JPH02145505A - Water-containing pack in a sheet form - Google Patents
Water-containing pack in a sheet formInfo
- Publication number
- JPH02145505A JPH02145505A JP29838188A JP29838188A JPH02145505A JP H02145505 A JPH02145505 A JP H02145505A JP 29838188 A JP29838188 A JP 29838188A JP 29838188 A JP29838188 A JP 29838188A JP H02145505 A JPH02145505 A JP H02145505A
- Authority
- JP
- Japan
- Prior art keywords
- water
- skin
- pack
- soluble polymer
- sheet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 26
- 229920003169 water-soluble polymer Polymers 0.000 claims abstract description 19
- 150000004781 alginic acids Chemical class 0.000 claims abstract description 16
- 235000010443 alginic acid Nutrition 0.000 claims abstract description 15
- 239000000783 alginic acid Substances 0.000 claims abstract description 15
- 229920000615 alginic acid Polymers 0.000 claims abstract description 15
- 229960001126 alginic acid Drugs 0.000 claims abstract description 15
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 7
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims abstract description 6
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims abstract description 6
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims abstract description 6
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims abstract description 6
- 239000001110 calcium chloride Substances 0.000 claims abstract description 5
- 229910001628 calcium chloride Inorganic materials 0.000 claims abstract description 5
- 239000000499 gel Substances 0.000 claims description 12
- 239000000017 hydrogel Substances 0.000 claims description 11
- 239000004615 ingredient Substances 0.000 claims description 11
- 235000011148 calcium chloride Nutrition 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 10
- 239000004745 nonwoven fabric Substances 0.000 abstract description 9
- 230000003796 beauty Effects 0.000 abstract description 2
- 239000011248 coating agent Substances 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 abstract description 2
- 230000007794 irritation Effects 0.000 abstract description 2
- 239000003906 humectant Substances 0.000 abstract 2
- 206010040880 Skin irritation Diseases 0.000 abstract 1
- 238000004132 cross linking Methods 0.000 abstract 1
- 230000002500 effect on skin Effects 0.000 abstract 1
- 230000036556 skin irritation Effects 0.000 abstract 1
- 231100000475 skin irritation Toxicity 0.000 abstract 1
- 210000003491 skin Anatomy 0.000 description 27
- 239000007864 aqueous solution Substances 0.000 description 12
- MTCFGRXMJLQNBG-REOHCLBHSA-N (2S)-2-Amino-3-hydroxypropansäure Chemical compound OC[C@H](N)C(O)=O MTCFGRXMJLQNBG-REOHCLBHSA-N 0.000 description 4
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000003020 moisturizing effect Effects 0.000 description 3
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- 229920003043 Cellulose fiber Polymers 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- CKLJMWTZIZZHCS-UHFFFAOYSA-N D-OH-Asp Natural products OC(=O)C(N)CC(O)=O CKLJMWTZIZZHCS-UHFFFAOYSA-N 0.000 description 2
- 108010010803 Gelatin Proteins 0.000 description 2
- CKLJMWTZIZZHCS-UWTATZPHSA-N L-Aspartic acid Natural products OC(=O)[C@H](N)CC(O)=O CKLJMWTZIZZHCS-UWTATZPHSA-N 0.000 description 2
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 2
- 102000016943 Muramidase Human genes 0.000 description 2
- 108010014251 Muramidase Proteins 0.000 description 2
- 108010062010 N-Acetylmuramoyl-L-alanine Amidase Proteins 0.000 description 2
- 229960005261 aspartic acid Drugs 0.000 description 2
- 230000003750 conditioning effect Effects 0.000 description 2
- -1 etc. are used Polymers 0.000 description 2
- 239000008273 gelatin Substances 0.000 description 2
- 229920000159 gelatin Polymers 0.000 description 2
- 235000019322 gelatine Nutrition 0.000 description 2
- 235000011852 gelatine desserts Nutrition 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000004325 lysozyme Substances 0.000 description 2
- 229960000274 lysozyme Drugs 0.000 description 2
- 235000010335 lysozyme Nutrition 0.000 description 2
- 229960001153 serine Drugs 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000002211 L-ascorbic acid Substances 0.000 description 1
- 235000000069 L-ascorbic acid Nutrition 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229940024606 amino acid Drugs 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229940088598 enzyme Drugs 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 210000001723 extracellular space Anatomy 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 229960002216 methylparaben Drugs 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 231100000344 non-irritating Toxicity 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 210000004243 sweat Anatomy 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/733—Alginic acid; Salts thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0212—Face masks
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/74—Biological properties of particular ingredients
- A61K2800/75—Anti-irritant
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Cosmetics (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、紫外線、汗、はこりなどで荒れた皮膚を正常
に戻すことを目的とした整肌および美容のためのパック
剤に関する。DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to a skin conditioning and beauty pack for the purpose of restoring rough skin due to ultraviolet rays, sweat, swelling, etc. to its normal state.
（従来の技術）
従来のパック剤は、泥状物を皮膚に塗布し、乾燥した後
、洗い流すか、剥がすかして使用していた。このような
パック剤では、塗布時に手指が汚れ、又乾燥に時間がか
かるなどの欠点があった。(Prior Art) Conventional packs are used by applying a slurry to the skin, drying it, and then washing it off or peeling it off. Such pack agents have the disadvantage that they stain hands and fingers during application and take a long time to dry.
この欠点を除くべく、近年、ポリアクリル酸及び／又は
ポリアクリル酸塩と架橋剤からなる架橋型含水ゲルを不
織布上に塗布したシート状パック剤が開発され（特開昭
５８−１８０４０８号公報）、又フィルム状物の片面に
α化澱粉、ポリアクリル酸ソーダ、カルボキシメチルセ
ルローズ、メチルセルローズ、ゼラチン、カゼインなど
わずかの水分により粘着性を発現する皮膚に無害な糊料
の乾燥薄層或は該糊料の微粉末の分散した層を設け、使
用時には水を付与するシート状のパック剤が開発され（
特開昭６０−１６５９０２号公報）でいる。In order to eliminate this drawback, in recent years, a sheet-like pack agent has been developed in which a cross-linked hydrogel consisting of polyacrylic acid and/or polyacrylate and a cross-linking agent is coated on a non-woven fabric (Japanese Patent Application Laid-Open No. 180408/1983). In addition, on one side of the film-like material, a dry thin layer of a glue that is harmless to the skin, such as pregelatinized starch, sodium polyacrylate, carboxymethyl cellulose, methyl cellulose, gelatin, or casein, which becomes sticky with a small amount of moisture, or A sheet-like pack agent has been developed that has a layer of dispersed fine powder of glue and adds water during use (
(Japanese Unexamined Patent Publication No. 165902/1982).
しかし、パック剤は、皮膚表面の汚れを吸着除去し、肌
を滑らかにする皮膚調整用の基礎化粧料であって、その
使用時には空気を遮断し、皮膚表面に分泌される皮膚成
分を空気酸化させることなくパック剤層の下に蓄積させ
１表皮を潤軟にし、又細胞間隙や皮孔を広げてパック剤
内の有効成分の吸収を促すものであり、そのため、パッ
ク剤は皮膚に密着し、皮膚を覆う層は緻密で透過性が小
さい必要がある。従来のシート状パック剤についてはこ
の点が未だ不十分であるとされていた。However, pack agents are basic cosmetics for skin conditioning that adsorb and remove dirt on the skin surface and smooth the skin. It accumulates under the pack agent layer without causing any damage, moisturizes the epidermis, and widens the intercellular spaces and skin pores to promote absorption of the active ingredients in the pack. Therefore, the pack adheres closely to the skin. , the layer covering the skin must be dense and have low permeability. Conventional sheet pack agents were considered to be insufficient in this respect.
（発明が解決しようとする課題）
本発明は、使用時に水を付与するなどの必要がなく、使
用が筒車であり、又皮膚への密着性、バック剤層の緻密
性を改善したシート状含水パック剤を目的とする６
（課題を解決するための手段）
本発明は、アルギン酸、水溶性高分子物及び架橋剤を必
須成分とする架橋型含水ゲルがシート状支持体上に保持
され、該含水ゲルに美肌成分が配合されているシート状
含水パック剤である。(Problems to be Solved by the Invention) The present invention does not require adding water during use, uses an hour wheel, and has a sheet-like form with improved adhesion to the skin and density of the backing agent layer. Aiming for a water-containing pack agent 6 (Means for solving the problem) The present invention provides a cross-linked hydrogel containing alginic acid, a water-soluble polymer, and a cross-linking agent as essential components, which is held on a sheet-like support, This is a sheet-shaped water-containing pack agent in which skin-beautifying ingredients are blended into the water-containing gel.
本発明における前記のシート状支持体に保持された架橋
型含水ゲルは、アルギン酸と水溶性高分子物の混合の水
溶液を、所定の形に切断したシート状支持体をセットし
た容器に流し込んで、該シート状支持体に該混合水溶液
を含浸させ、次いでこれを架橋剤水溶液、例えば塩化カ
ルシウム水溶液で処理して作る。The cross-linked hydrogel held on the sheet-like support in the present invention is obtained by pouring an aqueous solution of a mixture of alginic acid and a water-soluble polymer into a container set with a sheet-like support cut into a predetermined shape. The sheet-like support is impregnated with the mixed aqueous solution and then treated with an aqueous crosslinking agent solution, such as an aqueous calcium chloride solution.
この架橋型含水ゲルにおいては、アルギン酸の分子間に
カルシウムによる架橋が形成され、そして分子間架橋し
たアルギン酸の三次元網状構造がゲル骨格を形成し、水
溶性高分子物の分子がアルギン酸との水素結合によりゲ
ル内に内蔵された状態となる。又、このゲルは９０％以
上の水を含むことが出来る性質を持つので、美肌成分を
ゲル内に導入することができる。In this cross-linked hydrogel, calcium cross-links are formed between the alginic acid molecules, the three-dimensional network structure of the intermolecularly cross-linked alginic acid forms a gel skeleton, and the water-soluble polymer molecules combine with alginic acid to form hydrogen bonds. Due to binding, it becomes incorporated into the gel. Moreover, since this gel has the property of containing 90% or more of water, skin-beautifying ingredients can be introduced into the gel.
本発明のシート状含水パック剤においては、分子間が架
橋されたアルギン酸の三次元網状構造内に水可溶性高分
子物の水溶液が内蔵されているので、パラツク剤の層が
緻密になり、又このパック剤は、使用時に離水作用によ
り水溶性高分子物本溶液が皮膚面に供給されてパック剤
の皮膚への密−若作がよくなる。そのためパック効果が
著しく向上する。また使用後、皮膚面からパック剤を取
り去っても、水溶性高分子物の被覆が皮膚面に形成され
るので、皮膚の保湿効果が保持できる。水溶性高分子物
はアルギン酸のゲルに柔軟性を与える作用もするので、
パック剤の使用時の感触が良くなる。In the sheet-shaped water-containing pack agent of the present invention, an aqueous solution of a water-soluble polymer is contained within the three-dimensional network structure of alginic acid, which is intermolecularly cross-linked, so that the layer of the pack agent becomes dense and this When the pack agent is used, the main solution of the water-soluble polymer is supplied to the skin surface due to the water-repelling action, and the pack agent becomes more densely applied to the skin. Therefore, the pack effect is significantly improved. Furthermore, even if the pack agent is removed from the skin surface after use, a water-soluble polymer coating is formed on the skin surface, so that the moisturizing effect on the skin can be maintained. The water-soluble polymer also has the effect of giving flexibility to the alginic acid gel, so
The pack agent feels better when used.
また、本発明のシート状含水パック剤には美肌成分を含
ませたので、使用時に水溶性高分子物の水溶液と共に皮
膚に作用し、美肌効果を発揮する。In addition, since the sheet-shaped water-containing pack agent of the present invention contains a skin-beautifying ingredient, it acts on the skin together with the aqueous solution of the water-soluble polymer during use, and exhibits a skin-beautifying effect.
水溶性高分子物としては、ポリビニルピロリドン、ポリ
ビニルアルコール、ゼラチンなどが用いられるが、特に
ポリビニルピロリドンが、含水ゲルへの柔軟性付与、皮
膚への保湿効果が優れているので好ましい。アルギン酸
と水溶性高分子物との配合比は１：２〜３の範囲が好ま
しい。２より少ないとゲルは硬くなり、また３より大き
いと軟らかすぎる。架橋剤としてはアルギン酸を分子間
架橋し、ゲル化し得るものが用いられ、各種金属塩が使
用できるが、カルシウムの塩、例えば塩化カルシウムが
好ましい。また美肌成分としては、Ｌ−セリン、Ｌ−ア
スパラギン酸等のアミン酸、塩化リゾチーム等の酵素が
使用される。As the water-soluble polymer, polyvinylpyrrolidone, polyvinyl alcohol, gelatin, etc. are used, and polyvinylpyrrolidone is particularly preferred because it imparts flexibility to the hydrogel and has an excellent moisturizing effect on the skin. The blending ratio of alginic acid and water-soluble polymer is preferably in the range of 1:2 to 3. If it is less than 2, the gel will be hard, and if it is more than 3, it will be too soft. As the crosslinking agent, one that can intermolecularly crosslink alginic acid to form a gel is used, and various metal salts can be used, but calcium salts, such as calcium chloride, are preferred. Further, as skin beautifying ingredients, amino acids such as L-serine and L-aspartic acid, and enzymes such as lysozyme chloride are used.
シート状支持体としては、フィルム、紙、不織布、布帛
などが用いられるが、含水ゲルの保持性、価格の点から
して不織布を使用するのが好ましい。As the sheet-like support, a film, paper, non-woven fabric, cloth, etc. can be used, but it is preferable to use a non-woven fabric from the viewpoint of retention of hydrogel and cost.
又、不織布は含水ゲルを保持させるものであるため、親
水性であることが好ましく、したがって不織布は再生セ
ルローズ繊維等の親水性繊維で構成されたものが好まし
い。In addition, since the nonwoven fabric retains a hydrogel, it is preferably hydrophilic, and therefore, the nonwoven fabric is preferably composed of hydrophilic fibers such as recycled cellulose fibers.
本発明のシート状含水パック剤は、その保存時に揮発性
成分が揮散しないように、使用時までは密封容器内１例
えばアルミニウム・ラミネート袋などに保存しておくこ
とが好ましい。使用には、密封容器内から取り出し、直
ちに皮膚に当接できるので簡便である。The sheet-shaped water-containing pack agent of the present invention is preferably stored in a sealed container 1, such as an aluminum laminate bag, until it is used, to prevent volatile components from evaporating during storage. It is convenient to use because it can be removed from the sealed container and immediately applied to the skin.
実施例
アルギン酸ナトリウムの１％水溶液とポリビニルピロリ
ドンの１％水溶液を１＝３に混合する。所定の形に切断
した再生セルローズ繊維不織布を容器内に置き、これに
上記混合液を流し込み、不織布に混合液を含ませる。混
合液を含んだ不織布を、０．５モル濃度の塩化カルシウ
ム水溶液に３０分間浸漬してゲル化し、その後水洗いし
て過剰の塩化カルシウムを除去する。Example A 1% aqueous solution of sodium alginate and a 1% aqueous solution of polyvinylpyrrolidone are mixed in a ratio of 1=3. A regenerated cellulose fiber nonwoven fabric cut into a predetermined shape is placed in a container, and the liquid mixture is poured into the container so that the nonwoven fabric is impregnated with the liquid mixture. The nonwoven fabric containing the mixed solution is immersed in a 0.5 molar calcium chloride aqueous solution for 30 minutes to form a gel, and then washed with water to remove excess calcium chloride.
Ｌ−アスコルビン酸、Ｌ−セリン、Ｌ−アスパラギン酸
、塩化リゾチームを各々２重量％およびメチルパラベン
（Ｐ−オキシ安息香酸メチル）を０．２重量％含有する
ように１０％アルコール水溶液に加え美肌成分水溶液を
調整し、これに洗浄したゲルを１日間浸漬して美肌成分
を含浸させる。本発明のシート状含水パック剤が得られ
る。A skin-beautifying ingredient aqueous solution was added to a 10% alcohol aqueous solution to contain 2% by weight each of L-ascorbic acid, L-serine, L-aspartic acid, and lysozyme chloride, and 0.2% by weight of methylparaben (methyl P-oxybenzoate). The washed gel is soaked in the gel for one day to impregnate it with skin-beautifying ingredients. A sheet-like water-containing pack agent of the present invention is obtained.
（発明の効果）
本発明のシート状含水パック剤は、そのまま直ちに使用
でき簡便である。そして、生体に非刺激性のアルギン酸
を架橋型含水ゲルの原料に用い、又生成した架橋型含水
ゲルに水溶性高分子水溶液を内蔵させたから、シート状
支持体上に形成されたパック剤の層は柔軟性に富み、緻
密であり、又使用時には皮膚面に水溶性高分子水溶液が
供給されるので皮膚への密着性がよくなる。(Effects of the Invention) The sheet-shaped water-containing pack agent of the present invention is convenient and can be used immediately as it is. Since alginic acid, which is non-irritating to living organisms, was used as a raw material for the cross-linked hydrogel, and the resulting cross-linked hydrogel contained a water-soluble polymer aqueous solution, a layer of the pack agent was formed on the sheet-like support. is highly flexible and dense, and when used, a water-soluble polymer aqueous solution is supplied to the skin surface, resulting in good adhesion to the skin.
したがって、本発明のシート状含水パック剤は、皮膚へ
の刺激が少なく、バック剤層が柔軟且つ緻密で、又皮膚
への密着性がよいのでパック効果を高めることが出来る
。また、シート状含水パック剤には水溶性高分子水溶液
を含ませたから、使用後該パック剤を皮膚から取り除い
ても、皮膚面に水溶性高分子物の皮膜が形成され、保湿
効果を持続できる効果がある。Therefore, the sheet-shaped water-containing pack of the present invention causes less irritation to the skin, has a soft and dense backing agent layer, and has good adhesion to the skin, so that the pack effect can be enhanced. In addition, since the sheet-shaped water-containing pack contains a water-soluble polymer aqueous solution, even if the pack is removed from the skin after use, a film of the water-soluble polymer is formed on the skin surface, maintaining the moisturizing effect. effective.
さらに、本発明のシート状含水パック剤には美肌成分を
含ませたから、使用時に美肌成分が皮膚に作用し、パッ
ク効果と同時に美肌成分の効果を発揮させることができ
る。Furthermore, since the sheet-shaped water-containing pack agent of the present invention contains skin-beautifying ingredients, the skin-beautifying ingredients act on the skin during use, and the skin-beautifying ingredients can exhibit the effects of the skin-beautifying ingredients at the same time as the pack effect.
Claims (1)
とする架橋型含水ゲルがシート状支持体上に保持され、
該含水ゲルに美肌成分が配合されていることを特徴とす
るシート状含水パック剤。 ２ 架橋型含水ゲルがアルギン酸、ポリビニルピロリド
ン及び塩化カルシウムを必須成分とする請求項第１項記
載のシート状含水パック剤。 ３ アルギン酸とポリビニルピロリドンとの割合が重量
比で１：２〜３である請求項第２項記載のシート状含水
パック剤。[Claims] 1. A crosslinked hydrogel containing alginic acid, a water-soluble polymer, and a crosslinking agent as essential components is held on a sheet-like support,
A sheet-shaped water-containing pack agent characterized in that the water-containing gel contains a skin-beautifying ingredient. 2. The sheet-shaped water-containing pack agent according to claim 1, wherein the cross-linked hydrogel contains alginic acid, polyvinylpyrrolidone, and calcium chloride as essential components. 3. The sheet-shaped water-containing pack agent according to claim 2, wherein the ratio of alginic acid to polyvinylpyrrolidone is 1:2 to 3 by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63298381A JPH0725659B2 (en) | 1988-11-28 | 1988-11-28 | Sheet-shaped water-containing pack agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63298381A JPH0725659B2 (en) | 1988-11-28 | 1988-11-28 | Sheet-shaped water-containing pack agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02145505A true JPH02145505A (en) | 1990-06-05 |
| JPH0725659B2 JPH0725659B2 (en) | 1995-03-22 |
Family
ID=17858964
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63298381A Expired - Lifetime JPH0725659B2 (en) | 1988-11-28 | 1988-11-28 | Sheet-shaped water-containing pack agent |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0725659B2 (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07330575A (en) * | 1994-06-10 | 1995-12-19 | Kao Corp | Sheet-like pack |
| US6042844A (en) * | 1996-03-04 | 2000-03-28 | Kao Corporation | Sheet pack |
| US6306382B1 (en) | 1991-05-15 | 2001-10-23 | Kao Corporation | Keratotic plug remover |
| JP2002255742A (en) * | 2001-02-28 | 2002-09-11 | Kao Corp | Pack cosmetic |
| US6602513B2 (en) | 1997-11-27 | 2003-08-05 | Shiseido Co., Ltd. | Face pack |
| US6942869B2 (en) | 1999-05-12 | 2005-09-13 | Kao Corporation | Keratotic plug remover |
| JP2008519864A (en) * | 2004-11-12 | 2008-06-12 | ザ プロクター アンド ギャンブル カンパニー | Cosmetic treatment article comprising a substrate and a gel composition |
| KR100988604B1 (en) * | 2008-04-16 | 2010-10-18 | 한울생약 주식회사 | Manufacturing method of dermatological patch sheet |
| WO2010140146A2 (en) | 2009-06-01 | 2010-12-09 | Technion - Research & Development Foundation Ltd | Sealants, manufacturing thereof, and applications thereof |
| JP2011102281A (en) * | 2009-11-12 | 2011-05-26 | Adeka Corp | Sheet-like pack agent |
| CN111511592A (en) * | 2018-01-09 | 2020-08-07 | 法雷奥日本株式会社 | Vehicle air conditioner and method for controlling vehicle air conditioner |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI233810B (en) | 1999-02-19 | 2005-06-11 | Hisamitsu Pharmaceutical Co | A paster sheet |
| JP4557596B2 (en) * | 2004-04-28 | 2010-10-06 | 積水化成品工業株式会社 | External patch, method for producing the same, and method for using the same |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5070533A (en) * | 1973-10-26 | 1975-06-12 | ||
| JPS55127311A (en) * | 1979-03-23 | 1980-10-02 | Kishiyouhin Kagaku Kaihou Kenkyusho:Kk | Pack cosmetic |
| JPS55127312A (en) * | 1979-03-23 | 1980-10-02 | Kishiyouhin Kagaku Kaihou Kenkyusho:Kk | Pack cosmetic |
| JPS58180408A (en) * | 1982-04-15 | 1983-10-21 | Nitto Electric Ind Co Ltd | Pack in the sheet form |
| JPS6069012A (en) * | 1983-08-02 | 1985-04-19 | ブレンダツクス−ベルケ ア−ル．シユナイダ− ゲゼルシヤフト ミツト ベシユレンクテル ハフツンク ウント コンパニ− | Skin care composition |
| JPS60165902A (en) * | 1984-02-10 | 1985-08-29 | 旭化成株式会社 | Beauty pack material, its production and use |
| JPS61176512A (en) * | 1985-01-30 | 1986-08-08 | Kyoko Watanabe | Lip-protective agent |
| JPS61251607A (en) * | 1985-04-30 | 1986-11-08 | Shiseido Co Ltd | Pack cosmetic |
| JPS633551A (en) * | 1986-06-23 | 1988-01-08 | Nec Eng Ltd | Camp-on system |
| JPS6357508A (en) * | 1986-08-28 | 1988-03-12 | Mikimoto Seiyaku Kk | Film-forming cosmetic pack |
-
1988
- 1988-11-28 JP JP63298381A patent/JPH0725659B2/en not_active Expired - Lifetime
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5070533A (en) * | 1973-10-26 | 1975-06-12 | ||
| JPS55127311A (en) * | 1979-03-23 | 1980-10-02 | Kishiyouhin Kagaku Kaihou Kenkyusho:Kk | Pack cosmetic |
| JPS55127312A (en) * | 1979-03-23 | 1980-10-02 | Kishiyouhin Kagaku Kaihou Kenkyusho:Kk | Pack cosmetic |
| JPS58180408A (en) * | 1982-04-15 | 1983-10-21 | Nitto Electric Ind Co Ltd | Pack in the sheet form |
| JPS6069012A (en) * | 1983-08-02 | 1985-04-19 | ブレンダツクス−ベルケ ア−ル．シユナイダ− ゲゼルシヤフト ミツト ベシユレンクテル ハフツンク ウント コンパニ− | Skin care composition |
| JPS60165902A (en) * | 1984-02-10 | 1985-08-29 | 旭化成株式会社 | Beauty pack material, its production and use |
| JPS61176512A (en) * | 1985-01-30 | 1986-08-08 | Kyoko Watanabe | Lip-protective agent |
| JPS61251607A (en) * | 1985-04-30 | 1986-11-08 | Shiseido Co Ltd | Pack cosmetic |
| JPS633551A (en) * | 1986-06-23 | 1988-01-08 | Nec Eng Ltd | Camp-on system |
| JPS6357508A (en) * | 1986-08-28 | 1988-03-12 | Mikimoto Seiyaku Kk | Film-forming cosmetic pack |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6306382B1 (en) | 1991-05-15 | 2001-10-23 | Kao Corporation | Keratotic plug remover |
| US6607719B2 (en) | 1991-05-15 | 2003-08-19 | Kao Corporation | Keratotic plug remover |
| JPH07330575A (en) * | 1994-06-10 | 1995-12-19 | Kao Corp | Sheet-like pack |
| US6042844A (en) * | 1996-03-04 | 2000-03-28 | Kao Corporation | Sheet pack |
| US6221382B1 (en) | 1996-03-04 | 2001-04-24 | Kao Corporation | Sheet pack |
| US6602513B2 (en) | 1997-11-27 | 2003-08-05 | Shiseido Co., Ltd. | Face pack |
| US6942869B2 (en) | 1999-05-12 | 2005-09-13 | Kao Corporation | Keratotic plug remover |
| JP4719364B2 (en) * | 2001-02-28 | 2011-07-06 | 花王株式会社 | Pack cosmetic |
| JP2002255742A (en) * | 2001-02-28 | 2002-09-11 | Kao Corp | Pack cosmetic |
| JP2008519864A (en) * | 2004-11-12 | 2008-06-12 | ザ プロクター アンド ギャンブル カンパニー | Cosmetic treatment article comprising a substrate and a gel composition |
| KR100988604B1 (en) * | 2008-04-16 | 2010-10-18 | 한울생약 주식회사 | Manufacturing method of dermatological patch sheet |
| WO2010140146A2 (en) | 2009-06-01 | 2010-12-09 | Technion - Research & Development Foundation Ltd | Sealants, manufacturing thereof, and applications thereof |
| US20120132105A1 (en) * | 2009-06-01 | 2012-05-31 | Havazelet Bianco-Peled | Sealants, manufacturing thereof, and application thereof |
| EP2638922A1 (en) | 2009-06-01 | 2013-09-18 | Technion Research & Development Foundation Ltd. | Multi-components adhesives, manufacturing thereof, and applications thereof |
| US9216234B2 (en) | 2009-06-01 | 2015-12-22 | Technion Research & Development Foundation Ltd. | Sealants, manufacturing thereof, and application thereof |
| JP2011102281A (en) * | 2009-11-12 | 2011-05-26 | Adeka Corp | Sheet-like pack agent |
| CN111511592A (en) * | 2018-01-09 | 2020-08-07 | 法雷奥日本株式会社 | Vehicle air conditioner and method for controlling vehicle air conditioner |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0725659B2 (en) | 1995-03-22 |
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