JPH02184550A - Mortar composition for producing non-baked tile - Google Patents
Mortar composition for producing non-baked tileInfo
- Publication number
- JPH02184550A JPH02184550A JP375289A JP375289A JPH02184550A JP H02184550 A JPH02184550 A JP H02184550A JP 375289 A JP375289 A JP 375289A JP 375289 A JP375289 A JP 375289A JP H02184550 A JPH02184550 A JP H02184550A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- parts
- pts
- cement
- cement composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 32
- 239000004570 mortar (masonry) Substances 0.000 title claims abstract description 12
- 239000004568 cement Substances 0.000 claims abstract description 17
- 229920000742 Cotton Polymers 0.000 claims abstract description 13
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 10
- -1 alkali metal salt Chemical class 0.000 claims abstract description 10
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 8
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 6
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims abstract description 6
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000001110 calcium chloride Substances 0.000 claims abstract description 6
- 229910001628 calcium chloride Inorganic materials 0.000 claims abstract description 6
- 239000011398 Portland cement Substances 0.000 claims abstract description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 5
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052901 montmorillonite Inorganic materials 0.000 claims abstract description 5
- 239000004254 Ammonium phosphate Substances 0.000 claims abstract description 3
- 239000002253 acid Substances 0.000 claims abstract description 3
- 229910000148 ammonium phosphate Inorganic materials 0.000 claims abstract description 3
- 235000019289 ammonium phosphates Nutrition 0.000 claims abstract description 3
- 239000000440 bentonite Substances 0.000 claims abstract description 3
- 229910000278 bentonite Inorganic materials 0.000 claims abstract description 3
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 3
- CEDDGDWODCGBFQ-UHFFFAOYSA-N carbamimidoylazanium;hydron;phosphate Chemical compound NC(N)=N.OP(O)(O)=O CEDDGDWODCGBFQ-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000004927 clay Substances 0.000 claims abstract description 3
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 claims abstract description 3
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000003814 drug Substances 0.000 claims description 3
- 229940079593 drug Drugs 0.000 claims description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 239000000919 ceramic Substances 0.000 abstract description 7
- 238000000034 method Methods 0.000 abstract description 6
- 239000000835 fiber Substances 0.000 abstract description 5
- 239000004566 building material Substances 0.000 abstract description 4
- 238000004079 fireproofing Methods 0.000 abstract description 4
- 239000002699 waste material Substances 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 abstract description 2
- 235000013311 vegetables Nutrition 0.000 abstract description 2
- 239000003513 alkali Substances 0.000 abstract 1
- 238000005266 casting Methods 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 description 7
- 238000010521 absorption reaction Methods 0.000 description 4
- 239000002440 industrial waste Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- 239000011083 cement mortar Substances 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 239000004067 bulking agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000008194 pharmaceutical composition Substances 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- HIEHAIZHJZLEPQ-UHFFFAOYSA-M sodium;naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 HIEHAIZHJZLEPQ-UHFFFAOYSA-M 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/10—Coating or impregnating
- C04B20/12—Multiple coating or impregnating
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
Description
【発明の詳細な説明】
（発明の目的）
この発明は、焼成工程を経ることなく型枠への流し込み
成型より、建築物の壁面化粧用建材としてセラミックタ
イルにも匹敵する特性をもつタイルを生産する手段に関
するもので、その目的は無価値な産業廃棄物を組成物の
骨材に転用することによりこのような新建材を安価に生
産することを可能にする手段を提供することにある。[Detailed Description of the Invention] (Purpose of the Invention) This invention produces tiles with properties comparable to ceramic tiles as decorative wall materials for buildings by pouring into molds without going through a firing process. The purpose of this invention is to provide a means for producing such new building materials at low cost by converting worthless industrial waste into aggregate for compositions.
セラミックタイルは美麗滑沢な表面をもつとともに、強
度、耐火性、耐候性、低い吸水性などの優れた特質を兼
備するところから、オフィスビルやマンシジン等の壁面
化粧用建材として多用され、都市文化の向上とともにそ
の需要は拡大化の一途をたどっている。Ceramic tiles have a beautiful smooth surface and have excellent properties such as strength, fire resistance, weather resistance, and low water absorption, so they are often used as decorative wall materials for office buildings and buildings, and are popular in urban culture. The demand for this product continues to expand as the technology improves.
しかしながら、前記のような優れた特質をもつセラミッ
クタイルの生産には高温での焼成が必要なため、その生
産には著しい熱エネルギー消費と多大の労務を伴うとい
う欠点を避けることができない。However, since the production of ceramic tiles with the above-mentioned excellent properties requires firing at high temperatures, the production thereof cannot avoid the drawbacks of considerable thermal energy consumption and a large amount of labor.
そこで、この発明者の一名は壁面用建材としてのタイル
の生産上のこのような欠点を除去するための技術を開発
し、これらの技術は特開昭６２−１６７２４５号公報お
よび特開昭６２−１６７２４６号公報により開示されて
いる。すなわち、それらに開示されている事項は、特定
する数種の改質剤を少量添加したポートランドセメント
又はアルミナセメントに対し、１〜４倍容量の天然又は
人工の無機質骨材を配合した組成物を単なる型枠への流
し込みにより常温成型したものは、壁面化粧被覆用のタ
イルとしてセラミックタイルに匹敵する優れた性能を発
揮するということである。Therefore, one of the inventors developed a technique to eliminate such drawbacks in the production of tiles as a building material for walls, and these techniques were published in Japanese Patent Application Laid-Open No. 62-167245 and Japanese Patent Application Laid-open No. 62-1672. It is disclosed in the publication No.-167246. In other words, the matters disclosed therein are compositions in which 1 to 4 times the volume of natural or artificial inorganic aggregate is blended with Portland cement or alumina cement to which small amounts of several specified modifiers are added. When molded at room temperature by simply pouring it into a mold, it exhibits excellent performance comparable to ceramic tiles as a decorative wall covering tile.
前記した開示にかかるタイルは非焼成物であるためセラ
ミックタイルよりも著しく生産コストが低いのであるが
、この発明者はさらに一層のコスト低下をはかるため研
究を行い、その結果植物繊維である落綿に特定の薬剤組
成物で耐火処理を施したものにより前記した非焼成タイ
ルの組成分である無機質骨材の相当部分を置換してもタ
イルとしての特質は一層に低下しないことを見出したの
である。なお、落綿の耐火処理に使用する薬剤組成物に
ついてはこの発明者の一名が開発し、特公昭５２−４３
３５７号公報に開示された技術を利用した。Since the tile disclosed above is a non-fired product, the production cost is significantly lower than that of ceramic tiles, but the inventor conducted research to further reduce the cost, and as a result, the production cost was significantly lower than that of ceramic tiles. They discovered that even if a considerable portion of the inorganic aggregate, which is a component of the above-mentioned unfired tile, was replaced with a tile treated with a fireproofing agent using a specific chemical composition, the properties of the tile did not deteriorate further. . The pharmaceutical composition used for fireproofing fallen cotton was developed by one of the inventors and published in the Japanese Patent Publication No. 52-43.
The technique disclosed in Publication No. 357 was used.
（発明の構成）
さて、この発明にかかる非焼成タイル生産用モルタル組
成物は、下記するセメント組成物１００重量部に対し、
下記する繊維質骨材８〜４０重量部と無機質骨材１００
〜２００重量部とを配合してなっている。(Structure of the Invention) Now, the mortar composition for non-fired tile production according to the present invention contains 100 parts by weight of the cement composition described below.
8 to 40 parts by weight of the following fibrous aggregate and 100 parts by weight of inorganic aggregate
~200 parts by weight.
この発明において前記のセメント組成物はつぎのような
組成をもっている。すなわち、（１）ポートランドセメ
ント、アルミナセメントのうちの少なくとも１種
９３〜７７重量部と■モンモリロナイト、酸性白土、ベ
ントナイトのうちの少なくとも１種 ２〜ｌＯ重量
部と■ジルコニア、マグネシアのうちの少なくとも１種
２〜ｌＯ重量部と■ステア
リン酸アルカリ金属塩、ステアリン酸アルカリ土金属塩
のうちの少なくとも１種０．５〜３ 重量部と
■ナフタリンスルホン酸アルカリ金属塩０．５〜３ 重
量部と
０重炭酸アルカリ金属塩、塩化カルシウムのうちの少な
くとも１種 １〜３ 重量部とを配合したもの
である。ただし、上掲の■、■については配合を省略す
ることができる。In this invention, the cement composition has the following composition. That is, (1) at least one of Portland cement and alumina cement;
93 to 77 parts by weight, ■ at least one of montmorillonite, acid clay, and bentonite, 2 to 10 parts by weight, ■ 2 to 10 parts by weight of at least one of zirconia and magnesia, and ■ alkali metal stearate, stearic acid. 0.5 to 3 parts by weight of at least one of alkaline earth metal salts and 0.5 to 3 parts by weight of alkali metal naphthalene sulfonate and 0 at least one of alkali metal bicarbonates and calcium chloride 1 to 3 parts by weight 3 parts by weight. However, the combination of (1) and (2) above can be omitted.
この発明において前記した繊維質骨材は、落綿を素材と
し、これに下記する処理溶液を含浸乾燥させ、溶液中の
薬剤成分を１９〜２３重量％含有させたものである。こ
の処理溶液については、前記したように特公昭５２−４
３３５７号公報に開示されているものを利用する。すな
わち、この処理溶液は■燐酸アンモニウム２０〜５０重
量部に水８０〜５０重量部を加え１００重量部としたも
のを１２時間以上放置した溶液
６０〜７０重量部と
■燐酸グアニジン１５〜３５重量部に水８５〜６５重量
部を加え１００重量部としたものを６時間以上放置した
溶液
１５〜２５重量部と
■塩化マグネシウム、塩化カルシウムのうちの少なくと
も１種３０〜５０重量部に水７０〜５０重量部を加え１
００重量部としたものを３時間以上放置した溶液
１０〜２０重量部とを配合したものである。The fibrous aggregate described above in this invention is made of fallen cotton, impregnated with the treatment solution described below and dried, and containing 19 to 23% by weight of the drug component in the solution. Regarding this treatment solution, as mentioned above,
The method disclosed in Publication No. 3357 is used. That is, this treatment solution consists of: (1) 60 to 70 parts by weight of a solution obtained by adding 20 to 50 parts by weight of ammonium phosphate to 80 to 50 parts by weight of water to make 100 parts by weight and allowing it to stand for 12 hours or more, and (2) 15 to 35 parts by weight of guanidine phosphate. Add 85 to 65 parts by weight of water to make 100 parts by weight, then leave to stand for more than 6 hours. 15 to 25 parts by weight of a solution; 1. Add 30 to 50 parts by weight of at least one of magnesium chloride and calcium chloride to 70 to 50 parts by weight of water. Add weight part 1
00 parts by weight solution left for more than 3 hours
10 to 20 parts by weight.
この発明にかかるモルタル組成物は前記した組成を有し
ているのであるが、特に注目すべきは、この発明につい
ては前記した特開昭６２−１６７２４５号公報又は特開
昭６２−１６７２４６号公報において開示されたモルタ
ル組成物に含まれている無機質骨材の量の相当部分を植
物繊維からなる落綿の特定耐火処理物によって置換した
点である。The mortar composition according to the present invention has the above-mentioned composition, but it is particularly noteworthy that this invention is described in The point is that a considerable part of the amount of inorganic aggregate contained in the disclosed mortar composition is replaced by a specified fireproof treated product of fallen cotton made of vegetable fibers.
落綿は綿糸、綿布等の紡織過程において多量に排出され
、従来、利用できない無価値な産業廃棄物として焼却さ
れている。また、落綿に限らず一般に植物繊維をセメン
トモルタルの増量材として使用すれば、モルタル硬化物
は当然脆弱となるので、硬化後のモルタルの強度確保を
目的とする骨材としてはほとんど使用されなかったので
ある。A large amount of fallen cotton is discharged during the spinning process of cotton yarn, cotton cloth, etc., and conventionally, it has been incinerated as unusable and worthless industrial waste. In addition, if plant fibers, not just fallen cotton, are used as bulking agents for cement mortar, the cured mortar naturally becomes brittle, so it is rarely used as aggregate for the purpose of ensuring the strength of mortar after hardening. It was.
ところが、この発明者の研究により、落綿のように脆弱
な植物繊維も、前記した特定の耐火処理を施すことによ
り、セメントモルタル組成物に対する骨材としてきわめ
て優良であり、モルタルの組成にこれを相当量配合して
も成型物の強度の低下もなく、成型用型枠から取り出し
た常温成型によるタイルの表面滑沢性も全く損なわれな
いことがわかったのである。However, the inventor's research has shown that even brittle plant fibers such as fallen cotton can be used as aggregates for cement mortar compositions by subjecting them to the specific fireproofing treatment described above. It has been found that even when a considerable amount is added, there is no decrease in the strength of the molded product, and the surface smoothness of the tiles taken out of the mold and molded at room temperature is not impaired at all.
以下、この発明につき若干の実施例とそれらの組成物を
用いた成型物の強度その他についての実験成績を掲げる
。Below, some examples of this invention and experimental results regarding the strength and other properties of molded products using these compositions are listed.
〔実施例１〕
下記するセメント組成物１００重量部（１容量部）に対
し下記する繊維質骨材１６重量部（２容量部）と無機質
骨材である川砂１００重量部（ｌ容量部）とを配合した
モルタル組成物である。ただし、前記セメント組成物は
つぎの組成を有している。[Example 1] 16 parts by weight (2 parts by volume) of the following fibrous aggregate and 100 parts by weight (1 part by volume) of river sand, which is an inorganic aggregate, were added to 100 parts by weight (1 part by volume) of the cement composition described below. This is a mortar composition containing However, the cement composition has the following composition.
（以下空白）
（１）ポートランドセメント ９０ 重量部■
モンモリロナイト ３．５〃■ジルコ
ニア ３ 〃■ステアリン酸ナ
トリウム ｌ ＃■ナフタリンスルホン酸
ナトリウム １ ＃■重炭酸ナトリウム
１．５〃溶液組成 割合 重量部 放置時間
計 １００ 重量部
前記植物繊維質骨材としては落綿をつぎの処理溶液で処
理し、常温乾燥後において薬剤吸着量が２１％であるも
のを使用した。前記処理溶液の組成および各溶液の放置
時間はつぎの通りである。(Blank below) (1) Portland cement 90 parts by weight■
Montmorillonite 3.5〃■Zirconia 3〃■Sodium stearate l #■Sodium naphthalene sulfonate 1 #■Sodium bicarbonate
1.5 Solution composition Proportion Parts by weight Standing time 100 parts by weight The plant fiber aggregate used was one that had been treated with the following treatment solution from fallen cotton and had a drug adsorption amount of 21% after drying at room temperature. . The composition of the treatment solution and the standing time of each solution are as follows.
（以下空白）
計 １００重量部
〔実施例２〕
１掲の実施例１において繊維質骨材１６重量部にかえ２
４重量部としたほかは実施例１と同様である。(Blank below) Total: 100 parts by weight [Example 2] In Example 1 listed above, 16 parts by weight of fibrous aggregate was replaced with 2
It is the same as Example 1 except that the amount is 4 parts by weight.
〔実施例３〕
下記するセメント組成物１００重量部（１容量部）に対
し実施例１と同一の繊維質骨材８重量部（１容量部）と
、実施例１と同一の川砂１００重置部（１容量部）とを
配合したモルタル鉗成物である。ただし、前記セメント
組成物はつぎの組成を存している。[Example 3] 8 parts by weight (1 part by volume) of the same fibrous aggregate as in Example 1 and 100 parts by weight of the same river sand as in Example 1 were placed on 100 parts by weight (1 part by volume) of the following cement composition. (1 part by volume). However, the cement composition has the following composition.
■アルミナセメント ８５ 重量部■モン
モリロナイト ８ 〃■ジルコニ
ア ５．５〃■ステアリン酸ナト
リウム １．５〃お、硬度、鏡面反射率、お
よび表面の気泡数については８Ｃ１１Ｘ２Ｃ１ｌＸ１．
３Ｃ１１の型枠に流し込み、養生後測定した。■Alumina cement 85 parts by weight■Montmorillonite 8〃■Zirconia 5.5〃■Sodium stearate 1.5〃The hardness, specular reflectance, and number of bubbles on the surface are 8C11X2C11X1.
It was poured into a 3C11 mold and measured after curing.
つぎの表に実験成績を掲げる。The following table lists the experimental results.
（以下空白）
計 １００ 重量部
〔実施例４〕
上掲の実施例３において繊維質骨材８重量部にかえ１６
重量部としたほかは実施例３と同様である。(Blank below) Total: 100 parts by weight [Example 4] In Example 3 above, 8 parts by weight of fibrous aggregate was replaced with 16 parts by weight.
The same as in Example 3 except that parts by weight were used.
上掲の各実施例にかかるモルタル組成物にそれぞれ適量
の水を加えて混練し、板ガラス上に置いた４Ｃ１ｌＸ４
Ｃ１１Ｘ １２Ｃ１１の二連型枠に混練物を流し込み養
生すれば４ ｃｍ方形のタイル様固形物各３個が得られ
るので、それらにつき−軸圧縮強度、および吸水率を測
定した。ただし、吸水率の測定は試料を２４時間水漬し
たものについて行った。な（発明の効果）
すなわち、前掲の実験成績かられかるように、この発明
にかかるモルタル組成物を常温で流し込み成型すること
により、強度、硬度、表面の滑沢性、低吸水性等、建物
内外の壁面化粧用建材に須要な緒特性が前記特開昭６２
−１６７２５号公報および特開昭６２−１６７２６号公
報に開示されているものに対し遜色のない非焼成タイル
の生産が可能である。のみならずこの発明によれば、無
価値な廃棄物とされている落綿をタイルの強度確保上必
要なモルタルの骨材に転化できるので、この発明は非焼
成タイルの生産コスト低下に寄与するところが多大であ
り、同時に産業廃棄物の排出に伴う環境汚染対策として
もきわめて有用である。A suitable amount of water was added to each of the mortar compositions according to the above examples, kneaded, and placed on a plate glass.
By pouring the kneaded material into a double mold of C11X 12C11 and curing it, three 4 cm square tile-like solids were obtained, and the -axial compressive strength and water absorption were measured for each of them. However, the water absorption rate was measured on samples that had been immersed in water for 24 hours. (Effects of the Invention) That is, as can be seen from the above experimental results, by pouring and molding the mortar composition according to the present invention at room temperature, it is possible to improve the strength, hardness, surface smoothness, low water absorption, etc. of buildings. The characteristics essential for decorative building materials for interior and exterior walls were identified in the aforementioned Japanese Patent Application Laid-Open No. 62
It is possible to produce non-fired tiles that are comparable to those disclosed in Japanese Patent Application Laid-open No. 16725-16725 and Japanese Patent Application Laid-open No. 16726-1983. In addition, according to this invention, fallen cotton, which is considered to be worthless waste, can be converted into aggregate for mortar, which is necessary to ensure the strength of tiles, so this invention contributes to lowering the production cost of non-fired tiles. However, it is extremely useful as a countermeasure against environmental pollution caused by the discharge of industrial waste.
特許出願人 藤 増 次 部Patent Applicant: Fuji Masuji Department
Claims (1)
維質骨材８〜４０重量部と、無機質骨材１００〜２００
重量部とを配合してなり、 前記セメント組成物は１００重量部中 （１）ポートランドセメント、アルミナセメントのうち
の少なくとも１種 ９３〜７７重量部と （２）モンモリロナイト、酸性白土、ベントナイトのう
ちの少なくとも１種 ２〜１０重量部と （３）ジルコニア、マグネシアのうちの少なくとも１種
２〜１０重量部と （４）ステアリン酸アルカリ金属塩、ステアリン酸アル
カリ土金属塩のうちの少なくとも１種 ０．５〜３重量
部と の配合物に対しさらに （５）ナフタリンスルホン酸アルカリ金属塩 ０．５〜
３重量部と （６）重炭酸アルカリ金属塩、塩化カルシウムのうちの
少なくとも１種 １〜３重量部と を添加し又は添加せずしてなり、 前記繊維質骨材は、落綿に下記の処理溶液を含浸乾燥し
たことにより溶液の薬剤成分１９〜２３重量％を含有し
てなり、 前記処理溶液は１００重量部中 （１）燐酸アンモニウム２０〜５０重量部に水８０〜５
０重量部を加え１００重量部としたものを１２時間以上
放置した溶液 ６０〜７０重量部と （２）燐酸グアニジン１５〜３５重量部に水８５〜６５
重量部を加え１００重量部としたものを６時間以上放置
した溶液 １５〜２５重量部と （３）塩化マグネシウム又は塩化カルシウムのうちの少
なくとも１種３０〜５０重量部に水７０〜５０重量部を
加え１００重量部としたものを３時間以上放置した溶液
１０〜２０重量部と を配合してなる 非焼成タイル生産用モルタル組成物[Scope of Claims] 8 to 40 parts by weight of the following fibrous aggregate and 100 to 200 parts by weight of the inorganic aggregate to 100 parts by weight of the following cement composition.
The cement composition contains (1) 93 to 77 parts by weight of at least one of Portland cement and alumina cement, and (2) montmorillonite, acid clay, and bentonite in 100 parts by weight. 2 to 10 parts by weight of at least one of (3) 2 to 10 parts by weight of at least one of zirconia and magnesia, and (4) at least one of alkali metal stearate and alkaline earth metal stearate 0 (5) Naphthalene sulfonic acid alkali metal salt 0.5 to 3 parts by weight
3 parts by weight and (6) 1 to 3 parts by weight of at least one of an alkali metal bicarbonate and calcium chloride, and the fibrous aggregate contains the following in the fallen cotton: By impregnating and drying the treatment solution, the solution contains 19 to 23% by weight of the drug component, and the treatment solution contains (1) 20 to 50 parts by weight of ammonium phosphate and 80 to 5% by weight of water.
60 to 70 parts by weight of a solution made by adding 0 part by weight to make 100 parts by weight for 12 hours or more and (2) 85 to 65 parts by weight of water to 15 to 35 parts by weight of guanidine phosphate.
A solution obtained by adding parts by weight to make 100 parts by weight and leaving it for 6 hours or more. 15 to 25 parts by weight and (3) 30 to 50 parts by weight of at least one of magnesium chloride or calcium chloride, and 70 to 50 parts by weight of water. A mortar composition for producing non-fired tiles, which is prepared by adding 100 parts by weight to 10 to 20 parts by weight of a solution left for 3 hours or more.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP375289A JPH02184550A (en) | 1989-01-12 | 1989-01-12 | Mortar composition for producing non-baked tile |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP375289A JPH02184550A (en) | 1989-01-12 | 1989-01-12 | Mortar composition for producing non-baked tile |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02184550A true JPH02184550A (en) | 1990-07-19 |
| JPH0557223B2 JPH0557223B2 (en) | 1993-08-23 |
Family
ID=11565926
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP375289A Granted JPH02184550A (en) | 1989-01-12 | 1989-01-12 | Mortar composition for producing non-baked tile |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02184550A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05139863A (en) * | 1991-11-13 | 1993-06-08 | Jiro Fujimasu | Portland cement-based lightweight concrete composition |
| CN104072089A (en) * | 2014-06-26 | 2014-10-01 | 中材高新成都能源技术有限公司 | Building material |
| CN111253140A (en) * | 2018-11-30 | 2020-06-09 | 华能中天节能科技集团有限责任公司 | Waste cotton residue block and preparation method thereof |
-
1989
- 1989-01-12 JP JP375289A patent/JPH02184550A/en active Granted
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05139863A (en) * | 1991-11-13 | 1993-06-08 | Jiro Fujimasu | Portland cement-based lightweight concrete composition |
| CN104072089A (en) * | 2014-06-26 | 2014-10-01 | 中材高新成都能源技术有限公司 | Building material |
| CN111253140A (en) * | 2018-11-30 | 2020-06-09 | 华能中天节能科技集团有限责任公司 | Waste cotton residue block and preparation method thereof |
| CN111253140B (en) * | 2018-11-30 | 2022-04-19 | 华能中天节能科技集团有限责任公司 | Waste cotton residue block and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0557223B2 (en) | 1993-08-23 |
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