JPH02204464A - 1,3-dichloro-1,1,2,2,3-pentafluoropropane based azeotropic and pseudo-azeotropic mixture - Google Patents
1,3-dichloro-1,1,2,2,3-pentafluoropropane based azeotropic and pseudo-azeotropic mixtureInfo
- Publication number
- JPH02204464A JPH02204464A JP1023768A JP2376889A JPH02204464A JP H02204464 A JPH02204464 A JP H02204464A JP 1023768 A JP1023768 A JP 1023768A JP 2376889 A JP2376889 A JP 2376889A JP H02204464 A JPH02204464 A JP H02204464A
- Authority
- JP
- Japan
- Prior art keywords
- component
- azeotropic
- chloro
- mixture
- methylpropane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 26
- UJIGKESMIPTWJH-UHFFFAOYSA-N 1,3-dichloro-1,1,2,2,3-pentafluoropropane Chemical compound FC(Cl)C(F)(F)C(F)(F)Cl UJIGKESMIPTWJH-UHFFFAOYSA-N 0.000 title claims abstract description 7
- NBRKLOOSMBRFMH-UHFFFAOYSA-N tert-butyl chloride Chemical compound CC(C)(C)Cl NBRKLOOSMBRFMH-UHFFFAOYSA-N 0.000 claims abstract description 12
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 8
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 7
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 6
- AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 claims abstract 2
- UJPMYEOUBPIPHQ-UHFFFAOYSA-N 1,1,1-trifluoroethane Chemical compound CC(F)(F)F UJPMYEOUBPIPHQ-UHFFFAOYSA-N 0.000 claims 2
- FJSRPVWDOJSWBX-UHFFFAOYSA-N 1-chloro-4-[1-(4-chlorophenyl)-2,2,2-trifluoroethyl]benzene Chemical compound C=1C=C(Cl)C=CC=1C(C(F)(F)F)C1=CC=C(Cl)C=C1 FJSRPVWDOJSWBX-UHFFFAOYSA-N 0.000 claims 1
- QTBFPMKWQKYFLR-UHFFFAOYSA-N isobutyl chloride Chemical compound CC(C)CCl QTBFPMKWQKYFLR-UHFFFAOYSA-N 0.000 claims 1
- 239000002904 solvent Substances 0.000 abstract description 6
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 abstract description 5
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 abstract 1
- 238000011086 high cleaning Methods 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 238000009835 boiling Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- 239000004604 Blowing Agent Substances 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- -1 chlorine radicals Chemical class 0.000 description 3
- 238000004140 cleaning Methods 0.000 description 3
- 230000004907 flux Effects 0.000 description 3
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 3
- 239000010721 machine oil Substances 0.000 description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
- KDSNLYIMUZNERS-UHFFFAOYSA-N 2-methylpropanamine Chemical compound CC(C)CN KDSNLYIMUZNERS-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 235000013847 iso-butane Nutrition 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000003380 propellant Substances 0.000 description 2
- 239000003507 refrigerant Substances 0.000 description 2
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- JSZOAYXJRCEYSX-UHFFFAOYSA-N 1-nitropropane Chemical compound CCC[N+]([O-])=O JSZOAYXJRCEYSX-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- QQZOPKMRPOGIEB-UHFFFAOYSA-N 2-Oxohexane Chemical compound CCCCC(C)=O QQZOPKMRPOGIEB-UHFFFAOYSA-N 0.000 description 1
- NAMYKGVDVNBCFQ-UHFFFAOYSA-N 2-bromopropane Chemical compound CC(C)Br NAMYKGVDVNBCFQ-UHFFFAOYSA-N 0.000 description 1
- UENGBOCGGKLVJJ-UHFFFAOYSA-N 2-chloro-1-(2,4-difluorophenyl)ethanone Chemical compound FC1=CC=C(C(=O)CCl)C(F)=C1 UENGBOCGGKLVJJ-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- KFUSEUYYWQURPO-UPHRSURJSA-N cis-1,2-dichloroethene Chemical group Cl\C=C/Cl KFUSEUYYWQURPO-UPHRSURJSA-N 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 1
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 231100001231 less toxic Toxicity 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- YKYONYBAUNKHLG-UHFFFAOYSA-N n-Propyl acetate Natural products CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 1
- 125000004971 nitroalkyl group Chemical group 0.000 description 1
- MCSAJNNLRCFZED-UHFFFAOYSA-N nitroethane Chemical compound CC[N+]([O-])=O MCSAJNNLRCFZED-UHFFFAOYSA-N 0.000 description 1
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229940090181 propyl acetate Drugs 0.000 description 1
- KHMGIQHRSVLFQG-OZVSTBQFSA-M r044n53c06 Chemical compound COS([O-])(=O)=O.C1([C@@H](CO)C(=O)OC2C[C@@H]3[N+]([C@H](C2)[C@@H]2[C@H]3O2)(C)C)=CC=CC=C1 KHMGIQHRSVLFQG-OZVSTBQFSA-M 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N sec-butylidene Natural products CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000013020 steam cleaning Methods 0.000 description 1
- 239000005437 stratosphere Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
- 229940029284 trichlorofluoromethane Drugs 0.000 description 1
- 239000005436 troposphere Substances 0.000 description 1
- 238000004506 ultrasonic cleaning Methods 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は２代替フロンとして使用できるとともに溶剤等
として優れた特性を有する新規なフッ素化炭化水素系共
沸及び共沸様混合物に関するものである。[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a novel fluorinated hydrocarbon azeotrope and azeotrope-like mixture that can be used as a CFC substitute and has excellent properties as a solvent, etc. .
［従来の技術〕
フッ素化炭化水素系化合物（以下単にフロンという）は
、毒性が少なく化学的に安定なものが多く、標準沸点の
異なる各種フロンが入手できることから、これらの特性
を活かして溶剤、発泡剤、プロペラントあるいは冷媒等
として１．１．２− トリクロロ−１，２，２−トリフ
ルオロエタン（Ｒ１１３）が、発泡剤としてトリクロロ
モノフルオロメタン（Ｒ１１）が、プロペラントや冷媒
としてジクロロジフルオロメタン（Ｒ１２）が使われて
いる。[Prior art] Fluorinated hydrocarbon compounds (hereinafter simply referred to as fluorocarbons) are often less toxic and chemically stable, and various types of fluorocarbons with different standard boiling points are available.Using these characteristics, they can be used as solvents, 1.1.2-trichloro-1,2,2-trifluoroethane (R113) is used as a blowing agent, propellant or refrigerant, trichloromonofluoromethane (R11) is used as a blowing agent, and dichlorodifluoro is used as a propellant or refrigerant. Methane (R12) is used.
［発明が解決しようとする課題］
化学的に特に安定なＲ１１、Ｒ１２、Ｒ１１３は対流圏
内での寿命が長く、拡散して成層圏に達し、ここで太陽
光線により分解して発生する塩素ラジカルがオゾンと連
鎖反応を起こし、オゾン層を破壊するとのことから、こ
れら従来のフロンの使用規制が実施されることとなった
。このため、これらの従来のフロンに変わり、オゾン層
を破壊しにくい代替フロンの探索が活発に行なわれてい
る。[Problem to be solved by the invention] R11, R12, and R113, which are particularly stable chemically, have a long life in the troposphere and diffuse into the stratosphere, where they are decomposed by sunlight and generate chlorine radicals, which are converted into ozone. Conventional regulations on the use of these fluorocarbons have been implemented because they are believed to cause a chain reaction and destroy the ozone layer. For this reason, there is active search for alternative fluorocarbons that are less likely to deplete the ozone layer in place of these conventional fluorocarbons.
本発明は、従来のフロンの使用量を低減し、且つ該フロ
ンが有している優れた特性を満足しながら代替フロンと
して使用できる新規なフロン混合物を提供することを目
的とするものである。An object of the present invention is to provide a new fluorocarbon mixture that can be used as a fluorocarbon substitute while reducing the amount of conventional fluorocarbons used and satisfying the excellent properties of the fluorocarbons.
［課題を解決するための手段］
本発明は１，３−ジクロロ−１，１，２，２，３−ペン
タフルオロプロパン（Ｒ２２５ｃｂ）、１．１．２−
トリクロロ−１，２，２−トリフルオロエタン（Ｒ１１
３）、及び２−クロロ−２−メチルプロパンからなるフ
ッ素化炭化水素系共沸及び共沸様混合物に関するもので
ある０本発明の混合物は共沸組成が存在し、特に洗浄溶
剤として従来のＲ１１３単体より洗浄力が高いため、Ｒ
１１３代替として極めて有用なものである。[Means for Solving the Problems] The present invention provides 1,3-dichloro-1,1,2,2,3-pentafluoropropane (R225cb), 1.1.2-
Trichloro-1,2,2-trifluoroethane (R11
3), and fluorinated hydrocarbon azeotropic and azeotrope-like mixtures consisting of 2-chloro-2-methylpropane. R
It is extremely useful as an alternative to 113.
更に、リサイクルしても組成の変動が少ないこと、又従
来の単一フロンと同じ使い方ができ、従来技術の大幅な
変更を要しないこと等の利点がある。Furthermore, it has the advantage that there is little change in composition even after recycling, and it can be used in the same way as conventional single fluorocarbons, without requiring major changes to the conventional technology.
本発明の混合物としてはＲ２２５ｃｂが１７〜３８重量
％、Ｒ１１３が４１〜７５重量％、及び２−クロロ−２
−メチルプロパンが２〜２１重量％、好ましくは、Ｒ２
２５ｃｂが２６〜３６重量％、Ｒ１１３が５３〜６３重
量％、及び２−クロロ−２−メチルプロパンが６〜１６
重１％であり、さらに好ましくは、Ｒ２２５ｃｂの約３
１重量％、Ｒ１１３の約５８重量％及び、２−クロロ−
２−メチルプロパンの約１１重量％の共沸組成である。The mixture of the present invention contains 17-38% by weight of R225cb, 41-75% by weight of R113, and 2-chloro-2
- 2 to 21% by weight of methylpropane, preferably R2
26-36% by weight of 25cb, 53-63% by weight of R113, and 6-16% of 2-chloro-2-methylpropane.
1% by weight, more preferably about 3% by weight of R225cb.
1% by weight, about 58% by weight of R113 and 2-chloro-
It has an azeotropic composition of about 11% by weight of 2-methylpropane.
本発明の混合物には、用途に応じてその他の成分を更に
添加混合することができる０例えば、溶剤としての用途
においては、ペンタン、イソペンタン、ヘキサン、イソ
ヘキサン、ネオヘキサン、ヘプタン、イソへブタン、２
．３−ジメチルブタン、シクロペンタン等の炭化水素類
、ニトロメタン、ニトロエタン、ニトロプロパン等のニ
トロアルカン類、ジエチルアミン、トリエチルアミン、
イソプロピルアミン、ブチルアミン、イソブチルアミン
等のアミン類、メタノール、エタノール、ｎ−プロピル
アルコール、 ｉ−プロピルアルコール、ｎ−ブチルア
ルコール、ｉ−ブチルアルコール、Ｓ−ブチルアルコー
ル、ｔ−ブチルアルコール等のアルコール類、メチルセ
ロソルブ、テトラヒドロフラン、１．４−ジオキサン等
のエーテル類、アセトン、メチルエチルケトン、メチル
ブチルケトン等のケトン類、酢酸エチル、酢酸プロピル
、酢酸ブチル等のエステル類、ジクロロメタン、ｔｒａ
ｎｓ〜１．２−ジクロロエチレン、ｃｉｓ−１，２−ジ
クロロエチレン、２−ブロモプロパン等のハロゲン化炭
化水素類、その他、１．ｌ−ジクロロ−１−フルオロエ
タン等の本発明以外のフロン類等を適宜添加することが
できる。Other components may be further added to the mixture of the present invention depending on the application.
．． Hydrocarbons such as 3-dimethylbutane and cyclopentane, nitroalkanes such as nitromethane, nitroethane and nitropropane, diethylamine, triethylamine,
Amines such as isopropylamine, butylamine, isobutylamine, alcohols such as methanol, ethanol, n-propyl alcohol, i-propyl alcohol, n-butyl alcohol, i-butyl alcohol, S-butyl alcohol, t-butyl alcohol, Ethers such as methyl cellosolve, tetrahydrofuran, 1,4-dioxane, ketones such as acetone, methyl ethyl ketone, methyl butyl ketone, esters such as ethyl acetate, propyl acetate, butyl acetate, dichloromethane, tra
Halogenated hydrocarbons such as ns-1,2-dichloroethylene, cis-1,2-dichloroethylene, 2-bromopropane, etc., 1. Fluorocarbons other than those of the present invention, such as 1-dichloro-1-fluoroethane, can be added as appropriate.
Ｒ２２５ｃｂ、 Ｒ１１３及び、２−クロロ−２−メ
チルプロパンからなる本発明の共沸及び共沸様混合物は
、従来のフロンと同様、熱媒体や発泡剤等の各種用途に
使用でき、特に溶剤として用いた場合、従来のＲ１１３
より高い溶解力を有するため好適である。溶剤の具体的
な用途としては、フラックス、グリース、油、ワックス
、インキ等の除去剤、塗料用溶剤、抽出剤、ガラス、セ
ラミックス、プラスチック、ゴム、金属製各種物品、特
にＩＣ部品、電気機器、精密機械、光学レンズ等の洗浄
剤や水切り剤等を挙げることができる。洗浄方法として
は、手拭き、浸漬、スプレー 揺動、超音波洗浄、蒸気
洗浄等を採用すればよい。The azeotrope and azeotrope-like mixture of the present invention consisting of R225cb, R113, and 2-chloro-2-methylpropane can be used in various applications such as heat carriers and blowing agents, in the same way as conventional fluorocarbons, and in particular can be used as a solvent. If so, the conventional R113
It is preferable because it has higher dissolving power. Specific uses of solvents include removers for flux, grease, oil, wax, and ink, paint solvents, extractants, glass, ceramics, plastics, rubber, various metal products, especially IC parts, electrical equipment, Examples include cleaning agents and draining agents for precision instruments, optical lenses, etc. As cleaning methods, hand wiping, dipping, spray shaking, ultrasonic cleaning, steam cleaning, etc. may be used.
［実施例］ 以下に本発明の実施例を示す。[Example] Examples of the present invention are shown below.
実施例 １
下記の組成からなる溶剤混合物１０００ｇを蒸留フラス
コに入れ、理論段数２０段の精留塔を用い、大気圧下で
蒸留を行なった。Example 1 1000 g of a solvent mixture having the following composition was placed in a distillation flask and distilled under atmospheric pressure using a rectification column with 20 theoretical plates.
（組成） （重量％）Ｒ２２５ｃｂ
（沸点５５．４℃）３０Ｒ１１３（沸点４７．６℃）
６０
２−クロロ−２−メチルプロパン １０（沸点５
０．７℃）
その結果、留分４００ｇを得た。このものをガスクロマ
トグラフで測定した結果、次の組成であった。(Composition) (% by weight) R225cb
(boiling point 55.4℃) 30R113 (boiling point 47.6℃)
60 2-chloro-2-methylpropane 10 (boiling point 5
0.7° C.) As a result, 400 g of fraction was obtained. As a result of measuring this product with a gas chromatograph, it had the following composition.
（組成） （重量％）Ｒ２２５ｃｂ
３１Ｒ１１３５８
２−クロロ−２−メチルプロパン １１実施例 ２
本発明の混合物（Ｒ２２５ｃｂ／Ｒ１１３／２−クロロ
−２−メチルプ置型ン−３１重景％１５８重量％／１１
重景％）を用いて機械油の洗浄試験を行なった。(Composition) (% by weight) R225cb
31R11358 2-Chloro-2-methylpropane 11 Example 2 Mixture of the present invention (R225cb/R113/2-chloro-2-methylpropane) 158% by weight/11
A machine oil cleaning test was carried out using the following.
５Ｏ５−３０４のテストピース（２５＋＋ｕｌＩＸ ３
０ｍｍＸ ２ｒｎｍＮ）を機械油（日本石油製ＣＱ−３
０）中に浸漬した後、本発明の前記混合物に５分間浸漬
した。その結果、機械油は、Ｒ１１３と同様、良好に除
去できることが確認された。5O5-304 test piece (25++ulIX 3
0mm x 2rnmN) with machine oil (Nippon Oil CQ-3
0) and then immersed in the mixture of the present invention for 5 minutes. As a result, it was confirmed that machine oil could be removed as well as R113.
実施例 ３
実施例２の混合物（Ｒ２２５ｃｂ／Ｒ１１３／２−クロ
ロ−２−メチルプロパン・３１重量％１５８重量％／１
１重量％）を用いてフラックスの洗浄試験を行なった。Example 3 Mixture of Example 2 (R225cb/R113/2-chloro-2-methylpropane 31% by weight 158% by weight/1
A flux cleaning test was conducted using 1% by weight).
゛プリント基板全面にフラックス（りｂう製作所要りＡ
２−ＡＬ−４）を塗布し、２００℃の電気炉で２分間焼
成後、本発明の前記混合物に１分間浸漬した。その結果
、フラックスは良好に除去できることが確認された。゛Flux is applied to the entire surface of the printed circuit board (Requires Rib Manufacturing A)
2-AL-4) was applied and baked for 2 minutes in an electric furnace at 200°C, and then immersed in the mixture of the present invention for 1 minute. As a result, it was confirmed that flux could be removed satisfactorily.
［発明の効果］
本発明のフッ素化炭化水素系混合物は、従来のフロン類
が有している優れた特性を満足しながら該フロンの使用
量が低減できるとともに、共沸点が存在するため、リサ
イクル時に組成変動がない、従来の単一フロンと同じ使
い方でき、従来技術の大幅な変更を要しない等の利点が
ある。[Effects of the Invention] The fluorinated hydrocarbon mixture of the present invention can reduce the amount of fluorocarbon used while satisfying the excellent properties of conventional fluorocarbons, and has an azeotropic point, making it easy to recycle. It has the advantage that there is no change in composition, it can be used in the same way as conventional single fluorocarbons, and it does not require major changes to conventional technology.
Claims (1)
ルオロプロパン、１，１，２−トリクロロ−１，２，２
−トリフルオロエタン、及び２−クロロ−２−メチルプ
ロパンからなるフッ素化炭化水素系共沸混合物。 ２、１，３−ジクロロ−１，１，２，２，３−ペンタフ
ルオロプロパン３１重量％、１，１，２−トリクロロ−
１，２，２−トリフルオロエタン５８重量％、及び２−
クロロ−２−メチルプロパン１１重量％からなる請求項
１に記載の混合物。 ３、１，３−ジクロロ−１，１，２，２，３−ペンタフ
ルオロプロパン、１，１，２−トリクロロ−１，２，２
−トリフルオロエタン、及び２−クロロ−２−メチルプ
ロパンからなるフッ素化炭化水素系共沸様混合物。 ４、１，３−ジクロロ−１，１，２，２，３−ペンタフ
ルオロプロパン１７〜３８重量％、１，１，２−トリク
ロロ−１，２，２−トリフルオロエタン４１〜７５重量
％、及び２−クロロ−２−メチルプロパン２〜２１重量
％からなる請求項３に記載の混合物。[Claims] 1,1,3-dichloro-1,1,2,2,3-pentafluoropropane, 1,1,2-trichloro-1,2,2
-A fluorinated hydrocarbon azeotrope consisting of trifluoroethane and 2-chloro-2-methylpropane. 2,1,3-dichloro-1,1,2,2,3-pentafluoropropane 31% by weight, 1,1,2-trichloro-
58% by weight of 1,2,2-trifluoroethane, and 2-
A mixture according to claim 1, consisting of 11% by weight of chloro-2-methylpropane. 3,1,3-dichloro-1,1,2,2,3-pentafluoropropane, 1,1,2-trichloro-1,2,2
-A fluorinated hydrocarbon azeotrope-like mixture consisting of trifluoroethane and 2-chloro-2-methylpropane. 4,1,3-dichloro-1,1,2,2,3-pentafluoropropane 17-38% by weight, 1,1,2-trichloro-1,2,2-trifluoroethane 41-75% by weight, and 2-21% by weight of 2-chloro-2-methylpropane.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1023768A JPH02204464A (en) | 1989-02-03 | 1989-02-03 | 1,3-dichloro-1,1,2,2,3-pentafluoropropane based azeotropic and pseudo-azeotropic mixture |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1023768A JPH02204464A (en) | 1989-02-03 | 1989-02-03 | 1,3-dichloro-1,1,2,2,3-pentafluoropropane based azeotropic and pseudo-azeotropic mixture |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02204464A true JPH02204464A (en) | 1990-08-14 |
Family
ID=12119526
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1023768A Pending JPH02204464A (en) | 1989-02-03 | 1989-02-03 | 1,3-dichloro-1,1,2,2,3-pentafluoropropane based azeotropic and pseudo-azeotropic mixture |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02204464A (en) |
-
1989
- 1989-02-03 JP JP1023768A patent/JPH02204464A/en active Pending
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