JPH02185920A - Manufacture of directly softened wire rod or rod stock - Google Patents

Manufacture of directly softened wire rod or rod stock

Info

Publication number
JPH02185920A
JPH02185920A JP477989A JP477989A JPH02185920A JP H02185920 A JPH02185920 A JP H02185920A JP 477989 A JP477989 A JP 477989A JP 477989 A JP477989 A JP 477989A JP H02185920 A JPH02185920 A JP H02185920A
Authority
JP
Japan
Prior art keywords
steel
rod
rolling
wire rod
less
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP477989A
Other languages
Japanese (ja)
Other versions
JP2804278B2 (en
Inventor
Toshiyuki Hoshino
俊幸 星野
Nobuhisa Tabata
田畑 綽久
Toshio Fujita
利夫 藤田
Shozaburo Nakano
中野 昭三郎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JFE Steel Corp
Original Assignee
Kawasaki Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kawasaki Steel Corp filed Critical Kawasaki Steel Corp
Priority to JP1004779A priority Critical patent/JP2804278B2/en
Publication of JPH02185920A publication Critical patent/JPH02185920A/en
Application granted granted Critical
Publication of JP2804278B2 publication Critical patent/JP2804278B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Abstract

PURPOSE:To manufacture a directly softened wire rod or rod stock capable of eliminating heat treatment before cold working by forming a steel having a specific composition containing REM into a steel wire rod or steel rod by means of hot rolling and subjecting the above to specific cooling after the conclusion of rolling. CONSTITUTION:A steel which has a composition consisting of, by weight, 0.30-0.60% C, 0.15-0.35% Si, 0.60-1.70% Mn, <=0.03% P, <=0.03% S, <=0.050% Al, <=0.0050% O, <=0.0050% N, 0.0005-0.05% REM, and the balance Fe with inevitable impurities and further containing, it necessary, 0.60-1.2% Cr and/or 0.15-0.35% Mo is hot-rolled into a steel wire rod or steel rod. At this time, after the conclusion of rolling, cooling is carried out down to 500 deg.C at <=0.1 deg.C/s cooling rate, by which ferrite fraction in the steel structure is remarkably increased and lamellar spacing in a pearlitic part is widened to carry out softening. By this method, the directly softened steel wire rod or steel rod capable of eliminating or simplifying heat treatment prior to secondary working can be obtained.

Description

【発明の詳細な説明】 〈産業上の利用分野〉 本発明は、冷間鍛造用に用いられる直接軟化綿棒材の製
造方法に関する。
DETAILED DESCRIPTION OF THE INVENTION <Industrial Application Field> The present invention relates to a method for producing a directly softened cotton swab material used for cold forging.

〈従来の技術〉 冷間鍛造用の線材あるいは棒鋼は、冷間鍛造によりボル
ト、ナツト等の各種ファスナ類、あるいは自動車部品等
に成形される。ところが、これら冷間鍛造用線材あるい
は棒鋼は、圧延ままの状態では厳しい冷間加工に耐え得
る変形能に不足すると同時に変形抵抗が高い、このため
、変形能の向上と変形抵抗の低減のために軟化焼なまし
が行われる。
<Prior Art> Wire rods or steel bars for cold forging are formed into various fasteners such as bolts and nuts, automobile parts, etc. by cold forging. However, in the as-rolled state, these wire rods or steel bars for cold forging lack deformability to withstand severe cold working, and at the same time have high deformation resistance.Therefore, in order to improve deformability and reduce deformation resistance, A softening annealing is performed.

〈発明が解決しようとする課題〉 しかしながら、このような軟化焼なましは、高温長時間
保持が必要であり、そのため、高価な熱処理炉等の設備
が必要とされ、かつ、この設置11Iflを用いるとス
ケールロスが発生するなど生産性の面でも問題がある。
<Problems to be Solved by the Invention> However, such softening annealing requires holding at high temperatures for a long period of time, and therefore requires expensive equipment such as a heat treatment furnace. There are also problems in terms of productivity, such as scale loss.

これらの処理を回避するために、例えば特公昭59−3
1573号あるいは特開昭54−143716号公報に
開示されているように、圧延温度および圧延後の冷却速
度を特定の範囲内に制御することにより、軟化焼なまし
を省略可能なtgI線材の製造方法が提案されている。
In order to avoid these processes, for example,
As disclosed in No. 1573 or Japanese Unexamined Patent Publication No. 143716/1984, the production of tgI wire rods in which softening annealing can be omitted by controlling the rolling temperature and the cooling rate after rolling within a specific range. A method is proposed.

これらの内容は、いずれも圧延ままのミクロ組織をフェ
ライト・パーライトとすることにより軟質化を計ろうと
するものである。
These contents all attempt to soften the as-rolled microstructure by changing it to ferrite/pearlite.

しかし、これらの方法では従来の圧延方法に比較すれば
軟質化は計れるものの、オフラインでの軟化焼なまし材
に比較すれば、より高強度および低延性であり、軟化焼
なまし材よりも材質的に劣るという問題がある。
However, although these methods can soften the material compared to conventional rolling methods, they have higher strength and lower ductility compared to off-line softened and annealed materials, and the material quality is lower than that of softened and annealed materials. There is a problem that it is inferior in quality.

本発明は上記のような課題を解決すべくしてなされたも
のであって、2次加工前の熱処理の処理または簡略化を
可能とした直接軟化綿棒鋼の製造方法を堤供することを
目的とする。
The present invention has been made in order to solve the above-mentioned problems, and an object of the present invention is to provide a method for producing directly softened cotton rod steel that enables processing or simplification of heat treatment before secondary processing. .

〈課題を解決するだめの手段〉 本発明者らは、上記問題を解決するため鋭意検討を進め
た結果、以下の如き知見を得るに至った。
<Means for Solving the Problems> As a result of intensive studies to solve the above-mentioned problems, the present inventors have come to the following findings.

フェライト・パーライト組織の強度支配因子はフェライ
ト分率およびパーライト部のラメラ−間隔である。ここ
で軟質なフェライトが増加すれば強度は低下し、またラ
メラ−間隔が、増加すれば強度は低下する。したがって
、圧延ままで低強度化を計るためには、フェライト分率
を増加させると同時パーライト・ラメラ−間隔を広げる
ことが有効である。このようなミクロ組織形態を得る圧
延条件および冷却条件を検討すると、まずフェライト面
積率を増加させるためには、変態前のγ粒径を細粒とす
る必要がある。というのは、変態時にフェライトの発生
サイトとなるのはオーステナイトの結晶粒界であり、こ
の粒界面積が多いほど、すなわち、オーステナイト粒径
が細粒となるほどフェライト分率は増加する。このため
の圧延条件としては、γ粒が細粒となる低温仕上げが好
ましい。
The strength controlling factors of the ferrite-pearlite structure are the ferrite fraction and the lamella spacing of the pearlite portion. Here, if the soft ferrite increases, the strength decreases, and if the lamella spacing increases, the strength decreases. Therefore, in order to reduce the strength of as-rolled steel, it is effective to increase the ferrite fraction and at the same time widen the pearlite lamella spacing. When considering the rolling conditions and cooling conditions for obtaining such a microstructural form, first of all, in order to increase the ferrite area ratio, it is necessary to make the γ grain size before transformation fine. This is because the austenite grain boundaries are the sites where ferrite is generated during transformation, and the larger the grain boundary area, that is, the finer the austenite grain size, the greater the ferrite fraction. As the rolling conditions for this purpose, low-temperature finishing is preferable so that the γ grains become fine grains.

また、パーライト・ラメラ−間隔を広げるためには、冷
却速度をなるべく下げることが重要である。これは、冷
却速度が遅くなる程、パーライト変態温度が上がりパー
ライト・ラメラ−間隔は広くなるためである。従来の直
接軟化処理方法はこのような原ff1Jに従ったもので
あるが、先述したようにオフライン焼なまし材に比較し
て高強度および低延性である。これはオフライン焼なま
し材程度までの材質を得ようとすると、工業的に困難な
低温仕上および低冷却速度を施さざるを得ないという問
題が生じているためである。
Furthermore, in order to widen the pearlite lamella spacing, it is important to lower the cooling rate as much as possible. This is because the slower the cooling rate, the higher the pearlite transformation temperature and the wider the pearlite lamella spacing. The conventional direct softening treatment method follows such a raw material ff1J, but as mentioned above, it has higher strength and lower ductility than offline annealed material. This is because in order to obtain a material that is comparable to that of an offline annealed material, a problem arises in that low-temperature finishing and slow cooling rates, which are industrially difficult, have to be applied.

本発明者らは、上記問題を解決するために鋭意検討を行
った結果、稀土類元素であるI?EHの添加が同二圧延
条件においてフェライト分率を著しく増大させるとの知
見をIF)た、これは、R[!Mは極めて酸化物を形成
しやすい元素であり、鋼中のRE?1酸化物がフェライ
ト発生起点となり、従来のオーステナト粒界のみの場合
に比較してフェライト分率が飛躍的に増加するためであ
る。このため、同一圧延、冷却条件においても著しく低
強度−高延性の鋼線材または棒鋼を得ることが可能であ
る。
The present inventors conducted intensive studies to solve the above problem, and found that the rare earth element I? IF) found that the addition of EH significantly increases the ferrite fraction under the same rolling conditions, which indicates that R[! M is an element that easily forms oxides, and RE? This is because monooxide becomes the starting point for ferrite generation, and the ferrite fraction increases dramatically compared to the conventional case of only austenite grain boundaries. Therefore, it is possible to obtain a steel wire or bar with extremely low strength and high ductility even under the same rolling and cooling conditions.

本発明は、上記知見に基づいてなされたものであって、
その要旨とするところは、C:o、3o〜0゜60w 
L% Si : 0.15〜0.35wt%、 Mn 
: 0.60〜1.70wt%、  P : 0.03
wt%以下、  S :0.03wt%以下、^!: 
0.050 wt%以下、 O: 0.0050鰺L%
以下、Neo。
The present invention has been made based on the above findings, and includes:
The gist of it is: C: o, 3o~0°60w
L% Si: 0.15-0.35wt%, Mn
: 0.60-1.70wt%, P: 0.03
wt% or less, S: 0.03wt% or less, ^! :
0.050 wt% or less, O: 0.0050 mackerel L%
Below, Neo.

0050w L%以下、  RUM : 0.0005
〜0.05wt%を含有し、残部Feおよび不可避的不
純物よりなる鋼を、熱間圧延により鋼線材およびは棒鋼
とするに際し、圧延終了後、500″CまでをO9l″
C/ s以下で冷却することを特徴とする直接軟化綿棒
材の製造方法である。
0050w L% or less, RUM: 0.0005
~0.05wt%, with the remainder being Fe and unavoidable impurities, when hot rolling the steel into a steel wire rod or steel bar.
This is a method for producing a directly softened cotton swab material, which is characterized by cooling at a temperature below C/s.

また、上記した鋼の化学成分として、Cr : 0.6
0〜1.2 wt%、 Mo : 0.15〜0.35
wt%の1種又は2種を含有してもよい。
Further, as the chemical composition of the steel mentioned above, Cr: 0.6
0-1.2 wt%, Mo: 0.15-0.35
It may contain one or two wt%.

く作用〉 以下に限定理由を述べる。Effect〉 The reasons for this limitation are explained below.

C: Cは、機械部品としての強度を確保する上で有用な元素
であるので積極的に用いるが、0.30未満では強度を
確保する上で不充分であり、また0、60−1%を越え
て含有すると直接軟化が困難となるので、0.30〜0
.60wt%の範囲とする。
C: C is a useful element for ensuring strength as mechanical parts, so it is actively used, but if it is less than 0.30, it is insufficient to ensure strength, and if it is less than 0.60%, it is insufficient to ensure strength. If the content exceeds 0.30 to 0, direct softening becomes difficult.
.. The range is 60 wt%.

Si : Siは、脱酸に有用な元素であるのみでなく、機械部品
として必要な強度を確保する上で有用であるので積極的
に用いるが、0.15wt%未満ではその効果は小さく
 、 0.30wt%を越えて含有すると酸洗性が劣化
するので、0.15〜0.30wt%の範囲とする。
Si: Si is not only a useful element for deoxidation, but also useful for ensuring the strength required for mechanical parts, so it is actively used, but if it is less than 0.15 wt%, its effect is small. If the content exceeds .30 wt%, the pickling properties will deteriorate, so the content should be in the range of 0.15 to 0.30 wt%.

Mn: Mnは、機械部品としての強度を6′信保する上で有用
な元素であるので積極的に添加するが、0.30wt%
未満ではその効果は小さく、1.5 wt%を越えて含
有すると加工硬化が著しく冷間加工が困難となるので、
0.3〜1.5 wt%の範囲とする。
Mn: Mn is a useful element in increasing the strength of mechanical parts, so it is actively added, but at 0.30 wt%.
If the content is less than 1.5 wt%, the effect will be small, and if the content exceeds 1.5 wt%, work hardening will be significant and cold working will become difficult.
The content should be in the range of 0.3 to 1.5 wt%.

P: Pは粒界に偏析し熱間加工性の低下および調質処理時に
焼割れを生じるので低減することが望ましいが、0.0
3wt%以下まで許容される。
P: P segregates at grain boundaries and reduces hot workability and causes quench cracking during tempering treatment, so it is desirable to reduce it, but 0.0
It is allowed up to 3 wt%.

Sは切削性を向上させる一方、MnSを形成し冷間加工
性を劣化させる。このため、両特性を満足する0゜93
w t%以下の添加とする。
While S improves machinability, it forms MnS and deteriorates cold workability. Therefore, 0°93 which satisfies both characteristics.
Addition should be less than wt%.

Al: AI!は、脱酸のために有用な元素であるので積極的に
用いるが、0.05wt%を越えて含イfしてもその効
果は飽和して固溶強化を生じるので、0.05wt%以
下の添加とする。
Al: AI! Since it is a useful element for deoxidation, it is actively used, but even if it is contained in an amount exceeding 0.05 wt%, its effect will be saturated and solid solution strengthening will occur, so it should not exceed 0.05 wt%. The addition of

0: 0は、冷間鍛造性に有害なAlzOx系の酸化物を形成
するので低減することが望ましいが、0.0050諸t
%まで許容される。
0: 0 forms AlzOx-based oxides that are harmful to cold forgeability, so it is desirable to reduce it.
% is allowed.

N: Nは、冷間加工時に動的歪時効を生じるので低減するこ
とが望ましいが0.0050wt%まで許容される。
N: N causes dynamic strain aging during cold working, so it is desirable to reduce it, but it is allowed up to 0.0050 wt%.

REM  : REMは、γ−α変態時にCe酸化物がフェライトの核
形成場所となり、圧延後組織のフェライト分率を著しく
増加させ低強度化に有効であるのみでなく、冷間jJI
l工性に有害な伸長したMnSを冷間加工性に無害な紡
鍾形状に変化させて冷間加工性の向上にも有効であるの
で積極的に用いるが、0.0005−1%未満ではその
効果が小さく、また0、05wt%を越えて含有しても
その効果が飽和するので、o、ooos〜0.05wt
%の添加とする。
REM: In REM, Ce oxide serves as a nucleation site for ferrite during the γ-α transformation, and it is not only effective in significantly increasing the ferrite fraction in the rolled structure and lowering the strength, but also in cold JJI.
It is actively used because it is effective in improving cold workability by changing the elongated MnS, which is harmful to workability, into a spindle shape that is harmless to cold workability. The effect is small, and even if the content exceeds 0.05wt%, the effect is saturated, so o,ooos~0.05wt%
% addition.

また、上記した鋼の化学成分にCr : 0.60〜1
.2−t%1Mo : 0.15〜0.35wt%の1
種又は2種を含有させる理由は、Cr、Moともに焼入
性を著しく向上させる元素であり、部材が大型の場合に
は調質処理時の焼入深さ確保にきわめて有用であるから
積極的に用いるが、Crの場合、0.60賀t%以下で
はその効果が小さ(,1,2wt%を越えて含有すると
パーライト・ラメラ−間隔が小さくなり、圧延まま材の
強度を上昇せしめるので、0.6〜1.2wt%とする
。一方、Moは0.15wt%未満では焼入性向上への
効果が小さく、また、0゜35W【%を越えて含有する
と圧延まま材に硬質なベイナイトM1織が発止して本目
的に反するので、0.15〜0.35wt%とする。
In addition, the chemical components of the steel mentioned above include Cr: 0.60 to 1
.. 2-t%1Mo: 0.15 to 0.35wt% of 1
The reason for including one or two species is that both Cr and Mo are elements that significantly improve hardenability, and when the part is large, it is extremely useful for ensuring the hardening depth during tempering treatment, so it is actively used. However, in the case of Cr, if it is less than 0.60 wt%, the effect is small (if it is contained in excess of 1.2 wt%, the pearlite lamella spacing becomes smaller, increasing the strength of the as-rolled material. On the other hand, if Mo is less than 0.15 wt%, the effect on improving hardenability will be small, and if it is contained in excess of 0°35 W%, it will cause hard bainite in the as-rolled material. Since the M1 weave will develop, which is contrary to the purpose of the invention, the content should be 0.15 to 0.35 wt%.

さらに、圧延終了後、0.1℃/ s以下で500℃ま
で冷却するのは、パーライト・ラメラ−間隔を広げ低強
度化を計るためであるが、0.1℃/sを越える冷却速
度においてはその効果が小さいので、0.1’C/s以
下とする。なお、冷却終了温度を500″Cとするのは
、500℃以上の温度域においてフェライト−パーライ
ト変態が終了し、500℃未満の温度領域を0゜l’c
/s以下の冷却速度で処理しても軟質化への効果が乏し
いのみでなく、処理時間が長くなるので冷却終了温度は
500℃とする。
Furthermore, the reason for cooling to 500°C at a rate of 0.1°C/s or less after rolling is to widen the pearlite lamella spacing and reduce the strength, but if the cooling rate exceeds 0.1°C/s, Since the effect is small, it is set to 0.1'C/s or less. The cooling end temperature is set to 500"C because the ferrite-pearlite transformation ends in the temperature range of 500℃ or higher, and the temperature range of less than 500℃ is set to 0゜l'c.
Even if the treatment is performed at a cooling rate of less than /s, the softening effect is poor and the treatment time becomes longer, so the cooling end temperature is set at 500°C.

〈実施例〉 第1表に示す成分組成の鋼を転炉溶製し、分塊圧延によ
り150闘ビレツトとした後、線材圧延により14ff
lIIlφ線材とし、圧延後、第1表に示す冷却速度に
より冷却し、圧延まま材の機械的性質を調査した。この
結果を第1表に併せて示した。
<Example> Steel having the composition shown in Table 1 was melted in a converter furnace, and after being made into a 150mm billet by blooming rolling, it was made into a 14ff billet by wire rod rolling.
After rolling, the as-rolled material was cooled at the cooling rate shown in Table 1, and the mechanical properties of the as-rolled material were investigated. The results are also shown in Table 1.

No、 1−Nα6は本発明例である。またNα7〜1
2はRUM無添加の比較材、Nα13〜18はN[11
〜Nα6と同一素材を用いて冷却速度のみ本発明の範囲
からはずれている。N(119〜No、24は、Nα7
〜12と同一素材を用いて第1図に示ずヒートサイクル
により、680℃X3hに加熱した後空冷して軟化焼な
ましを施したものである。
No. 1-Nα6 is an example of the present invention. Also, Nα7~1
2 is a comparative material without RUM addition, Nα13 to 18 are N[11
- Using the same material as Nα6, only the cooling rate is outside the scope of the present invention. N (119~No, 24 is Nα7
Using the same material as those in 12 to 12, it was heated to 680° C. for 3 hours by a heat cycle not shown in FIG. 1, and then air cooled to undergo softening annealing.

第1表より明らかなように、オフライン焼鈍材並の機械
的性質を得ているのは、Hαl〜6の本発明例のみであ
ることがわかる。
As is clear from Table 1, it can be seen that only the inventive example of Hαl~6 has mechanical properties comparable to the offline annealed material.

〈発明の効果〉 以上説明したように、本発明を用いることにより、圧延
ままで軟化焼なまし材並の機械的性質を確保することが
可能であり、したがって、冷間加工前の軟化焼なましの
省略が可能である。これによって、冷間加工による機械
部品の生産性の向上に寄与することが可能である。
<Effects of the Invention> As explained above, by using the present invention, it is possible to secure mechanical properties comparable to softened and annealed materials as rolled, and therefore It is possible to omit it. This can contribute to improving the productivity of mechanical parts through cold working.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は、オフラインによる軟化焼なまし時のし一トサ
イクルを示す特性図である。
FIG. 1 is a characteristic diagram showing an elongation cycle during off-line softening annealing.

Claims (1)

【特許請求の範囲】 1、C:0.30〜0.60wt%、Si:0.15〜
0.35wt%、Mn:0.60〜1.70wt%、P
:0.03wt%以下、S:0.03wt%以下、Al
:0.050wt%以下、O:0.0050wt%以下
、N:0.0050wt%以下、REM:0.0005
〜0.05wt%を含有し、残部Feおよび不可避的不
純物よりなる鋼を、熱間圧延により鋼線材あるいは棒鋼
とするに際し、圧延終了後、500℃までを0.1℃/
s以下で冷却することを特徴とする直接軟化線棒材の製
造方法。 2、C:0.30〜0.60wt%、Si:0.15〜
0.35wt%、Mn:0.60〜1.7wt%、P:
0.03wt%以下、S:0.03wt%以下、Al:
0.010〜0.050wt%、O:0.0050wt
%以下、N:0.0050wt%以下、REM:0.0
005〜0.05wt%さらに、Cr:0.60〜1.
2wt%、Mo:0.15〜0.35wt%の1種又は
2種を含有し残部Feおよび不可避的不純物よりなる鋼
であることを特徴とする請求項1記載の直接軟化線棒材
の製造方法。
[Claims] 1. C: 0.30-0.60wt%, Si: 0.15-0.15%
0.35wt%, Mn: 0.60-1.70wt%, P
: 0.03wt% or less, S: 0.03wt% or less, Al
: 0.050wt% or less, O: 0.0050wt% or less, N: 0.0050wt% or less, REM: 0.0005
~0.05 wt%, with the remainder being Fe and unavoidable impurities, when hot rolling the steel into a steel wire or bar, the temperature is 0.1°C/0.1°C/up to 500°C after rolling.
1. A method for producing a directly softened wire bar, characterized by cooling at a temperature of s or less. 2, C: 0.30~0.60wt%, Si: 0.15~
0.35wt%, Mn: 0.60-1.7wt%, P:
0.03wt% or less, S: 0.03wt% or less, Al:
0.010-0.050wt%, O: 0.0050wt
% or less, N: 0.0050wt% or less, REM: 0.0
005 to 0.05 wt%, furthermore, Cr: 0.60 to 1.
2 wt%, Mo: 0.15 to 0.35 wt%, and the remainder is Fe and unavoidable impurities. Method.
JP1004779A 1989-01-13 1989-01-13 Direct softening wire rod manufacturing method Expired - Fee Related JP2804278B2 (en)

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Application Number Priority Date Filing Date Title
JP1004779A JP2804278B2 (en) 1989-01-13 1989-01-13 Direct softening wire rod manufacturing method

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JPH02185920A true JPH02185920A (en) 1990-07-20
JP2804278B2 JP2804278B2 (en) 1998-09-24

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110438411A (en) * 2019-08-31 2019-11-12 武汉钢铁有限公司 A kind of flattening steel wire wire rod and its production method for exempting recrystallization annealing process
CN114959479A (en) * 2022-05-30 2022-08-30 包头钢铁(集团)有限责任公司 Steel for rare earth wear-resistant alloy steel bar and production method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59159931A (en) * 1983-03-03 1984-09-10 Daido Steel Co Ltd Production of steel material
JPS62263923A (en) * 1986-05-07 1987-11-16 Kawasaki Steel Corp Manufacture of directly-softened steel wire rod

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS59159931A (en) * 1983-03-03 1984-09-10 Daido Steel Co Ltd Production of steel material
JPS62263923A (en) * 1986-05-07 1987-11-16 Kawasaki Steel Corp Manufacture of directly-softened steel wire rod

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110438411A (en) * 2019-08-31 2019-11-12 武汉钢铁有限公司 A kind of flattening steel wire wire rod and its production method for exempting recrystallization annealing process
CN114959479A (en) * 2022-05-30 2022-08-30 包头钢铁(集团)有限责任公司 Steel for rare earth wear-resistant alloy steel bar and production method thereof
CN114959479B (en) * 2022-05-30 2023-08-25 包头钢铁(集团)有限责任公司 Steel for rare earth wear-resistant alloy steel bar and production method thereof

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