JPH0219571A - Heat-retentive cloth - Google Patents

Heat-retentive cloth

Info

Publication number
JPH0219571A
JPH0219571A JP16904388A JP16904388A JPH0219571A JP H0219571 A JPH0219571 A JP H0219571A JP 16904388 A JP16904388 A JP 16904388A JP 16904388 A JP16904388 A JP 16904388A JP H0219571 A JPH0219571 A JP H0219571A
Authority
JP
Japan
Prior art keywords
fabric
cloth
heat
resin
substance
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP16904388A
Other languages
Japanese (ja)
Other versions
JP2728438B2 (en
Inventor
Fumio Shibata
二三男 柴田
Shunzo Kawasaki
俊三 川崎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Teijin Ltd
Original Assignee
Teijin Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Teijin Ltd filed Critical Teijin Ltd
Priority to JP63169043A priority Critical patent/JP2728438B2/en
Publication of JPH0219571A publication Critical patent/JPH0219571A/en
Application granted granted Critical
Publication of JP2728438B2 publication Critical patent/JP2728438B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Laminated Bodies (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

PURPOSE:To obtain the title cloth capable of raising cloth temperature by laminating the surface of a cloth containing a near infrared ray-absorptive substance capable of absorbing rays falling within the specified wavelength range with a resin or film containing a substance of specific infrared emissivity. CONSTITUTION:The objective cloth can be obtained by laminating the surface of a cloth made of fiber incorporated with a near infrared ray-absorptive substance capable of absorbing rays falling within the wavelength range 700-2,000mum with a resin or film containing a substance >=0.4 in infrared emissivity (e.g. siliconium) (e.g. moisture-permeable film of polyurethane resin).

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は、保温性布帛に関する。[Detailed description of the invention] (Industrial application field) The present invention relates to a heat retaining fabric.

(従来技術) 従来から、織物1編物、不織布等の布帛の保温性を高め
るために布帛自体の厚さを増すものや、布帛の表面を起
毛して布帛の空気含有率を増加させるもの等が知られて
いた。
(Prior art) Conventionally, fabrics such as knitted fabrics and non-woven fabrics have been made by increasing the thickness of the fabric itself in order to improve its heat retention properties, and by raising the surface of the fabric to increase the air content of the fabric. It was known.

しかし、これらの布帛は布帛自体が厚いため、重いこと
や、起毛しているためた嵩ぼる等の欠点がありその用途
も限られていた。一方、布帛に樹脂をコーティングした
り、フィルムをラミネートする手段により保温性を上げ
る方法が知られていいる。これらは布帛の通気性を低く
し、対流による熱損失を少くして保温性を上げる方法で
ある。
However, since these fabrics are thick, they have disadvantages such as being heavy and being bulky due to raised naps, and their uses are limited. On the other hand, there are known methods of increasing heat retention by coating a fabric with a resin or laminating a film. These methods lower the breathability of the fabric to reduce heat loss due to convection and increase heat retention.

さらに、該樹脂やフィルムとして、アルミニューム等の
金属粉末を含有するものを用いることも行なわれている
。これは通気性を低くすることに加えて金属粉末が有す
る体からの輻射熱に対する反射率が高い性質を利用して
衣服の内側の保温性を上げる方法である。
Furthermore, resins and films containing metal powders such as aluminum have also been used. In addition to lowering breathability, this method uses the property of metal powder to have a high reflectivity against radiant heat from the body to increase heat retention inside clothing.

又、樹脂やフィルムと金属粉末の組合せにおいて、該金
属粉末の代りにセラミックス粉末を組合せることも行な
われている。この場合は、通気性を低くすることと衣服
に内側に用いて、セラミックス粉末の体からの輻射熱(
遠赤外等)の放射性を利用した保温方法と考えられでい
る。
Furthermore, in the combination of resin or film and metal powder, ceramic powder is also used instead of the metal powder. In this case, the radiant heat from the body of the ceramic powder (
It is thought to be a heat retention method that utilizes radioactivity (far infrared, etc.).

放射性等の熱的性質はセラミックス自体の組成で決まる
もので一般に高い放射特性値を持ったものが選ばれる。
Thermal properties such as radioactivity are determined by the composition of the ceramic itself, and ceramics with high radiation characteristics are generally selected.

しかしながら、これらの金属粉末やセラミックスを用い
て、コーティング又は、ラミネートした布帛を衣服内側
に用いた場合、これらの金属粉末やセラミックスを含有
する樹脂はせいぜい人体からの放射熱を利用するにすぎ
ず、その保温性には限界がある。
However, when fabrics coated or laminated with these metal powders and ceramics are used on the inside of clothing, the resin containing these metal powders and ceramics can only utilize radiant heat from the human body. There are limits to its heat retention.

(発明の目的) 本発明の目的は、布帛表面からの太陽放射等の熱を積極
的に蓄熱し、さらに効率的に衣服の内部に熱放射するこ
とができる保温性の布帛を提供することにある。
(Object of the Invention) An object of the present invention is to provide a heat-retaining fabric that can actively store heat such as solar radiation from the surface of the fabric and more efficiently radiate heat into the inside of clothing. be.

(発明の構成) 本発明は、波長領域700ミリミクロン〜2000ミリ
ミクロンの範囲で吸収能を有する近赤外線吸収物質を含
有する布帛の表面に赤外線放射率が0.4以上の物質を
含有する樹脂若しくは、フィルムが積層されていること
を特徴とする保温性布帛にある。
(Structure of the Invention) The present invention provides a resin containing a substance with an infrared emissivity of 0.4 or more on the surface of a fabric containing a near-infrared absorbing substance having an absorption ability in a wavelength range of 700 millimicrons to 2000 millimicrons. Alternatively, it is a heat-retaining fabric characterized by being laminated with films.

本発明に使用する700mμから2000mμの波長領
域に吸収能のある近赤外線吸収物質としてはアンソラキ
ノン系化合物、ナフタロシアニン化合物。
Near-infrared absorbing substances having absorption ability in the wavelength region of 700 mμ to 2000 mμ used in the present invention include anthoraquinone compounds and naphthalocyanine compounds.

金属錯体化合物が有効に使用される。Metal complex compounds are effectively used.

かかる近赤外吸収性物質を含有する布帛を得るには、 ■ 合成繊維のポリマーに該近赤外吸収物質をブレンド
した後、通常の方法で繊維となし、この繊維を全部又は
一部に使用して通常の方法で織編し、必要に応じ染色及
び仕上加工を行って得るもの。
In order to obtain a fabric containing such a near-infrared absorbing substance, the following steps can be taken: (1) After blending the near-infrared absorbing substance with a synthetic fiber polymer, it is made into fibers by a conventional method, and this fiber is used in whole or in part. It is obtained by weaving and knitting in the usual way, and dyeing and finishing as necessary.

■ 布帛を該近赤外線吸収物資を含む水中又は溶媒中で
浸漬処理し、吸着させて得る。
(2) It is obtained by immersing a fabric in water or a solvent containing the near-infrared absorbing material and adsorbing it.

この場合の吸着処理は、通常の染色と同時に、又は染色
の前又は後に行っても良い。
In this case, the adsorption treatment may be performed simultaneously with normal dyeing, or before or after dyeing.

熱可塑性合成繊維を含む布帛の場合に於ては水中又は溶
媒中での吸着処理の代りにパディング処理と熱処理等を
組合せて吸着させる事も可能である。
In the case of fabrics containing thermoplastic synthetic fibers, instead of adsorption treatment in water or a solvent, it is also possible to perform adsorption using a combination of padding treatment and heat treatment.

■ 糸又は線状での処理で吸着させた後、通常の方法で
布帛となし■と同様に染色や加工を行って得る方法であ
る。
(2) This is a method in which the material is adsorbed by thread or linear treatment, and then dyed and processed in the same manner as in (2) using fabrics and pears in the usual manner.

本発明は、これらの布帛に赤外線放射性物質を付与する
0本発明で使用する赤外線放射率が0.4以上の物質と
は酸化シリコニューム、酸化ケイ素。
The present invention provides these fabrics with an infrared emissive substance.The substances used in the present invention with an infrared emissivity of 0.4 or more include silicon oxide and silicon oxide.

酸化チタン等の金属酸化物、炭゛化シリコニューム。Metal oxides such as titanium oxide, silicon carbide.

炭化ケイ素等の金属炭化物、其の他室化チタンや各種セ
ラミックス等が単独に又は組合せて使用できる。また、
これらの赤外線放射性物質を近赤外線吸収物質を含有す
る布帛に付与するには、コーティングする方法や、フィ
ルムラミネートする方法を使用するが、かかるコーティ
ングやフィルムラミネートに於て使用される樹脂として
はウレタン系樹脂、アクリル系樹脂が一般に使用される
Metal carbides such as silicon carbide, titanium oxide, various ceramics, etc. can be used alone or in combination. Also,
To apply these infrared emitting substances to fabrics containing near-infrared absorbing substances, coating methods and film lamination methods are used, but urethane-based resins are used for such coatings and film laminations. Resins and acrylic resins are commonly used.

赤外線放射物質は、樹脂コーティングの場合は樹脂にブ
レンドして、また、フィルムラミネートの場合はフィル
ム作成用の樹脂に予めブレンドしてフィルム層に入れる
か、または、接着剤にブレンドして接着層に入れるか、
さらに好ましくはフィルム層、接着層の両方に入れるこ
とも可能である。
Infrared emitting substances can be blended with the resin in the case of resin coatings, pre-blended with the film-making resin and placed in the film layer in the case of film laminates, or blended with the adhesive and placed in the adhesive layer. Should I put it in?
More preferably, it can be included in both the film layer and the adhesive layer.

また、一般の衣料用に用いる場合に於ては特に樹脂層、
フィルム層は着用快適性の点から透湿性の良いものが好
ましい。
In addition, when used for general clothing, especially resin layers,
The film layer preferably has good moisture permeability from the viewpoint of wearing comfort.

(発明の作用) 本発明によって得られた布帛は、近赤外線量の多いアウ
トドアーの太陽光線の下で使用した場合には、近赤外線
吸収物質の影響で、まず布帛の温度が高くなる0次いで
、布帛の温度と共に樹脂層若しくは、フィルム層の温度
が高くなりセラミックスからの熱放射が増加して布帛裏
面の温度が高まる。
(Action of the invention) When the fabric obtained by the present invention is used outdoors under sunlight with a large amount of near-infrared rays, the temperature of the fabric increases first due to the influence of the near-infrared absorbing substance. As the temperature of the fabric increases, the temperature of the resin layer or the film layer increases, heat radiation from the ceramic increases, and the temperature of the back surface of the fabric increases.

本発明の布帛は、かかる性質を利用して吸熱性放熱性の
両方の性質を有するすぐれた衣服用素材として使用され
る。更に、中綿入りの布団の測地や、中綿入りの衣服部
材として、本発明の布帛に用いた場合には、中綿の優れ
た蓄熱効果を組合されることにより一層の保温性が増す
The fabric of the present invention can be used as an excellent clothing material that has both heat-absorbing and heat-radiating properties by utilizing such properties. Furthermore, when the fabric of the present invention is used as a material for a futon with padding or as a clothing member with batting, the heat retention property is further increased by combining the excellent heat storage effect of the batting.

本発明の布帛は、通常の染色を行うだけでなく、必要に
応じて撓水性や、訓電加工、濃染加工等の各種の加工を
行うことは同等差支えない、アウトドアー用の衣服とし
て使用される場合は、特に攬水加工によって防水性を向
上させておくことは好ましい事である。以下、実施例に
より本発明の詳細な説明する。
The fabric of the present invention can be used not only for ordinary dyeing, but also for various treatments such as water repellency, electric shock treatment, dark dyeing, etc. as necessary, and can be used as outdoor clothing. In such cases, it is particularly desirable to improve waterproofness by water-impregnation treatment. Hereinafter, the present invention will be explained in detail with reference to Examples.

(実施例1) 経糸及び緯糸にポリエステル仮撚加工糸(75デニール
/72フイラメント)を用いた平組織織物を経糸密度1
87本/ 3.79(Im 、緯糸富度140本/3.
790で織成し、該織物を通常の方法でリラックス・精
練後に乾燥セットして基布とした。
(Example 1) A plain weave fabric using polyester false twisted yarn (75 denier/72 filaments) for the warp and weft was fabricated with a warp density of 1.
87/3.79 (Im, weft richness 140/3.
790, and the woven fabric was relaxed and scoured in a conventional manner, and then dry-set to obtain a base fabric.

次いで、該基布に近赤外吸収物質としてIRQ−750
(最大吸収波長は700ミリミクロン、日本化薬社製)
の30%水分散体を用い、基布重量に対して4%が付着
するよう染色機にて処理(温度130℃X時間60分)
を行った。
Next, IRQ-750 was added to the base fabric as a near-infrared absorbing material.
(Maximum absorption wavelength is 700 millimicrons, manufactured by Nippon Kayaku Co., Ltd.)
Using a 30% aqueous dispersion, process with a dyeing machine so that 4% of the weight of the base fabric adheres (temperature 130℃ x time 60 minutes)
I did it.

得られた処理布帛(緑色)を乾燥後、沸素系の挽水剤(
アサヒガードA G 710旭ガラス社製)の5%水溶
液でパディング法による碗水加工を行った。更に、温度
160℃の熱カレンダーで圧縮加工を行って原布としな
After drying the obtained treated fabric (green), a fluorine-based water grinding agent (
A wansui process was performed using a padding method using a 5% aqueous solution of Asahi Guard AG 710 (manufactured by Asahi Glass Co., Ltd.). Furthermore, compression processing is performed using a thermal calendar at a temperature of 160°C to obtain a raw fabric.

該原布に、表1に示すポリウレタン系樹脂を用いて作成
した透湿性フィルムを、表2に示す組成を有する接着剤
を用いてラミネートして、本発明の布帛を得た。
A moisture permeable film made using a polyurethane resin shown in Table 1 was laminated onto the raw fabric using an adhesive having a composition shown in Table 2 to obtain a fabric of the present invention.

比較用として、前記基布にIRQ−750の代りに70
0ミリミクロンから2000ミリミクロンの波長領域に
最大吸収波長を持たない分散染料、デイパースブルーK
(チバガイギー社製)ダイヤニヅクスブルーACE (
三菱化成工業社製)、ダイヤニックスイエローACE 
(三菱化成社製)を各々織物重量に対して0.5%、 
0.14%、 0.24%用いて該原布と同等の色相濃
度に染色し、原布と同様に撓水加工、カレンダー処理を
行った染色基布に、表1に示す組成を有するフィルムを
表2に示す接着剤を用いて比較例1の布帛を得た。
For comparison, IRQ-750 was used instead of IRQ-750 on the base fabric.
Deeper Blue K is a disperse dye that does not have a maximum absorption wavelength in the wavelength range of 0 mm to 2000 mm.
(manufactured by Ciba Geigy) Diamond Blue ACE (
(Manufactured by Mitsubishi Chemical Industries, Ltd.), Diamondx Yellow ACE
(manufactured by Mitsubishi Kasei Corporation), each at 0.5% based on the weight of the fabric,
A film having the composition shown in Table 1 was applied to a dyed base fabric that was dyed using 0.14% and 0.24% to the same hue density as the original fabric, and subjected to water repellent treatment and calender treatment in the same way as the original fabric. A fabric of Comparative Example 1 was obtained using the adhesive shown in Table 2.

さらに、比較用として、前記原布に、表1に示す樹脂組
成から炭化シリコニューム粉末を除いたものを用いたフ
ィルムを、表2の接着用樹脂組成から炭化シリコニュー
ム粉末を除いたものを用いた接着剤によりラミネートし
て比較例2の布帛を得た。
Furthermore, for comparison, a film using the resin composition shown in Table 1 with the silicon carbide powder removed was used for the raw fabric, and a film using the adhesive resin composition shown in Table 2 with the silicon carbide powder removed was used as the base fabric. The fabric of Comparative Example 2 was obtained by laminating with an adhesive.

表1 フィルム作成用樹脂組成 りリスボン3314 クリスボンアシスター5D−17 アディティブ Np、10 イソプロピルアルコール トルエン 炭化シリコニューム粉末 100部(大日本インキ社製) 3.3部(ツノ      ) 0.5部(/7     ) 12部 12部 13部(日本新金属社製) 10分間照射し、各布帛の裏面温度を温度センサーを用
いて表面に接触させて実測した結果を表3に示す。
Table 1 Resin composition for film making Lisbon 3314 Lisbon Assister 5D-17 Additive Np, 10 Isopropyl alcohol Toluene Silicon carbide powder 100 parts (manufactured by Dainippon Ink Co., Ltd.) 3.3 parts (horn) 0.5 parts (/7 ) 12 parts, 12 parts, 13 parts (manufactured by Nihon Shinkinzoku Co., Ltd.) After irradiation for 10 minutes, the temperature of the back surface of each fabric was actually measured by contacting it with the surface using a temperature sensor. Table 3 shows the results.

表3 表2接着用樹脂組成 りリスボン4260 クリスボン4070 ゾルテックスCL−45 アクセル T トルエン ジメチルホルムアルデヒド 炭化シリコニューム粉末 50部(大日本インキ社製) 50部(11) 15部(J/   ) 1.5部()I      ) 70部 10部 5部(日本新金属社製) さらに、前記原布にフィルムラミネートをしないものを
比較例3として用い、太陽光線に近い波長分布を有する
東芝■製陽光ランプD 400を用いて実施例1による
ものは、近赤外線吸収物質および赤外線放射物質を含ま
ないもの(比較例4)に比して優れていることは勿論、
近赤外線吸収物質又は、赤外線放射物質のいずれか一方
を含有するもの(比較例1.比較例2)と比べても優れ
ているものである。
Table 3 Table 2 Adhesive resin composition Lisbon 4260 Crisbon 4070 Soltex CL-45 Accel T Toluene dimethyl formaldehyde silicon carbide powder 50 parts (manufactured by Dainippon Ink Co., Ltd.) 50 parts (11) 15 parts (J/ ) 1.5 parts ()I) 70 parts, 10 parts, 5 parts (manufactured by Nippon Shinkinzoku Co., Ltd.) Furthermore, using the raw cloth without film lamination as Comparative Example 3, a sunlight lamp D 400 manufactured by Toshiba ■, which has a wavelength distribution close to that of sunlight, was used. Of course, the one according to Example 1 using
It is also superior to those containing either a near-infrared absorbing substance or an infrared emitting substance (Comparative Example 1 and Comparative Example 2).

(実施例2) 実施例1に示した方法で作成した本発明の布帛を測地に
使用し、中綿にアイザックID −80k(余人■製)
を用いた布団(実施例2)と、比較用として、比較例1
で得な布帛を測地に使用し、中綿としては実施例2で用
いたものを用いた布帛(比較例5)と用い、太陽光線の
下に60分間放置し、その間中綿の温度を温度センサー
にて測定した。
(Example 2) The fabric of the present invention produced by the method shown in Example 1 was used for geodetic measurements, and the filling was Isaac ID-80k (manufactured by Yojin ■).
(Example 2) and Comparative Example 1 for comparison.
For geodetic measurements, a fabric made of a special fabric was used for geodetic measurements, and the fabric used in Example 2 (Comparative Example 5) was used as the filling, and the fabric was left under sunlight for 60 minutes, during which time the temperature of the filling was measured using a temperature sensor. It was measured using

測定した温度は、実施例2によるものが43℃、比較例
5によるものが温度35℃であり、本発明の布帛使用の
布団は、吸熱性に優れるものであった。
The measured temperature was 43° C. for Example 2 and 35° C. for Comparative Example 5, indicating that the futon using the fabric of the present invention had excellent heat absorbing properties.

Claims (1)

【特許請求の範囲】[Claims] 波長領域700ミリミクロン〜2000ミリミクロンの
範囲で吸収能を有する近赤外線吸収物質を含有する布帛
の表面に赤外線放射率が0.4以上の物質を含有する樹
脂若しくは、フィルムが積層されていることを特徴とす
る保温性布帛。
A resin or film containing a substance with an infrared emissivity of 0.4 or more is laminated on the surface of a fabric containing a near-infrared absorbing substance that has an absorption ability in the wavelength range of 700 mm to 2000 mm. A heat-retaining fabric characterized by
JP63169043A 1988-07-08 1988-07-08 Insulating fabric Expired - Lifetime JP2728438B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP63169043A JP2728438B2 (en) 1988-07-08 1988-07-08 Insulating fabric

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63169043A JP2728438B2 (en) 1988-07-08 1988-07-08 Insulating fabric

Publications (2)

Publication Number Publication Date
JPH0219571A true JPH0219571A (en) 1990-01-23
JP2728438B2 JP2728438B2 (en) 1998-03-18

Family

ID=15879261

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63169043A Expired - Lifetime JP2728438B2 (en) 1988-07-08 1988-07-08 Insulating fabric

Country Status (1)

Country Link
JP (1) JP2728438B2 (en)

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WO2002000433A1 (en) * 2000-06-27 2002-01-03 Ks Dyeing & Printing Co., Ltd. Moisture-permeable, waterproof and heat insulating fabric and moisture-permeable, waterproof and heat insulating resin film with releasing paper
JP2002011833A (en) * 2000-06-27 2002-01-15 Ks Senshoku Kk Waterproof heat insulation cloth
JP2009203596A (en) * 2008-01-30 2009-09-10 Komatsu Seiren Co Ltd Infrared ray-absorbing fabric and method for producing the same
JP2012011722A (en) * 2010-07-02 2012-01-19 Teijin Fibers Ltd Woven fabric for lining and fiber product
AT14001U1 (en) * 2014-01-29 2015-02-15 Neuson Hydrotec Gmbh Removable piston-cylinder unit

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6059419B2 (en) * 2010-10-07 2017-01-11 帝人フロンティア株式会社 Thermal storage fabrics and textile products

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WO2002000433A1 (en) * 2000-06-27 2002-01-03 Ks Dyeing & Printing Co., Ltd. Moisture-permeable, waterproof and heat insulating fabric and moisture-permeable, waterproof and heat insulating resin film with releasing paper
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JP2009203596A (en) * 2008-01-30 2009-09-10 Komatsu Seiren Co Ltd Infrared ray-absorbing fabric and method for producing the same
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AT14001U1 (en) * 2014-01-29 2015-02-15 Neuson Hydrotec Gmbh Removable piston-cylinder unit

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