JPH02207035A - Azeotropic and pseudo-azeotropic composition of dichloropentafluoropropane - Google Patents
Azeotropic and pseudo-azeotropic composition of dichloropentafluoropropaneInfo
- Publication number
- JPH02207035A JPH02207035A JP1025650A JP2565089A JPH02207035A JP H02207035 A JPH02207035 A JP H02207035A JP 1025650 A JP1025650 A JP 1025650A JP 2565089 A JP2565089 A JP 2565089A JP H02207035 A JPH02207035 A JP H02207035A
- Authority
- JP
- Japan
- Prior art keywords
- composition
- dichloro
- azeotropic
- weight
- pentafluoropropane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 29
- COAUHYBSXMIJDK-UHFFFAOYSA-N 3,3-dichloro-1,1,1,2,2-pentafluoropropane Chemical group FC(F)(F)C(F)(F)C(Cl)Cl COAUHYBSXMIJDK-UHFFFAOYSA-N 0.000 title claims abstract description 7
- UJIGKESMIPTWJH-UHFFFAOYSA-N 1,3-dichloro-1,1,2,2,3-pentafluoropropane Chemical compound FC(Cl)C(F)(F)C(F)(F)Cl UJIGKESMIPTWJH-UHFFFAOYSA-N 0.000 claims abstract description 6
- NDKGUMMLYBINOC-UHFFFAOYSA-N 1,2-dichloro-1-fluoroethane Chemical compound FC(Cl)CCl NDKGUMMLYBINOC-UHFFFAOYSA-N 0.000 claims abstract description 4
- 150000002430 hydrocarbons Chemical class 0.000 claims description 6
- 229930195733 hydrocarbon Natural products 0.000 claims description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- UHCBBWUQDAVSMS-UHFFFAOYSA-N fluoroethane Chemical compound CCF UHCBBWUQDAVSMS-UHFFFAOYSA-N 0.000 claims 2
- 239000002904 solvent Substances 0.000 abstract description 10
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 abstract description 4
- 238000004064 recycling Methods 0.000 abstract description 3
- 238000013329 compounding Methods 0.000 abstract 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 5
- 238000009835 boiling Methods 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 230000004907 flux Effects 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 239000004604 Blowing Agent Substances 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 3
- 239000010721 machine oil Substances 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- HNRMPXKDFBEGFZ-UHFFFAOYSA-N 2,2-dimethylbutane Chemical compound CCC(C)(C)C HNRMPXKDFBEGFZ-UHFFFAOYSA-N 0.000 description 2
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical compound CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 description 2
- KDSNLYIMUZNERS-UHFFFAOYSA-N 2-methylpropanamine Chemical compound CC(C)CN KDSNLYIMUZNERS-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- -1 chlorine radicals Chemical class 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000003380 propellant Substances 0.000 description 2
- 239000003507 refrigerant Substances 0.000 description 2
- FRCHKSNAZZFGCA-UHFFFAOYSA-N 1,1-dichloro-1-fluoroethane Chemical compound CC(F)(Cl)Cl FRCHKSNAZZFGCA-UHFFFAOYSA-N 0.000 description 1
- LGXVIGDEPROXKC-UHFFFAOYSA-N 1,1-dichloroethene Chemical group ClC(Cl)=C LGXVIGDEPROXKC-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- OPLWDQVQIWKMSG-UHFFFAOYSA-N 1-chloro-1-fluoropropane Chemical compound CCC(F)Cl OPLWDQVQIWKMSG-UHFFFAOYSA-N 0.000 description 1
- JSZOAYXJRCEYSX-UHFFFAOYSA-N 1-nitropropane Chemical compound CCC[N+]([O-])=O JSZOAYXJRCEYSX-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- QQZOPKMRPOGIEB-UHFFFAOYSA-N 2-Oxohexane Chemical compound CCCCC(C)=O QQZOPKMRPOGIEB-UHFFFAOYSA-N 0.000 description 1
- NAMYKGVDVNBCFQ-UHFFFAOYSA-N 2-bromopropane Chemical compound CC(C)Br NAMYKGVDVNBCFQ-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 239000004338 Dichlorodifluoromethane Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 1
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- YKYONYBAUNKHLG-UHFFFAOYSA-N n-Propyl acetate Natural products CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 1
- 125000004971 nitroalkyl group Chemical group 0.000 description 1
- MCSAJNNLRCFZED-UHFFFAOYSA-N nitroethane Chemical compound CC[N+]([O-])=O MCSAJNNLRCFZED-UHFFFAOYSA-N 0.000 description 1
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229940090181 propyl acetate Drugs 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000013020 steam cleaning Methods 0.000 description 1
- 239000005437 stratosphere Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
- 229940029284 trichlorofluoromethane Drugs 0.000 description 1
- 239000005436 troposphere Substances 0.000 description 1
- 238000004506 ultrasonic cleaning Methods 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5036—Azeotropic mixtures containing halogenated solvents
- C11D7/504—Azeotropic mixtures containing halogenated solvents all solvents being halogenated hydrocarbons
- C11D7/5045—Mixtures of (hydro)chlorofluorocarbons
Abstract
Description
【発明の詳細な説明】
[産業上の利用分野]
本発明は1代替フロンとして使用できるとともに溶剤等
として優れた特性を有する新規なフッ素化炭化水素系共
沸及び擬共沸組成物に関するものである。[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a novel fluorinated hydrocarbon azeotropic and near-azeotropic composition that can be used as a CFC substitute and has excellent properties as a solvent. be.
[従来の技術]
フッ素化炭化水素系化合物(以下単にフロンという)は
、毒性が少なく不燃で化学的に安定なものが多く、標準
沸点の異なる各種フロンが入手できることから、これら
の特性を活かして溶剤、発泡剤、プロペラントあるいは
冷媒等として1、1.2−トリクロロ−1,2,2−)
リフルオロエタン(1113)が、発泡剤としてトリク
ロロモノフルオロメタン(R11)が、プロペラントや
冷媒としてジクロロジフルオロメタン(R12)が使わ
れている。[Prior art] Fluorinated hydrocarbon compounds (hereinafter simply referred to as fluorocarbons) are mostly non-toxic, non-flammable, and chemically stable, and various types of fluorocarbons with different standard boiling points are available. 1,1,2-trichloro-1,2,2-) as a solvent, blowing agent, propellant, refrigerant, etc.
Lifluoroethane (1113) is used, trichloromonofluoromethane (R11) is used as a blowing agent, and dichlorodifluoromethane (R12) is used as a propellant or refrigerant.
[発明が解決しようとする課題]
化学的に特に安定なR11、R12、R113は対流圏
内での寿命が長く、拡散して成層圏に達し、ここで太陽
光線により分解して発生する塩素ラジカルがオゾンと連
鎖反応を起こし、オゾン層を破壊するとのことから、こ
れら従来のフロンの使用規制が実施されることとなった
。このため、これらの従来のフロンに変わり、オゾン層
を破壊しにくい代替フロンの探索が活発に行なわれてい
る。[Problem to be solved by the invention] R11, R12, and R113, which are particularly stable chemically, have a long life in the troposphere and diffuse into the stratosphere, where they are decomposed by sunlight and generate chlorine radicals, which are converted into ozone. Conventional regulations on the use of these fluorocarbons have been implemented because they are believed to cause a chain reaction and destroy the ozone layer. For this reason, there is active search for alternative fluorocarbons that are less likely to deplete the ozone layer in place of these conventional fluorocarbons.
本発明は、従来のフロンと間部な種々の優れた特性を有
しており代替フロンとして有用な炭素数が3の新規な含
水素クロロフルオロプロパン系フロンを含む組成物を提
供することを目的とするものである。An object of the present invention is to provide a composition containing a novel hydrogen-containing chlorofluoropropane-based fluorocarbon having 3 carbon atoms, which has various excellent properties comparable to those of conventional fluorocarbons and is useful as an alternative fluorocarbon. That is.
[課題を解決するための手段]
本発明は1.1−ジクロロ−2,2,3,3,3−ペン
タフルオロプロパン(R225ca)、1.3−ジクロ
ロ−1,1,2,2,3−ペンタフルオロプロパン(R
225cb)、及び1.2−ジクロロ−1−フルオロエ
タン(R141)からなるフッ素化炭化水素系共沸及び
擬共沸組成物に関するものである。[Means for Solving the Problems] The present invention provides 1,1-dichloro-2,2,3,3,3-pentafluoropropane (R225ca), 1,3-dichloro-1,1,2,2,3 -pentafluoropropane (R
225cb) and 1,2-dichloro-1-fluoroethane (R141).
本発明の組成物は不燃性であるとともに共沸組成が存在
し、特に洗浄溶剤として従来のR113単体よりも洗浄
力が高いため、 R113代替として極めて有用なも
のである。The composition of the present invention is nonflammable, has an azeotropic composition, and has higher detergency as a cleaning solvent than conventional R113 alone, so it is extremely useful as a substitute for R113.
更に、リサイクルしても組成の変動が少ないこと、又従
来の単一フロンと同じ使い方ができ、従来技術の大幅な
変更を要しないこと等の利点かある。Furthermore, it has the advantage that there is little change in composition even after recycling, it can be used in the same way as conventional single fluorocarbons, and it does not require major changes to the conventional technology.
本発明の組成物としてはR225caが44〜92重量
%、R225cbが2〜41重量%、及びR141が1
〜17重量%重量ましくは、R225caが78〜89
重量%、R225cbが3〜14重量%重量びR141
が2〜13重量%重量り、さらに好ましくは、R225
caの約84重量%、R225cbの約8重量%及び、
R141の約8重量%からなる共沸組成物である。The composition of the present invention contains 44 to 92% by weight of R225ca, 2 to 41% by weight of R225cb, and 1% by weight of R141.
~17% weight or R225ca is 78-89
Weight%, R225cb is 3-14% by weight and R141
is 2 to 13% by weight, more preferably R225
about 84% by weight of ca, about 8% by weight of R225cb, and
It is an azeotropic composition consisting of about 8% by weight of R141.
本発明の組成物には、用途に応じてその他の成分を更に
添加混合することができる0例えば、溶剤としての用途
においては、ペンタン、イソペンタン、ヘキサン、イソ
ヘキサン、ネオ゛ヘキサン、ヘプタン、イソへブタン、
2,3−ジメチルブタン、シクロベンタン等の炭化水素
類、ニトロメタン、ニトロエタン、ニトロプロパン等の
ニトロアルカン類、ジエチルアミン、トリエチルアミン
、イソプロピルアミン、ブチルアミン、イソブチルアミ
ン等のアミン類、メタノール、エタノール、n −プロ
ピルアルコール、 i−プロピルアルコール、n−ブチ
ルアルコール、i−ブチルアルコール、S−ブチルアル
コール、t−ブチルアルコール等のアルコール類、メチ
ルセロソルブ、テトラヒドロフラン、1.4−ジオキサ
ン等のエーテル類、アセトン、メチルエチルケトン、メ
チルブチルケトン等のケトン類、酢酸エチル、酢酸プロ
ピル、酢酸ブチル等のエステル類、ジクロロメタン、t
rans−1,2−ジクロロエチレン、cis−1,2
−ジクロロエチレン、2−ブロモプロパン等のハロゲン
化炭化水素類、その他、1.1−ジクロロ−1−フルオ
ロエタン等の本発明以外のフロン類等を適宜添加するこ
とができる。Other components may be further added to the composition of the present invention depending on the intended use.For example, when used as a solvent, pentane, isopentane, hexane, isohexane, neohexane, heptane, isohexane, etc. ,
Hydrocarbons such as 2,3-dimethylbutane and cyclobentane, nitroalkanes such as nitromethane, nitroethane, and nitropropane, amines such as diethylamine, triethylamine, isopropylamine, butylamine, and isobutylamine, methanol, ethanol, n-propyl Alcohol, alcohols such as i-propyl alcohol, n-butyl alcohol, i-butyl alcohol, S-butyl alcohol, t-butyl alcohol, ethers such as methyl cellosolve, tetrahydrofuran, 1,4-dioxane, acetone, methyl ethyl ketone, Ketones such as methyl butyl ketone, esters such as ethyl acetate, propyl acetate, butyl acetate, dichloromethane, t
rans-1,2-dichloroethylene, cis-1,2
- Halogenated hydrocarbons such as dichloroethylene and 2-bromopropane, and other fluorocarbons other than those of the present invention such as 1,1-dichloro-1-fluoroethane can be added as appropriate.
R225ca、 R225cb及び、R141からな
る本発明の共沸及び擬共沸組成物は、従来のフロンと同
様、熱媒体や発泡剤等の各種用途に使用でき、特に溶剤
として用いた場合、従来のR113より高い溶解力を有
するなめ好適である。溶剤の具体的な用途としては、フ
ラックス、グリース、油、ワックス、インキ等の除去剤
、塗料用溶剤、抽出剤、ガラス、セラミックス、プラス
チック、ゴム、金属製各種物品、特にIC部品、電気機
器、精密8!11i、光学レンズ等の洗浄剤や水切り剤
等を挙げることができる。洗浄方法としては、手拭き、
浸漬、スプレー 揺動、超音波洗浄、蒸気洗浄等を採用
すればよい。The azeotropic and near-azeotropic compositions of the present invention consisting of R225ca, R225cb, and R141 can be used in various applications such as heating media and blowing agents, similar to conventional fluorocarbons, and especially when used as a solvent, they can be used as a solvent for conventional R113. Licks with higher dissolving power are preferred. Specific uses of solvents include removers for flux, grease, oil, wax, and ink, paint solvents, extractants, glass, ceramics, plastics, rubber, various metal products, especially IC parts, electrical equipment, Examples include cleaning agents for Precision 8!11i, optical lenses, etc., and draining agents. Cleaning methods include hand wiping,
Dipping, spray shaking, ultrasonic cleaning, steam cleaning, etc. may be used.
[実施例] 以下に本発明の実施例を示す。[Example] Examples of the present invention are shown below.
実施例 1
下記の組成からなる溶剤組成物1000gを蒸留フラス
コに入れ、理論段数20段の精留塔を用い、大気圧下で
蒸留を行なった。Example 1 1000 g of a solvent composition having the composition shown below was placed in a distillation flask and distilled under atmospheric pressure using a rectification column with 20 theoretical plates.
(組成) (重量%)R225ca
(沸点51.3℃)80R225cb (沸点55.
4℃)10R141(沸点75.7℃)
10その結果、領分350gを得た。このものをガスク
ロマトグラフで測定した結果、次の組成であった。(Composition) (Weight%) R225ca
(Boiling point 51.3℃) 80R225cb (Boiling point 55.
4℃) 10R141 (boiling point 75.7℃)
10 As a result, 350 g of portion was obtained. As a result of measuring this product with a gas chromatograph, it had the following composition.
(組成) (重量%)R225ca
84R225cb
8R1418
実施例 2
本発明の組成物(R225ca/R225cb/R14
1=84重量%/8重量%/8重量%)を用いて機械油
の洗浄試験を行なった。(Composition) (Weight%) R225ca
84R225cb
8R1418 Example 2 Composition of the present invention (R225ca/R225cb/R14
A machine oil cleaning test was conducted using 1=84% by weight/8% by weight/8% by weight).
5US−304のテストピース(25mmX 30mm
X 2mm厚)を機械油(日本石油製CQ−30)中に
浸漬した後、本発明の前記組成物に5分間浸漬した。そ
の結果、機械油は、R113と同様、良好に除去できる
ことが確認された。5US-304 test piece (25mm x 30mm
X 2 mm thick) was immersed in machine oil (Nippon Oil Co., Ltd. CQ-30) and then immersed in the composition of the present invention for 5 minutes. As a result, it was confirmed that machine oil could be removed as well as R113.
実施例 3
実施例2の組成物(R225ca/R225cb/R1
41=84重量%/8重量%/8重量%)を用いてフラ
ックスの洗浄試験を行なった。Example 3 Composition of Example 2 (R225ca/R225cb/R1
A flux cleaning test was conducted using 41=84% by weight/8% by weight/8% by weight).
プリント基板全面にフラックス(りb5製作所製りム5
−AL−4)を塗布し、200℃の電気炉で2分間焼成
後、本発明の前記混合物に1分間浸漬した。その結果、
フラックスは良好に除去できることが確認された。Flux (Rim 5 manufactured by Rib5 Seisakusho) is applied to the entire printed circuit board.
-AL-4) was applied, baked for 2 minutes in an electric furnace at 200°C, and then immersed in the mixture of the present invention for 1 minute. the result,
It was confirmed that flux could be removed well.
実施例 4
実施例2の組成物(R225ca/R225cb/R1
41=84重量%/8重量%/8重量%)についてタグ
式測定法(JIS−に2265 )に従って測定したと
ころ引火点がなく不燃であることが確認された。Example 4 Composition of Example 2 (R225ca/R225cb/R1
41=84% by weight/8% by weight/8% by weight) was measured according to the tag method (JIS-2265), and it was confirmed that it had no flash point and was nonflammable.
[発明の効果]
本発明のフッ素化炭化水素系組成物は、不燃性で従来の
フロン類が有している優れた特性と同等以上の特性を有
する。又、共沸点が存在する、リサイクル時に組成変動
が少なく、従来の単一フロンと同じ使い方ができ、従来
技術の大幅な変更を必要とせず、そのまま適用できる等
の利点がある。[Effects of the Invention] The fluorinated hydrocarbon composition of the present invention is nonflammable and has properties equivalent to or superior to those of conventional fluorocarbons. It also has the advantage of having an azeotropic point, having little compositional variation during recycling, and can be used in the same way as conventional single fluorocarbons, and can be applied as is without requiring major changes to conventional technology.
Claims (1)
ルオロプロパン、1,3−ジクロロ−1,1,2,2,
3−ペンタフルオロプロパン、及び1,2−ジクロロ−
1−フルオロエタンからなるフッ素化炭化水素系共沸組
成物。 2、1,1−ジクロロ−2,2,3,3,3−ペンタフ
ルオロプロパン84重量%、1,3−ジクロロ−1,1
,2,2,3−ペンタフルオロプロパン8重量%、及び
1,2−ジクロロ−1−フルオロエタン8重量%からな
る請求項1に記載の組成物。 3、1,1−ジクロロ−2,2,3,3,3−ペンタフ
ルオロプロパン、1,3−ジクロロ−1,1,2,2,
3−ペンタフルオロプロパン、及び1,2−ジクロロ−
1−フルオロエタンからなるフッ素化炭化水素系擬共沸
組成物。 4、1,1−ジクロロ−2,2,3,3,3−ペンタフ
ルオロプロパン44〜92重量%、1,3−ジクロロ−
1,1,2,2,3−ペンタフルオロプロパン2〜41
重量%、及び1,2−ジクロロ−1−フルオロエタン1
〜17重量%からなる請求項3に記載の組成物。[Claims] 1,1,1-dichloro-2,2,3,3,3-pentafluoropropane, 1,3-dichloro-1,1,2,2,
3-pentafluoropropane, and 1,2-dichloro-
A fluorinated hydrocarbon azeotropic composition consisting of 1-fluoroethane. 2,1,1-dichloro-2,2,3,3,3-pentafluoropropane 84% by weight, 1,3-dichloro-1,1
, 8% by weight of 2,2,3-pentafluoropropane, and 8% by weight of 1,2-dichloro-1-fluoroethane. 3,1,1-dichloro-2,2,3,3,3-pentafluoropropane, 1,3-dichloro-1,1,2,2,
3-pentafluoropropane, and 1,2-dichloro-
A fluorinated hydrocarbon pseudoazeotropic composition consisting of 1-fluoroethane. 4,1,1-dichloro-2,2,3,3,3-pentafluoropropane 44-92% by weight, 1,3-dichloro-
1,1,2,2,3-pentafluoropropane 2-41
% by weight, and 1,2-dichloro-1-fluoroethane 1
4. A composition according to claim 3 consisting of ~17% by weight.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1025650A JPH02207035A (en) | 1989-02-06 | 1989-02-06 | Azeotropic and pseudo-azeotropic composition of dichloropentafluoropropane |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1025650A JPH02207035A (en) | 1989-02-06 | 1989-02-06 | Azeotropic and pseudo-azeotropic composition of dichloropentafluoropropane |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH02207035A true JPH02207035A (en) | 1990-08-16 |
Family
ID=12171697
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1025650A Pending JPH02207035A (en) | 1989-02-06 | 1989-02-06 | Azeotropic and pseudo-azeotropic composition of dichloropentafluoropropane |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH02207035A (en) |
-
1989
- 1989-02-06 JP JP1025650A patent/JPH02207035A/en active Pending
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