JPH02125878A - Production of surface treated steel sheet coated with monophenylsilica film - Google Patents
Production of surface treated steel sheet coated with monophenylsilica filmInfo
- Publication number
- JPH02125878A JPH02125878A JP27837588A JP27837588A JPH02125878A JP H02125878 A JPH02125878 A JP H02125878A JP 27837588 A JP27837588 A JP 27837588A JP 27837588 A JP27837588 A JP 27837588A JP H02125878 A JPH02125878 A JP H02125878A
- Authority
- JP
- Japan
- Prior art keywords
- steel sheet
- film
- monophenyltrialkoxysilane
- surface treated
- treated steel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 23
- 239000010959 steel Substances 0.000 title claims abstract description 23
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 150000004703 alkoxides Chemical class 0.000 claims abstract description 7
- 238000010438 heat treatment Methods 0.000 claims abstract description 7
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 5
- 229910052721 tungsten Inorganic materials 0.000 claims abstract description 5
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 4
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 3
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 3
- 229910052727 yttrium Inorganic materials 0.000 claims abstract description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 13
- 238000000034 method Methods 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 7
- 239000000377 silicon dioxide Substances 0.000 claims description 7
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical class C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 claims description 5
- 230000001476 alcoholic effect Effects 0.000 abstract description 7
- 238000000576 coating method Methods 0.000 abstract description 6
- 239000011248 coating agent Substances 0.000 abstract description 5
- 229910044991 metal oxide Inorganic materials 0.000 abstract description 3
- 150000004706 metal oxides Chemical class 0.000 abstract description 3
- YRKCREAYFQTBPV-UHFFFAOYSA-N acetylacetone Chemical compound CC(=O)CC(C)=O YRKCREAYFQTBPV-UHFFFAOYSA-N 0.000 abstract 2
- 229910052809 inorganic oxide Inorganic materials 0.000 description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- 238000005260 corrosion Methods 0.000 description 4
- 230000007797 corrosion Effects 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000009833 condensation Methods 0.000 description 3
- 230000005494 condensation Effects 0.000 description 3
- 230000018044 dehydration Effects 0.000 description 3
- 238000006297 dehydration reaction Methods 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- RYSXWUYLAWPLES-MTOQALJVSA-N (Z)-4-hydroxypent-3-en-2-one titanium Chemical compound [Ti].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O RYSXWUYLAWPLES-MTOQALJVSA-N 0.000 description 1
- YOBOXHGSEJBUPB-MTOQALJVSA-N (z)-4-hydroxypent-3-en-2-one;zirconium Chemical compound [Zr].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O YOBOXHGSEJBUPB-MTOQALJVSA-N 0.000 description 1
- SIKJAQJRHWYJAI-UHFFFAOYSA-O 1H-indol-1-ium Chemical compound C1=CC=C2[NH2+]C=CC2=C1 SIKJAQJRHWYJAI-UHFFFAOYSA-O 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- HHFAWKCIHAUFRX-UHFFFAOYSA-N ethoxide Chemical compound CC[O-] HHFAWKCIHAUFRX-UHFFFAOYSA-N 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- -1 methyl silica Chemical compound 0.000 description 1
- 229960005235 piperonyl butoxide Drugs 0.000 description 1
- IKNCGYCHMGNBCP-UHFFFAOYSA-N propan-1-olate Chemical compound CCC[O-] IKNCGYCHMGNBCP-UHFFFAOYSA-N 0.000 description 1
- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
- C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
- C23C18/1204—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material inorganic material, e.g. non-oxide and non-metallic such as sulfides, nitrides based compounds
- C23C18/1208—Oxides, e.g. ceramics
- C23C18/1216—Metal oxides
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/02—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition
- C23C18/12—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material
- C23C18/1204—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by thermal decomposition characterised by the deposition of inorganic material other than metallic material inorganic material, e.g. non-oxide and non-metallic such as sulfides, nitrides based compounds
- C23C18/1208—Oxides, e.g. ceramics
- C23C18/1212—Zeolites, glasses
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Inorganic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemically Coating (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、有機官能基を有するシリカ膜を被覆した表面
処理鋼板の耐熱性を改善したものの製造方法に関する。DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to a method for producing a surface-treated steel sheet coated with a silica film having an organic functional group and having improved heat resistance.
（従米技術）
鋼板の耐久性を向」二させるノｊ法として、鋼板衣■
面に無機酸化物皮膜を形成する方法がある。しかし、無
機酸化物皮膜は、加工時に割れや剥離を生じや１いので
、例えば、メチルシリカ膜のように、酸化物皮膜中にメ
チル基を導入して皮膜を柔軟にするＪＪ法が行なわれて
いる。(Junior technology) As a method for improving the durability of steel sheets, there is a method of forming an inorganic oxide film on the coating surface of the steel sheets. However, inorganic oxide films are prone to cracking and peeling during processing, so for example, the JJ method, which introduces methyl groups into the oxide film to make the film flexible, is used, as in the case of methyl silica films. ing.
（発明が解決しようとする問題点）
しかしながら、無機酸化物皮膜中にメチル基を導入した
ものは、有機官能基を導入しない純粋な無機酸化物皮膜
に比べて加工性は良好であるが、加熱した場合、メチル
基が熱分解してしまい、耐熱性が劣るという問題があっ
た。(Problems to be Solved by the Invention) However, inorganic oxide films with methyl groups introduced have better processability than pure inorganic oxide films without organic functional groups; In this case, there was a problem that the methyl group would be thermally decomposed, resulting in poor heat resistance.
本発明は、かかる点に鑑み、耐熱性を改善した金属酸化
物皮膜の表面処理鋼板の製造方法を提供するものである
。In view of this point, the present invention provides a method for manufacturing a steel sheet surface-treated with a metal oxide film that has improved heat resistance.
（問題点を解決するための手Ｐｆｆｉ ）本発明は、有
機官能基を導入した無機酸化物皮膜のうち、ｅにシリカ
皮膜に着目して、メチル基を熱分Ｍ温度の高いフェニル
基にして耐熱性を向上させた。(Hands for solving the problem Pffi) The present invention focuses on a silica film for e among inorganic oxide films into which organic functional groups have been introduced, and replaces methyl groups with phenyl groups having a high thermal M temperature. Improved heat resistance.
ｒなわち、本発明は、モ７フェニルトリアルコキシシラ
ンの０．００５モル／ｌ以上のアルコール溶液またはこ
の溶液に８１、ＴＩ、Ｚｒ、Ａｌ、Ｗ、 Ｃｅ、 Ｓｎ
、Ｙのアルコキシドまたはアセチルアセトネート塩の１
種または２種以上をモアフェニルトリアルコキシシラン
に対して、１モル％以１−添加した溶液を鋼板に塗布し
た後、１ （１０℃以上に加熱することによりモノフェ
ニルシリカ膜被覆表面処理鋼板を製造するようにした。In other words, the present invention provides an alcoholic solution of mo7phenyltrialkoxysilane of 0.005 mol/l or more or a solution containing 81, TI, Zr, Al, W, Ce, Sn.
, 1 of the alkoxide or acetylacetonate salt of Y
After coating a steel plate with a solution containing at least 1 mol % of the monophenyltrialkoxysilane, the monophenyl silica film-coated surface-treated steel plate is heated to 10°C or higher. I decided to manufacture it.
モアフェニルトリアルコキシシランのアルコル溶液を鋼
板に塗布して、１１１０ ℃以上１こ加熱すると、千７
フエニルトリアルコキシシランは、脱水縮合して架橋し
、それらの酸化物皮膜を形成する。同様にＳｉ、 Ｔｉ
、Ｚｒなどのアルコキシドまたはアセチルアセトネート
塩のアルコール溶液を鋼板に塗布して、１００℃以−ヒ
に加熱すると、脱水縮合、架橋し、それらの金属の酸化
物皮膜を形成Ｖる。When an alcoholic solution of moaphenyltrialkoxysilane is applied to a steel plate and heated to 1110°C or higher,
Phenyltrialkoxysilanes undergo dehydration condensation and crosslinking to form their oxide films. Similarly, Si, Ti
When an alcoholic solution of an alkoxide or acetylacetonate salt such as , Zr, etc. is applied to a steel plate and heated to 100° C. or higher, dehydration condensation and crosslinking occur to form an oxide film of these metals.
本発明で使用するモアフェニルトリアルコキシシランと
しては、アルコキシ基がメトキシ基、エトキシ基、プロ
ポキシ基、【１−ブトキシ基などでよく、また、Ｓｌ、
ｌ’ｉ、 Ｚｒ、Ａｌ、Ｗ、 Ｃｅ、 Ｓｎ、Ｙのアル
コキシドとしては、メＩ・キシド、エトキシド、プロポ
キシド、１１−ブ１キシドなどでよい、さらに、アセチ
ルアセｌネート塩としては、アセチルアセ１ネー１ジル
コニウム、アセチルアセ１ネートチタン、アセチルアセ
トネートインドリウムなどでよい。In the moaphenyltrialkoxysilane used in the present invention, the alkoxy group may be a methoxy group, an ethoxy group, a propoxy group, a [1-butoxy group, etc.;
The alkoxide of l'i, Zr, Al, W, Ce, Sn, Y may be methyl oxide, ethoxide, propoxide, 11-butoxide, etc. Furthermore, the acetylacelate salt may be acetylacelate salt. It may be zirconium acetylacetonate, titanium acetylacetonate, indolium acetylacetonate, or the like.
モアフェニルトリアルコキシシランのアルフル溶液は、
塗布に上り均一な皮膜を形成するために、濃度を０．０
０５モル／Ｃ以上にする必要がある。Arfur solution of moaphenyltrialkoxysilane is
In order to form a uniform film upon application, the concentration was set to 0.0.
It is necessary to make it more than 0.05 mol/C.
また、皮膜の耐食性、耐湿性を改善するために、Ｓｌ、
１□ｉ、７ｒ、Ａｌ、Ｗ、Ｃｅ、 Ｓ＋＋、Ｙのアルコ
キシドまたはアセチルアセ１ネート塩を添加する場合は
、モアフェニルトリアルコキシシランに対して、１モル
％以上添加する。In addition, in order to improve the corrosion resistance and moisture resistance of the film, Sl,
When an alkoxide or acetylacemonate salt of 1□i, 7r, Al, W, Ce, S++, or Y is added, it is added in an amount of 1 mol % or more based on the moaphenyltrialkoxysilane.
モアフェニルトリアルコキシシランやアセチルアセトネ
ート塩を分散、溶解するアルコールは、これらを均一に
分散、溶解できるものであればよく、例えば、メタノー
ル、エタ／−ル、イソプロピルアルコール、ブタメール
などでよい。また、トルエン、キシレンなどの芳香族炭
化水素を使用できる。The alcohol for dispersing and dissolving the moaphenyltrialkoxysilane and the acetylacetonate salt may be any alcohol that can uniformly disperse and dissolve them, such as methanol, ethanol, isopropyl alcohol, butamel, and the like. Furthermore, aromatic hydrocarbons such as toluene and xylene can be used.
鋼板への塗布は、浸漬引き上げ法、スプレー法、ロール
コート法、スピン法など溶液を均一に塗布できる方法に
よればよい。塗布祉は、乾燥皮膜厚で０．０１μｍ以上
にするのが好ましい、。The solution may be applied to the steel plate by any method capable of uniformly applying the solution, such as a dipping method, a spray method, a roll coating method, or a spin method. The coating thickness is preferably 0.01 μm or more in terms of dry film thickness.
アルコール溶液塗布後の鋼板加熱は、Ｉ （１（１’Ｃ
以上で行う。１ （＋ （１℃未満であると、脱水縮合
か不十分なため、十分架橋せず、均一な皮膜が形成され
ない。加熱温度の−に限は４ （１（１’Ｃにするのが
好ましい。４００℃より高くすると、フェニル基の分解
が起こり、完全なモノフェニルシリカ膜となりに（い。Heating the steel plate after applying the alcohol solution is I (1(1'C
Do the above. 1 (+ (If it is less than 1℃, the dehydration condensation will be insufficient, so it will not be crosslinked sufficiently and a uniform film will not be formed. If the temperature is higher than 400°C, the phenyl groups will decompose, resulting in a complete monophenyl silica film.
鋼板としては、目的、用途に応じて選択すればよく、例
えば、ステンレス鋼板、酸化Ｘ１色ステンレス鋼板、各
種めっき鋼板などを使用すればよい。The steel plate may be selected depending on the purpose and use, and for example, a stainless steel plate, an oxidized X1 color stainless steel plate, various plated steel plates, etc. may be used.
（実施例）
モノフェニルトリアルフキ２２９２１モルにヌ・１して
、Ｉ！２０および１１３１１０．をそれぞれ４モルおよ
び０．０５モル添加したモノフェニルトリアルコキシシ
ランのアルコール溶液またはこの溶液にＳｌ、１゛１、
Ｚ＋などのアルコキシドまたはアヤチルアセトネ１塩を
添加したものを調製して、これらの溶液にアセトン中で
１５分間超音波脱脂した鋼板を浸漬し、（１，Ｉ＋ｎ／
分の一定速度で引き」−げ、均一に塗布した。(Example) Add 1 to 22,921 moles of monophenyl trialfoxy, and I! 20 and 113110. An alcoholic solution of monophenyltrialkoxysilane to which 4 mol and 0.05 mol of were added, respectively, or to this solution Sl, 1゛1,
A solution containing an alkoxide such as Z+ or ayathylacetone monosalt is prepared, and a steel plate that has been ultrasonically degreased in acetone is immersed in these solutions for 15 minutes to obtain (1,I+n/
The coating was applied uniformly by pulling at a constant speed of 1 minute.
その後、３５０ ℃の電気炉中に１分間入れ、酸化物皮
膜にし、次の試験を実施した。Thereafter, it was placed in an electric furnace at 350° C. for 1 minute to form an oxide film, and the following tests were conducted.
（１）加熱油耐食性試験
試験片にエリクセン押出しく４＋ｎ＋ｎ）と３Ｔ曲げを
施した後、塩水噴霧試験２５０時間と１ｇ潤試験５（）
０時間を実施し、錆の発生程度を次の基準て゛評価した
。(1) Heated oil corrosion resistance test After applying Erichsen extrusion (4+n+n) and 3T bending to the test piece, salt spray test for 250 hours and 1g moisture test (5)
The test was carried out for 0 hours, and the degree of rust generation was evaluated based on the following criteria.
○ 錆の発生なし
△ 錆かわずかに発生
× 錆が著しく発生
（２）加熱後耐食性試験
試験片を４００℃の電気炉中で２４時間加熱した後、１
１１ｊ記の加熱１ｔｔｊ耐食性試験を実施して同様の基
準で・錆の発生程度を評価した。○ No rust △ Slight rust × Significant rust (2) Corrosion resistance test after heating After heating the test piece in an electric furnace at 400°C for 24 hours,
The heating 1ttj corrosion resistance test described in Section 11j was conducted and the degree of rust generation was evaluated using the same criteria.
第１表にこの結果を示［。Table 1 shows the results [.
（発明の効果）
以］−のごとく、シリカ皮膜のメチル基を７エル基にす
る本発明によれば、酸化物皮膜の耐熱性を向上させるこ
とができる。(Effects of the Invention) As described below, according to the present invention, the heat resistance of the oxide film can be improved by changing the methyl group of the silica film to a 7-el group.
特、ｉ７１出願人 ■新製銅体式会社 代 理 人 進 藤 満Special, i71 applicant ■New copper body type company representative person Mitsuru Susumu Fuji
Claims (1)
ｌ以上のアルコール溶液またはこの溶液にＳｉ、Ｔｉ、
Ｚｒ、Ａｌ、Ｗ、Ｃｅ、Ｓｎ、Ｙのアルコキシドまたは
アセチルアセトネート塩の１種または２種以上をモノフ
ェニルトリアルコキシシランに対して、１モル％以上添
加した溶液を鋼板に塗布した後、１００℃以上に加熱す
ることを特徴とするモノフェニルシリカ膜被覆表面処理
鋼板の製造方法。0.005 mol/monophenyltrialkoxysilane
1 or more of alcohol solution or this solution contains Si, Ti,
After applying a solution containing 1 mol % or more of Zr, Al, W, Ce, Sn, Y alkoxide or acetylacetonate salt to monophenyltrialkoxysilane to a steel plate, 100% A method for producing a surface-treated steel sheet coated with a monophenyl silica film, the method comprising heating the steel sheet to a temperature above ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP27837588A JPH02125878A (en) | 1988-11-02 | 1988-11-02 | Production of surface treated steel sheet coated with monophenylsilica film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP27837588A JPH02125878A (en) | 1988-11-02 | 1988-11-02 | Production of surface treated steel sheet coated with monophenylsilica film |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02125878A true JPH02125878A (en) | 1990-05-14 |
Family
ID=17596462
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP27837588A Pending JPH02125878A (en) | 1988-11-02 | 1988-11-02 | Production of surface treated steel sheet coated with monophenylsilica film |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02125878A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1062378A1 (en) * | 1998-03-12 | 2000-12-27 | Natural Coating Systems LLC. | Improved protective coatings for metals and other surfaces |
| US7267740B2 (en) | 2004-05-14 | 2007-09-11 | Tokai Rubber Industries, Ltd. | Vibration-damping device for vehicles and method of manufacturing the same |
| JP2008174769A (en) * | 2007-01-16 | 2008-07-31 | Sumitomo Osaka Cement Co Ltd | Coating liquid for forming thermal discoloration preventive film of stainless steel, and method for preventing thermal discoloration of stainless steel |
| JP2012193458A (en) * | 2012-07-09 | 2012-10-11 | Sumitomo Osaka Cement Co Ltd | Coating liquid for forming thermal discoloration preventive film of stainless steel, and method for preventing thermal discoloration of stainless steel |
-
1988
- 1988-11-02 JP JP27837588A patent/JPH02125878A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1062378A1 (en) * | 1998-03-12 | 2000-12-27 | Natural Coating Systems LLC. | Improved protective coatings for metals and other surfaces |
| EP1062378A4 (en) * | 1998-03-12 | 2003-07-09 | Natural Coating Systems Intern | Improved protective coatings for metals and other surfaces |
| US7267740B2 (en) | 2004-05-14 | 2007-09-11 | Tokai Rubber Industries, Ltd. | Vibration-damping device for vehicles and method of manufacturing the same |
| JP2008174769A (en) * | 2007-01-16 | 2008-07-31 | Sumitomo Osaka Cement Co Ltd | Coating liquid for forming thermal discoloration preventive film of stainless steel, and method for preventing thermal discoloration of stainless steel |
| JP2012193458A (en) * | 2012-07-09 | 2012-10-11 | Sumitomo Osaka Cement Co Ltd | Coating liquid for forming thermal discoloration preventive film of stainless steel, and method for preventing thermal discoloration of stainless steel |
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