-dichloroethylene is 24 to 35% by weight, more preferably is R2
Approximately 58% by weight of 25ca, approximately 12% by weight of R225cb
and about 30% by weight of cis-1,2-dichloroethylene.
本発明の混合物には、用途に応じてその他の成分を更に
添加混合することができる０例えば、溶剤としての用途
においては、ペンタン、インペンタン、ヘキサン、イソ
ヘキサン、ネオヘキサン、ヘプタン、イソへブタン、２
．３−ジメチルブタン、シクロペンタン等の炭化水素類
、ニトロメタン、ニトロエタン、ニトロプロパン等のニ
トロアルカン類、ジエチルアミン、トリエチルアミン、
イソプロピルアミン、ブチルアミン、イソブチルアミン
等のアミン類、メタノール、エタノール、ｎ −プロピ
ルアルコール、ｌ−プロピルアルコール、ｎ−ブチルア
ルコール、ｉ−ブチルアルコール、Ｓ−ブチルアルコー
ル、ｔ−ブチルアルコール等のアルコール類、メチルセ
ロソルブ、テトラヒドロフラン、１．４−ジオキサン等
のエーテル類、アセトン、メチルエチルケトン、メチル
ブチルケトン等のケトン類、酢酸エチル、酢酸プロピル
、酢酸ブチル等のエステル類、ジクロロメタン、ｔｒａ
ｎｓ−１，２−ジクロロエチレン、２−ブロモプロパン
等のハロゲン化炭化水素類、その他、１．１−ジクロロ
−１−フルオロエタン等の本発明以外のフロン類等を適
宜添加することができる。Other components may be further added to the mixture of the present invention depending on the use. For example, in the case of use as a solvent, pentane, impentane, hexane, isohexane, neohexane, heptane, isohexane, 2
．． Hydrocarbons such as 3-dimethylbutane and cyclopentane, nitroalkanes such as nitromethane, nitroethane and nitropropane, diethylamine, triethylamine,
Amines such as isopropylamine, butylamine, isobutylamine, alcohols such as methanol, ethanol, n-propyl alcohol, l-propyl alcohol, n-butyl alcohol, i-butyl alcohol, S-butyl alcohol, t-butyl alcohol, Ethers such as methyl cellosolve, tetrahydrofuran, 1,4-dioxane, ketones such as acetone, methyl ethyl ketone, methyl butyl ketone, esters such as ethyl acetate, propyl acetate, butyl acetate, dichloromethane, tra
Halogenated hydrocarbons such as ns-1,2-dichloroethylene and 2-bromopropane, and other fluorocarbons other than those of the present invention such as 1,1-dichloro-1-fluoroethane can be added as appropriate.
Ｒ２２５ｃａ、 Ｒ２２５ｃｂ及び、ｃｉｓ−１，２
−ジクロロエチレンからなる本発明の共沸混合物及び共
沸様混合物は、従来のフロンと同様、熱媒体や発泡剤等
の各種用途に使用でき、特に溶剤として用いた場合、従
来のＲ１１３より高い溶解力を有するため好適である。R225ca, R225cb and cis-1,2
- The azeotrope and azeotrope-like mixture of the present invention consisting of dichloroethylene can be used for various purposes such as heat carriers and blowing agents, similar to conventional fluorocarbons, and especially when used as a solvent, has higher dissolving power than conventional R113. It is suitable because it has the following.
溶剤の具体的な用途としては、フラックス、グリース、
油、ワックス、インキ等の除去剤、塗料用溶剤、抽出剤
、ガラス、セラミックス、プラスチック、ゴム、金属製
各種物品、特にＩＣ部品、電気機器、精密機械、光学レ
ンズ等の洗浄剤や水切り剤等を挙げることができる。洗
浄方法としては、手拭き、浸漬、スプレー 揺動、超音
波洗浄、蒸気洗浄等を採用すればよい。Specific uses of solvents include flux, grease,
Removers for oil, wax, ink, etc., paint solvents, extractants, cleaning agents and draining agents for glass, ceramics, plastics, rubber, various metal products, especially IC parts, electrical equipment, precision machinery, optical lenses, etc. can be mentioned. As cleaning methods, hand wiping, dipping, spray shaking, ultrasonic cleaning, steam cleaning, etc. may be used.
［実施例］ 以下に本発明の実施例を示す。[Example] Examples of the present invention are shown below.
実施例 １
下記の組成からなる溶剤混合物１０００ｇを蒸留フラス
コに入れ、理論段数２０段の精留塔を用い、大気圧下で
蒸留を行なった。Example 1 1000 g of a solvent mixture having the following composition was placed in a distillation flask and distilled under atmospheric pressure using a rectification column with 20 theoretical plates.
（組成） （重量％）Ｒ２２５ｃａ
（沸点５１．３℃）６０Ｒ２２５ｃｂ （沸点５５．
４℃）１０ｃｉｓ−１，２−ジクロロエチレン
３０（沸点６０．６℃）
その結果、留分４００ｇを得た。このものをガスクロマ
トグラフで測定した結果、次の組成であった。(Composition) (Weight%) R225ca
(boiling point 51.3℃) 60R225cb (boiling point 55.
4°C) 10cis-1,2-dichloroethylene
30 (boiling point: 60.6°C) As a result, 400 g of a fraction was obtained. As a result of measuring this product with a gas chromatograph, it had the following composition.
（組成） （重量％）Ｒ２２５ｃａ
５８Ｒ２２５ｃｂ
１２ｃｉｓ−１，２−ジクロロエチレン
３０実施例 ２
本発明の混合物（Ｒ２２５ｃａ／Ｒ２２５ｃｂ／ｃｉｓ
−１，２−ジクロロエチレン・５８重量％／１２重量％
／３０重量％）を用いて機械油の洗浄試験を行なった。(Composition) (Weight%) R225ca
58R225cb
12cis-1,2-dichloroethylene 30 Example 2 Mixture of the present invention (R225ca/R225cb/cis
-1,2-dichloroethylene・58% by weight/12% by weight
/30% by weight) was used to conduct a machine oil cleaning test.
５Ｏ３−３０４のテストピース（２５ｍｍＸ ３０ｍｍ
Ｘ ２ｍａｉＦＥ ）を機械油（日本石油製ＣＱ−３０
）中に浸漬した後、本発明の前記混合物に５分間浸漬し
た。その結果、機械油は、Ｒ１１３と同様、良好に除去
できることが確認された。5O3-304 test piece (25mmX 30mm
X 2maiFE) and machine oil (Nippon Oil CQ-30
) and then immersed in the mixture of the invention for 5 minutes. As a result, it was confirmed that machine oil could be removed as well as R113.
実施例 ３
実施例２の混合物（Ｒ２２５ｃａ／Ｒ２２５ｃｂ／ｃｉ
ｓ−１，２−ジクロロエチレン・５８重量％／１２重量
％／３０重量％）を用いてフラックスの洗浄試験を行な
った。Example 3 Mixture of Example 2 (R225ca/R225cb/ci
A flux cleaning test was conducted using s-1,2-dichloroethylene (58% by weight/12% by weight/30% by weight).
プリント基板全面にフラックス（りムラ製作断裂９１．
５−ＡＬ−４）を塗布し、２００℃の電気炉で２分間焼
成後、本発明の前記混合物に１分間浸漬した。その結果
、フラックスは良好に除去できることが確認された。Flux (uneven fabrication fracture 91.
5-AL-4) was applied and baked for 2 minutes in an electric furnace at 200°C, and then immersed in the mixture of the present invention for 1 minute. As a result, it was confirmed that flux could be removed satisfactorily.
［発明の効果］
本発明のフッ素化炭化水素系混合物は、従来のフロン類
が有している優れた特性と同等以上の特性を有する。又
、共沸点が存在する、リサイクル時に組成変動が少なく
、従来の単一フロンと同じ使い方ができ、従来技術の大
幅な変更を必要とせず、そのまま適用できる等の利点が
ある。[Effects of the Invention] The fluorinated hydrocarbon mixture of the present invention has properties equivalent to or superior to those of conventional fluorocarbons. It also has the advantage of having an azeotropic point, having little compositional variation during recycling, and can be used in the same way as conventional single fluorocarbons, and can be applied as is without requiring major changes to conventional technology.
Claims (1)
ルオロプロパン、１，３−ジクロロ−１，１，２，２，
３−ペンタフルオロプロパン、及びｃｉｓ−１，２−ジ
クロロエチレンからなるフッ素化炭化水素系共沸混合物
。 ２、１，１−ジクロロ−２，２，３，３，３−ペンタフ
ルオロプロパン５８重量％、１，３−ジクロロ−１，１
，２，２，３−ペンタフルオロプロパン１２重量％、及
びｃｉｓ−１，２−ジクロロエチレン３０重量％からな
る請求項１に記載の混合物。 ３、１，１−ジクロロ−２，２，３，３，３−ペンタフ
ルオロプロパン、１，３−ジクロロ−１，１，２，２，
３−ペンタフルオロプロパン、及びｃｉｓ−１，２−ジ
クロロエチレンからなるフッ素化炭化水素系共沸様混合
物。 ４、１，１−ジクロロ−２，２，３，３，３−ペンタフ
ルオロプロパン６〜７０重量％、１，３−ジクロロ−１
，１，２，２，３−ペンタフルオロプロパン４〜７４重
量％、及びｃｉｓ−１，２−ジクロロエチレン２０〜３
８重量％からなる請求項３に記載の混合物。[Claims] 1,1,1-dichloro-2,2,3,3,3-pentafluoropropane, 1,3-dichloro-1,1,2,2,
A fluorinated hydrocarbon azeotrope consisting of 3-pentafluoropropane and cis-1,2-dichloroethylene. 2,1,1-dichloro-2,2,3,3,3-pentafluoropropane 58% by weight, 1,3-dichloro-1,1
2,2,3-pentafluoropropane, and 30% by weight of cis-1,2-dichloroethylene. 3,1,1-dichloro-2,2,3,3,3-pentafluoropropane, 1,3-dichloro-1,1,2,2,
A fluorinated hydrocarbon azeotrope-like mixture consisting of 3-pentafluoropropane and cis-1,2-dichloroethylene. 4,1,1-dichloro-2,2,3,3,3-pentafluoropropane 6-70% by weight, 1,3-dichloro-1
, 4-74% by weight of 1,2,2,3-pentafluoropropane, and 20-3% of cis-1,2-dichloroethylene.
Mixture according to claim 3, consisting of 8% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1025647A JPH02207032A (en) | 1989-02-06 | 1989-02-06 | Azeotropic mixture and azeotrope-like mixture of dichloropentafluoropropane |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1025647A JPH02207032A (en) | 1989-02-06 | 1989-02-06 | Azeotropic mixture and azeotrope-like mixture of dichloropentafluoropropane |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02207032A true JPH02207032A (en) | 1990-08-16 |
Family
ID=12171622
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1025647A Pending JPH02207032A (en) | 1989-02-06 | 1989-02-06 | Azeotropic mixture and azeotrope-like mixture of dichloropentafluoropropane |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02207032A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1991013934A1 (en) * | 1990-03-12 | 1991-09-19 | E.I. Du Pont De Nemours And Company | Ternary azeotropic compositions of dichloropentafluoropropane and trans-1,2-dichloroethylene with methanol or ethanol or isopropanol |
| US5116526A (en) * | 1989-10-06 | 1992-05-26 | Allied-Signal Inc. | Azeotrope-like compositions of dichloropentafluoropropane and 1,2-dichloroethylene |
| US5288819A (en) * | 1989-10-06 | 1994-02-22 | Alliedsignal Inc. | Azeotrope-like compositions of dichloropentafluoropropane and 1,2-dichloroethylene |
-
1989
- 1989-02-06 JP JP1025647A patent/JPH02207032A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5116526A (en) * | 1989-10-06 | 1992-05-26 | Allied-Signal Inc. | Azeotrope-like compositions of dichloropentafluoropropane and 1,2-dichloroethylene |
| US5288819A (en) * | 1989-10-06 | 1994-02-22 | Alliedsignal Inc. | Azeotrope-like compositions of dichloropentafluoropropane and 1,2-dichloroethylene |
| WO1991013934A1 (en) * | 1990-03-12 | 1991-09-19 | E.I. Du Pont De Nemours And Company | Ternary azeotropic compositions of dichloropentafluoropropane and trans-1,2-dichloroethylene with methanol or ethanol or isopropanol |
| US5116525A (en) * | 1990-03-12 | 1992-05-26 | E. I. Du Pont De Nemours And Company | Ternary azeotropic compositions of dichloropentafluoropropane and trans-1,2-dichloroethylene with methanol or ethanol or isopropanol |
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